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To date, organic-based redox flow batteries (RFBs) have relatively low open-circuit voltages (OCVs), limiting their commercial viability. Achieving higher OCVs with pH-decoupled RFBs faces challenges due to severe ion crossover, prompting new research that proposes an acid–base regeneration cell to address this limitation.
Understanding how power systems fail—and the nature of cascading failures—as a result of hurricanes is important to increase future resilience. Here the authors present a co-evolution approach to modelling wind-induced power line failures caused by hurricanes and assess the potential impact of line hardening on grids.
Surface reconstruction, chemo-mechanical degradation, and interfacial side reactions are major factors limiting the cyclability of Ni-rich cathodes. A strategy based on entropy-assisted epitaxial coating is now shown to effectively mitigate these issues, leading to improved battery performance and promising advances in electrochemical energy storage.
Layered Ni-rich oxide cathodes are susceptible to challenges with surface reconstruction and strain propagation, limiting their cyclability. The authors propose a solution involving oriented attachment-driven reactions, utilizing Wadsley–Roth nanocrystals and layered oxide to induce an epitaxial entropy-assisted coating, effectively addressing these issues.
deQuilettes et al. show that hexylammonium bromide forms an iodide-rich 2D structure and bromide gradient at the surface of 3D perovskite, both of which limit interfacial charge and energy losses in perovskite solar cells.
Achieving extremely fast charging while maintaining high energy density remains a challenge in the battery field. Here the authors conceptualize a porous current collector that successfully reduces the effective Li+ transport distance by half, quadrupling the diffusion-limited C-rate capability without compromising battery energy density.
Non-flammable electrolytes are essential for ensuring the safe operation of sodium-metal batteries; however, challenges arise in applications due to limited stability between the electrolytes and electrodes. Now, an electrolyte engineering approach using salts as a diluent is proposed to achieve both high interfacial stability and improved safety.
Manufacturing of perovskite solar cells under ambient conditions is desirable. Meng et al. show that dimethylammonium formate suppresses halide oxidation and deprotonation of organic cations, enabling air-processed inverted solar cells with 24.7% efficiency.
Injecting hydrogen into subsurface environments could provide seasonal energy storage, but understanding of technical feasibility is limited as large-scale demonstrations are scarce. Now, field tests show that hydrogen can be stored and microbially converted to methane in a depleted underground hydrocarbon reservoir.
The scarcity of raw materials and complex synthesis procedures have impeded the development of electrolytes for Mg and Ca metal batteries. Research now reports a facile synthesis of organoborate electrolytes through cation replacement reactions, offering highly reversible Mg or Ca electrochemistry.
The clean-cooking transition in the Global South can support major improvements in public and environmental health and societal conditions. This study draws on survey data from greater than 7,000 households in Ghana to understand determinants of household fuel use through the transition and proposes a stage-based framework to support policy interventions.
Establishing pH differences in aqueous flow batteries widens their voltage window, but acid–base mixing shortens their lifespan. In this study, the authors introduced a pH recovery system to address crossover issues, ensuring long-lasting, high-voltage pH-decoupled flow batteries.
Keller et al. use high-concentration silver alloying and steep gallium grading close to the back contact to minimize bandgap fluctuations and thus voltage losses, achieving 23.6% certified efficiency in Cu(In,Ga)Se2 solar cells.
Electrolytes with non-flammable solvents are important for the safe operation of sodium-metal batteries. Here the authors report an electrolyte engineering approach, employing salts as a diluent, to enhance interfacial stability and overall safety.
Geologic formations could be used for hydrogen storage and conversion to methane, yet technical feasibility is unclear as field-scale data are lacking. Here the authors perform field tests demonstrating that hydrogen can be stored and microbially converted to methane in a depleted underground hydrocarbon reservoir.
Inhomogeneities in the optoelectronic properties of polycrystalline Cu(In,Ga)Se2 absorbers can limit solar cell performance. Now, researchers quantify the spatial distribution of charge carrier concentration with nanometre resolution and show how different alkali-metal post-deposition treatments reduce the grain-to-grain fluctuations.
