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Redox flow batteries

Decoupled architecture enables pH decoupling

To date, organic-based redox flow batteries (RFBs) have relatively low open-circuit voltages (OCVs), limiting their commercial viability. Achieving higher OCVs with pH-decoupled RFBs faces challenges due to severe ion crossover, prompting new research that proposes an acid–base regeneration cell to address this limitation.

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Fig. 1: Examples of redox couples used in aqueous redox flow batteries (ARFBs) and the new pH-decoupled ARFB design.

References

  1. Li, Z. & Lu, Y.-C. Adv. Mater. 32, 2002132 (2020).

    Article  Google Scholar 

  2. Perry, M. L., Rodby, K. E. & Brushett, F. R. ACS Energy Lett. 7, 659–667 (2022).

    Article  Google Scholar 

  3. Dmello, R. et al. J. Power Sources 330, 261–272 (2016).

    Article  Google Scholar 

  4. Gregory, T. D., Albertus, P. & Perry, M. L. J. Power Sources 499, 229965 (2021).

    Article  Google Scholar 

  5. Brushett, F. R., Aziz, M. J. & Rodby, K. E. ACS Energy Lett. 5, 879–884 (2020).

    Article  Google Scholar 

  6. Xi, D. et al. Nat. Energy https://doi.org/10.1038/s41560-024-01474-1 (2024).

    Article  Google Scholar 

  7. Rodby, K. E., Perry, M. L. & Brushett, F. R. J. Power Sources 506, 230085 (2021).

    Article  Google Scholar 

  8. Robb, B. H. et al. Cell Rep. Phys. Sci. 3, 101118 (2022).

    Article  Google Scholar 

Download references

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Correspondence to Mike L. Perry.

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Competing interests

M.L.P. is employed by Largo Clean Energy, which is an RFB system developer.

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Perry, M.L. Decoupled architecture enables pH decoupling. Nat Energy 9, 367–368 (2024). https://doi.org/10.1038/s41560-024-01481-2

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