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    • Radical-pairing interactions were, until recently, considered something of a chemical curiosity. But these weak interactions, on par with hydrogen bonds, are easily switched on and off and, as a result, have become widely exploited in supramolecular chemistry, particularly in the assembly of out-of-equilibrium structures.

      • Kang Cai
      • Long Zhang
      • J. Fraser Stoddart
      Review Article
    • Molecular decoders are single host matrices able to differentiate analytes by their distinct structural accommodations. Ten years ago, Susumu Kitagawa and co-workers described the prototypical molecular decoder and paved the way for molecular sensing. We now revisit this seminal study and discuss some of the advances that have followed.

      • Soumya Mukherjee
      • Sujit K. Ghosh
      News & Views
    • Implementing effective chemomechanical coupling in the microscopic world is challenging. This Perspective describes recent advances of chemically-powered swimming or diffusion of objects on the molecular scale, nanoscale and microscale.

      • Yifei Zhang
      • Henry Hess
      Perspective
    • Charge-separated organic molecules find diverse applications as functional materials. This Review describes zwitterionicity as a general design principle for ‘smart’ coordination chemistry and the activation of strong bonds.

      • Dominik Munz
      • Karsten Meyer
      Review Article
    • The early 1980s witnessed the report of a molecular ruthenium complex active for dehydrogenation of alcohols and hydrogenation of carbonyl compounds. The ligand used represented a new paradigm that influences homogeneous catalysis to this day.

      • Rosie J. Somerville
      News & Views
  • Laser ablation enables the study of discrete metal difluorides and their reactions with dioxygen and ozone. Metal-fluoride vibrational energies give an indication of the charge on a metal difluoride moiety and help us rationalize the resultant structures.

    • David Schilter
    Research Highlight
  • An experiment that challenged established dogma opened an entirely new avenue for research in the assembly and control of mechanically interlocked compounds.

    • Ali Trabolsi
    Comment
  • A range of aryl and alkenyl organosodium reagents can be prepared by halogen–sodium exchange reactions with neopentylsodium and may be a useful alternative to widely used organolithium reagents.

    • Stephen G. Davey
    Research Highlight
  • Our review of Nano is the the joint work of Rosalind (9) and Kristy, her Mum.

    • Rosalind N. Turner
    • Kristy L. Turner
    Books & Arts
  • Twisted nanoribbons with up to 322 atoms in the aromatic core (53 rings) have been prepared.

    • Thomas West
    Research Highlight
  • As scientists of all stripes grow as leaders, it becomes their responsibility to shed light on the opportunities that may be hidden within an apparent failure. Presented as a letter to his younger self, Marc Reid looks back at the time when he could scarcely handle professional rejection and examines the lessons he learned.

    • Marc Reid
    Comment
Celebrating 15 Years of Covalent Organic Frameworks

Celebrating 15 Years of Covalent Organic Frameworks

This collection celebrates 15 years of research on covalent organic frameworks and highlights some of the contributions that were published in journals of the Nature Research portfolio. We hope you enjoy exploring these snippets on the synthesis and structure of COFs, their physical properties, and their application in fields encompassing energy, catalysis, storage and separation.
  • Johannes Kreutzer
Collection