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Rational screening low-cost counter electrodes for dye-sensitized solar cells
The main constraint on the large-scale use of platinum catalyst in energy-conversion devices is its cost. Hou et al.propose a screening strategy to search for non-platinum-based alternatives, which suggests that inexpensive and abundant ferric oxides exhibit comparable electrocatalytic activity to platinum.
- Yu Hou
- , Dong Wang
- & Hua Gui Yang
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| Open AccessTuneable enhancement of the salt and thermal stability of polymeric micelles by cyclized amphiphiles
The cyclic structure of cell membrane lipids is known to allow thermophilic archaea to survive in extreme environments. Here, Honda et al.report an improvement in thermal and salt stability of self-assembled micelles by cyclized polymeric amphiphiles.
- Satoshi Honda
- , Takuya Yamamoto
- & Yasuyuki Tezuka
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Moderate doping leads to high performance of semiconductor/insulator polymer blend transistors
Blends of different polymer compounds are widely used for organic field-effect transistors. Here, Neher and colleagues show that moderate carrier doping is important to achieve maximum performance in blends of insulating and semiconducting polymers.
- Guanghao Lu
- , James Blakesley
- & Dieter Neher
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X-ray observation of a helium atom and placing a nitrogen atom inside He@C60 and He@C70
Helium has not, to date, been observed crystallographically. Here, the authors report the first crystallographic observation of a helium atom, encapsulated in a fullerene, and show that it exerts a small but detectable influence on the electronic structure of a coencapsulated nitrogen atom.
- Yuta Morinaka
- , Satoru Sato
- & Yasujiro Murata
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A hydrothermal anvil made of graphene nanobubbles on diamond
The hardness and incompressibility of diamond makes it an ideal material for high-pressure anvil cells. Here, a method for generating static pressure is described in which graphene-coated diamond is heated, forming graphene nanobubbles that trap water at pressures sufficient to etch the surface of diamond.
- Candy Haley Yi Xuan Lim
- , Anastassia Sorkin
- & Kian Ping Loh
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Substrate-mediated band-dispersion of adsorbate molecular states
Charge carrier mobility in molecular condensate is usually limited to small values by disorder and small intermolecular coupling. This work shows band dispersion of molecular states when hybridized with a metal substrate, resulting in enhanced carrier mobility.
- M. Wießner
- , J. Ziroff
- & F. Reinert
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| Open AccessExcitation-dependent visible fluorescence in decameric nanoparticles with monoacylglycerol cluster chromophores
Organic fluorescent nanoparticles have potential biomaterials applications due to their low-toxicity and ‘green’ synthesis. Here, a series of self-assembled nanoparticles and polymers are synthesized with intense visible fluorescence stemming from chromophores of hydrogen-bonded monoacylglycerol clusters.
- Kwang-Ming Lee
- , Wan-Yin Cheng
- & Bi-Yun Lin
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Colloidal ribbons and rings from Janus magnetic rods
Materials with magnetic dipoles commonly form the building blocks of complex structures at many different length scales. Yan et al. show that by using cylindrical magnetic Janus colloids, greater control over the shape of the hierarchical structures formed by self-assembly can be achieved.
- Jing Yan
- , Kundan Chaudhary
- & Steve Granick
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Porous materials with pre-designed single-molecule traps for CO2 selective adsorption
The synthesis of porous materials designed with specific applications in mind is fundamentally challenging. Here, the authors fabricate single-molecule trap cavities designed for complimentary interactions with CO2 and show that these traps can be assembled into materials with high CO2selectivity.
- Jian-Rong Li
- , Jiamei Yu
- & Hong-Cai Zhou
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Influenza neuraminidase operates via a nucleophilic mechanism and can be targeted by covalent inhibitors
New influenza neuramidase inhibitors may increase preparedness against influenza outbreaks. Vavricka et al.confirm the catalytic mechanism of neuramidase and show that it can be inhibited irreversibly with covalent inhibitors.
- Christopher J. Vavricka
- , Yue Liu
- & George F. Gao
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Ion-association complexes unite classical and non-classical theories for the biomimetic nucleation of calcium phosphate
In many solution systems, nanometre-sized structural units are present before nucleation, but little is known about these pre-nucleation clusters. Habraken et al.show that, for the crystallization of calcium phosphate, these nanometre-sized units are calcium triphosphate complexes.
- Wouter J. E. M. Habraken
- , Jinhui Tao
- & Nico A. J. M. Sommerdijk
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Chemically programmed self-sorting of gelator networks
The fabrication self-sorting supramolecular gels, containing co-existing homomolecular assemblies with similar physical and chemical properties, is challenging. Here pH-controlled self-sorting gelators are reported, where the order of assembly of each component is predetermined by gelator pKa.
- Kyle L. Morris
- , Lin Chen
- & Dave J. Adams
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Organic topological insulators in organometallic lattices
Topological insulators are bulk insulators with conductive boundary states, and until now have been based only on inorganic materials. Wang et al.use first-principles calculations to predict a class of organic topological insulators based on organometallic lattices exhibiting robust topological edge states.
- Z.F Wang
- , Zheng Liu
- & Feng Liu
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Electrical power generation by mechanically modulating electrical double layers
Electricity can be generated by moving wires in magnetic fields, but this is not the only method. Moon et al. develop an electrochemical device that produces an AC current in a controlled manner by mechanically modulating water bridges sandwiched between two conducting plates.
- Jong Kyun Moon
- , Jaeki Jeong
- & Hyuk Kyu Pak
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Ground-state proton transfer in the photoswitching reactions of the fluorescent protein Dronpa
The ‘on’ and ‘off’ states of the photoswitchable protein Dronpa have been characterized, but the interconversion process remains poorly understood. Here the authors perform time-resolved ultrafast infrared measurements to follow both the structural changes and proton transfer events that occur during conversion.
- Mark M. Warren
- , Marius Kaucikas
- & Jasper J. van Thor
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Spatial separation of photogenerated electrons and holes among {010} and {110} crystal facets of BiVO4
Charge separation determines the efficiency of semiconductor-based photocatalysts. Here Li et al. show that, in BiVO4, photogenerated electrons and holes accumulate on different crystal facets and the targeted deposition of cocatalysts increases the efficiency of photocatalytic water oxidation.
- Rengui Li
- , Fuxiang Zhang
- & Can Li
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Engineering the architectural diversity of heterogeneous metallic nanocrystals
Engineering heterogeneous metallic nanocrystals could produce diverse materials with tunable properties. Here the authors develop a strategy for the rational and independent programming of each architecture-determining element, such as the shape, size and spatial relationship of the component nanocrystals.
- Yue Yu
- , Qingbo Zhang
- & Jim Yang Lee
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Electronic signature of the instantaneous asymmetry in the first coordination shell of liquid water
There are conflicting views about the symmetrical/asymmetrical nature of the hydrogen-bond network in water. This theoretical study reveals that water molecules in liquid form highly asymmetric hydrogen bonds and that this asymmetry relaxes rapidly towards an average symmetrical structure.
- Thomas D. Kühne
- & Rustam Z. Khaliullin
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A six-carbon 10π-electron aromatic system supported by group 3 metals
Aromaticity predicts the existence of the benzene tetra-anion, although it has not been unambiguously observed. Here, the authors have synthesized a tetra-anionic substituted benzene as a ligand and characterize the six-carbon, 10 π-electron system by structural, spectroscopic and theoretical techniques.
- Wenliang Huang
- , Florian Dulong
- & Paula L. Diaconescu
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| Open AccessJanus graphene from asymmetric two-dimensional chemistry
Janus materials have distinct chemical functionalities on opposite faces. Zhang et al.report that a two-step covalent functionalisation and poly(methyl methacrylate)-mediated transfer process facilitates the synthesis of nonsymmetrically modified single-layer graphene.
- Liming Zhang
- , Jingwen Yu
- & Zhongfan Liu
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Solution-phase epitaxial growth of noble metal nanostructures on dispersible single-layer molybdenum disulfide nanosheets
The ‘wet’ chemical epitaxial growth of nanostructures on semiconducting surfaces is usually hindered by surface defects. Here, the authors show that large surface area single-layer molybdenum disulphide is an ideal substrate for epitaxial growth of a range of metallic nanoparticles.
- Xiao Huang
- , Zhiyuan Zeng
- & Hua Zhang
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| Open AccessGlobally homochiral assembly of two-dimensional molecular networks triggered by co-absorbers
The construction of homochiral surfaces may play a significant role in applications including heterogeneous catalysis and bio-sensors. Here, globally homochiral two-dimensional assemblies of achiral molecules are formed via co-assembly with chiral co-adsorbers, demonstrating a ‘majority rules’ effect.
- Ting Chen
- , Wen-Hong Yang
- & Li-Jun Wan
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Unprecedented high-temperature CO2 selectivity in N2-phobic nanoporous covalent organic polymers
Porous materials are well studied for gas capture and separation technologies. Here, the authors report nitrogen-rich, nanoporous polymers, which display very high CO2/N2 selectivity with increasing temperature, which may be attributable to an entropically driven N2-phobicity effect.
- Hasmukh A. Patel
- , Sang Hyun Je
- & Ali Coskun
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Hydrogen bond-promoted metallic state in a purely organic single-component conductor under pressure
Purely organic materials are generally insulating and while charge-carrier generation can provide electrical conductivity, it is rare for single-component systems. Here, symmetric hydrogen bonding between tetrathiafulvalene-based molecules gives rise to room-temperature conductivity and low pressure metallic state transitions.
- Takayuki Isono
- , Hiromichi Kamo
- & Hatsumi Mori
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Probing the catalytic activity of porous graphene oxide and the origin of this behaviour
Graphene oxide has been proposed as an alternative to precious metals for the catalysis of aerobic oxidative reactions; however, high catalyst loadings are needed. Here a simple base and acid treatment is shown to enhance its catalytic activity for the oxidative coupling of amines under ambient conditions.
- Chenliang Su
- , Muge Acik
- & Kian Ping Loh
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| Open AccessAbove-room-temperature ferroelectricity and antiferroelectricity in benzimidazoles
There are only a few known organic ferroelectrics, particularly ones that operate at high temperatures. Here the discovery of ferroelectricity above room temperature in members of an ubiquitous family of organic molecules reveals the possibility of novel low-cost electronic applications.
- Sachio Horiuchi
- , Fumitaka Kagawa
- & Yoshinori Tokura
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| Open AccessBolaform surfactants with polyoxometalate head groups and their assembly into ultra-small monolayer membrane vesicles
Bolaform amphiphiles are surfactants with two hydrophilic end groups, known to form stable micelles. Polarz et al.have synthesized dipolar bolaform surfactants with polyoxometallate head groups, which have a very low self-organization concentration and form nanoscale monolayer vesicles.
- Steve Landsmann
- , Martin Luka
- & Sebastian Polarz
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Homo-coupling of terminal alkynes on a noble metal surface
Acetylenes can be covalently linked by oxidative coupling reactions. Zhanget al. report terminal alkyne Csp-H bond activation and concomitant homo-coupling on a silver surface, yielding polymeric networks with a conjugated backbone.
- Yi-Qi Zhang
- , Nenad Kepčija
- & Johannes V. Barth
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| Open AccessExpansion–contraction of photoresponsive artificial muscle regulated by host–guest interactions
Polymer-based actuators, which deform in response to external stimuli, may advance the understanding of biological movement or realization of soft robotics. Here, Harada et al. report a photo-responsive supramolecular hydrogel that displays expansion–contraction abilities owing to host–guest interactions.
- Yoshinori Takashima
- , Shogo Hatanaka
- & Akira Harada
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Single-particle structure determination by correlations of snapshot X-ray diffraction patterns
Free-electron lasers enable diffractive imaging of single nanostructures, but algorithms, such as correlation analyses, are needed to determine their diffraction volume from accumulated data. Starodub et al.present such a method for X-ray diffractive imaging of nanometre-scale polystyrene dimers.
- D. Starodub
- , A. Aquila
- & M.J. Bogan
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Stretchable heterogeneous composites with extreme mechanical gradients
Heterogeneous composite materials, which are potentially useful for flexible electronics, are widespread in nature but synthetic examples are rare. Here, a site-specific hierarchical approach is used to fabricate composites with extreme local variations in elastic modulus and which are reversibly stretchable.
- Rafael Libanori
- , Randall M. Erb
- & André R. Studart
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Iron-catalysed transformation of molecular dinitrogen into silylamine under ambient conditions
The transition metal-catalysed reduction of nitrogen, vital for the production of fertilizer, usually requires expensive molybdenum catalysts. Here, Yuki et al.describe the iron-catalysed reduction of nitrogen under ambient conditions and propose a reaction pathway supported by DFT calculations.
- Masahiro Yuki
- , Hiromasa Tanaka
- & Yoshiaki Nishibayashi
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Biomimetic superelastic graphene-based cellular monoliths
The exploitation of the properties of graphene, such as mechanical strength and electrical conductivity, in deformable macroscopic materials is desirable. Here, a combination of graphene chemistry and ice physics is used to fabricate biomimetic, ultralight and superelastic graphene cellular monoliths.
- Ling Qiu
- , Jeffery Z. Liu
- & Dan Li
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Nanosecond white-light Laue diffraction measurements of dislocation microstructure in shock-compressed single-crystal copper
Intense lasers enable scientists to study the behaviour of matter under extreme pressures, but obtaining information about its atomic structure is challenging. In this work, Suggit et al. demonstrate the use of white-light X-ray diffraction to probe the structure of laser-shocked copper on nanosecond timescales.
- Matthew J. Suggit
- , Andrew Higginbotham
- & Justin S. Wark
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A seamless three-dimensional carbon nanotube graphene hybrid material
Graphene and single-walled carbon nanotubes have high electrical conductivities and large specific surface areas. Here, these properties are extended into three dimensions by producing a seamless carbon nanotube graphene hybrid material.
- Yu Zhu
- , Lei Li
- & James M. Tour
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| Open AccessCarbon nanotube–liposome supramolecular nanotrains for intelligent molecular-transport systems
There is growing interest in the development of artificial molecular-transport systems. Miyakoet al. develop a supramolecular system consisting of carbon nanotubes and liposomes that allows the directional transport and controlled release of cargo molecules.
- Eijiro Miyako
- , Kenji Kono
- & Yoshihisa Hagihara
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Non-syngas direct steam reforming of methanol to hydrogen and carbon dioxide at low temperature
Proton exchange membrane fuel cells are good potential power sources for mobile devices but require very pure H2 production at low temperatures. Yu et al. report the use of a CuZnGaOx catalyst capable of producing CO-free H2from methanol via a non-syngas direct steam-reforming route at 150–200 °C.
- Kai Man Kerry Yu
- , Weiyi Tong
- & Shik Chi Edman Tsang
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Scalable organocatalytic asymmetric Strecker reactions catalysed by a chiral cyanide generator
The Strecker synthesis is an established method for the production of α-amino acids. Here, a scalable catalytic asymmetric Strecker reaction is reported that allows one-pot synthesis of enantiomerically pure α-amino acids.
- Hailong Yan
- , Joong Suk Oh
- & Choong Eui Song
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| Open AccessSynthesis of chiral TiO2 nanofibre with electron transition-based optical activity
Optical activity resulting from electronic transitions in chiral inorganic materials is rare. Liu et al. report the synthesis of amino acid-derived amphiphile templated chiral TiO2fibres, which exhibit an optical response to polarized light resulting from valence to conduction band electronic transitions.
- Shaohua Liu
- , Lu Han
- & Shunai Che
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Spectroscopic observation of iodosylarene metalloporphyrin adducts and manganese(V)-oxo porphyrin species in a cytochrome P450 analogue
Metalloporphyrin compounds are studied as models of cytochrome P450, which is capable of catalysing oxidative reactions. Here, reaction conditions are varied to allow spectroscopic observation of oxidant-metalloporphyrin adducts and metal-oxo intermediates, which may elucidate reaction mechanisms.
- Mian Guo
- , Hang Dong
- & Aiwen Lei
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Orthogonal switching of a single supramolecular complex
Orthogonal switching has been achieved in supramolecular systems, in which different responses can be triggered on demand by different stimuli. Tian et al.report host–guest heteroternary complexes with both redox- and light-responsive guests in a single, supramolecular entity.
- Feng Tian
- , Dezhi Jiao
- & Oren A. Scherman
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Tracking lithium transport and electrochemical reactions in nanoparticles
Developing next generation batteries requires better understanding of the dynamics of electrochemical reactions in working electrodes. Using a transmission electron microscope, Wanget al. develop a means to track the real time flow of lithium atoms in electrodes during the discharge of a functioning electrochemical cell.
- Feng Wang
- , Hui-Chia Yu
- & Jason Graetz
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Article
| Open AccessDetermination of monolayer-protected gold nanoparticle ligand–shell morphology using NMR
Binary mixtures of molecules on the surface of nanoparticles can arrange randomly or into different domains to form Janus, patchy or striped particles. Liuet al.show that NMR can be used to determine the ligand-shell morphology of particles coated with aliphatic and aromatic ligands.
- Xiang Liu
- , Miao Yu
- & Francesco Stellacci
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A general method for the large-scale synthesis of uniform ultrathin metal sulphide nanocrystals
Ultrathin metal sulphides are attractive components for electronic and optical devices and are promising anode materials for lithium-ion batteries. Here, a universal, soft colloidal templating strategy is employed for the large-scale synthesis of uniform, ultrathin metal sulphide nanomaterials.
- Yaping Du
- , Zongyou Yin
- & Hua Zhang
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Lithium–sulphur batteries with a microporous carbon paper as a bifunctional interlayer
The practical performance of lithium sulphide batteries is much less than their predicted performance because redox products dissolve over time. Su and Manthiram show that microporous carbon membranes inserted between cathode and separator localize soluble polysulphide species and improve battery cycling characteristics.
- Yu-Sheng Su
- & Arumugam Manthiram
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One-piece micropumps from liquid crystalline core-shell particles
Liquid crystal elastomers can perform mechanical motion triggered by external stimuli, and are light weight, flexible materials that may be integrated into micromechanical systems. Here they are used to fabricate a one-piece temperature-responsive micropump viaa microfluidic double-emulsion process.
- Eva-Kristina Fleischmann
- , Hsin-Ling Liang
- & Rudolf Zentel
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High strain rate deformation of layered nanocomposites
Bullet-proof materials made of nanostructured composites outperform conventional materials, yet little is known of their nanoscale response to high-speed impact. Using laser-propelled microscopic projectiles, Lee et al.directly visualize this process in layered nanocomposites.
- Jae-Hwang Lee
- , David Veysset
- & Edwin L. Thomas
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Article
| Open AccessSimilarities between protein folding and granular jamming
Granular matter is rigid when jammed, and flows under external loads. Here temperature- and force-unfolding molecular dynamics stimulations are used to demonstrate that proteins display features of jamming, characterized by a force distribution peak on folding and a slowdown of stress relaxation.
- Prasanth P Jose
- & Ioan Andricioaei
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Electrografting of calix[4]arenediazonium salts to form versatile robust platforms for spatially controlled surface functionalization
The spontaneous adsorption of alkanethiols is widely utilized to fabricate functional surfaces but gives limited stability and regularity. Mattiuzziet al. report a method that uses preorganized platforms (rigid tetrapodant calix[4]arenes), which allows further surface functionalization and spatial control.
- Alice Mattiuzzi
- , Ivan Jabin
- & Corinne Lagrost
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