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| Open AccessGiant regular polyhedra from calixarene carboxylates and uranyl
Self-assembly of multi-component systems can be used to construct discrete, well-defined, nanoscopic-sized cages. Pasqualeet al. report the self-assembly of conical-shaped carboxylic acid derivatives of calix[4]arene and calix[5]arene, and the uranyl cation UO22+into octahedral and icosahedral anionic metallocages.
- Sara Pasquale
- , Sara Sattin
- & Javier de Mendoza
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Article
| Open AccessRedox-responsive self-healing materials formed from host–guest polymers
Stimulus-responsive hydrogels have previously been developed that display heat-, light-, pH- or redox-induced sol–gel transitions. Nakahataet al. develop a self-healing supramolecular hydrogel based on host–guest polymers in which redox potential can induce a reversible sol–gel phase transition.
- Masaki Nakahata
- , Yoshinori Takashima
- & Akira Harada
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| Open AccessTheoretical models of nonlinear effects in two-component cooperative supramolecular copolymerizations
In multi-component mixtures of self-assembling molecules, small differences in association energy between components can be amplified by nonlinear effects. This theoretical investigation of self-assembling systems rationalizes chiral amplification in cooperative supramolecular copolymerizations.
- Albert J. Markvoort
- , Huub M.M. ten Eikelder
- & E.W. Meijer
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Responsive nematic gels from the self-assembly of aqueous nanofibres
Hydrogels have a variety of applications including tissue engineering and controlled drug delivery. Here, liquid-crystal hydrogels are developed which transform into a fluid solution upon cooling; cells can be encapsulated in the gel at room temperature, then released at physiological temperatures.
- Zhegang Huang
- , Hyojin Lee
- & Myongsoo Lee
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Metallosupramolecular self-assembly of a universal 3-ravel
There has been recent progress in the synthesis of complex intertwined supramolecular topologies. In this study, Liet al.report the self-assembly of an intertwined structure based on a universal 3-ravel.
- Feng Li
- , Jack K. Clegg
- & George V. Meehan
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Porous organic molecular solids by dynamic covalent scrambling
The construction of porous solids from discrete organic molecules usually involves the formation of regular porous crystals. In this study, a covalent scrambling reaction gives molecules with a range of shapes that do not pack effectively — manipulation of the reagent ratio allows fine control of porosity.
- Shan Jiang
- , James T. A. Jones
- & Andrew I. Cooper
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Article
| Open AccessCrystallographic observation of 'induced fit' in a cryptophane host–guest model system
Cryptophane-A is a prototypical organic host molecule that binds reversibly to neutral guest molecules. Taratulaet al.report X-ray structures of cryptophane-A complexed with a range of host molecules to show that the cryptophane host–guest system exhibits ‘induced fit’.
- Olena Taratula
- , P. Aru Hill
- & Ivan J. Dmochowski
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Self-assembled aggregates formed by single-molecule magnets on a gold surface
The spontaneous ordering of molecules into two-dimensional arrays is usually a result of directional intermolecular interactions. Here, it is shown that electrospray-deposited Mn12(acetate)16forms filamentary aggregates driven by anisotropic interactions, which are a consequence of the complex shape of the molecule.
- Alex Saywell
- , Graziano Magnano
- & Peter H. Beton
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Fluidic supramolecular nano- and microfibres as molecular rails for regulated movement of nanosubstances
Microtubules act as molecular tracks for the transport of substances within cells, and have inspired the construction of artificial supramolecular fibres. Here, self-assembled glycol–lipid fibres are shown to be sufficiently fluid to allow directional movement of attached molecules, proteins and nanobeads.
- Shun-ichi Tamaru
- , Masato Ikeda
- & Itaru Hamachi