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Formation of aligned periodic patterns during the crystallization of organic semiconductor thin films
Material depletion and accumulation at the crystallization front of organic semiconductors films induce the formation of large-area regular patterns, with a periodicity relevant to optoelectronic applications in the visible and near-infrared range.
- John S. Bangsund
- , Thomas R. Fielitz
- & Russell J. Holmes
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Article |
Diffraction imaging of nanocrystalline structures in organic semiconductor molecular thin films
Scanning electron nanobeam diffraction is used to monitor the morphology of organic thin films with nanometre resolution, revealing information on the arrangement of crystalline domains useful for structure–property relationship understanding.
- Ouliana Panova
- , Colin Ophus
- & Andrew M. Minor
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Article |
Highly stable fullerene-based porous molecular crystals with open metal sites
Porous molecular crystals are easy to fabricate but thought to have limited stability as they are bound by non-covalent interactions. Here, a porous crystal composed of C60 and phthalocyanine is demonstrated with stability to heat, acid, base and high pressures.
- C. Grazia Bezzu
- , Luke A. Burt
- & Neil B. McKeown
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News & Views |
Organic LEDs and solar cells united
Organic donor–acceptor heterojunctions can show efficient electroluminescence and at the same time generate charges under photovoltaic operation.
- Wolfgang Brütting
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Article |
Molecular parameters responsible for thermally activated transport in doped organic semiconductors
The investigation of a range of n- and p-doped small-molecule organic semiconductors reveals the role of the integer charge transfer complexes formed by host and dopant ions on conductivity and its thermal activation energy.
- Martin Schwarze
- , Christopher Gaul
- & Karl Leo
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Article |
Chiral crystal-like droplets displaying unidirectional rotational sliding
A chiral discotic triphenylene derivative spontaneously forms millimetre-sized assemblies with high structural order and fluid-like behaviour.
- Takashi Kajitani
- , Kyuri Motokawa
- & Takanori Fukushima
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News & Views |
Beyond 100% doping efficiency
A single dopant molecule can exchange more than one charge with the hosting polymer semiconductor, doubling the maximum doping efficiency achievable.
- Björn Lüssem
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Article |
Double doping of conjugated polymers with monomer molecular dopants
A monomer molecular dopant with high electron affinity is shown to accept up to two electrons from conjugated polymers with low ionization efficiency and then generate free charge carriers with an efficiency of up to 170%.
- David Kiefer
- , Renee Kroon
- & Christian Müller
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Article |
Shape-based separation of synthetic microparticles
A fluorescence-activated cell sorter is used to purify microparticles from colloidal mixtures.
- Peter L. Mage
- , Andrew T. Csordas
- & H. Tom Soh
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Article |
Real-time insight into the doping mechanism of redox-active organic radical polymers
Organic radical polymers are currently being considered as active materials for fast-charging battery electrodes but their transport and charge storage characteristics are not well understood. A quantitative view of in situ ion transport and doping in these systems during the redox process is now provided.
- Shaoyang Wang
- , Fei Li
- & Jodie L. Lutkenhaus
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News & Views |
Inflating to shape
An elastomer sheet with programmed inner channel architecture swiftly shapes into a desired three-dimensional geometry upon the application of pressure.
- Efi Efrati
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Letter |
Bio-inspired pneumatic shape-morphing elastomers
Elastomer sheets with programmable air channel organization swiftly shape into complex three-dimensional structures upon the application of pressure.
- Emmanuel Siéfert
- , Etienne Reyssat
- & Benoît Roman
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Article |
Coatings super-repellent to ultralow surface tension liquids
Liquid repellent coatings are important for several applications. Now, a coating that repels ultralow surface tension liquids and simultaneously shows robustness and transparency is reported.
- Shuaijun Pan
- , Rui Guo
- & Frank Caruso
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Letter |
Interparticle hydrogen bonding can elicit shear jamming in dense suspensions
Dense suspensions of hard particles readily display discontinuous shear thickening under shear but not reversible shear jamming. Here it is shown that the formation of interparticle hydrogen bonds is crucial for the shear jamming of these suspensions.
- Nicole M. James
- , Endao Han
- & Heinrich M. Jaeger
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Article |
Programmed assembly of synthetic protocells into thermoresponsive prototissues
Protocells are synthetic cell-like entities that mimic distinct cellular functions. A synthetic prototissue based on an interlinked protein–polymer protocells community that shows reversible contractibility is now reported.
- Pierangelo Gobbo
- , Avinash J. Patil
- & Stephen Mann
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Article |
Ultrafast water harvesting and transport in hierarchical microchannels
Ultrafast water transport in the surface of Sarracenia trichome is reported and demonstrated in synthetic bioinspired materials, where nano- and microchannels induce high-speed sliding of droplets on top of a thin water film.
- Huawei Chen
- , Tong Ran
- & Lei Jiang
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News & Views |
Rolling sound waves
A quantitative description of sound wave propagation in suspensions of self-propelled colloidal particles is achieved by combining microfluidics, video microscopy and theory.
- Jörn Dunkel
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Letter |
Sounds and hydrodynamics of polar active fluids
Sound wave propagation is used to quantitatively describe the hydrodynamics of an active colloidal medium.
- Delphine Geyer
- , Alexandre Morin
- & Denis Bartolo
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News & Views |
Single-element glass to record data
Monatomic glassy antimony can now be achieved via melt-quenching in a nanoconfined volume in a device setting. In contrast to alloys currently used in phase-change memories, deviation from optimized composition is no longer an issue in this simple material.
- Wei Zhang
- & Evan Ma
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Letter |
Homochiral porous nanosheets for enantiomer sieving
By using stacked macrocycle dimers, a 2D nanosheet self-assembles that exclusively captures a single enantiomer, and can release it by external stimulus via salt addition.
- Bo Sun
- , Yongju Kim
- & Myongsoo Lee
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Article |
Self-assembled highly ordered acid layers in precisely sulfonated polyethylene produce efficient proton transport
Polymer synthesis can provide control over chain microstructure and conformation. Well-controlled chain folding in sulfonated polyethylene, leading to highly uniform hydrated acid layers of subnanometre thickness with high proton conductivity, is demonstrated.
- Edward B. Trigg
- , Taylor W. Gaines
- & Karen I. Winey
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Article |
An autonomously electrically self-healing liquid metal–elastomer composite for robust soft-matter robotics and electronics
Liquid metal droplets dispersed in an elastomer can form conducting paths when the composite is exposed to extreme mechanical pressure. This ability is used to realize flexible circuits that autonomously electrically self-heal after puncturing or tearing.
- Eric J. Markvicka
- , Michael D. Bartlett
- & Carmel Majidi
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Letter |
Motorizing fibres with geometric zero-energy modes
Active rotational motion of pre-strained materials is achieved by elastic deformations that break rotational symmetry around their axes.
- Arthur Baumann
- , Antoni Sánchez-Ferrer
- & Igor M. Kulić
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Article |
Hole trap formation in polymer light-emitting diodes under current stress
Quantitative analysis of polymer LED degradation under current stress provides insight on the role of hole traps and their formation. Blending of the emitting material with large-bandgap semiconductors leads to trap dilution and improved stability.
- Quan Niu
- , Roland Rohloff
- & N. Irina Crăciun
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News & Views |
Multilevel robustness
A combination of hard, soft and nanoscale organic components results in robust superhydrophobic surfaces that can withstand mechanical abrasion and chemical oxidation, and exhibit excellent substrate adhesion.
- Henri-Louis Girard
- , Sami Khan
- & Kripa K. Varanasi
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All-organic superhydrophobic coatings with mechanochemical robustness and liquid impalement resistance
Coatings made of flexible, organic layered nanocomposites achieve high water repellence under harsh mechanical and chemical environments.
- Chaoyi Peng
- , Zhuyang Chen
- & Manish K. Tiwari
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Article |
Universal strategy for Ohmic hole injection into organic semiconductors with high ionization energies
It is shown that Ohmic contacts for the injection of hole carriers into organic semiconductors with high ionization energy can be formed by adding ultrathin interlayers with higher ionization energy.
- Naresh B. Kotadiya
- , Hao Lu
- & Gert-Jan A. H. Wetzelaer
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Article |
Quantitative relations between interaction parameter, miscibility and function in organic solar cells
This work reports a quantitative investigation of the interaction parameter and miscibility of donor and acceptor organic molecules and their relationship with the fill factor and photovoltaic performance of bulk-heterojunction organic solar cells.
- Long Ye
- , Huawei Hu
- & Harald Ade
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News & Views |
Chiral interactions in liquid crystals
The chirality of colloids dispersed in achiral liquid crystals shapes colloidal dynamics and interactions, giving rise to chiral supramolecular assemblies and attractive or repulsive colloidal motions.
- Karthik Nayani
- , Young-Ki Kim
- & Nicholas L. Abbott
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Editorial |
A cure for mobility problems
As the electronic performance of organic semiconductors and other emergent materials improves, researchers call for attention in extracting charge mobility values from field-effect transistors.
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Article |
Control of piezoelectricity in amino acids by supramolecular packing
Proceeding from quantum mechanical predictions, a high shear piezoelectric constant of 178 pm V−1 was measured for the amino acid crystal beta glycine. This originates from the efficient packing of the molecules of the amino acid.
- Sarah Guerin
- , Aimee Stapleton
- & Damien Thompson
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Chiral liquid crystal colloids
Colloidal chiral springs and helices are formed by light inside a nematic liquid crystal suspension, predefining the mesoscopic superstructures self-assembled in such systems.
- Ye Yuan
- , Angel Martinez
- & Ivan I. Smalyukh
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Article |
Beating the thermodynamic limit with photo-activation of n-doping in organic semiconductors
The activation of cleavable organometallic dimers upon exposure to ultraviolet radiation allows air-stable n-type doping of organic materials with electron affinity lower than the expected thermodynamic reducing strength of the dimers.
- Xin Lin
- , Berthold Wegner
- & Antoine Kahn
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Letter |
Topological defects govern crack front motion and facet formation on broken surfaces
In brittle soft materials, topological defects determine fracture propagation and faceted patterning.
- Itamar Kolvin
- , Gil Cohen
- & Jay Fineberg
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News & Views |
No need to wait
In contrast with protocols reporting self-assembly of nanocrystals after synthesis, Pd nanocrystals rapidly form 3D micrometre-size superlattices during growth. The nanocrystals keep growing after assembly, tuning the size of the lattice.
- Kun Liu
- & Eugenia Kumacheva
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Letter |
Bronze-mean hexagonal quasicrystal
A two-dimensional quasicrystalline tiling based on the bronze-mean hexagonal pattern is proposed.
- Tomonari Dotera
- , Shinichi Bekku
- & Primož Ziherl
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News & Views |
Enhanced by organic surfaces
Nanostructured films of organic semiconductors are now shown to enhance the Raman signal of probe molecules, paving the way to the realization of substrates for Raman spectroscopy with molecular selectivity.
- John R. Lombardi
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News & Views |
Living bandgaps
Sound waves drive the organization of particle scatterers into stable structures, exhibiting phononic band gaps that heal from disturbances and adapt to changes in the drive.
- Kyle J. M. Bishop
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Article |
Formation of porous crystals via viscoelastic phase separation
Viscoelastic phase separation of colloidal suspensions can be interrupted to form gels either by glass transition or crystallization. A kinetic pathway to spontaneously form network or porous structures made of metallic and semiconducting crystals is proposed.
- Hideyo Tsurusawa
- , John Russo
- & Hajime Tanaka
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Emergence of an enslaved phononic bandgap in a non-equilibrium pseudo-crystal
The dynamic self-assembly of a pseudo-crystal, characterized by a phononic bandgap bound to the wavelength of an external coherent driving field.
- Nicolas Bachelard
- , Chad Ropp
- & Xiang Zhang
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Electrochemical strain microscopy probes morphology-induced variations in ion uptake and performance in organic electrochemical transistors
Electrochemical strain microscopy reveals the interconnection between ion uptake and nanoscale variations of morphology in organic semiconductor films. Such changes locally affect the operation regime of organic transistors exposed to electrolytes.
- R. Giridharagopal
- , L. Q. Flagg
- & D. S. Ginger
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Article |
Phagocytosis-inspired behaviour in synthetic protocell communities of compartmentalized colloidal objects
Droplets with magnetite membranes are designed to engulf in a phagocytosis-inspired manner smaller colloidal objects, demonstrating a route for sequential cargo delivery and release followed by internalized reactions.
- Laura Rodríguez-Arco
- , Mei Li
- & Stephen Mann
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Molecular engineering of chiral colloidal liquid crystals using DNA origami
DNA origami allows the design of rod-shaped particles with specific geometrical features. This is exploited to examine how particle-level characteristics affect properties of the bulk phase and the superstructures such colloids assemble into.
- Mahsa Siavashpouri
- , Christian H. Wachauf
- & Zvonimir Dogic
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Printable elastic conductors by in situ formation of silver nanoparticles from silver flakes
Printing and heating of a fluorinated elastomer mixed with silver flakes, a fluorine surfactant and methylisobutylketone leads to the formation of in situ silver nanoparticles, which boost the conductivity of this highly stretchable composite material.
- Naoji Matsuhisa
- , Daishi Inoue
- & Takao Someya
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Tuning crystallization pathways through sequence engineering of biomimetic polymers
AFM measurements of peptoids assembling into sheets and networks show that the crystallization mechanism is determined by the molecular structure, where the addition of a hydrophobic segment alters the crystal formation process into a two-step pathway.
- Xiang Ma
- , Shuai Zhang
- & James J. De Yoreo
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News & Views |
Let's twist again
The magnetization in a chiral ferromagnetic fluid can be twisted and linked to form a stable three-dimensional topological soliton known as a hopfion.
- Paul Sutcliffe