Featured
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Perspective |
The changing state of porous materials
Highly ordered crystalline porous solids are useful for many applications. This Perspective explores the evolution of these systems from the ordered state to the glassy and liquid states, discusses the different types of porous liquid and considers possible applications of these disordered systems.
- Thomas D. Bennett
- , François-Xavier Coudert
- & Andrew I. Cooper
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Article |
Coatings super-repellent to ultralow surface tension liquids
Liquid repellent coatings are important for several applications. Now, a coating that repels ultralow surface tension liquids and simultaneously shows robustness and transparency is reported.
- Shuaijun Pan
- , Rui Guo
- & Frank Caruso
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Letter |
Interparticle hydrogen bonding can elicit shear jamming in dense suspensions
Dense suspensions of hard particles readily display discontinuous shear thickening under shear but not reversible shear jamming. Here it is shown that the formation of interparticle hydrogen bonds is crucial for the shear jamming of these suspensions.
- Nicole M. James
- , Endao Han
- & Heinrich M. Jaeger
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News & Views |
Multilevel robustness
A combination of hard, soft and nanoscale organic components results in robust superhydrophobic surfaces that can withstand mechanical abrasion and chemical oxidation, and exhibit excellent substrate adhesion.
- Henri-Louis Girard
- , Sami Khan
- & Kripa K. Varanasi
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Article |
All-organic superhydrophobic coatings with mechanochemical robustness and liquid impalement resistance
Coatings made of flexible, organic layered nanocomposites achieve high water repellence under harsh mechanical and chemical environments.
- Chaoyi Peng
- , Zhuyang Chen
- & Manish K. Tiwari
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Article |
Nanoscale capillary freezing of ionic liquids confined between metallic interfaces and the role of electronic screening
Ionic liquids are important for energy storage and lubrication but their behaviour at electrified interfaces remains elusive. Confined ionic liquids are now shown to exhibit a dramatic change to a solid-like phase pointing to capillary freezing.
- Jean Comtet
- , Antoine Niguès
- & Alessandro Siria
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Article |
Biredox ionic liquids with solid-like redox density in the liquid state for high-energy supercapacitors
Electrochemical storage devices in the liquid state are promising but they suffer from low redox species density. An approach based on biredox ionic liquids now demonstrates bulk-like redox density compatible with supercapacitor applications.
- Eléonore Mourad
- , Laura Coustan
- & Olivier Fontaine
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News & Views |
Negative refraction of sound
Porous rubber microbeads suspended in a gel are found to exhibit a negative acoustic index of refraction, which makes these metamaterials promising for underwater acoustic applications.
- Bogdan-Ioan Popa
- & Steven A. Cummer
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Article |
New metastable form of ice and its role in the homogeneous crystallization of water
At sufficiently low temperature, liquid water crystallizes into ices with cubic or hexagonal symmetry. A simulation study now shows that the nucleation of water into atomic stackings of cubic and hexagonal ices occurs through a metastable precursor phase with tetragonal symmetry, and that this scenario provides an explanation for the unusual pressure dependence of water’s homogeneous crystal-nucleation temperature.
- John Russo
- , Flavio Romano
- & Hajime Tanaka
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Article |
Irreversible nanogel formation in surfactant solutions by microporous flow
Viscoelastic gels can be made by using flow to induce structure into solutions containing surfactant micelles. However, the gels disintegrate soon after flow stoppage. By using a microfluidic-assisted laminar-flow process to generate very high extension rates, it is now shown that permanent gels can be made, creating new opportunities for applications.
- Mukund Vasudevan
- , Eric Buse
- & Radhakrishna Sureshkumar
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Letter |
Generality of shear thickening in dense suspensions
In most suspensions viscosity decreases with increasing shear rate. The opposite effect, shear thickening, is a problem for industrial applications. An understanding of how particle interactions in suspensions influence shear thickening may lead to a solution of this problem through the design of smart suspensions.
- Eric Brown
- , Nicole A. Forman
- & Heinrich M. Jaeger