Chemistry articles within Nature Communications

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  • Article |

    Membrane-less electrochemical systems eliminate the need for costly ion-exchange membranes, but typically suffer from low-power densities. Braff et al.propose a hydrogen bromine laminar flow battery, which rivals the performance of the best membrane-based systems.

    • William A. Braff
    • , Martin Z. Bazant
    •  & Cullen R. Buie

  • Article |

    A physical description of supercritical fluids remains challenging because common approximations for solids and gases do not apply to liquids. Bolmatov et al. identify a liquid/gas dynamic crossover of specific heat above the critical point, and formulate a theory to shed light on its nature.

    • Dima Bolmatov
    • , V. V. Brazhkin
    •  & K. Trachenko

  • Article |

    Crystalline porous materials are commonly based around negatively charged frameworks, so ion-exchange is limited to cations. Here, the authors report a series of positive metal-organic frameworks, capable of ion exchange of large organic anions, with potential in separation and purification applications.

    • Xiang Zhao
    • , Xianhui Bu
    •  & Pingyun Feng

  • Article |

    Techniques for shape-controlling of hydrogels, that is, crosslinked networks of polymers, could make possible various biomimetic applications. Palleau et al.propose a strategy to pattern three-dimensional hydrogels using electric potential, which allows directed bending and fast controllable actuation.

    • Etienne Palleau
    • , Daniel Morales
    •  & Orlin D. Velev

  • Article
    | Open Access

    Platinum nanoclusters are well-known catalysts for the oxygen reduction reaction, although the performance of clusters smaller than 2 nm is poorly studied. Here, the authors report 1.4 nm platinum clusters supported on DNA–graphene oxide composites and demonstrate promising electrochemical activity and stability.

    • Jitendra N. Tiwari
    • , Krishna Nath
    •  & Kwang S. Kim

  • Article
    | Open Access

    Electrically insulating ligands and doping of colloidal semiconductor nanocrystals continue to be significant challenges for practical nanocrystal-based optoelectronics. Wheeler et al.demonstrate a new surface chemistry technique that confronts both of these challenges simultaneously.

    • Lance M. Wheeler
    • , Nathan R. Neale
    •  & Uwe R. Kortshagen

  • Article |

    Fundamental understanding of gold–carbon bonding in homogeneous catalysts is vital for improved catalyst design, although spectroscopic information is limited. Here, the authors probe the bonding in gold–alkyne complexes using a combination of photoelectron spectroscopy and ab initiocalculations.

    • Hong-Tao Liu
    • , Xiao-Gen Xiong
    •  & Lai-Sheng Wang

  • Article |

    Lead-acid batteries are used worldwide, but their recycling remains challenging because of lead pollution and high energy consumption. Pan et al. solve these problems in a high-yield, hydrometallurgical process based on hydrogen-lead oxide fuel cell reactions, which produce water as the by-product.

    • Junqing Pan
    • , Yanzhi Sun
    •  & Arumugam Manthiram

  • Article |

    Ultrafast laser pulses are useful to study electron dynamics in chemical bonds, but their influence on bond breaking is not fully understood. Wu et al. study H2 bond breaking with coincidence techniques, and find a phase-dependent anisotropy of the H+fragmentation even for isotropic multicycle laser pulses.

    • J. Wu
    • , M. Magrakvelidze
    •  & R. Dörner

  • Article
    | Open Access

    Many interesting chemical problems like photosynthesis and photovoltaics involve non-adiabatic dynamical phenomena, which are difficult to predict theoretically. Here, the authors develop a new numerical method capable of recovering quantum interferences that are neglected by conventional methods.

    • Vyacheslav N. Gorshkov
    • , Sergei Tretiak
    •  & Dmitry Mozyrsky

  • Article |

    Assembly of functional colloidal nanoparticles has many technological applications, but its three-dimensional realization remains challenging. Kim et al.report a spontaneous self-orientation of gold nanorods at an oil/water interface and use it to amplify signal in surface-enhanced Raman spectroscopy.

    • Kihoon Kim
    • , Hye Soo Han
    •  & Taewook Kang

  • Article
    | Open Access

    Chemical reactions on femtolitre scales are necessary to study confined biological processes. Here, the authors use a microfluidic pen lithography technique to perform a series of discrete femtoscale acid-base and synthetic reactions, and crystallizations on a surface with high registration accuracy.

    • Carlos Carbonell
    • , Kyriakos C. Stylianou
    •  & Daniel Maspoch

  • Article
    | Open Access

    The enantiopurity of chiral compounds is key in determining their activity or therapeutic action. Here, the authors present a versatile NMR method of enantiomeric excess determination using a symmetrical achiral molecule as resolving agent, based on complexation with analyte, without formation of diastereomers.

    • Jan Labuta
    • , Shinsuke Ishihara
    •  & Jonathan P. Hill

  • Article
    | Open Access

    Elemental sulphur is an insulator in the bulk phase, although it may become conducting under ultrahigh-pressure conditions. Here, the authors report a one-dimensional conducting form of sulphur formed by encapsulation inside single-walled and double-walled carbon nanotubes.

    • Toshihiko Fujimori
    • , Aarón Morelos-Gómez
    •  & Katsumi Kaneko

  • Article |

    The direct transformation of cellulose into high-value chemicals is a key process in the establishment of biomass-derived chemical production. Here, the authors present the lead(II)-catalysed conversion of cellulose into lactic acid via a cascade reaction, which proceeds in water under mild conditions.

    • Yanliang Wang
    • , Weiping Deng
    •  & Huilin Wan

  • Article
    | Open Access

    Porous solids have potential applications in energy storage, gas separation and catalysis technologies. Here, the authors report a hierarchical solid with porosity spanning the micro, meso and macro ranges, which is synthesized using templating silica, and potassium ions as both templates and reactive species.

    • Yu Ren
    • , Zhen Ma
    •  & Peter G. Bruce

  • Article |

    Since the isolation of graphene, there has been extensive interest in other two-dimensional structures including metallic nanosheets. Here, the authors report the use of ladder polysilane ligands for the synthesis of palladium clusters containing eleven metal ions, made up of two heptametallic nanosheets.

    • Yusuke Sunada
    • , Ryohei Haige
    •  & Hideo Nagashima

  • Article |

    The final state of self-assembled systems is determined by both their thermodynamic and kinetic pathways. Di Michele et al.develop a strategy to realize predesigned amorphous structures of complex DNA colloidal mixtures by selectively activating local inter- or intra-species interactions upon freezing.

    • Lorenzo Di Michele
    • , Francesco Varrato
    •  & Erika Eiser

  • Article |

    Rapid, highly multiplexed molecular detection platforms may enable more specific and effective disease diagnosis. Here, a solution-based circuit is reported that enables the analysis of samples for panels of pathogens and antibiotic-resistance profiles at clinically relevant levels in less than 2 min.

    • Brian Lam
    • , Jagotamoy Das
    •  & Shana O. Kelley

  • Article
    | Open Access

    Nonvolatile luminescent liquids are solvent-free fluids with a range of flexible electronic applications. Here, the authors show that anthracenes enveloped in branched aliphatic compounds are stable emissive liquids, with emissive and thermoresponsive properties that may be tuned by addition of dopants.

    • Sukumaran Santhosh Babu
    • , Martin J. Hollamby
    •  & Takashi Nakanishi

  • Article
    | Open Access

    Conjugated microporous polymers are highly flexible materials that may be used for gas storage and catalysis applications. Here, the authors report metal-functionalized conjugated microporous polymers capable of both capturing CO2and functioning as a heterogeneous catalyst in its conversion to propylene carbonate.

    • Yong Xie
    • , Ting-Ting Wang
    •  & Wei-Qiao Deng

  • Article |

    Membranes for molecular-level sieving based on processable, permeable polymers are desirable for industrial processes. Here, the authors report the photo-oxidative surface modification of these membranes, which results in asymmetric materials with high selectivity and permeability for gas separations.

    • Qilei Song
    • , Shuai Cao
    •  & Easan Sivaniah

  • Article |

    Noble metallic subnanometre clusters exhibit superior catalytic activities, but their stability remains a problem. Zhang et al. report that single niobium atoms can be stabilized in graphitic layers and the resulting carbide complex exhibits higher activity compared with commercial platinum nanoclusters.

    • Xuefeng Zhang
    • , Junjie Guo
    •  & Matthew F. Chisholm

  • Article |

    Small interfering RNA is degraded by plasma and can’t cross the cell membrane due to its negative charge. Here, the authors present an influenza inspired polymer carrier, capable of local RNA delivery, which degrades to a non-toxic by-product, and is thus suitable for multiple doses.

    • Nghia P Truong
    • , Wenyi Gu
    •  & Michael J Monteiro

  • Article |

    Hyperbranched polymers have desirable properties as novel materials, and may be synthesized from homopolymerization of multi-vinyl momomers, although this can form insoluble products at low conversions. Here, the authors produce hyperbranched polymers in high yield owing to a kinetic control mechanism.

    • Tianyu Zhao
    • , Yu Zheng
    •  & Wenxin Wang

  • Article |

    The expression of specific genes can be controlled by the combination of DNA-binding proteins, which determines their binding site selectivity. Here, simplified synthetic basic region leucine zipper-based peptides are induced to dimerize either through their C- or N-terminus, and thus are targeted to different DNA sequences.

    • Jesús Mosquera
    • , Adrián Jiménez-Balsa
    •  & José L Mascareñas

  • Article
    | Open Access

    AChBP is used as a structurally accessible prototype for studying ligand binding to nicotinic acetylcholine receptors. Stornaiuolo et al. report that a small molecule binds AChBP in an ordered p–p stack of three molecules per binding site, which may lead to new approaches in drug design.

    • Mariano Stornaiuolo
    • , Gerdien E. De Kloe
    •  & Titia K. Sixma

  • Article
    | Open Access

    Currently, gold recovery from waste materials requires inorganic cyanides and more environmentally benign methods are required. Here, the authors report that host–guest interactions between α-cyclodextrin and gold lead to the precipitation of one-dimensional superstructures, offering a selective and green alternative.

    • Zhichang Liu
    • , Marco Frasconi
    •  & J. Fraser Stoddart

  • Article |

    Metal-air batteries are promising for energy storage because of their high theoretical energy density, but their realization is hampered by the lack of efficient and robust air catalysts. Li et al. construct stable zinc-air batteries using novel catalysts for oxygen reduction and evolution reactions.

    • Yanguang Li
    • , Ming Gong
    •  & Hongjie Dai

  • Article |

    Lithium air batteries have among the highest energy storage capacities, but their effective lifetime is short when using liquid electrolytes. Zhang et al. realize a lithium air battery with much improved cycling stability in ambient air by combining a solid electrolyte and a gel cathode.

    • Tao Zhang
    •  & Haoshen Zhou

  • Article
    | Open Access

    Chiral molecules form one-handed supramolecular assemblies but may be induced to switch to the other handed assembly, although the mechanisms driving these processes are unclear. Here, the authors demonstrate control of the supramolecular assembly handedness via the introduction of achiral counter ions.

    • Toshiyuki Sasaki
    • , Ichiro Hisaki
    •  & Mikiji Miyata

  • Article |

    The development of materials for the effective removal of oils and solvents from water is of global importance. Here, the authors show that porous, hexagonal boron nitride nanosheets are capable of absorbing many times their own weight in oil while repelling water, and may be cleaned for reuse by heating or burning in air.

    • Weiwei Lei
    • , David Portehault
    •  & Ying Chen

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