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Achieving extremely fast charging while maintaining high energy density remains a challenge in the battery field. Here the authors conceptualize a porous current collector that successfully reduces the effective Li+ transport distance by half, quadrupling the diffusion-limited C-rate capability without compromising battery energy density.
Non-flammable electrolytes are essential for ensuring the safe operation of sodium-metal batteries; however, challenges arise in applications due to limited stability between the electrolytes and electrodes. Now, an electrolyte engineering approach using salts as a diluent is proposed to achieve both high interfacial stability and improved safety.
Manufacturing of perovskite solar cells under ambient conditions is desirable. Meng et al. show that dimethylammonium formate suppresses halide oxidation and deprotonation of organic cations, enabling air-processed inverted solar cells with 24.7% efficiency.
Injecting hydrogen into subsurface environments could provide seasonal energy storage, but understanding of technical feasibility is limited as large-scale demonstrations are scarce. Now, field tests show that hydrogen can be stored and microbially converted to methane in a depleted underground hydrocarbon reservoir.
The scarcity of raw materials and complex synthesis procedures have impeded the development of electrolytes for Mg and Ca metal batteries. Research now reports a facile synthesis of organoborate electrolytes through cation replacement reactions, offering highly reversible Mg or Ca electrochemistry.
The clean-cooking transition in the Global South can support major improvements in public and environmental health and societal conditions. This study draws on survey data from greater than 7,000 households in Ghana to understand determinants of household fuel use through the transition and proposes a stage-based framework to support policy interventions.
Establishing pH differences in aqueous flow batteries widens their voltage window, but acid–base mixing shortens their lifespan. In this study, the authors introduced a pH recovery system to address crossover issues, ensuring long-lasting, high-voltage pH-decoupled flow batteries.
Keller et al. use high-concentration silver alloying and steep gallium grading close to the back contact to minimize bandgap fluctuations and thus voltage losses, achieving 23.6% certified efficiency in Cu(In,Ga)Se2 solar cells.
Electrolytes with non-flammable solvents are important for the safe operation of sodium-metal batteries. Here the authors report an electrolyte engineering approach, employing salts as a diluent, to enhance interfacial stability and overall safety.
Geologic formations could be used for hydrogen storage and conversion to methane, yet technical feasibility is unclear as field-scale data are lacking. Here the authors perform field tests demonstrating that hydrogen can be stored and microbially converted to methane in a depleted underground hydrocarbon reservoir.
Inhomogeneities in the optoelectronic properties of polycrystalline Cu(In,Ga)Se2 absorbers can limit solar cell performance. Now, researchers quantify the spatial distribution of charge carrier concentration with nanometre resolution and show how different alkali-metal post-deposition treatments reduce the grain-to-grain fluctuations.
Achieving high selectivity towards the formation of a single type of multi-carbon product from CO2 electroreduction is difficult. Here Wu and colleagues show that the valence state of Cu can be tuned by functionalization of the catalyst surface with organic salts, boosting selectivity towards ethylene.
Development ramifications of global decarbonization efforts for fossil fuel-producing low and lower–middle income countries remain underexplored. This Perspective suggests three transition pathways for navigating these ramifications.
Carbon monoxide can be reacted with water to synthesize hydrocarbons, but low activity and poor selectivity has plagued the conventional thermal catalytic route. Now, leveraging photocatalytic and thermocatalytic effects, a TiO2–x/Ni catalyst is shown to produce C2+ hydrocarbons directly from carbon monoxide and water with high yield and selectivity.
Decision makers need sector-specific, policy-focused, dynamic economic models with rich representations of technological progress. These allow them to understand how the energy transition is likely to unfold with different policies and what its impacts might be. A new generation of models is emerging to meet these demands, but more action is needed.