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Bipolar membranes

Ions block up the junction

Nature Energy volume 8, pages 1313–1314 (2023)Cite this article

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Bipolar membranes are emerging as an enabling component in numerous energy-relevant electrochemical devices, but a greater understanding of how they operate in complex electrolytes is needed. Research now reveals that ionic species in mixed-ion electrolytes can block the heart of the membrane, the bipolar junction, hampering its performance.

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Fig. 1: Energy penalties in forward-bias bipolar membrane CO2 electrolysers.

References

  1. Oener, S. Z., Foster, M. J. & Boettcher, S. W. Science 369, 1099–1103 (2020).

    Article  Google Scholar 

  2. Seeberger, D., McLaughlin, D., Hauenstein, P. & Thiele, S. Sustain. Energy Fuels 4, 2508–2518 (2020).

    Article  Google Scholar 

  3. Vermaas, D. A. & Smith, W. A. ACS Energy Lett. 1, 1143–1148 (2016).

    Article  Google Scholar 

  4. Toh, W. L., Dinh, H. Q., Chu, An, T., Sauvé, E. R. & Surendranath, Y. Nat. Energy https://doi.org/10.1038/s41560-023-01404-7 (2023).

    Article  Google Scholar 

  5. Disch, J., Ingenhoven, S. & Vierrath, S. Adv. Energy Mater. 13, 2301614 (2023).

    Article  Google Scholar 

  6. Monteiro, M. C. O., Philips, M. F., Schouten, K. J. P. & Koper, M. T. M. Nat. Commun. 12, 4943 (2021).

    Article  Google Scholar 

  7. Chen, L., Xu, Q. & Boettcher, S. W. Joule 7, 1867–1886 (2023).

    Article  Google Scholar 

  8. Oener, S. Z., Twight, L. P., Lindquist, G. A. & Boettcher, S. W. ACS Energy Lett. https://doi.org/10.1021/acsenergylett.0c02078 (2021).

    Article  Google Scholar 

  9. Lucas, É. et al. Preprint at ChemRxiv https://doi.org/10.26434/chemrxiv-2023-n4c6x (2023).

  10. Luo, T., Abdu, S. & Wessling, M. J. Memb. Sci. 555, 429–454 (2018).

    Article  Google Scholar 

Download references

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  1. Department of Interface Science, Fritz-Haber Institute of the Max Planck Society, Berlin, Germany

    Sebastian Z. Oener

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  1. Sebastian Z. Oener
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Correspondence to Sebastian Z. Oener.

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Oener, S.Z. Ions block up the junction. Nat Energy 8, 1313–1314 (2023). https://doi.org/10.1038/s41560-023-01410-9

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