News & Views |
Featured
-
-
Article |
Ultrastable glasses from in silico vapour deposition
Glasses with extraordinary kinetic stability have been made in the laboratory by physical vapour deposition. A computational algorithm that mimics such a deposition process now reveals that deposition at the temperature at which the configurational entropy vanishes leads to ultrastable glasses that are truly amorphous, pack uniformly and have energies that are equivalent to those of equilibrium supercooled liquids.
- Sadanand Singh
- , M. D. Ediger
- & Juan J. de Pablo
-
Letter |
Hidden polymorphs drive vitrification in B2O3
Whether a liquid forms a crystal or a glass on solidification depends on many factors. The finding now that a disordered structure is favoured in B2O3 because the system cannot choose between several crystalline polymorphs of similar energy highlights a link between glass formation and crystallization.
- Guillaume Ferlat
- , Ari Paavo Seitsonen
- & Francesco Mauri
-
-
News & Views |
Clearing the water
Evidence of a transition between two coexisting liquids of the same composition in a water–glycerol mixture, where glycerol prevents the crystallization of water, provides a unique link to an elusive liquid–liquid transition in pure water.
- Austen Angell
-
News & Views |
Family traits
The finding that metallic glasses inherit their elastic properties from solvent atoms leads to a new understanding of the complex relationship between glassy structure, deformation and mechanical properties.
- Wei Hua Wang
-
News & Views |
From gas to nanoglobular glass
When quenching a liquid to form a glass, order-of-magnitude changes in cooling speed have small effects on the glass's properties. It is now shown that laser-assisted vapour deposition produces nanostructured glassy polymer films with a higher glass transition temperature and lower density than conventional quenched polymer glasses.
- Mark D Ediger
- & Lian Yu
-
Article |
Ultrastable nanostructured polymer glasses
The realization of ultrastable, nanostructured glassy polymer films by pulsed-laser evaporation is reported. Compared with standard poly(methyl methacrylate) glass, these polymer glasses are 40% less dense and have a 40-degree-higher glass transition temperature. Their unique properties, which are a manifestation of their globular nanostructure, should make these glasses attractive for applications where weight and stability are critical.
- Yunlong Guo
- , Anatoli Morozov
- & Rodney D. Priestley
-
Letter |
A micromechanical model to predict the flow of soft particle glasses
Toothpaste, mayonnaise and other systems are soft particle glasses. In these, the soft particles are jammed so that the glasses behave like weak solids at rest but at sufficient stress flow like liquids. This has made their theoretical understanding difficult. A new micromechanical model is now able to predict the rheology of these soft particle glasses.
- Jyoti R. Seth
- , Lavanya Mohan
- & Roger T. Bonnecaze
-
Article |
Structural origin of enhanced slow dynamics near a wall in glass-forming systems
Container walls are known to have a significant influence on the dynamics of glass formation. Computations now suggest that structural order is the origin of the slower dynamics of a glass-forming liquid near container walls.
- Keiji Watanabe
- , Takeshi Kawasaki
- & Hajime Tanaka
-
Article |
Local elastic properties of a metallic glass
In contrast to the long-range order of crystalline materials, non-crystalline compounds, such as metallic glasses, have a more inhomogeneous distribution of atoms on a local scale. Atomic force acoustic microscopy now demonstrates how these local variations translate into much stronger variations in local elastic properties of a metallic glass compared with its crystalline counterpart.
- Hannes Wagner
- , Dennis Bedorf
- & Konrad Samwer
-
Article |
Memory and topological frustration in nematic liquid crystals confined in porous materials
Computer simulations of nematic liquid crystals confined in bicontinuous porous geometries show that frustration and topology lead to multiple, metastable trajectories of defect lines that can be memorized on application of external fields. These topologically enabled metastable states could be exploited to optically functionalize orientationally ordered materials.
- Takeaki Araki
- , Marco Buscaglia
- & Hajime Tanaka
-
News & Views |
Damage tolerance at a price
Metallic glasses are strong but can be brittle. The discovery of a metallic glass that also shows a high toughness against fracture is remarkable, and establishes metallic glasses, at least those based on noble metals, as materials with the highest known damage tolerance.
- A. Lindsay Greer
-
Article |
A damage-tolerant glass
Metallic glasses are strong but at the same time are brittle once they yield. A new Pd-based metallic glass now shows significantly enhanced fracture toughness. The unique combination of yield strength and toughness makes this glass comparable to the toughest as well as strongest materials known.
- Marios D. Demetriou
- , Maximilien E. Launey
- & Robert O. Ritchie
-
News & Views |
Reflections from the glass maze
The first diffraction patterns from the individual atomic packing clusters in a metallic glass finally enable the direct study of local order in amorphous alloys.
- Evan Ma
- & Ze Zhang
-
Letter |
Direct observation of local atomic order in a metallic glass
The atomic configuration of metallic glasses is a long-standing issue important to the understanding of their properties. Nanobeam electron diffraction experiments now enable a direct determination of the local atomic order in a metallic glass.
- Akihiko Hirata
- , Pengfei Guan
- & Mingwei Chen
-
Letter |
Atomistic free-volume zones and inelastic deformation of metallic glasses
The amorphous nature of metallic glasses makes them interesting for structural applications. However, the interplay between the nature of atomic structures and mechanical properties remains poorly understood. Dynamic micropillar tests now show the important contribution of the inelastic deformation of atomistic free-volume zones to the deformation behaviour of metallic glasses.
- J. C. Ye
- , J. Lu
- & Y. Yang
-
Letter |
Transformation-mediated ductility in CuZr-based bulk metallic glasses
Bulk metallic glasses (BMGs) show good compressive mechanical properties that make them attractive for applications. However, BMGs tend to fail under tensile strain. Through secondary phases these problems can be remedied to some degree. A mechanism is now demonstrated where BMGs show enhanced tensile ductility though the deformation-induced precipitation of nanocrystals.
- S. Pauly
- , S. Gorantla
- & J. Eckert
-
Article |
Critical-like behaviour of glass-forming liquids
As a liquid approaches its glass transition its dynamics slow down and simultaneously the material becomes more heterogeneous. A static structural heterogeneity, now shown to be widely present in glass-forming liquids, is suggested to be the origin of this dynamic heterogeneity that links structural parameters to the glass transition.
- Hajime Tanaka
- , Takeshi Kawasaki
- & Keiji Watanabe
-
Letter |
Transition from a strong-yet-brittle to a stronger-and-ductile state by size reduction of metallic glasses
The mechanical properties of many materials are different on the nanoscale than they are in the bulk. In the case of metallic glasses, nanometre-scale samples show enhanced ductility. This tensile ductility has now been quantified for samples with diameters down to 100 nm, where a new regime of increased ductility during deformation is observed.
- Dongchan Jang
- & Julia R. Greer
-
Letter |
Three-dimensional jamming and flows of soft glassy materials
Jamming transitions of disordered systems such as foams, gels and colloidal suspensions, describe the change from a liquid to a solid state. An investigation of the three-dimensional properties of jamming shows how, for example, unjamming occurs simultaneously in all directions even if it is induced in one direction only.
- G. Ovarlez
- , Q. Barral
- & P. Coussot