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Polymer glasses

From gas to nanoglobular glass

When quenching a liquid to form a glass, order-of-magnitude changes in cooling speed have small effects on the glass's properties. It is now shown that laser-assisted vapour deposition produces nanostructured glassy polymer films with a higher glass transition temperature and lower density than conventional quenched polymer glasses.

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Figure 1: Pulsed-laser evaporation and deposition of polymer molecules to form ultrastable, low-density polymer glasses1.

References

  1. Guo, Y. et al. Nature Mater. 11, 337–343 (2012).

    Article  CAS  Google Scholar 

  2. Shirota, Y. & Kageya, H. Chem. Rev. 107, 953–1010 (2007).

    Article  CAS  Google Scholar 

  3. Meijer, H. E. H. & Govaert, L. Prog. Polym. Sci. 30, 915–938 (2005).

    Article  CAS  Google Scholar 

  4. Swallen, S. F. et al. Science 315, 353–356 (2007).

    Article  CAS  Google Scholar 

  5. Ramos, S. L. L. M., Oguni, M., Ishii, K. & Nakayama, H. J. Phys. Chem. B 115, 14327–14332 (2011).

    Article  CAS  Google Scholar 

  6. Leon-Gutierrez, E., Sepulveda, A., Garcia, G., Clavaguera-Mora, M. T. & Rodriguez-Viejo, J. Phys. Chem. Chem. Phys. 12, 14693–14698 (2010).

    Article  CAS  Google Scholar 

  7. Singh, S. & de Pablo, J. J. J. Chem. Phys. 134, 194903 (2011).

    Article  Google Scholar 

  8. Kearns, K. L., Whitaker, K. R., Ediger, M. D., Huth, H. & Schick, C. J. Chem. Phys. 133, 014702 (2010).

    Article  Google Scholar 

Download references

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Correspondence to Mark D Ediger.

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Ediger, M., Yu, L. From gas to nanoglobular glass. Nature Mater 11, 267–268 (2012). https://doi.org/10.1038/nmat3281

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