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Keller et al. use high-concentration silver alloying and steep gallium grading close to the back contact to minimize bandgap fluctuations and thus voltage losses, achieving 23.6% certified efficiency in Cu(In,Ga)Se2 solar cells.
Electrolytes with non-flammable solvents are important for the safe operation of sodium-metal batteries. Here the authors report an electrolyte engineering approach, employing salts as a diluent, to enhance interfacial stability and overall safety.
Geologic formations could be used for hydrogen storage and conversion to methane, yet technical feasibility is unclear as field-scale data are lacking. Here the authors perform field tests demonstrating that hydrogen can be stored and microbially converted to methane in a depleted underground hydrocarbon reservoir.
Inhomogeneities in the optoelectronic properties of polycrystalline Cu(In,Ga)Se2 absorbers can limit solar cell performance. Now, researchers quantify the spatial distribution of charge carrier concentration with nanometre resolution and show how different alkali-metal post-deposition treatments reduce the grain-to-grain fluctuations.
Achieving high selectivity towards the formation of a single type of multi-carbon product from CO2 electroreduction is difficult. Here Wu and colleagues show that the valence state of Cu can be tuned by functionalization of the catalyst surface with organic salts, boosting selectivity towards ethylene.
Development ramifications of global decarbonization efforts for fossil fuel-producing low and lower–middle income countries remain underexplored. This Perspective suggests three transition pathways for navigating these ramifications.
Carbon monoxide can be reacted with water to synthesize hydrocarbons, but low activity and poor selectivity has plagued the conventional thermal catalytic route. Now, leveraging photocatalytic and thermocatalytic effects, a TiO2–x/Ni catalyst is shown to produce C2+ hydrocarbons directly from carbon monoxide and water with high yield and selectivity.
Decision makers need sector-specific, policy-focused, dynamic economic models with rich representations of technological progress. These allow them to understand how the energy transition is likely to unfold with different policies and what its impacts might be. A new generation of models is emerging to meet these demands, but more action is needed.
Polymer nanocomposite-based dielectric capacitors are promising candidates for high- power-density energy storage devices. However, they exhibit poor performance at high temperatures. A polymer nanocomposite based on sub-nanosheets shows high energy density at elevated temperatures due to the unique structure, geometry, and high surface area to volume ratio of the nanosheets.
The efficiency of perovskite quantum dot solar cells based on organic cations is relatively low. Aqoma et al. develop an alkyl ammonium iodide-based ligand exchange strategy for the replacement of the long-chain oleyl ligands and phase stabilization that enables 18.1%-efficiency solar cells.
Oxidation of halides and subsequent segregation limit the stability of perovskite solar cells. Wu et al. synthesize anthraquinone derivatives to suppress oxidation while also passivating defects, achieving 25.2%-efficiency organic/perovskite tandem solar cells.
Not all Australian communities are equally protected by consumer electricity retail regulations, with remote and Indigenous communities more likely to be underserved on multiple fronts. Communities in regions potentially critical to energy transition are often underserved by regulations that would otherwise ensure their own energy needs, hindering progress toward a just transition.
Gasoline prices have increasingly become a focus of attention for climate policy. This study uses survey and retail gasoline price data to explore associations between gasoline prices and public acceptability of different climate policies, finding in part that support for phasing out fossil fuel-powered cars decreases when prices rise.
Ideal photoelectrochemical systems for hydrogen production should be highly efficient, stable and scalable. Here the authors report that a perovskite-based system with promising efficiency and stability can be scaled to cells of several square centimetres in area as well as formed into mini-modules with overall area >100 cm2.
Retaining high performance of perovskite solar cells over large areas is a challenge. Yang et al. use a thermotropic liquid crystal with high diffusivity that does not co-crystallize with the perovskite, suppressing defect formation and enabling large-area solar modules with improved stability and efficiency.