Abstract
In this work, sawdust, a biomass waste, is converted into a magnetic porous carbonaceous (MPC) solid acid catalyst by an integrated fast pyrolysis–sulfonation process. The resultant magnetic solid acid has a porous structure with high surface area of 296.4 m2 g−1, which can be attributed to the catalytic effect of Fe. The catalytic activity and recyclability of the solid acid catalyst are evaluated during three typical acid-catalyzed reactions: esterification, dehydration and hydrolysis. The favorable catalytic performance in all three reactions is attributed to the acid's high strength with 2.57 mmol g−1 of total acid sites. Moreover, the solid acid can be reused five times without a noticeable decrease in catalytic activity, indicating the stability of the porous carbon (PC)–sulfonic acid group structure. The findings in the present work offer effective alternatives for environmentally friendly utilization of abundant biomass waste.
Similar content being viewed by others
Introduction
With the depletion of fossil fuels, development of renewable energy has attracted an increasing amount of interest. Acidic materials are widely used in the catalytic production of a variety of renewable fuels (e.g., biodiesels) and fine chemicals (e.g., furfurals and sugars)1,2,3. In the past, liquid mineral acids (e.g., HCl, H2SO4 and H3PO4) have been widely used to catalyze these reactions1,4. However, many disadvantages, such as strong corrosiveness, costly and inefficient separation from homogeneous reaction mixtures and creation of a large amount of waste by-products, have limited the applications of liquid mineral acids in many fields5. Alternatively, solid acids including solid Brønsted acids (e.g., SO3H functionalized carbon and polymers)6,7,8,9 in addition to solid Lewis acids (transition-metal (W, Zr, Nb) oxides)10,11 are easily separated from the reaction mixture and can be reused. Thus, solid acids have been used to replace liquid mineral acids in catalytic reactions such as esterification, dehydration and hydrolysis during biofuel production to minimize adverse effects on the environment and to reduce expenses5,12,13,14,15,16. Porous carbonaceous (PC) solid acids are widely used catalysts in acid-catalyzed reactions. Nakajima et al.6 reported that these acids can be synthesized by sulfonation of partially carbonized organic matter including sugars, cellulosic materials and synthetic polymers and can be used in many acid catalytic reacions such as hydrolysis of β-1,4 glucan and biodiesel production. Arancon et al.17 synthesized a PC solid acid from corncob residue, which demonstrated favorable catalytic performance in the esterification/transesterification of waste oils. Wu et al.18 prepared sulfonated bio-char as a solid acid for the hydrolysis of crystalline cellulose.
Compared with conventional solid acids, magnetic solid acids can be separated more easily in the presence of external magnetic fields, particularly in viscous or solid reaction mixtures19,20. The most common method used for synthesis of magnetic solid acid catalysts is sulfonation of a mesoporous structure with a magnetic core, generally Fe3O4. In a previous study, a magnetic solid acid with a high acid strength of 2.2–2.5 H+/mol was prepared through sulfonation of polystyrene-encapsulated Fe3O4 spheres21. More recently, a series of magnetic nano-sized solid acid catalysts was synthesized by sulfonation of a series of particles containing Fe3O4 cores with various shell materials (e.g., polystyrene, poly(glycidyl methacrylate) and silica)22. All of these catalysts exhibit high activity and excellent separability in the acid-catalyzed reactions. However, many magnetic solid acid catalysts reported thus far have been determined as unsatisfactory for acid catalyzed reactions. For example, SO3H-functionalized polymers often exhibit low thermal stability and are costly23. In addition, the preparation of these magnetic solid acid catalysts involves complex synthetic procedures and often requires expensive reagents, which impedes large-scale production and commercialization.
In our continuing efforts toward biomass waste disposal and resource recovery24,25,26,27, we have developed a rapid, low-cost and readily scalable approach for synthesizing a magnetic porous carbonaceous solid acid catalyst (MPC–SO3H) by using biomass waste as a precursor. This method involves fast pyrolysis of Fe-preloaded biomass to produce MPC material; subsequent sulfonation of the obtained material is used to prepare a solid acid catalyst. This process also produces bio-oil, a renewable liquid that can be used for fuel and chemical production28,29,30.
Results
A schematic illustration of the synthetic pathway for MPC–SO3H is shown in Fig. 1. Synthesis of MPC precursor materials is the primary step for MPC-SO3H synthesis, which includes the following steps: The Fe preloaded on the biomass in the form of FeCl3 is hydrolyzed to Fe hydroxides (FeO(OH)) in the drying process (Eqs. 1, 2). The Fe-preloaded biomass is then subjected to a pyrolysis process to be converted into MPC material. In this process, the Fe-preloaded biomass is thermally decomposed and the produced volatile components are swept out by the carrier gas (N2) and condensed to produce bio-oil. The FeO(OH) is reduced to Fe3O4 under mesothermal conditions at 673–873 K by reducing components including H2, CO and amorphous carbon, which were formed during the pyrolysis process (Eqs. 3–5)31,32. For comparison, PC materials without magnetism that were derived from raw biomass are also synthesized.
Figure 2a shows X-ray diffraction (XRD) patterns of MPC (Pattern A) and PC (Pattern B). Both patterns show a weak but broad diffraction peak of 2θ at ~23°, which can be attributed to the amorphous carbon composed of aromatic carbon sheets oriented in a relatively random manner33. The XRD peaks in Pattern A of 2θ at 30.1°, 35.7°, 37.1°, 43.2°, 53.6°, 62.7° and 74.9° indicate the formation of Fe3O4 crystallite in the fast pyrolysis process according to Joint Committee on Powder Diffraction Standard (JCPDS) 19-0629. Figure 2b shows the nitrogen sorption isotherms of MPC and PC. For Pattern A, the isotherms exhibit a typical type III pattern with an H2-type hysteresis loop at high relative pressures, indicating that the pores of MPC have uniform sizes and shapes34. For Pattern B, however, the isotherms exhibit a typical type II pattern without a significant hysteresis loop, suggesting that PC is nearly devoid of pores. Based on the nitrogen quantity adsorbed at different relative pressures, the surface area of the MPC is calculated by the Brunauer–Emmett–Teller (BET) method to be 391.7 m2 g−1, which is significantly higher than that of PC at 14.0 m2 g−1. This result indicates that the presence of Fe can catalyze the formation of porous structures during biomass carbonization mainly because the dehydration and decomposition of FeCl3 can enhance the release of volatile matter such as HCl, H2O, CO and CO2 (Eqs. 1–5) during the biomass pyrolysis process, which generally produces an increase in surface area and pore volume. Similar phenomena have been observed in the carbonization of FeCl3-impregnated pinewood sawdust and carbon aerogels containing Fe35,36. FeCl3 easily dehydrates carbohydrate polymers (e.g., cellulose and hemicellulose) at high temperatures and can change the decomposition pathway of lignocellulosic biomass during fast pyrolysis to inhibit the formation of heavy tars that may block pore structures, thus improving the formation of open pores in the carbon matrix. Furthermore, the formed Fe species, e.g., FeOOH or Fe3O4 may act as an in situ catalyst in the fast pyrolysis process for the generation of porous structures37.
Scanning electron microscopy (SEM) and transmission electron microscopy (TEM) show a very rough MPC surface morphology (Fig. 2c). Energy dispersive X-ray (EDX) results indicate that the surface is composed mainly of C, O and Fe elements (Fig. 2d) and many wire-like structures, which are also confirmed by TEM (Fig. 2e). In addition, porous structures are also observed in the TEM image. Conversely, neither wire-like nor porous structures are detected in the SEM and TEM images for PC (Figs. 2f and 2g). These results confirm those of the nitrogen sorption isotherms, which indicate that MPC has porous structures with high surface area and PC has very low surface area and is nearly devoid of porous structures.
A sulfonation process is applied to both MPC and PC to produce MPC–SO3H and PC–SO3H. Figure 3a shows the XRD pattern of MPC–SO3H, which indicates that Fe3O4 remains after sulfonation. The density and distribution of the S and Fe elements in MPC–SO3H are evaluated by quantitative EDX mapping. S is determined to be homogeneously distributed on the entire surface of MPC–SO3H (Fig. 3e), suggesting effective sulfonation of the carbonaceous precursor material. As shown in Fig. 3f, Fe is also homogeneously distributed on the entire surface of MPC–SO3H after sulfonation, which is consistent with the XRD results such that the Fe3O4 structure is not damaged in the sulfonation reaction and thus the magnetism of the solid acid catalyst remains. The results of analysis of surface area and pore volume of MPC–SO3H and PC–SO3H by nitrogen adsorption–desorption isotherms are shown in Fig. 3b, Fig. S1 and Table S1. The surface area and pore volume of MPC–SO3H are 296.4 m2 g−1 and 0.14 cm−3 g−1, respectively, which are slightly lower than those of MPC. This result suggests that pore structure of MPC has been partially damaged in the sulfonation process. However, as shown in the SEM and TEM images (Figs. 3c and 3d), the wire-like and porous structures of MPC are nearly unchanged after the sulfonation process.
The surface composition of MPC–SO3H is analyzed by X-ray photoelectron spectroscopy (XPS). The C 1s spectrum includes six peaks with differentiated binding energy values via deconvolution (Fig. 3g). These peaks could be assigned to the carbon atoms in the forms of C–S (284.1 eV), C–C (284.6 and 284.9 eV), C–O (alcoholic, phenolic hydroxyl and/or ether, 285.4 eV), C = O (carbonyl and/or quinine, 286.7 eV) and O = C–O (carboxyl groups, 289.0 eV)38,39. For comparison, the C 1s spectrum of MPC prior to sulfonation is shown in Fig. S2, in which only two carbon forms, C–C and C–O, are apparent. This result indicates that the sulfonation process not only introduces SO3H groups on the carbon matrix through the formation of C–S bonds but also modifies the surface of the materials with additional oxygenated functional groups (e.g., C = O and O–C = O). The S 2p spectrum of MPC–SO3H shows three different peaks (Fig. 3h), which could be attributed to the S–C (168.1 eV), S–O (168.9 eV) and S = O bonds (169.9 eV)6,40. These three bonds further indicate that the S in MPC–SO3H is mainly in the form of SO3H groups bonded to carbon matrix41.
Because the XPS results indicate that the S in MPC–SO3H is mainly associated with SO3H groups, the SO3H contents of MPC–SO3H can be estimated from the S content. The S content of MPC–SO3H and PC–SO3H is 5.6 wt.% and 3.1 wt.%, respectively (Table S2). Thus, the SO3H contents of MPC–SO3H and PC–SO3H are calculated to be 1.75 mmol g−1 and 0.97 mmol g−1, respectively. The total acid sites of MPC–SO3H and PC–SO3H are 2.57 mmol g−1 and 1.26 mmol g−1, respectively, as determined through titration of a NaOH solution. The larger contents of the acid sites compared with those of SO3H in the solid acid suggest that acidic groups other than SO3H groups, such as COOH, are also present in the solid acid18,42. This theory is confirmed through XPS and Fourier transform infrared spectroscopy (FTIR) (Fig. S3).
The catalytic activities of the solid acids are evaluated in three typical acid-catalyzed reactions (Fig. 4). For Reaction A, MPC–SO3H exhibits high activity for the catalytic formation of benzyl acetate with a yield of 93%, which is significantly higher than that of PC–SO3H at 63% and comparable to that of concentrated sulfuric acid at 89% (Fig. 5a). For Reaction B, one of the primary reactions for the production of furfural from renewable biomass, only 35% of the xylose is converted in the absence of a catalyst and no furfural is produced (Fig. 5b). The furfural yields of 45%, 61% and 65% with the catalysis of PC–SO3H, MPC–SO3H and commercially available H2SO4, respectively, indicate a favorable catalytic performance of the magnetic solid acid43,44. Moreover, as shown in Fig. S4, more than 96% of the xylose can be converted within 6 h with the catalysis of MPC–SO3H. For Reaction C, no sucrose is hydrolyzed in the absence of a catalyst (Fig. 5c); however, a hydrolysis conversion of 89% with the catalysis of PC–SO3H is noted with a glucose and fructose yield of 83%. These results are significantly lower than those of MPC–SO3H and H2SO4, in which the hydrolysis conversions are both near 100% with monosaccharide yields of 94% and 97%, respectively. Furthermore, MPC–SO3H catalyzed hydrolysis of the sucrose occurs rapidly because more than 90% of the sucrose can be hydrolyzed in the first hour (Fig. S5).
For the solid acid catalyst, one of the most important advantages over the liquid mineral acid in the acid-catalyzed reaction is that it can be separated and reused easily. In the present study, the spent solid acid catalyst is separated from the reaction mixture by using a magnet (Fig. S6a) and is reused in the same esterification reaction. After five reuses, the catalytic activity of MPC–SO3H remains unchanged with an average benzyl acetate yield of ~90% (Fig. 5d). Moreover, the magnetism of MPC–SO3H also remains after five reuses (Fig. S6b). SEM image (Fig. S7) of MPC–SO3H after five repeated experiments shows no significant difference in surface morphology compared to that of the raw catalyst (Fig. 3a). The XPS results of the reused MPC–SO3H (Table S3 and Fig. S8) show no noticeable change in surface element compositions of C, O, S and Fe, which indicates high stability of MPC–SO3H in the acid–catalytic reaction. In addition, MPC–SO3H also exhibits high thermal stability (Fig. S9).
Discussion
MP solid acid was synthesized through an integrated fast pyrolysis–sulfonation process. This process minimizes the environmental impact of large-scale production because it uses naturally abundant, renewable biomass waste as feedstock. The full advantage of such a process can be achieved if the loading of Fe can be achieved by using the biomass as a sorbent for extraction of Fe in wastewater. Bio-oil, a renewable fuel resource, was also produced during the fast pyrolysis process, which may result in additional economic benefits.
Magnetic solid acids exhibit strong acid strength and are readily separable. Therefore, they provide promising substitutions for liquid acids in some acid catalyzed reactions, which can minimize adverse effects on the environment and human health. Furthermore, because the solid acid catalyst here is easily separated and shows high catalytic activity in reuse, it offers promising applications as a low cost, environmentally friendly and recyclable acid catalyst in the production of fine chemicals.
In summary, we have synthesized a porous magnetic solid acid catalyst through a facile integrated fast pyrolysis–sulfonation process by using naturally abundant biomass waste. During this process, the biomass waste is first used as a sorbent to adsorb Fe(III) ions from water to obtain Fe-loaded biomass, which is then used as pyrolysis feedstock for energy and resource recovery by creating bio-oil. The pyrolysis bio-char is then subjected to a sulfonation process to synthesize the MPC solid acid catalyst. It has been determined that the loaded Fe(III) on the biomass can be converted into Fe3O4 during the fast pyrolysis process, endowing the materials with magnetism that remains after the sulfonation process. In addition, the loaded Fe can improve formation of the porous structure on carbonaceous materials. The magnetic solid acid has a porous structure with a high surface area of 296.4 m2 g−1 and high acid strength with total acid sites of 2.57 mmol g−1. Moreover, this acid exhibits excellent catalytic performance, favorable separability and high durability in typical acid-catalyzed reactions. The results presented in this work offer new opportunities for the development of facile and environmentally friendly methods of synthesizing functional materials from naturally abundant biomass waste.
Methods
Materials
All reagents and solvents were purchased from Sinopharm Chemical Reagent Co., Shanghai, China and used without further purification. The biomass used in this work was fir sawdust, a naturally abundant lignocellulosic biomass waste obtained from a local timber treatment plant in Hefei, China. After collected, the biomass was initially washed to remove impurity particles and then dried in an oven at 378 K overnight. The dried biomass was crushed using a high-speed rotary cutting mill and the biomass with the particle size smaller than 120 mesh were collected. The proximate analysis and elemental composition of the biomass were determined and the results were reported in our previous work24.
Synthesis of the magnetic porous carbonaceous solid acid catalyst
The precursor of solid acid catalyst was the Fe-loaded biomass, which was prepared in a biosorption process using biomass as an adsorbent at ambient temperature. Briefly, 10.0 g of biomass and 1,000 mL of FeCl3 solution with a concentration of 10 mmol L−1 were mixed in a flask and shaken in a constant temperature oscillator at 200 rpm for 300 min. Then, the water in the mixture was evaporated and the solid residue was dried at 378 K overnight and sieved again to collect the particles with a size smaller than 120 mesh and the Fe-loaded biomass with Fe content of approximately1.0 mmol g−1 was obtained.
The magnetic porous carbonaceous solid acid catalyst was synthesized by fast pyrolysis of the Fe-loaded biomass and subsequent sulfonation of the produced bio-char. The fast pyrolysis experiments were carried out in a vertical drop fixed bed reactor described in our previous work27. A 7.0 g portion of the Fe-loaded biomass sample was first placed in the feed pipe under a nitrogen flow of 400 mL min−1 and the nitrogen flow was maintained for 20 min to remove air from the pyrolysis system. Subsequently, when the temperature rose to the setting value of 773 K, the Fe-loaded biomass sample was inserted into the quartz tubular reactor with a piston for pyrolysis. The volatiles produced in the pyrolysis process were swept out by a nitrogen flow of 200 mL min−1 and condensed by cold ethanol to obtain bio-oil. When the fast pyrolysis process was accomplished, the temperature of the heating zone was increased to 873 K and the bio-char was further carbonized for 1 hour. Finally, the reactor was moved out of the heating zone and cooled in the nitrogen flow to room temperature and the magnetic porous carbonaceous material was obtained.
The solid acid catalyst was synthesized by sulfonation of the magnetic porous carbonaceous material. Briefly, the magnetic porous carbonaceous material was mixed with concentrated sulfuric acid (10 mL of sulfuric acid to 1 gram of solid), sonicated for 15 min and subsequently heated under vigorous stirring at 423 K for 10 hours to introduce sulfo-group (SO3H) on the surface of the materials. Afterwards, the mixture was cooled to room temperature and then slowly added to a beaker containing 500-mL deionized water. The suspension mixture was then filtered off and washed repeatedly with deionized water until there was no sulfate ions (SO42−) detected in the washing (detected by Ba2+ solution). The solid was further washed with absolute ethanol to remove the water and then dried at 353 K overnight. The dried sample was the magnetic porous carbonaceous solid acid and was stored for further use (MPC–SO3H). For comparison, another carbonaceous solid acid was synthesized in the same way using raw biomass without Fe-loading as precursor (PC–SO3H).
Characterization
The carbon (C) and sulfur (S) contents of the solid acids were analyzed using a high-frequency infrared carbon and sulfur analyzer (CS-600, LECO, USA), while the Fe content of the MPC-SO3H was determined by an X-ray fluorescence spectrometer (XRF-1800, Shimadzu Co., Japan). The total amount of acid sites was determined by an acid-base titration method using NaOH solution (10 mmol L−1)45.
FTIR spectra were recorded on a Fourier transform infrared spectroscopy (Bruker EQUINOX55, Germany) to analyze the functional groups of the solid acid. The thermal stability of the solid acid was characterized with a DTG-60H/DSC-60 thermogravimetric analyzer (TGA, Shimadzu Co., Japan). The structural features of the solid acids were analyzed by nitrogen adsorption-desorption isotherms, performing at 77 K on a Micromeritics Gemini apparatus (ASAP 2020 M+C, Micromeritics Co. USA) after degassing the sample at 393 K under vacuum for 10 hours. Specific surface areas of the solid acid were measured by tBET method, while their pore volumes were calculated by the amount of nitrogen adsorbed at a relative pressure of 0.99. The surface morphology of the solid acid was analyzed using TEM (JEOL-2100F, Japan) and SEM (Sirion 200, FEI electron optics company, USA) coupled with EDX (INCA energy, UK). XPS measurements of the solid acid were performed using a Thermo VG-Scientific spectrometer (ESCALAB250, USA) with a monochromatized Al Ka radiation (1486.92 eV). XRD analysis of the solid acids was carried out in an 18-KW rotating anode X-ray diffractometer (MXPAHF, Japanese Make Co., Japan).
Acid-catalyzed reactions
The catalytic activities of the solid acids were evaluated in three typical acid-catalyzed reactions, including esterification of benzylacohol and acetic acid (Reaction A), dehydration of the xylose to produce furfural (Reaction B) and hydrolysis of sucrose (Reaction C).
The esterification reaction was performed in a solvent-free system as follows: 0.100 g of catalyst was added to a 25 mL reaction tube, followed by the dose of 0.108 g (1.0 mmol) of benzyl alcohol and 0.290 g (5.0 mmol) of acetic acid. Then, the mixture was vigorously stirred with a magnetic stirrer at 363 K to conduct the reaction. The reaction was completed in a nitrogen atmosphere and monitored by a thin layer chromatograph (TLC). After the reactions were accomplished (no benzyl alcohol was detected in the TLC), the reaction mixture was washed with cyclohexane of 10 mL and the catalyst was separated with the aid of a powerful magnet. The remaining cyclohexane solution was washed with NaHCO3 solution of 0.01 mol L−1 to remove the unreacted acetic acid and then dried over anhydrous MgSO4. Finally, the products (benzyl acetate) was obtained after removal of the solvent under reduced pressure and confirmed by comparing the retention time with that of the pure benzyl acetate in a gas chromatograph. After reaction, the catalyst was separated by an external magnet, then washed with ethyl acetate several times, then dried at 333 K overnight and reused for subsequent reactions.
For the dehydration reaction, d−(+)−xylose (0.150 g, 1 mmol), DMSO (5.000 g) and acid catalyst (0.100 g) were loaded into a 25-mL reaction tube. The mixture was vigorously stirred and heated in a constant-temperature oil bath (423 K) for 300 min. After reaction, the mixture was cooled to room temperature. The concentration of formed furfural was analyzed by gas chromatography and the unreacted xylose content was determined by a phloroglucinol colorimetric assay using a UV–vis spectrophotometer (UV-1700, Phenix Optical Scientific Instrument Co., China)46. The conversion of xylose and yield of furfural were calculated with Eqs. 6 and 7, respectively.
For the hydrolysis reaction, sucrose (0.342 g, 1 mmol), water (20 mL) and acid catalyst (0.100 g) were added into a 100-mL round bottomed flask. The mixture was vigorously stirred and heated in a constant temperature oil bath (353 K) for 150 min. After reaction, the mixture was cooled to room temperature. The hydrolysis products, i.e., glucose and fructose, were determined by a 3,5-dinitrosalicylic acid colorimetric assay on a UV–vis spectrophotometer (UV-1700, Phenix Optical Scientific Instrument Co., China)47. The unreacted sucrose was analyzed using the same method after hydrolysis in 6-mM HCl solution (373 K) for 5 min. The conversion of sucrose and yields of hydrolysis products were calculated with Eqs. 8 and 9, respectively.
References
Zhou, C.-H., Xia, X., Lin, C.-X., Tong, D.-S. & Beltramini, J. Catalytic conversion of lignocellulosic biomass to fine chemicals and fuels. Chem. Soc. Rev. 40, 5588 (2011).
Hara, M. Biomass conversion by a solid acid catalyst. Energy Environ. Sci. 3, 601 (2010).
Taarning, E. et al. Zeolite-catalyzed biomass conversion to fuels and chemicals. Energy Environ. Sci. 4, 793 (2011).
Tanabe, K. & Hölderich, W. F. Industrial application of solid acid–base catalysts. Appl. Catal. A. 181, 399 (1999).
Takagaki, A., Tagusagawa, C., Hayashi, S., Hara, M. & Domen, K. Nanosheets as highly active solid acid catalysts for green chemical syntheses. Energy Environ. Sci. 3, 82 (2010).
Nakajima, K. & Hara, M. Amorphous Carbon with SO3H Groups as a Solid Brønsted Acid Catalyst. ACS Catal. 2, 1296 (2012).
Xing, R. et al. Novel solid acid catalysts: Sulfonic acid group-functionalized mesostructured polymers. Adv. Func. Mater. 17, 2455 (2007).
Liu, F., Kong, W., Qi, C., Zhu, L. & Xiao, F.-S. Design and synthesis of mesoporous polymer-based solid acid catalysts with excellent hydrophobicity and extraordinary catalytic activity. ACS Catal. 2, 565 (2012).
Akiyama, G., Matsuda, R., Sato, H., Takata, M. & Kitagawa, S. Cellulose hydrolysis by a new porous coordination polymer decorated with sulfonic acid functional groups. Adv. Mater. 23, 3294 (2011).
Tagusagawa, C. et al. Highly active mesoporous Nb–W oxide solid-acid catalyst. Angew. Chem. Int. Ed. 49, 1128 (2010).
Li, W. et al. Design of mesoporous SO42−/ZrO2–SiO2(Et) hybrid material as an efficient and reusable heterogeneous acid catalyst for biodiesel production. Green Chem. 12, 2135 (2010).
Gürbüz, E. I. et al. Conversion of hemicellulose into furfural using solid acid catalysts in γ-valerolactone. Angew. Chem. Int. Ed. 52, 1270–1274 (2012).
Hu, X., Lievens, C. & Li, C.-Z. Acid-catalyzed conversion of xylose in methanol-rich medium as part of biorefinery. ChemSusChem 5, 1427 (2012).
Lange, J.-P., van de Graaf, W. D. & Haan, R. J. Conversion of furfuryl alcohol into ethyl levulinate using solid acid catalysts. ChemSusChem 2, 437 (2009).
Wang, J. et al. Direct conversion of carbohydrates to 5-hydroxymethylfurfural using Sn-Mont catalyst. Green Chem. 14, 2506 (2012).
Shuai, L. & Pan, X. Hydrolysis of cellulose by cellulase-mimetic solid catalyst. Energy Environ. Sci. 5, 6889 (2012).
Arancon, R. A., Barros, H. R., Jr, Balu, A. M., Vargas, C. & Luque, R. Valorisation of corncob residues to functionalised porous carbonaceous materials for the simultaneous esterification/transesterification of waste oils. Green Chem. 13, 3162 (2011).
Wu, Y. et al. Microwave-assisted hydrolysis of crystalline cellulose catalyzed by biomass char sulfonic acids. Green Chem. 12, 696 (2010).
Gill, C. S., Price, B. A. & Jones, C. W. Sulfonic acid-functionalized silica-coated magnetic nanoparticle catalysts. J. Catal. 251, 145 (2007).
Lai, D.-m., Deng, L., Guo, Q.-x. & Fu, Y. Hydrolysis of biomass by magnetic solid acid. Energy Environ. Sci. 4, 3552 (2011).
Feyen, M., Weidenthaler, C., Schüth, F. & Lu, A.-H. Synthesis of structurally stable colloidal composites as magnetically recyclable acid catalysts. Chem. Mater. 22, 2955 (2010).
Zillillah, Z., Tan, G. & Li, Z. Highly active, stable and recyclable magnetic nano-size solid acid catalysts: Efficient esterification of free fatty acid in grease to produce biodiesel. Green Chem. 14, 3077–3086 (2012).
Zafiropoulos, N. A., Ngo, H. L., Foglia, T. A., Samulski, E. T. & Lin, W. Catalytic synthesis of biodiesel from high free fatty acid-containing feedstocks. Chem. Comm. 3670–3672 (2007).
Liu, W.-J. et al. Selectively Improving the Bio-oil quality by catalytic fast pyrolysis of heavy-metal-polluted biomass: Take copper (Cu) as an example. Environ. Sci. Technol. 46, 7849 (2012).
Liu, W.-J., Zeng, F.-X., Jiang, H., Zhang, X.-S. & Yu, H.-Q. Techno-economic evaluation of the integrated biosorption–pyrolysis technology for lead (Pb) recovery from aqueous solution. Bioresour. Technol. 102, 6260 (2011).
Liu, W.-J., Zeng, F.-X., Jiang, H. & Zhang, X.-S. Preparation of high adsorption capacity bio-chars from waste biomass. Bioresour. Technol. 102, 8247 (2011).
Liu, W.-J., Zeng, F.-X., Jiang, H. & Yu, H.-Q. Total recovery of nitrogen and phosphorus from three wetland plants by fast pyrolysis technology. Bioresour. Technol. 102, 3471 (2011).
Mohan, D., Pittman, C. U. & Steele, P. H. Pyrolysis of wood/biomass for bio-oil: A critical review. Energy Fuels 20, 848 (2006).
Czernik, S. & Bridgwater, A. V. Overview of applications of biomass fast pyrolysis oil. Energy Fuels 18, 590 (2004).
Huber, G. W., Iborra, S. & Corma, A. Synthesis of transportation fuels from biomass: Chemistry, catalysts and engineering. Chem. Rev. 106, 4044 (2006).
Patwardhan, P. R., Brown, R. C. & Shanks, B. H. Product distribution from the fast pyrolysis of hemicellulose. ChemSusChem 4, 636 (2011).
Gong, F. et al. Direct reduction of iron oxides based on steam reforming of bio-oil: a highly efficient approach for production of DRI from bio-oil and iron ores. Green Chem. 11, 2001 (2009).
Okamura, M. et al. Acid-catalyzed reactions on flexible polycyclic aromatic carbon in amorphous carbon. Chem. Mater. 18, 3039 (2006).
Tagusagawa, C. et al. Synthesis and characterization of mesoporous Ta−W oxides as strong solid acid catalysts. Chem. Mater. 22, 3072 (2010).
Liu, Z. & Zhang, F.-S. Nano-zerovalent iron contained porous carbons developed from waste biomass for the adsorption and dechlorination of PCBs. Bioresour. Technol. 101, 2562 (2010).
Maldonado-Hódar, F. J., Moreno-Castilla, C., Rivera-Utrilla, J., Hanzawa, Y. & Yamada, Y. Catalytic graphitization of carbon aerogels by transition metals. Langmuir 16, 4367 (2000).
Atkinson, J. D. et al. Synthesis and characterization of iron-impregnated porous carbon spheres prepared by ultrasonic spray pyrolysis. Carbon 49, 587 (2011).
Lim, S.-F., Zheng, Y.-M., Zou, S.-W. & Chen, J. P. Characterization of copper adsorption onto an alginate encapsulated magnetic sorbent by a combined FT-IR, XPS and mathematical modeling study. Environ. Sci. Technol. 42, 2551 (2008).
Toupin, M. & Belanger, D. Spontaneous functionalization of carbon black by reaction with 4-nitrophenyldiazonium cations. Langmuir 24, 1910 (2008).
Liu, F. et al. Sulfated graphene as an efficient solid catalyst for acid-catalyzed liquid reactions. J. Mater. Chem. 22, 5495 (2012).
Maciá-Agulló, J. A., Sevilla, M., Diez, M. A. & Fuertes, A. B. Synthesis of carbon-based solid acid microspheres and their application to the production of biodiesel. ChemSusChem 3, 1352 (2010).
Li, X. et al. Sulfonated copolymers with SO3H and COOH groups for the hydrolysis of polysaccharides. J. Mater. Chem. 22, 1283 (2012).
Lam, E. et al. Synthesis of Furfural from Xylose by heterogeneous and reusable nafion catalysts. ChemSusChem 4, 535 (2011).
Agirrezabal-Telleria, I., Requies, J., Guemez, M. B. & Arias, P. L. Furfural production from xylose + glucose feedings and simultaneous N2-stripping. Green Chem. 14, 3132–3140 (2012).
Jones, C. W., Tsuji, K. & Davis, M. E. Organic-functionalized molecular sieves as shape-selective catalysts. Nature 393, 52 (1998).
Eberts, T., Sample, R., Glick, M. & Ellis, G. A simplified, colorimetric micromethod for xylose in serum or urine, with phloroglucinol. Clin. Chem. 25, 1440–1443 (1979)
Tong, D. S. et al. Catalytic hydrolysis of cellulose to reducing sugar over acid-activated montmorillonite catalysts. Appl. Clay Sci. 74, 147–153 (2013).
Acknowledgements
The authors gratefully acknowledge financial support from National 863 Program (2012AA063608-01), National Key Technology R&D Program of the Ministry of Science and Technology (2012BAJ08B00) and the Key Special Program on the S&T for the Pollution Control and Treatment of Water Bodies (No.2012ZX07103-001).
Author information
Authors and Affiliations
Contributions
W.J.L. designed and conducted the experiments, analyzed the data and wrote the manuscript; H.J. provided guidance on the manuscript preparation, modified the manuscript and supervised the whole work; K.T. conducted part of the experiments; H.Q.Y. modified this manuscript and provided important suggestions. All authors contributed through scientific discussions.
Ethics declarations
Competing interests
The authors declare no competing financial interests.
Electronic supplementary material
Supplementary Information
SI solid acid
Rights and permissions
This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivs 3.0 Unported License. To view a copy of this license, visit http://creativecommons.org/licenses/by-nc-nd/3.0/
About this article
Cite this article
Liu, WJ., Tian, K., Jiang, H. et al. Facile synthesis of highly efficient and recyclable magnetic solid acid from biomass waste. Sci Rep 3, 2419 (2013). https://doi.org/10.1038/srep02419
Received:
Accepted:
Published:
DOI: https://doi.org/10.1038/srep02419
This article is cited by
-
A review on catalytic pyrolysis for high-quality bio-oil production from biomass
Biomass Conversion and Biorefinery (2023)
-
Controlling cellulose feedstock size allows for modification of cellulose-based carbon-based solid acid size
Cellulose (2023)
-
Methyl orange dye adsorbed biochar as a potential Brønsted acid catalyst for microwave-assisted biodiesel production
Environmental Science and Pollution Research (2023)
-
Synthesis of magnetic basic palm kernel shell catalyst for biodiesel production and characterisation and optimisation by Taguchi method
Applied Nanoscience (2022)
-
Improved lignin pyrolysis over attapulgite-supported solid acid catalysts
Biomass Conversion and Biorefinery (2022)
Comments
By submitting a comment you agree to abide by our Terms and Community Guidelines. If you find something abusive or that does not comply with our terms or guidelines please flag it as inappropriate.