Abstract
The differentiation of basaltic magmas to form more silica-rich magma is a fundamental process in crustal magmatism. However, suites of volcanic rocks erupted from individual volcanic centres rarely exhibit a compositional continuum between basalt and rhyolite. Instead, some rock suites exhibit marked compositional gaps1. The origin of such gaps has been attributed to partial melting of the crust2, the immiscibility of different magma types3, crystallization of specific mineral phases4 and processes occurring within magma chambers1,5,6. Here we couple high pressure and temperature experiments on mantle-derived basalt from St Vincent Volcano, Lesser Antilles, with variable water contents, to thermal models of magma differentiation. We show that the compositional distribution of the derivative magma varies as a function of water and heat content of the magmatic system, which is, in turn, related to the flux and duration of magma input. Systems that have relatively low heat content are characterized by compositional gaps, whose extent varies systemically with the water in the parent basalt. Irrespective of water content, compositional gaps diminish with time. Our approach can be used to retrieve information from volcanic rocks on their magmatic heat and water content in the parent basalt and hence explore these parameters as functions of tectonic settings and age.
This is a preview of subscription content, access via your institution
Access options
Subscribe to this journal
Receive 12 print issues and online access
$259.00 per year
only $21.58 per issue
Buy this article
- Purchase on Springer Link
- Instant access to full article PDF
Prices may be subject to local taxes which are calculated during checkout
Similar content being viewed by others
References
Brophy, J. G. Composition gaps, critical crystallinity, and fractional crystallisation in orogenic (calc-alkaline) magmatic systems. Contrib. Mineral. Petrol. 109, 173–182 (1991).
Suneson, N. H. & Lucchitta, I. Origin of bimodal volcanism, southern Basin and Range province, west-central Arizona. Geol. Soc. Am. Bull. 94, 1005–1019 (1983).
Charlier, B. et al. Large-scale silicate liquid immiscibility during differentiation of tholeiitic basalt to granite and the origin of the Daly gap. Geology 39, 907–910 (2011).
Grove, T. L. & Donnelly-Nolan, J. M. The evolution of young silicic lavas at Medicine Lake Volcano, California: Implications for the origin of compositional gaps in calc-alkaline series lavas. Contrib. Mineral. Petrol. 92, 281–302 (1986).
Freundt-Malecha, B., Schmincke, H. U. & Freundt, A. Plutonic rocks of intermediate composition on Gran Canaria: The missing link of the bimodal volcanic rock suite. Contrib. Mineral. Petrol. 141, 430–445 (2001).
Lakhssassi, M., Guy, B., Touboul, E. & Cottin, J-Y. Bimodal distribution of the solid products in a magmatic chamber: Modelling by fractional crystallization and coupling of the chemical exchanges with the differential melt/solid transport. C. R. Geosci. 342, 701–709 (2010).
Roberston, R. The Volcanic Geology of the Pre-Soufriere Rocks on St Vincent, West Indies. PhD thesis, Univ. West Indies (2002).
Pichavant, M., Mysen, B. O & Macdonald, R. Source and H2O content of high-MgO magmas in island arc settings: An experimental study of a primitive calc-alkaline basalt from St Vincent, Lesser Antilles arc. Geochim. Cosmochim. Acta 66, 2193–2209 (2002).
Heath, E., Macdonald, R., Belkin, H., Hawkesworth, C. & Sigurdsson, H. Magmagenesis at Soufriere Volcano, St Vincent, Lesser Antilles Arc. J. Petrol. 39, 1721–1764 (1998).
Villiger, S., Ulmer, P. & Müntener, O. Equilibrium and fractional crystallisation experiments at 0.7 GPa; the effect of pressure on phase relations and liquid compositions of tholeiitic magmas. J. Petrol. 48, 159–184 (2007).
Pilet, S., Ulmer, P. & Villiger, S. Liquid line of descent of basanitic liquid at 1.5 GPa: Constraints on the formation of metasomatic veins. Contrib. Mineral. Petrol. 159, 621–643 (2010).
Whitaker, M. L., Nekvasil, H., Lindsley, D. H. & McCurry, M. Can crystallisation of olivine tholeiite give rise to potassic rhyolites–An experimental investigation. Bull. Volcanol. 70, 417–434 (2008).
Ghiorso, M. S. & Sack, R. O. Chemical mass transfer in magmatic processes. IV. A revised and internally consistent thermodynamic model for the interpolation and extrapolation of liquid–solid equilibria in magmatic systems at elevated temperatures and pressures. Contrib. Mineral. Petrol. 119, 197–212 (1995).
Annen, C., Blundy, J. D. & Sparks, R. S. J. The genesis of intermediate and silicic magmas in deep crustal hot zones. J. Petrol. 47, 505–539 (2006).
Johannes, W. & Holtz, F. Petrogenesis and Experimental Petrology of Granitic Rocks (Springer, 1996).
Bouvier, A-S., Metrich, N. & Deloule, E. Slab-derived fluids in the magma sources of St Vincent (Lesser Antilles arc): Volatile and light element imprints. J. Petrol. 49, 1427–1448 (2008).
Briden, J. C., Rex, D. C., Faller, A. M. & Tomblin, J. F. K–Ar geochronology and paleomagnetism of volcanic rocks in the lesser antilles island arc. Phil. Trans. R. Soc. Lond. A291, 485–528 (1979).
Takeuchi, S. Preeruptive magma viscosity: An important measure of magma eruptibility. J. Geophys. Res. 116, B10201 (2011).
Hacker, B. R. & Abers, G. A. Subduction Factory 3: An Excel worksheet and macro for calculating the densities, seismic wave speeds, and H2O contents of minerals and rocks at pressure and temperature. Geochem. Geophys. Geosyst. 5, Q01005 (2004).
Ochs, F. A. & Lange, R. A. The density of hydrous magmatic liquids. Science 283, 1314–1317 (1999).
Giordano, D., Russell, J. K. & Dingwell, D. B. Viscosity of magmatic liquids: A model. Earth Planet. Sci. Lett. 271, 123–134 (2008).
Sparks, R. S. J. & Marshall, L. A. Thermal and mechanical constraints on mixing between mafic and silicic magmas. J. Volc. Geotherm. Res. 29, 99–124 (1986).
Reubi, O. & Blundy, J. A dearth of intermediate melts at subduction zone volcanoes and the petrogenesis of arc andesites. Nature 461, 1269–1273 (2009).
Lange, R. A., Cashman, K. V. & Navrotsky, A. Direct measurements of latent heat during crystallization and melting of a ugandite and an olivine basalt. Contrib. Mineral. Petrol. 118, 169–181 (1994).
Marsh, B. D. On the crystallinity, probability of occurrence, and rheology of lava and magma. Contrib. Mineral. Petrol. 78, 85–98 (1981).
Kägi, R., Müntener, O., Ulmer, P. & Ottolini, L. Piston-cylinder experiments on H2O undersaturated Fe-bearing system: An experimental setup approaching fO2 conditions of natural calc-alkaline magmas. Am. Mineral. 90, 708–717 (2005).
Müntener, O. & Ulmer, P. Experimentally derived high-pressure cumulates from hydrous arc magmas and consequences for the seismic velocity structure of lower arc crust. Geophys. Res. Lett. 33, L21308 (2006).
O’Neill, H. St. C. & Wall, V. J. The olivine-orthopyroxene-spinel oxygen geobarometer, the nickel precipitation curve, and the oxygen fugacity of the earth’s upper mantle. J. Petrol. 28, 1169–1191 (1987).
Lesne, P. et al. Experimental simulation of closed-system degassing in the system basalt-H2O–CO2–S–Cl. J. Petrol. 52, 1737–1762 (2011).
Acknowledgements
This work was supported by grants from the Leverhulme Trust and European Research Council (CRITMAG and VOLDIES). We thank Edinburgh Ion Microprobe Facility staff for analytical support.
Author information
Authors and Affiliations
Contributions
E.M. performed the experimental and analytical work; C.A. devised and ran the models; J.B. formulated the hypothesis and constructed the text.
Corresponding author
Ethics declarations
Competing interests
The authors declare no competing financial interests.
Supplementary information
Supplementary Information
Supplementary Information (PDF 517 kb)
Rights and permissions
About this article
Cite this article
Melekhova, E., Annen, C. & Blundy, J. Compositional gaps in igneous rock suites controlled by magma system heat and water content. Nature Geosci 6, 385–390 (2013). https://doi.org/10.1038/ngeo1781
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1038/ngeo1781
This article is cited by
-
The compositional diversity and temporal evolution of an active andesitic arc stratovolcano: Tongariro, Taupō Volcanic Zone, New Zealand
Contributions to Mineralogy and Petrology (2023)
-
Mixing dry and wet magmas in the lower crust of a continental arc: new petrological insights from the Bear Valley Intrusive Suite, southern Sierra Nevada, California
Contributions to Mineralogy and Petrology (2021)
-
Timescales and thermal evolution of large silicic magma reservoirs during an ignimbrite flare-up: perspectives from zircon
Contributions to Mineralogy and Petrology (2021)
-
Evidence from plutonic xenoliths for magma differentiation, mixing and storage in a volatile-rich crystal mush beneath St. Eustatius, Lesser Antilles
Contributions to Mineralogy and Petrology (2019)
-
Methane-bearing fluids in the upper mantle: an experimental approach
Contributions to Mineralogy and Petrology (2019)