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| Open AccessThree dimensional band-filling control of complex oxides triggered by interfacial electron transfer
Band-filling control of transition metal ions in oxide heterostructures is typically limited to the two-dimensional interface. Here, the authors report a three-dimensional modulation of the band-filling and a topotactic phase transition in LaCoO3, triggered by charge transfer at LaCoO3/LaTiO3 interface.
- Meng Meng
- , Yuanwei Sun
- & Jiandong Guo
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Article
| Open AccessDiscovery of electrochemically induced grain boundary transitions
Electric fields and currents can alter microstructures of materials in unexpected ways. Here the authors report how electrochemical reduction can cause a grain boundary disorder-to-order transition and show the electric field effects on microstructural stability and evolution.
- Jiuyuan Nie
- , Chongze Hu
- & Jian Luo
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Article
| Open AccessCreating polar antivortex in PbTiO3/SrTiO3 superlattice
While the role of PbTiO3 in PbTiO3/SrTiO3 superlattices has been widely studied, little attention is paid to possible polar topologies in SrTiO3. Here, the authors create atomic-scale vortex–antivortex pairs in the superlattices, expanding the understanding of topological structures.
- Adeel Y. Abid
- , Yuanwei Sun
- & Peng Gao
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Article
| Open AccessReal-space observation of ferroelectrically induced magnetic spin crystal in SrRuO3
There is an ongoing debate in the origin of unusual bumps in the resistive Hall measurements in SrRuO3 systems. Here, the authors analyze surface inversion symmetry breaking and confirm the role of an interfacial Dzyaloshinskii–Moriya interaction at the heart of the system, revealing a magnetic spin crystal emergent across the unusual bumps.
- S. D. Seddon
- , D. E. Dogaru
- & M. Alexe
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| Open AccessNear-room temperature ferromagnetic insulating state in highly distorted LaCoO2.5 with CoO5 square pyramids
Here, Zhang et al. succeed in creating a heavily distorted oxygen deficient film of lanthanum cobaltite. The new phase of LaCoO2.5 has several unique properties, most notably, a Curie temperature of 284 K, significantly larger than the films from which it was derived.
- Qinghua Zhang
- , Ang Gao
- & Lin Gu
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Article
| Open AccessIn situ microbeam surface X-ray scattering reveals alternating step kinetics during crystal growth
The basal-plane surfaces of hexagonal close-packed crystals typically exhibit an alternating sequence of A and B steps with different atomic structures and growth kinetics. Here the authors demonstrate a method to determine whether A or B steps have faster kinetics under specific growth conditions.
- Guangxu Ju
- , Dongwei Xu
- & G. Brian Stephenson
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Article
| Open AccessLeidenfrost droplet trampolining
The classic Leidenfrost phenomenon is familiar, yet its physics is rather complex. Graeber et al. observe the unexpected development of repeated hopping of a droplet trampolining on its own vapor cushion on a hot plate and show under which conditions this self-initiated motion occurs.
- Gustav Graeber
- , Kartik Regulagadda
- & Dimos Poulikakos
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Article
| Open AccessReversible hydrogen control of antiferromagnetic anisotropy in α-Fe2O3
One major challenge for antiferromagnetic spintronics is how to control the antiferromagnetic state. Here Jani et al. demonstrate the reversible ionic control of the room-temperature magnetic anisotropy and spin reorientation transition in haematite, via the incorporation and removal of hydrogen.
- Hariom Jani
- , Linghu Jiajun
- & T. Venkatesan
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Article
| Open AccessAtomic-layer Rashba-type superconductor protected by dynamic spin-momentum locking
The effect of Rashba spin orbit coupling (SOC) on superconductivity remains elusive. Here, the authors report largely enhanced in-plane upper critical magnetic field due to Rashba SOC induced dynamic spin-momentum locking on the surfaces of an atomic-layer superconductor.
- Shunsuke Yoshizawa
- , Takahiro Kobayashi
- & Takashi Uchihashi
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Article
| Open AccessCurrent-induced switching of proximity-induced ferromagnetic surface states in a topological insulator
Electrical manipulation of magnetization in devices made of topological materials may be an essential route towards future spintronics technology. Here, Mogi et al. show efficient current-induced switching of surface ferromagnetism in hetero-bilayers of topological insulator (Bi1-xSbx)2Te3 and ferromagnetic insulator Cr2Ge2Te6.
- Masataka Mogi
- , Kenji Yasuda
- & Yoshinori Tokura
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Article
| Open AccessObservation of magnetic adatom-induced Majorana vortex and its hybridization with field-induced Majorana vortex in an iron-based superconductor
Braiding Majorana modes is essential for topological quantum computing, but it remains difficult to find a suitable platform. Here, the authors report the evidence of hybridization between field-induced and magnetic adatom induced Majorana modes in an iron-based superconductor FeTe0.55Se0.45, providing a possible single-material platform for braiding Majorana modes.
- Peng Fan
- , Fazhi Yang
- & Hong-Jun Gao
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Article
| Open AccessDirect imaging and electronic structure modulation of moiré superlattices at the 2D/3D interface
Here, advanced scanning transmission electron microscopy techniques are used to image the atomic structure at the interface between 2D MoS2 and 3D Au nanoislands, revealing a moiré superlattice and illustrating the potential for (opto-)electronic moiré engineering at the 2D/3D interface.
- Kate Reidy
- , Georgios Varnavides
- & Frances M. Ross
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Article
| Open AccessInterfacial engineering of Bi2S3/Ti3C2Tx MXene based on work function for rapid photo-excited bacteria-killing
MXenes have emerged as potential antimicrobial materials. Here, the authors report on the creation of a Schottky junction to increase the charge separation between MXenes and semiconductor to increase photodynamic creation of reactive oxygen species under near infrared irradiation for antibacterial purposes.
- Jianfang Li
- , Zhaoyang Li
- & Shuilin Wu
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Article
| Open AccessCorrelating Josephson supercurrents and Shiba states in quantum spins unconventionally coupled to superconductors
The impact of local magnetic impurities on superconducting order parameter remains largely unexplored. Here, the authors visualize the effect of different magnetic perturbations on a superconductor, unveiling a rich correlation of the interplay between quantum spins and superconductivity in different spectroscopic regimes.
- Felix Küster
- , Ana M. Montero
- & Paolo Sessi
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Article
| Open AccessA scalable molecule-based magnetic thin film for spin-thermoelectric energy conversion
Spin-thermoelectrics have great promise for waste heat conversion, however scaling up is challenging for device using standard magnetic insulators. Here, Oh et al demonstrate the molecular-magnet, Prussian blue analogues as a viable candidate for spin-thermoelectrics.
- Inseon Oh
- , Jungmin Park
- & Jung-Woo Yoo
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Article
| Open AccessUltrafast generation and decay of a surface metal
Metallization by photoexcitation of defect excitons is observed on very long time scales in bulk semiconductors, while ultrafast control of the conduction properties is appealing. Here, the authors demonstrate the ultrafast (20 fs) generation of a metal at the surface of ZnO upon photoexcitation.
- L. Gierster
- , S. Vempati
- & J. Stähler
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Article
| Open AccessElucidating intrinsic contribution of d-orbital states to oxygen evolution electrocatalysis in oxides
Despite many studies on the oxygen-evolution perovskite-type electrocatalysts thus far, significant constraints prevent precise evaluations of catalytic activity. Here authors examine over 50 heteroepitaxial LaNiO3 and LaCoO3 (001) thin films to assess the intrinsic catalytic behaviors.
- Tae Gyu Yun
- , Yoon Heo
- & Sung-Yoon Chung
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Article
| Open AccessObservation and control of the weak topological insulator state in ZrTe5
Topological side surface, characterization of a weak topological insulator (WTI), has rarely been investigated. Here, Zhang et al. visualize a quasi-one dimensional, spin-momentum locked band on the side surface of the WTI candidate ZrTe5, and manipulate the bulk band gap by strain.
- Peng Zhang
- , Ryo Noguchi
- & Takeshi Kondo
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| Open AccessCharge-polarized interfacial superlattices in marginally twisted hexagonal boron nitride
Here, moiré superlattices generated by twisted insulating crystals of hexagonal boron nitride are shown to have a ferroelectric-like character, attributed to strain-induced polarized dipoles formed by pairs of interfacial boron and nitrogen atoms that create bilayer-thick ferroelectric domains.
- C. R. Woods
- , P. Ares
- & L. Fumagalli
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| Open AccessAnomalous circular bulk photovoltaic effect in BiFeO3 thin films with stripe-domain pattern
The authors study the evolution of the bulk photovoltaic effect in BiFeO3 thin films with stripe-domains as the polarization of light is modulated from linear to circular. A relationship between the anomalous photo-response and differential light-domain interaction is established.
- David S. Knoche
- , Matthias Steimecke
- & Akash Bhatnagar
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Article
| Open AccessThe coupling and competition of crystallization and phase separation, correlating thermodynamics and kinetics in OPV morphology and performances
Designing efficient blue perovskite LEDs by using mixed halides perovskite is still a challenge, limited mainly by the phase segregation issue. Here, the authors demonstrate in situ fabrication of quasi-2D CsPbClBr2 nanocrystal films with mixed ligands to overcome the constraint.
- Zaiyu Wang
- , Ke Gao
- & Feng Liu
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Article
| Open AccessHow ice grows from premelting films and water droplets
Melting and crystallization of ice close to the triple point is mediated by a thin liquid layer of water. Within an extended theoretical-numerical model, Sibley et al. capture both equilibrium properties and kinetic aspects of the film evolution to arrive at a broader perspective of how ice grows.
- David N. Sibley
- , Pablo Llombart
- & Luis G. MacDowell
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Article
| Open AccessNanoscale decoupling of electronic nematicity and structural anisotropy in FeSe thin films
Here, in contrast to previous observations in Fe-based superconductors, scanning tunnelling microscopy of strain-patterned FeSe thin films reveals a local decoupling of electron nematicity and structural anisotropy, pointing towards a stiffness of the nematic order parameter at the nanoscale.
- Zheng Ren
- , Hong Li
- & Ilija Zeljkovic
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| Open AccessInterface-induced sign reversal of the anomalous Hall effect in magnetic topological insulator heterostructures
Berry curvature connects to exotic electronic phases hence it provides important insights to understand quantum materials. Here, the authors report sign change of the anomalous Hall effect resulted from Berry curvature change at the interface of a topological insulator/magnetic topological insulator heterostructure.
- Fei Wang
- , Xuepeng Wang
- & Cui-Zu Chang
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Article
| Open AccessStrain-stabilized superconductivity
Epitaxial strain is a promising control knob to modulate Tc to enhance superconductivity. Here, the authors show that a metallic oxide RuO2 can be turned superconducting through application of epitaxial strain in thin films grown on a (110)-oriented TiO2 substrate.
- J. P. Ruf
- , H. Paik
- & K. M. Shen
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Article
| Open AccessControlling hot electron flux and catalytic selectivity with nanoscale metal-oxide interfaces
Chemical interaction between metal and oxide supports is an important molecular-level factor that influences the catalytic selectivity of a desirable reaction. Here, using Pt nanowires/TiO2 catalytic nanodiodes, the authors investigate an enhancement of both selectivity and hot electron generation on metal-oxide interfacial sites.
- Si Woo Lee
- , Jong Min Kim
- & Jeong Young Park
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Article
| Open AccessLearning grain boundary segregation energy spectra in polycrystals
Predicting segregation energies of alloy systems can be challenging even for a single grain boundary. Here the authors propose a machine-learning framework, which maps the local environments on a distribution of segregation energies, to predict segregation energies of alloy elements in polycrystalline materials.
- Malik Wagih
- , Peter M. Larsen
- & Christopher A. Schuh
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Article
| Open AccessCoexistence of distinct skyrmion phases observed in hybrid ferromagnetic/ferrimagnetic multilayers
Topological spin textures are of technological interest due to their potential as a store of information. Here the authors experimentally demonstrate two distinct topological spin textures, tubular and incomplete skyrmions, and their mutual conversion in a ferromagnetic/ferromagnetic heterostructure.
- Andrada-Oana Mandru
- , Oğuz Yıldırım
- & Hans Josef Hug
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| Open AccessOne-dimensional confinement and width-dependent bandgap formation in epitaxial graphene nanoribbons
Here, the authors investigate armchair graphene nanoribbons by angle-resolved photoelectron spectroscopy, and show the development of a width-dependent semiconducting gap driven by quantum confinement effects, and an ideal one-dimensional electronic behaviour.
- Hrag Karakachian
- , T. T. Nhung Nguyen
- & Ulrich Starke
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| Open AccessExploring physics of ferroelectric domain walls via Bayesian analysis of atomically resolved STEM data
Ferroelectric domain wall profiles can be modeled by phenomenological Ginzburg-Landau theory, with different candidate models and parameters. Here, the authors solve the problem of model selection by developing a Bayesian inference framework allowing for uncertainty quantification and apply it to atomically resolved images of walls. This analysis can also predict the level of microscope performance needed to detect specific physical phenomena.
- Christopher T. Nelson
- , Rama K. Vasudevan
- & Sergei V. Kalinin
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Article
| Open AccessA new view on the origin of zero-bias anomalies of Co atoms atop noble metal surfaces
Transition-metal atoms deposited on metal surfaces exhibit zero bias anomalies, which have been detected by scanning tunnelling spectroscopy and are commonly attributed to Kondo resonances. Here the authors explain the zero-bias anomalies in terms of gapped spin-excitations in contrast to Kondo resonances, which reproduce well the experiments.
- Juba Bouaziz
- , Filipe Souza Mendes Guimarães
- & Samir Lounis
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Article
| Open AccessVoltage-driven motion of nitrogen ions: a new paradigm for magneto-ionics
In magneto-ionics, ion migration through the material is used to change the materials magnetic properties. Typically oxygen is used as the mobile ion. In this manuscript, the authors demonstrate controlled migration of nitrogen in a CoN film, expanding the possibilities of magneto-ionics.
- Julius de Rojas
- , Alberto Quintana
- & Jordi Sort
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Article
| Open AccessThe epitaxy of 2D materials growth
Advances in our ability to manipulate genetics leads to deeper understanding of biological systems. In this perspective, the authors argue that synthetic genomics facilitates complex modifications that open up new areas of research.
- Jichen Dong
- , Leining Zhang
- & Feng Ding
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| Open AccessIn-situ monitoring of interface proximity effects in ultrathin ferroelectrics
How to maintain a robust polarization in ferroelectrics despite its inherent suppression when going to the thin-film limit is a long-standing issue. Here, the authors propose the concept of competitive and cooperative interfaces and establish robust polarization states in the ultrathin regime.
- Nives Strkalj
- , Chiara Gattinoni
- & Morgan Trassin
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| Open AccessPhotobase effect for just-in-time delivery in photocatalytic hydrogen generation
Efficient photocatalytic hydrogen generation relies on highly choreographed delivery of protons and electrons to the reaction site such that they arrive just in time. Here, authors show that proton transport can be controlled by light with the photobase effect to increase H2 generation rate.
- Jiawen Fang
- , Tushar Debnath
- & Jacek K. Stolarczyk
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| Open AccessStabilizing hidden room-temperature ferroelectricity via a metastable atomic distortion pattern
Previous studies are limited to modulate oxygen octahedral rotation angles within the same pattern, and engineering the pattern remains a challenge. Here, the authors demonstrate a designed nonequilibrium oxygen octahedral rotation pattern leads to room-temperature ferroelectricity in CaTiO3.
- Jeong Rae Kim
- , Jinhyuk Jang
- & Daesu Lee
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Article
| Open AccessFlexopiezoelectricity at ferroelastic domain walls in WO3 films
Observation of a strain-gradient-induced piezoresponse at domain walls remains a challenge. Here, the authors find the piezoelectric response to be enhanced in the ferroelastic domain walls of centrosymmetric tungsten trioxide thin films due to a large strain gradient over a wide width of the wall.
- Shinhee Yun
- , Kyung Song
- & Chan-Ho Yang
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Article
| Open AccessFabrication of a novel magnetic topological heterostructure and temperature evolution of its massive Dirac cone
Magnetic topological heterostructures are promising devices to manipulate emergent quantum effects. Here, Hirahara et al. fabricate a novel magnetic topological heterostructure with a massive Dirac cone which becomes a massless one tuned by temperature.
- T. Hirahara
- , M. M. Otrokov
- & E. V. Chulkov
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Article
| Open AccessFundamental dissipation due to bound fermions in the zero-temperature limit
Understanding dynamics of fermionic bound states is important for their potential application in quantum devices. Here the authors study zero temperature dynamics and dissipation of fermions bound on a moving goal-post shaped wire in superfluid 3He-B.
- S. Autti
- , S. L. Ahlstrom
- & D. E. Zmeev
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Perspective
| Open AccessStructural lubricity in soft and hard matter systems
Structural lubricity is one of the most interesting concepts in modern tribology, which promises to achieve ultra-low friction over a wide range of length-scales. Here the authors highlight novel research lines in this area achievable by combining theoretical and experimental efforts on hard two-dimensional materials and soft colloidal and cold ion systems.
- Andrea Vanossi
- , Clemens Bechinger
- & Michael Urbakh
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Article
| Open AccessAsymmetric elastoplasticity of stacked graphene assembly actualizes programmable untethered soft robotics
Developing programmable untethered soft robotics remains a challenge. Here the authors apply the asymmetric elastoplasticity of stacked graphene assembly to address this challenge and realize untethered thermoresponsive morphing in tandem with high configurational programmability.
- Shuai Wang
- , Yang Gao
- & Tao Chen
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Article
| Open AccessStrange semimetal dynamics in SrIrO3
It remains challenging to resolve the dynamics of charges with different mobilities in multi-band systems. Here, the authors report a Raman scattering study of the dynamics of holes and electrons in semimetallic SrIrO3, which is well described by a marginal Fermi liquid phenomenology, with frequency dependent scattering rates close to the Planckian limit.
- K. Sen
- , D. Fuchs
- & M. Le Tacon
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Article
| Open AccessUltrafast coupled charge and spin dynamics in strongly correlated NiO
Nickel Oxide (NiO) is a strongly correlated insulator with antiferromagnetic (AFM) ordering. Here, using pump-probe photoemission on NiO, the authors observe coherent terahertz oscillations in the photoemission signal, a signature of an in-gap state coupled to the AFM background.
- Konrad Gillmeister
- , Denis Golež
- & Wolf Widdra
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Article
| Open AccessAtomic-scale phase separation induced clustering of solute atoms
Dealloying usually relies on chemical dissolution of an alloy component. By contrast, the authors demonstrate an atomic-scale phase separation process that differs completely from the chemical dealloying mechanism and thus represents a significant departure from the well-known Hume-Rothery rules.
- Lianfeng Zou
- , Penghui Cao
- & Guangwen Zhou
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Article
| Open AccessThe emergence of magnetic ordering at complex oxide interfaces tuned by defects
In the interfaces of non-magnetic complex oxides, it is unclear which defects are responsible for the magnetic interfaces. Here, the authors find the B-site cation stoichiometry is crucial for the creation and control of magnetism at the interface between non-magnetic ABO3-perovskite oxides.
- D.-S. Park
- , A. D. Rata
- & N. Pryds
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Article
| Open AccessPiezoelectric domain walls in van der Waals antiferroelectric CuInP2Se6
Domain walls in van der Waals layered ferrielectric CuInP2Se6 exhibit piezoelectric response. This striking departure from traditional ferroelectric behavior is ascribed to a partially polarized antiferroelectric state, where the domain wall separates coexisting regions of ferrielectric and antiferroelectric phases.
- Andrius Dziaugys
- , Kyle Kelley
- & Petro Maksymovych
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Article
| Open AccessUltra-fast vortex motion in a direct-write Nb-C superconductor
To realize ultra-fast dynamics of superconducting vortices one needs to overcome the practical issue of flux-flow instability (FFI). Here, Dobrovolskiy et al. demonstrate ultra-fast vortex motion at 10-15 km/s velocity in a Nb-C superconductor where the FFI is described by the edge-controlled FFI model.
- O. V. Dobrovolskiy
- , D. Yu Vodolazov
- & M. Huth
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Article
| Open AccessLarge magnetoelectric coupling in multiferroic oxide heterostructures assembled via epitaxial lift-off
Key properties of transition metal perovskite oxides are degraded after epitaxial growth on ferroelectric substrates due to lattice-mismatch strain. Here, the authors use epitaxial lift-off and transfer to overcome this problem and demonstrate electric field control of a bulk-like magnetization.
- D. Pesquera
- , E. Khestanova
- & N. D. Mathur
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Article
| Open AccessHot carriers perspective on the nature of traps in perovskites
The benign nature of defects in lead halide perovskites is widely regarded as the basis for their outstanding optoelectronic properties. Here Righetto et al. overthrew this perception, revealing the defects’ surprising potency to hot carriers and devised a strategy to suppress them.
- Marcello Righetto
- , Swee Sien Lim
- & Tze Chien Sum