Skip to main content

Thank you for visiting You are using a browser version with limited support for CSS. To obtain the best experience, we recommend you use a more up to date browser (or turn off compatibility mode in Internet Explorer). In the meantime, to ensure continued support, we are displaying the site without styles and JavaScript.

Observation of magnetic adatom-induced Majorana vortex and its hybridization with field-induced Majorana vortex in an iron-based superconductor


Braiding Majorana zero modes is essential for fault-tolerant topological quantum computing. Iron-based superconductors with nontrivial band topology have recently emerged as a surprisingly promising platform for creating distinct Majorana zero modes in magnetic vortices in a single material and at relatively high temperatures. The magnetic field-induced Abrikosov vortex lattice makes it difficult to braid a set of Majorana zero modes or to study the coupling of a Majorana doublet due to overlapping wave functions. Here we report the observation of the proposed quantum anomalous vortex with integer quantized vortex core states and the Majorana zero mode induced by magnetic Fe adatoms deposited on the surface. We observe its hybridization with a nearby field-induced Majorana vortex in iron-based superconductor FeTe0.55Se0.45. We also observe vortex-free Yu-Shiba-Rusinov bound states at the Fe adatoms with a weaker coupling to the substrate, and discover a reversible transition between Yu-Shiba-Rusinov states and Majorana zero mode by manipulating the exchange coupling strength. The dual origin of the Majorana zero modes, from magnetic adatoms and external magnetic field, provides a new single-material platform for studying their interactions and braiding in superconductors bearing topological band structures.


The band structure of iron-based superconductor FeTe0.55Se0.45 has a nontrivial Z2 topological invariant and supports helical Dirac fermion topological surface states (TSS)1,2, which was confirmed recently by spin-resolved and angle-resolved photoemission spectroscopy3. Remarkably, below the bulk transition temperature Tc, superconducting (SC) TSS were observed with a pairing gap3. This makes FeTe0.55Se0.45 a novel single-material platform for generating Majorana zero modes (MZMs) at the ends of a vortex line2,4,5. Recently, strong evidence of MZMs inside the magnetic field-induced vortices have been observed by scanning tunneling microscope/spectroscopy (STM/S) on the vortex lattice of this type-II superconductor6,7,8,9.

This Majorana platform also presents new challenges for the basic understanding of defect excitations in superconductors with a topological nontrivial band structure, and new possibilities for creating MZMs under different physical conditions. In general, superconductors can host two kinds of defect excitations as in-gap bound states: the Yu-Shiba-Rusinov (YSR) states10,11,12,13,14,15,16,17 localized at a magnetic impurity and the Caroli-de-Gennes-Matricon (CdGM) states18,19,20,21,22,23,24,25,26 inside a magnetic vortex core. To date, these excitations have appeared distinctly in nature; a magnetic impurity induces the YSR states carrying spin, whereas an external magnetic field creates vortices of the whirling supercurrents. In stark contrast to the traditional YSR states, robust zero-bias peaks (ZBPs), sharing the quintessential spectroscopic properties of MZMs, were observed by STM/S at the magnetic interstitial Fe impurities in FeTe0.55Se0.4527, but without applying a magnetic field. A recent theoretical proposal28 attributes the observed ZBP to a MZM bound to a quantum anomalous vortex (QAV) nucleated spontaneously at the magnetic Fe atom. The role of the magnetic field is played by the exchange coupling of the spin and orbital moment of the Fe impurity located at the C4 symmetric sites, which generates circulating supercurrents by the spin–orbit coupling and modulates the phase of the superconducting order parameter. When the exchange coupling is strong enough, a condition favored by the very small Fermi energy (~5 meV) in FeTe0.55Se0.453, a transition from the vortex-free YSR states to the QAV was predicted to take place28. A MZM emerges inside the QAV core from the superconducting TSS, since the Berry phase of the Dirac fermions transforms the total angular momentum quantum number of the CdGM vortex core states18 into integers, naturally supporting a zero-energy bound state8,28.


Characterizations of samples and Fe adatoms

To probe the remarkable nature of defect excitations in the superconducting TSS, we deposit magnetic Fe adatoms on the cleaved (001) surface of a single crystal of FeTe0.55Se0.45 (Fig. 1a, b) with the substrate temperature below 20 K. Before depositing the Fe adatoms, we scan the surface to ensure that there is no interstitial Fe adatom (see Supplementary Note 1), to avoid the mix of interstitial Fe adatoms and deposited Fe adatoms. In contrast to the growth-induced interstitial Fe impurity in the bulk, the adsorbed Fe adatoms are distributed at various heights above the surface and in different planar locations with respect to the C4 symmetry sites. As a result, the magnetic Fe adatoms with varying exchange couplings reveal much richer phenomena of the defect excitations of the superconducting TSS.

Fig. 1: Characterization of deposited Fe adatoms on FeTe0.55Se0.45 surface.
figure 1

a Crystal structure of Fe(Te,Se). b Schematics of Fe adatoms deposited on the surface of FeTe0.55Se0.45. The adsorption sites are random, including both on and off of the C4 symmetric sites in the center of four Te/Se atoms and at various heights above the surface (Supplementary Note 1). c A STM image (Vs = −10 mV, It = 100 pA) after atomic Fe atom deposition. The bright dots correspond to Fe adatoms with a coverage of 0.04%. Inset: A 4 × 4 nm atomic-resolution topographic image showing a single-Fe adatom located at a high-symmetry site. d A dI/dV map (Vs = −10 mV, It = 100 pA) of c at zero energy. The high conductance areas and the Fe adatom positions are in good spatial correspondence, as highlighted by the red dashed circles. e Typical dI/dV spectra (Vs = −10 mV, It = 200 pA) showing the zero-bias peak on type-I Fe adatoms (red curve), YSR states (green curve) on type-II Fe adatoms, and the clean superconducting (SC) gap away from the adatoms (gray curve).

The STM image of a surface region after the atomic deposition (Fig. 1c) shows scattered Fe adatoms as the bright spots with a coverage of ~0.04%. The zero-energy dI/dV map in the same area of Fig. 1c, displays relatively high density of states at the locations of the Fe adatoms (Fig. 1d), consistent with the physical picture that magnetic Fe impurities generate in-gap states. From the statistics of >100 measurements (Supplementary Note 1 and Supplementary Fig. 2), we identify two types of in-gap states localized around the Fe adatoms with distinct dI/dV spectra exemplified in Fig. 1e. The type-I adatoms, which represent about 10% of our measurements, exhibit a sharp ZBP reminiscent of a MZM coexisting with other in-gap states in the dI/dV spectrum. In contrast, the conductance spectrum of the type-II adatoms, which represent about 90% of our measurements, shows the YSR states, featuring a pair of in-gap states at particle-hole symmetric peak energy positions, but with asymmetric peak weights. In comparison, the typical dI/dV spectrum on the clean surface without the adatom shows a hard superconducting gap without in-gap states (Fig. 1e).

QAV states in type-I Fe adatoms

We begin with the type-I Fe adatoms. A high-resolution topographic image (Fig. 2a) shows an isolated type-I adatom. A circular pattern appears in the zero-energy dI/dV map in the vicinity of the Fe site (Fig. 2b), with the zero-energy intensity center slightly offset from the Fe site. The breaking of the rotation symmetry is likely due to the canting of the magnetic moment of the Fe adatom away from the surface normal and the presence of spin–orbit coupling. The waterfall-like dI/dV spectra (Fig. 2c) and the intensity plot (Fig. 2d) along the red dashed line-cut in Fig. 2a clearly resolve the ZBP and other peaks at nonzero energies inside the superconducting gap. The ZBP persists to about 2.5 nm from the center, indicating the existence of a localized zero-energy state bound to the Fe adatom with the spatial extent comparable to that of the MZM in a magnetic field-induced vortex core in FeTe0.55Se0.456. To explore the nature of the discretized in-gap states, we extract several dI/dV spectra from Fig. 2c and show them as a stacking plot in Fig. 2e. Doing so accounts for the spatial distributions of the in-gap states and the sample inhomogeneity6,7 due to Te/Se alloying, which has proven to be useful for studying the core states of magnetic field-induced vortices in FeTe0.55Se0.458. The sequence of discretized bound states, including the zero-energy state, is clearly visible as the pronounced peaks labeled by L0, L±1, L±2. The energy positions of the conductance peaks (Ln) are plotted in Fig. 2f. Intriguingly, the average energies (solid lines) of the discrete quantum states bound to the Fe adatom follow closely a sequence of integer quantization \(E_n \approx n\varepsilon\), \(n = 0,\, \pm {\!}1,\, \pm {\!}2, \ldots ,\) with the minigap \(\varepsilon \sim 1.0\) meV, the same integer sequence (with a minigap ~0.6 meV) followed by the quantized vortex core states observed recently8 in magnetic field-induced vortices that host the MZM6,7. The different values of the minigap are caused by the fluctuation of the superconducting gap Δ and Fermi energy Ef on different surface, due to the inhomogeneous Te and Se atoms in FeTe0.55Se0.45. More cases are shown in Supplementary Fig. 3 for the type-I Fe adatoms. Such an integer quantized sequence is the hallmark of the CdGM vortex core states of the superconducting TSS in the quantum limit8,28. Our observations thus provide substantiated and compelling evidence that vortex-like topological defect excitations such as the QAVs nucleate spontaneously at the type-I Fe adatoms and the ZBP corresponds to a vortex MZM.

Fig. 2: ZBP and integer quantized in-gap states on type-I Fe adatoms.
figure 2

a An atomic-resolution topographic image (Vs = −10 mV, It = 100 pA) of a single type-I Fe adatom (red circle). b A zero-energy dI/dV map (Vs = −10 mV, It = 100 pA) of the same area in a. c and d dI/dV spectra and the corresponding intensity plot (Vs = −10 mV, It = 200 pA) along the line-cut indicated by the red dashed and arrowed line in a and b. The decay length of the ZBP is about 2.5 nm. e A stacking plot of several dI/dV spectra (Vs = −10 mV, It = 200 pA) marked by the red arrows in c. The energies of the in-gap states are labeled as L0, L±1, L±2. f The energies of the in-gap states at different spatial positions along the line-cut. Error bars are the FWHM of a Gaussian fit. The energy values of the solid lines are calculated as the average energy of the in-gap states, showing the same integer quantization as the topological vortex core states anchored by the MZM. g Temperature dependence of the dI/dV spectra (Vs = −10 mV, It = 200 pA) measured at zero-energy intensity center (white circle in b) with the corresponding spectrum (the black curve) pointed by the black arrow in c. The ZBP intensity decreases with increasing temperature and becomes indiscernible at 4.2 K. h Magnetic field dependence of the dI/dV spectra (Vs = −10 mV, It = 200 pA) also acquired at the zero-energy intensity center (white circle in b) at 0.4 K. The ZBP remains robustly at zero energy without splitting.

It is necessary to check the temperature and magnetic field dependence of the ZBP, since a vortex MZM would respond differently than vortex-free defect states. The temperature evolution of the ZBP on the Fe adatom turns out to be very similar to that of the MZM in a field-induced vortex6. The ZBP intensity of the center spectrum pointed by the black arrow in Fig. 2c decreases with increasing temperatures, and becomes almost invisible at 4.2 K (Fig. 2g). The magnetic field dependence is also very similar to that of a vortex MZM as the ZBP does not split or broaden for fields up to 8 T (Fig. 2h), provided that no field-induced vortices enter the region near the adatom when the magnetic field is applied. The ZBP is, however, sensitive to the location of the adsorbed Fe adatom. We found that all type-I adatoms producing integer quantized bound states anchored by the ZBP are adsorbed at the high-symmetry sites in the center of four Te/Se atoms. To test the robustness of this finding, we manipulate a type-I adatom by the STM tip to a different location away from the C4 symmetric site. The ZBP disappears and a pair of in-gap state at nonzero energy emerges (Supplementary Note 3 and Supplementary Fig. 4). After annealing the sample to 15 K and performing the measurement again at 0.4 K, the adatom diffuses back to its original high-symmetry site and the ZBP reappears. Thus, the high-symmetry site is a prerequisite for the induced ZBP, which agrees with the proposed theory that the orbital magnetic moment of the Fe adatoms at C4 symmetric locations plays an important role for the nucleation of the QAV28.

YSR states in type-II Fe adatoms

Next, we turn to study the type-II Fe adatoms (Supplementary Note 4). In contrast to the type-I adatoms, the conductance exhibits predominantly a pair of in-gap peaks at nonzero energies without the ZBP. Applying an external magnetic field, we observe that the peaks shift approximately linearly to higher energies (Supplementary Fig. 5d) away from the Fermi level, consistent with a pair of spin-polarized YSR in-gap states. We find that the type-II Fe adatoms are adsorbed at myriad locations on or off the high-symmetry axis and induce YSR states at different energies, indicative of broadly varying exchange couplings to the superconducting quasiparticles. In special cases, we also observe YSR states located very close to zero energy, which nevertheless split under the magnetic field (Supplementary Note 4 and Supplementary Fig. 6) and are, therefore, distinct from the robust ZBP observed on the type-I Fe adatoms.

Reversible transition between YSR states and MZMs in some type-II Fe adatoms

These observations motivate us to manipulate the exchange coupling between the magnetic adatoms and the substrate by tuning the tip to sample distance29,30. In the approaching-tip process, the STM tip needs to be positioned on top of the Fe adatom, which makes it impossible to acquire spatial maps while keeping the position of the Fe adatom frozen. The electrostatic force of an approaching-tip can prod and move the Fe adatom in directions parallel and perpendicular to the surface (Fig. 3a), which can affect the atomic orbital moment of the Fe adatom and the spin–orbit exchange coupling to the superconductor. In STM/S, the tunnel-barrier conductance \(G_N \equiv I_t/V_s\), where It is the tunneling current and Vs is the bias voltage, governs the tunnel coupling and changes with the tip-sample distance. Performing tunneling conductance measurements as a function of GN, we find that the energies of the YSR states are modulated ubiquitously when the tip approaches the type-II Fe adatoms (Supplementary Note 5). The observed crossing and reversal of the in-gap states (Supplementary Fig. 7), a trademark of the YSR states, confirms that reducing the tip to sample distance monotonically increases the exchange coupling between the Fe atom and the superconductor.

Fig. 3: Reversible transitions between YSR states and a robust ZBP/MZM induced by modulating the exchange coupling of type-II Fe adatoms using the STM tip.
figure 3

a Schematics illustrating an approaching STM tip on top of a type-II Fe adatom can move the Fe adatom in directions parallel and perpendicular to the Te/Se surface and modulate the spin–orbit exchange coupling (Jex) to the superconductor. b Schematic phase diagram from the vortex-free YSR states to an anomalous vortex MZM represented by the ZBP with the increasing exchange coupling Jex. c and d Tunnel-barrier conductance dependence of the dI/dV spectra in c and its intensity plots in d, showing the evolution of vortex-free YSR states into a robust ZBP at 0 T under an approaching-tip. Red arrow in d indicates the position of an accidental near degeneracy of the YSR states. Black circles in d trace the peak positions. e and f are the same as c and d, but measured in a magnetic field of 6 T. Black circles in f trace the peak positions. The accidental degeneracy of the YSR states in 0 T in d is removed by the 6 T magnetic field, while the evolution to the ZBP remains robust. g and h are the same as e and f, but showing the transition from ZBP to YSR states by withdrawing the STM tip at 6 T, indicating the transition is reversible.

Unexpectedly, as the STM tip approaches a significant number of the type-II Fe adatoms (~27%), the pair of YSR states modulates with increasing GN, but then coalesces into a single ZBP in the waterfall plot of dI/dV spectra (Fig. 3c) and the intensity plot (Fig. 3d), which remains robust under further increase of the barrier conductance. Note that the emergence of the ZBP out of the YSR states is different from the transition point between the screened spin-singlet and doublet-ground states29,31, where the two YSR states are approximately degenerate at zero energy as marked by the red arrow in Fig. 3d. To probe the change in the nature of the in-gap states with different barrier conductance, we repeated the entire process under an applied magnetic field. The dI/dV spectra and the intensity plot obtained under 6 T (Fig. 3e, f) show that the vortex-free YSR states no longer cross zero energy, due to the Zeeman splitting that removes the accidental degeneracy. However, the emergence of the unsplit ZBP at higher GN is unabridged even at such a high field, indicating that ZBP corresponds to a single-MZM robust against an applied magnetic field. This identification is further corroborated by performing the measurements on type-I Fe adatoms that show the ZBP associated with the MZM upholds its integrity and does not shift or split with increasing GN in a field as high as 6 T (Supplementary Note 6 and Supplementary Fig. 8). The compelling evidence attributes the novel coalescence of in-gaps states toward the ZBP to the change in the nature of the magnetic impurity-induced defect state from the vortex-free YSR state to a vortex state with a vortex MZM (Fig. 3b), which is fully consistent with the theoretical prediction that increasing the exchange coupling of an Fe impurity induces a transition from the YSR states to the QAV states hosting a MZM in FeTe0.55Se0.45 superconductors28. We note that the entire tip-manipulation process is carried out locally without affecting the stability of the superconducting topological surface states. The SC gap in the STM spectrum (Fig. 3) does not close and the transition to the QAV state is reversible. The vortex MZM naturally arises in the QAV core due to the superconducting topological surface states on the surface of FeTeSe28. Manipulating the Fe adatom by the approaching-tip to the C4 symmetric site and closer to the superconducting surface allows the magnetic Fe to sustain its orbital magnetic moment in addition to the spin moment and increases the spin–orbit exchange coupling, which generates the circulating supercurrents around the defect, leading to the flux trapping and the nucleation of a vortex state. The transition between the YSR states and the MZM is even reversible, as the dI/dV spectra as a function of the barrier conductance retrace that shown in Fig. 3e, f upon withdrawing the tip (Fig. 3g, h) in a controlled manner. The transition is also replicable when the type-II Fe adatom under the tip in Fig. 3 is moved to a different location about 1 nm away (Supplementary Fig. 9). These observations reveal the unprecedented nature of defect excitations in the superconducting TSS where local magnetic moment and screening currents are inextricably connected through the magnetoelectric effect.

Hybridization between MZMs in QAV and field-induced vortex

The phase coherence of the MZMs is stored nonlocally and protected by the topological degeneracy against environmental decoherence caused by local perturbations, which is the central to the idea of topological quantum computing32,33. The coupling of two MZMs sufficiently close by annihilates of the nonabelian anyonic zero modes and creates a pair of fermionic states at nonzero energies. This coupling process usually requires two overlapping magnetic field-induced vortices, which is difficult to control on the Abrikosov lattice7,8,34. Our system allows a new possibility, i.e., the hybridization between MZMs hosted in a QAV and a field-induced vortex (Fig. 4). The zero-energy dI/dV map (Fig. 4a) shows a MZM in the QAV nucleated at a type-I Fe adatom in a magnetic field of −0.2 T, also visible in the intensity plot (Fig. 4b) as sharp ZBPs along the line-cut across the adatom. A field-induced vortex is observed to enter the field of view subsequently. The latter sits very close to the Fe site, thus enlarges significantly the region with spectral weight at zero-energy (Fig. 4c). Remarkably, acquiring the intensity plot along the same line-cut shows that the ZBP splits into two peaks separated by an energy spacing ~0.25 meV (Fig. 4d). During the second round of the measurements, the vortex creeps away. The zero-energy map recovers (Fig. 4e) and the ZBP reemerges in the intensity plot (Fig. 4f). Throughout the hybridization process, the temperature and the magnetic field are kept stable and the change in the position of the field-induced vortex is due to the spontaneous vortex creeping. It is necessary to point out that the creeping of the vortices is observed quite often when we detected MZMs in the filed-induced vortices in our previous work. Three representative dI/dV spectra corresponding to the three conditions are extracted and displayed in Fig. 4g for a better comparison. Repeating the measurements on the same Fe adatom in a higher magnetic field of −3 T reveals again the splitting of the ZBP caused by the presence of a nearby field-induced vortex (Fig. 4h), with a larger energy spacing ~0.35 meV (Fig. 4i), possible due to the shorter distance and stronger overlap of the two MZMs as indicated by the smaller ring feature in the zero-energy map in Fig. 4h compared to Fig. 4c. Moreover, a field-induced vortex can also enter the field of view without causing detectable splitting of the ZBP bound to the Fe adatom or the vortex MZM when they are relatively far apart (Supplementary Note 8 and Supplementary Fig. 10). These observations further support the identification of the ZBP induced by type-I Fe atoms as the MZM and concurrently provide the first experimental evidence for the hybridization between two vortex MZMs as illustrated in Fig. 4j.

Fig. 4: Hybridization between two MZMs in the QAV and field-induced vortex.
figure 4

a Zero-energy dI/dV map (Vs = −10 mV, It = 100 pA) around a type-I Fe adatom in a magnetic field of −0.2 T, showing the spatial distribution of the MZM in an isolated QAV nucleated at the adatom. b Intensity plot of dI/dV spectra (Vs = −10 mV, It = 200 pA) along the line-cut indicated by the arrowed red dashed line in a, showing a robust ZBP. c and d are the same as a and b, but with an additional field-induced vortex pinned near the same Fe adatom visible in the zero-energy map in c. The ZBP disappears in the intensity plot of the dI/dV spectra along the same line-cut in d and two in-gap states with an energy level spacing of 0.25 meV emerge. e and f are the same as c and d, but after the field-induced vortex creeps away. The MZM returns and the zero-energy dI/dV map and the intensity plot of the dI/dV spectra along the line-cut recover those in a and b. g Three dI/dV spectra obtained on the Fe adatom in a, c, and e (Vs = −10 mV, It = 200 pA), respectively. h Zero-energy dI/dV map around the same Fe adatom at −3 T (Vs = −10 mV, It = 100 pA), showing an additional field-induced vortex pinned close to the adatom. i dI/dV spectra obtained on the Fe adatom in h and c (Vs = −10 mV, It = 200 pA). Both spectra show disappearance of ZBP and emergence of two in-gap states separated by an energy spacing that is larger (0.35 meV) in the case of h compared to c (0.25 meV). j Schematics of the interaction between two MZMs in the QAV and the field-induced vortex.


Our STM/S measurements on magnetic Fe adatoms deposited on the surface of FeTe0.55Se0.45 superconductors revealed the spontaneous formation of anomalous vortex matter with integer quantized core states and MZMs in zero external field, and the reversible transition between a YSR impurity and a QAV with increasing exchange interaction strength. These fundamental properties, previously unobserved in superconductors, are consistent with the predications of the theoretical proposal of the QAV28. They have broad implications for superconductors with a nontrivial topological band structure and spin-momentum locked superconducting TSS, which have also been found in several other iron-based superconductors such as LiFeAs35,36, (Li0.84Fe0.16)OHFeSe37, and CaKFe4As438. We also noticed a recent preprint posted on the arxiv39, where the result shows absence of spin-polarization on a ZBP. It can be included in our results of type-II Fe adatoms, where the YSR states can locate at a quantum phase transition point. This result can be clarified by measurements under a high magnetic field. Together with the observed hybridization of the MZMs in the QAV nucleated at the Fe adatom and the nearby field-induced Abrikosov vortex, our findings demonstrate that magnetic adatoms coupled to the superconducting TSS provide a realistic materials platform for creating and studying the interactions between the nonabelian topological vortex MZMs.


Materials and measurement

High-quality single crystals of FeTe0.55Se0.45 with Tc of 14.5 K are grown using the self-flux method6. The samples are cleaved in situ and immediately transferred into a STM head. The Fe adatoms are deposited from a high-purity (99.95%) single-crystal Fe rod acquired from ESPI METALS to the surface of FeTe0.55Se0.45 at a temperature below 20 K. Before Fe deposition, we scan the surface of FeTe0.55Se0.45 to ensure that there is no visible interstitial Fe impurity (IFI). The STM experiments are performed in an ultrahigh vacuum (1 × 10−11 mbar) LT-STM systems (USM-1300s-3He), which can apply a perpendicular magnetic field up to 11 T. STM images are acquired in the constant-current mode with a tungsten tip. The energy resolution calibrated on a clean Pb (111) surface is about 0.27 meV. The voltage offset calibration is followed by a standard method of overlapping points of IV curves. Differential conductance (dI/dV) spectra are acquired by a standard lock-in amplifier at a frequency of 973.1 Hz, under modulation voltage Vmod = 0.1 mV. Low temperature of 0.4 K is achieved by a single-shot 3He cryostat.

Data availability

All relevant data are available from the corresponding authors upon reasonable request.


  1. Wang, Z. J. et al. Topological nature of the FeSe0.5Te0.5 superconductor. Phys. Rev. B 92, 115119 (2015).

    ADS  Article  Google Scholar 

  2. Xu, G., Lian, B., Tang, P. Z., Qi, X. L. & Zhang, S. C. Topological superconductivity on the surface of Fe-based superconductors. Phys. Rev. Lett. 117, 047001 (2016).

    ADS  Article  Google Scholar 

  3. Zhang, P. et al. Observation of topological superconductivity on the surface of an iron-based superconductor. Science 360, 182–186 (2018).

    ADS  Article  Google Scholar 

  4. Hosur, P., Ghaemi, P., Mong, R. S. & Vishwanath, A. Majorana modes at the ends of superconductor vortices in doped topological insulators. Phys. Rev. Lett. 107, 097001 (2011).

    ADS  Article  Google Scholar 

  5. Fu, L. & Kane, C. L. Superconducting proximity effect and majorana fermions at the surface of a topological insulator. Phys. Rev. Lett. 100, 096407 (2008).

    ADS  Article  Google Scholar 

  6. Wang, D. F. et al. Evidence for Majorana bound states in an iron-based superconductor. Science 362, 333–335 (2018).

    ADS  CAS  Article  Google Scholar 

  7. Machida, T. et al. Zero-energy vortex bound state in the superconducting topological surface state of Fe(Se,Te). Nat. Mater. 18, 811–815 (2019).

    ADS  CAS  Article  Google Scholar 

  8. Kong, L. et al. Half-integer level shift of vortex bound states in an iron-based superconductor. Nat. Phys. 15, 1181–1187 (2019).

    CAS  Article  Google Scholar 

  9. Zhu, S. Y. et al. Nearly quantized conductance plateau of vortex zero mode in an iron-based superconductor. Science 367, 189–192 (2020).

    ADS  CAS  Article  Google Scholar 

  10. Yu, L. Bound state in superconductors with paramagnetic impurities. Acta Phys. Sin. 21, 75–91 (1965).

    CAS  Google Scholar 

  11. Shiba, H. Classical spins in superconductors. Prog. Theor. Phys. 40, 435–451 (1968).

    ADS  Article  Google Scholar 

  12. Rusinov, A. I. & Fiz, P. M. Z. E. T. On the theory of gapless superconductivity in alloys containing paramagnetic impurities. JETP Lett. 9, 1101–1106 (1968).

    Google Scholar 

  13. Yazdani, A., Jones, B. A., Lutz, C. P., Crommie, M. F. & Eigler, D. M. Probing the local effects of magnetic impurities on superconductivity. Science 275, 1767–1770 (1997).

    CAS  Article  Google Scholar 

  14. Choi, D. J. et al. Influence of magnetic ordering between Cr adatoms on the Yu-Shiba-Rusinov states of the beta-Bi2Pd superconductor. Phys. Rev. Lett. 120, 167001 (2018).

    ADS  CAS  Article  Google Scholar 

  15. Cornils, L. et al. Spin-resolved spectroscopy of the Yu-Shiba-Rusinov states of individual atoms. Phys. Rev. Lett. 119, 197002 (2017).

    ADS  CAS  Article  Google Scholar 

  16. Salkola, M. I., Balatsky, A. V. & Schrieffer, J. R. Spectral properties of quasiparticle excitations induced by magnetic moments in superconductors. Phys. Rev. B 55, 12648–12661 (1997).

    ADS  CAS  Article  Google Scholar 

  17. Flatté, M. E. & Byers, J. M. Local electronic structure of a single magnetic impurity in a superconductor. Phys. Rev. Lett. 78, 3761–3764 (1997).

    ADS  Article  Google Scholar 

  18. Caroli, C., De Gennes, P. G. & Matricon, J. Bound Fermion states on a vortex line in a type II superconductor. Phys. Lett. 9, 307–309 (1964).

    ADS  Article  Google Scholar 

  19. Bardeen, J., Kümmel, R., Jacobs, A. E. & Tewordt, L. Structure of vortex lines in pure superconductors. Phys. Rev. 187, 556–569 (1969).

    ADS  Article  Google Scholar 

  20. Hess, H. F., Robinson, R. B. & Waszczak, J. V. Vortex-core structure observed with a scanning tunneling microscope. Phys. Rev. Lett. 64, 2711–2714 (1990).

    ADS  CAS  Article  Google Scholar 

  21. Gygi, F. & Schluter, M. Self-consistent electronic structure of a vortex line in a type-II superconductor. Phys. Rev. B 43, 7609–7621 (1991).

    ADS  CAS  Article  Google Scholar 

  22. Hayashi, N., Isoshima, T., Ichioka, M. & Machida, K. Low-lying quasiparticle excitations around a vortex core in quantum limit. Phys. Rev. Lett. 80, 2921 (1998).

    ADS  CAS  Article  Google Scholar 

  23. Shan, L. et al. Observation of ordered vortices with Andreev bound states in Ba0.6K0.4Fe2As2. Nat. Phys. 7, 325–331 (2011).

    CAS  Article  Google Scholar 

  24. Hanaguri, T. et al. Scanning tunneling microscopy/spectroscopy of vortices in LiFeAs. Phys. Rev. B 85, 214505 (2012).

    ADS  Article  Google Scholar 

  25. Massee, F. et al. Imaging atomic-scale effects of high-energy ion irradiation on superconductivity and vortex pinning in Fe(Se, Te). Sci. Adv. 1, e1500033 (2015).

    ADS  Article  Google Scholar 

  26. Chen, M. et al. Discrete energy levels of Caroli-de Gennes-Matricon states in quantum limit in FeTe0.55Se0.45. Nat. Commun. 9, 970 (2018).

    ADS  Article  Google Scholar 

  27. Yin, J. X. et al. Observation of a robust zero-energy bound state in iron-based superconductor Fe(Te,Se). Nat. Phys. 11, 543–546 (2015).

    CAS  Article  Google Scholar 

  28. Jiang, K., Dai, X. & Wang, Z. Q. Quantum anomalous vortex and Majorana zero mode in iron-based superconductor Fe(Te,Se). Phys. Rev. X 9, 011033 (2019).

    CAS  Google Scholar 

  29. Farinacci, L. et al. Tuning the coupling of an individual magnetic impurity to a superconductor: quantum phase transition and transport. Phys. Rev. Lett. 121, 196803 (2018).

    ADS  CAS  Article  Google Scholar 

  30. Malavolti, L. et al. Tunable spin–superconductor coupling of spin 1/2 vanadyl phthalocyanine molecules. Nano Lett. 18, 7955–7961 (2018).

    ADS  CAS  Article  Google Scholar 

  31. Hatter, N., Heinrich, B. W., Ruby, M., Pascual, J. I. & Franke, K. J. Magnetic anisotropy in Shiba bound states across a quantum phase transition. Nat. Commun. 6, 8988 (2015).

    ADS  CAS  Article  Google Scholar 

  32. Kitaev, A. Y. Fault-tolerant quantum computation by anyons. Ann. Phys. 303, 2–30 (2003).

    ADS  MathSciNet  CAS  Article  Google Scholar 

  33. Nayak, C., Simon, S. H., Stern, A., Freedman, M. & Das Sarma, S. Non-Abelian anyons and topological quantum computation. Rev. Mod. Phys. 80, 1083–1159 (2008).

    ADS  MathSciNet  CAS  Article  Google Scholar 

  34. Chiu, C. K., Machida, T., Huang, Y. Y., Hanaguri, T. & Zhang, F. C. Scalable Majorana vortex modes in iron-based superconductors. Sci. Adv. 6, eaay0443 (2020).

    ADS  CAS  Article  Google Scholar 

  35. Zhang, P. et al. Multiple topological states in iron-based superconductors. Nat. Phys. 15, 41–47 (2019).

    CAS  Article  Google Scholar 

  36. Zhang, S. S. et al. Field-free platform for Majorana-like zero mode in superconductors with a topological surface state. Phys. Rev. B 101, 100507 (2020).

    ADS  CAS  Article  Google Scholar 

  37. Liu, Q. et al. Robust and clean Majorana zero mode in the vortex core of high-temperature superconductor (Li0.84Fe0.16)OHFeSe. Phys. Rev. X 8, 041056 (2018).

    CAS  Google Scholar 

  38. Liu, W. et al. A new Majorana platform in an Fe-As bilayer superconductor. Nat. Commun. 11, 5688 (2020).

    ADS  CAS  Article  Google Scholar 

  39. Wang, D., Wiebe, J., Zhong, R., Gu, G. & Wiesendanger, R. Spin-polarized Yu-Shiba-Rusinov states in an iron based superconductor. Preprint at (2020).

Download references


We thank Xi Dai, Shengshan Qin, Shiyu Peng, Sankar Das Sarma for useful discussions. The work at IOP is supported by grants from the National Natural Science Foundation of China (11888101, 61888102, 11674371 and 52022105), the National Key Research and Development Projects of China (2016YFA0202300, 2018YFA0305800 and 2019YFA0308500), and the Chinese Academy of Sciences (XDB28000000, XDB07000000, 112111KYSB20160061). The work at BNL and BC is supported by grants from US DOE, Basic Energy Sciences (DE-SC0012704, DE-FG02-99ER45747).

Author information




H.-J.G. and H.D. designed STM experiments. P.F., G.Q., and H.C. performed STM experiments with assistance of F.Y., Z.H., Y.X., and C.S.. J.S., R.Z., and G.G. provided samples. K.J. and Z.Q.W. provided theoretical explanations. P.F., F.Y., G.Q., and H.C. processed experimental data with input from Y.Z., G.L., L.K., W.L., and S.D.. All the authors participated in analyzing experimental data, plotting figures, and writing the manuscript. Z.Q.W., H.D., and H.-J. G. supervised the project.

Corresponding authors

Correspondence to Ziqiang Wang, Hong Ding or Hong-Jun Gao.

Ethics declarations

Competing interests

The authors declare no competing interests.

Additional information

Peer review information Nature Communications thanks Berthold Jaeck and the other, anonymous, reviewer(s) for their contribution to the peer review of this work. Peer reviewer reports are available.

Publisher’s note Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Supplementary information

Rights and permissions

Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit

Reprints and Permissions

About this article

Verify currency and authenticity via CrossMark

Cite this article

Fan, P., Yang, F., Qian, G. et al. Observation of magnetic adatom-induced Majorana vortex and its hybridization with field-induced Majorana vortex in an iron-based superconductor. Nat Commun 12, 1348 (2021).

Download citation

  • Received:

  • Accepted:

  • Published:

  • DOI:

Further reading


By submitting a comment you agree to abide by our Terms and Community Guidelines. If you find something abusive or that does not comply with our terms or guidelines please flag it as inappropriate.


Quick links

Nature Briefing

Sign up for the Nature Briefing newsletter — what matters in science, free to your inbox daily.

Get the most important science stories of the day, free in your inbox. Sign up for Nature Briefing