News & Views |
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News & Views |
No free lunch for non-fullerene acceptors
Non-fullerene acceptors have successfully overcome energy losses that were thought to be unavoidable in organic solar cells based on fullerene derivatives. However, it is now shown that they have limits too.
- Justin M. Hodgkiss
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Article |
Intrinsic efficiency limits in low-bandgap non-fullerene acceptor organic solar cells
A systematic analysis of a series of donor–acceptor organic blends shows that in solar cells based on low-bandgap non-fullerene acceptors an ionization energy offset of about 0.5 eV is required to ensure efficient charge separation.
- Safakath Karuthedath
- , Julien Gorenflot
- & Frédéric Laquai
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Article |
Electrical bioadhesive interface for bioelectronics
A graphene nanocomposite hydrogel showing anisotropic swelling is used to realize an electrically conducting and removable bioadhesive that improves the mechanical and electrical integration of bioelectronics devices with wet dynamic tissues.
- Jue Deng
- , Hyunwoo Yuk
- & Xuanhe Zhao
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News & Views |
The looks of a million-year-old polymer glass
Polymeric glasses with significant thermodynamic and kinetic stability have been fabricated using physical vapour deposition, providing a mean to gather insight into the properties of glasses aged for millions of years.
- Juan J. de Pablo
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Article |
Mechanistic insights of evaporation-induced actuation in supramolecular crystals
Experiments and molecular dynamics simulations show that the dehydration-induced actuation of nanoporous tripeptide crystals is a result of pore contraction caused by the strengthening of the water hydrogen-bonding network inside the pore, which creates mechanical stress that deforms the crystal lattice.
- Roxana Piotrowska
- , Travis Hesketh
- & Xi Chen
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Article |
Predictive modelling of structure formation in semiconductor films produced by meniscus-guided coating
Numerical simulations allow the prediction of domain morphology, from aligned to stretched and isotropic, in crystalline organic thin films formed by meniscus-guided coating, as a function of various deposition parameters.
- Jasper J. Michels
- , Ke Zhang
- & Tomasz Marszalek
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Article |
Tunable assembly of hybrid colloids induced by regioselective depletion
Hybrid colloidal suprastructures and superlattices are assembled by exploring depletion forces to selectively control the interactions between colloidal particles.
- Mingzhu Liu
- , Xiaolong Zheng
- & Marcus Weck
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Article |
Ultrastable monodisperse polymer glass formed by physical vapour deposition
The physical vapour deposition of ultrastable monodispersed polymer glasses is reported. This technique allows for the high tunability of glass transition temperatures of the deposited polymers, which could be useful for technological applications.
- Adam N. Raegen
- , Junjie Yin
- & James A. Forrest
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Letter |
Chirality-induced relaxor properties in ferroelectric polymers
Relaxor ferroelectric polymers are a material of choice for applications such as electrostrictive actuators or electrocaloric cooling. Here, the origin of relaxor behaviour at the molecular level is investigated and found to arise from conformational disorder.
- Yang Liu
- , Bing Zhang
- & Qing Wang
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News & Views |
Interfacial crystallization under DNA control
Programmable DNA hybridization is used to mediate the self-assembly of substrate-bound DNA-grafted gold nanoparticles into single-crystalline Winterbottom and non-Winterbottom constructions with particular size, shape and orientation.
- Chang Liu
- & Qian Chen
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Article |
Supramolecular–covalent hybrid polymers for light-activated mechanical actuation
Peptide amphiphile supramolecular polymers with a crosslinked spiropyran network respond to light by expelling water, enabling the fabrication of soft actuators or light-driven crawlers.
- Chuang Li
- , Aysenur Iscen
- & Samuel I. Stupp
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Letter |
A biohybrid synapse with neurotransmitter-mediated plasticity
A cell culture interfacing an organic neuromorphic device in a microfluidic system reversibly modifies the device synaptic weight through chemical reactions mediated by the release of dopamine, a neurotransmitter used in biological synapses.
- Scott T. Keene
- , Claudia Lubrano
- & Francesca Santoro
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Correspondence |
Stresses in thin sheets at fluid interfaces
- Deepak Kumar
- , Thomas P. Russell
- & Narayanan Menon
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News & Views |
Minerals from colloidal assembly
Magnetite crystals form by the aggregation and subsequent merger of crystalline precursors, which can be interpreted in terms of colloidal assembly.
- Jeffrey D. Rimer
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News & Views |
Lowering the threshold for bioelectronics
A high-speed, high-gain enhancement-mode ion-gated transistor shows promise for low-power chronically implanted bioelectronic systems.
- Scott Keene
- & Yoeri van de Burgt
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News & Views |
Mutual electrical doping in polymers
Two initially neutral conjugated semiconducting polymers are found to transfer electrons when put in contact in the solid state, leading to mutual electrical doping.
- Bernard Kippelen
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News & Views |
Seeing crystal formation one particle at a time
Low-electron-dose liquid-cell transmission electron microscopy reveals a two-step nucleation process during the crystallization of triangular nanoplatelets in water at the single-particle level.
- Yilong Han
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Article |
Ground-state electron transfer in all-polymer donor–acceptor heterojunctions
Doping through spontaneous electron transfer between donor and acceptor polymers is obtained by selecting organic semiconductors with suitable electron affinity and ionization energy, achieving high conductivity in blends and bilayer configuration.
- Kai Xu
- , Hengda Sun
- & Simone Fabiano
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Article |
Contact and macroscopic ageing in colloidal suspensions
The progressive stiffening of the solid–solid contacts that freeze dense colloidal suspensions are shown to cause the macroscopic ageing of such materials.
- Francesco Bonacci
- , Xavier Chateau
- & Anaël Lemaître
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Article |
Thiol-free self-assembled oligoethylene glycols enable robust air-stable molecular electronics
Chemisorbed molecules combining glycol-ether moieties and fullerenes are shown to form uniform and air-stable self-assembled bilayers on coinage metals, and are amenable to versatile functionalization by in-place exchange of the top layer.
- Xinkai Qiu
- , Viktor Ivasyshyn
- & Ryan C. Chiechi
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Article |
Ordered three-dimensional nanomaterials using DNA-prescribed and valence-controlled material voxels
Three-dimensional DNA frames can be created with controlled valence and coordination for the assembly of ordered arrays of biological and inorganic nanomaterials.
- Ye Tian
- , Julien R. Lhermitte
- & Oleg Gang
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News & Views |
Electroshock tuning of photonic crystals
Photonic crystals with optical bandgaps across the entire visible spectrum are generated by reconfiguring three-dimensional blue phase liquid crystalline lattices into long-lived metastable non-cubic structures using sequences of electric pulses.
- Slobodan Žumer
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News & Views |
Lighting up soft robotics
A transparent, high-permittivity elastomeric dielectric material shows potential for light-emitting soft robots and stretchable optoelectronics that can self-heal.
- Jonathan Rossiter
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News & Views |
Some stirring required
Polymer precipitation under turbulent flow is used for the high-throughput synthesis of soft microparticles with fractal coronas that display significant adhesive properties.
- Theodore Hueckel
- & Stefano Sacanna
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Article |
Three-dimensional printing of multicomponent glasses using phase-separating resins
Photopolymerization-induced phase separation of resins enables the high-resolution 3D printing of glass oxides with intricate shapes and distinct chemical composition.
- David G. Moore
- , Lorenzo Barbera
- & André R. Studart
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Article |
Extracellular matrix anisotropy is determined by TFAP2C-dependent regulation of cell collisions
The generation of aligned extracellular matrices by fibroblasts is shown to depend on cell reorientation following collision, leading to closer alignment of the cells’ long axes. This cell collision guidance depends on the transcription factor TFAP2C and localized regulation of actomyosin contractility.
- Danielle Park
- , Esther Wershof
- & Erik Sahai
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Article |
Kinetic pathways of crystallization at the nanoscale
Low-dose liquid-phase transmission electron microscopy, particle tracking and numerical simulations are used to characterize the crystallization kinetics and pathways of gold nanoprisms at the single-particle level.
- Zihao Ou
- , Ziwei Wang
- & Qian Chen
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Article |
Reconfiguration of three-dimensional liquid-crystalline photonic crystals by electrostriction
Repetitive electrical pulse stimulation of blue-phase liquid crystals promotes their reconfiguration into stable non-cubic structures with promising electro-optical responses for display technologies.
- Duan-Yi Guo
- , Chun-Wei Chen
- & Tsung-Hsien Lin
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News & Views |
Forced to line up for perfect order
Physical confinement and magnetic fields are used to align organic molecules that self-assemble into large-size single crystals with perfect positional order.
- Andrei V. Petukhov
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News & Views |
The shape of things to come
Shape-directed assembly of engineered microparticles enables multicomponent machines that can reconfigure dynamically to control their field-driven locomotion.
- Kyle J. M. Bishop
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Letter |
Crystallization by particle attachment is a colloidal assembly process
The kinetics and thermodynamics of the nucleation of magnetite crystals from primary particles are shown to be described by colloidal assembly theory, allowing for predictions of crystal sizes to be made.
- Giulia Mirabello
- , Alessandro Ianiro
- & Nico A. J. M. Sommerdijk
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Letter |
Soft dendritic microparticles with unusual adhesion and structuring properties
Polymer precipitation under turbulent flows generates soft microparticles with branched dendritic coronas and high adhesive properties.
- Sangchul Roh
- , Austin H. Williams
- & Orlin D. Velev
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Article |
Collective topo-epitaxy in the self-assembly of a 3D quantum dot superlattice
A structural investigation on the formation of 3D superlattices of colloidal PbSe quantum dots reveals a topotactic transition from the self-assembled phase of ligand-capped quantum dots to the epitaxially fused phase typical of conductive solids.
- Alex Abelson
- , Caroline Qian
- & Matt Law
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Meeting Report |
Sparking to life
Scientists recently gathered in Asilomar, California, to discuss the latest developments in bioelectronics research. Interfaces between our body and advanced technologies for biomedical and other applications are becoming ever more diverse and effective.
- Nicholas A. Melosh
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Letter |
A window to trap-free charge transport in organic semiconducting thin films
Water clusters induce hole traps in organic semiconductor thin films. Detrimental effects of hole and electron traps on charge transport can be avoided by using materials with ionization energy and electron affinity within an energy window of 2.4 eV.
- Naresh B. Kotadiya
- , Anirban Mondal
- & Gert-Jan A. H. Wetzelaer
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News & Views |
Beware the nanovoids
Nanovoids in organic semiconductors can serve as hosts for water inclusions that lead to trapping of electrons and holes.
- David J. Yaron
- & Tomasz Kowalewski
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News & Views |
Making weak dopants strong
Lewis acids are shown to react with water, forming a complex with Brønsted acidity able to effectively dope semiconducting polymers through backbone protonation and internal charge transfer.
- Han Yan
- & Wei Ma
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News & Views |
Moving hydrogels to the fourth dimension
Materials that permit spatiotemporal control of biomolecule presentation have long been a challenge in the field. A method has now been developed to reversibly pattern cell-laden hydrogels with site-specifically immobilized proteins using sortase-mediated transpeptidation without compromising bioactivity.
- Jonathan H. Galarraga
- & Jason A. Burdick
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Article |
Programming shape using kirigami tessellations
Geometric analysis and constrained optimization algorithms allow for the design of kirigami patterns that can be deployed into any two- or three-dimensional shape.
- Gary P. T. Choi
- , Levi H. Dudte
- & L. Mahadevan
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Review Article |
Organic mixed ionic–electronic conductors
From optoelectronic to biomedical and energy storage applications, the interest in organic mixed ionic–electronic conductors is expanding. This Review describes current understanding of the processes occurring in these materials and their structure–property relations.
- Bryan D. Paulsen
- , Klas Tybrandt
- & Jonathan Rivnay
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Article |
Active particles sense micromechanical properties of glasses
The rotational dynamics of self-propelled microparticles suspended in a colloidal glass is sharply increased at the glass transition of the system while their translation diffusion is strongly hindered.
- Celia Lozano
- , Juan Ruben Gomez-Solano
- & Clemens Bechinger
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News & Views |
Radically more stable
Violating the Aufbau principle is shown to be a successful strategy to improve the stability of neutral organic radicals used in organic light-emitting diodes.
- Sebastian Reineke
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News & Views |
Little probe, big data
Thousands of electron diffraction patterns, collected stepwise by scanning transmission electron microscopy, are synchronized and mined to provide unprecedented maps of the nanostructure of ordered domains in organic electronics films.
- Gitti L. Frey
- & Yaron Kauffmann
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Letter |
Surface charge printing for programmed droplet transport
Rewritable surface charge density gradients enable the direct, high-speed and long-distance transport of droplets on distinct surfaces without the need of additional energy input.
- Qiangqiang Sun
- , Dehui Wang
- & Xu Deng
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Article |
A hybrid material that reversibly switches between two stable solid states
Mechanically switchable materials made of supercooled fluids embedded in a polymer matrix reversibly shift between soft and hard solid states upon stimulation.
- Fut (Kuo) Yang
- , Aleksander Cholewinski
- & Boxin Zhao
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Article |
Quantum jamming transition to a correlated electron glass in 1T-TaS2
Optical or electric perturbations create a hyperuniform pattern in a correlated electron glass.
- Yaroslav A. Gerasimenko
- , Igor Vaskivskyi
- & Dragan Mihailovic
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Article |
Shape-encoded dynamic assembly of mobile micromachines
Mobile micromachines with advanced configurations and functions self-assembled through designed dielectrophoretic interactions between structural and motor units.
- Yunus Alapan
- , Berk Yigit
- & Metin Sitti
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Article |
Single crystal texture by directed molecular self-assembly along dual axes
Macroscopic single crystals with controlled texture are formed from a self-assembled columnar discotic liquid crystal.
- Xunda Feng
- , Kohsuke Kawabata
- & Chinedum O. Osuji
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News & Views |
Electric potentials at the atomic scale
Quantitative atomic-scale images of electric potentials at surfaces have now been obtained with a non-contact atomic force microscope by functionalizing the tip as a quantum dot sensor.
- Mats Persson