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| Open AccessGraphene-edge dielectrophoretic tweezers for trapping of biomolecules
The capability of positioning target molecules onto the edges of patterned graphene nanostructures is highly desirable. Here, the authors demonstrate that the atomically sharp edges of graphene can be used as dielectrophoretic tweezers for gradient-force-based trapping applications.
- Avijit Barik
- , Yao Zhang
- & Sang-Hyun Oh
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| Open AccessControl of enzyme reactions by a reconfigurable DNA nanovault
DNA nanostructures can cage enzymes but currently fall short of controlling their reactions with substrates. Here, the authors enclose an enzyme inside a dynamic DNA vault, which regulates its access to substrate molecules—and thus its enzymatic activity—through a multi-lock mechanism.
- Guido Grossi
- , Mette Dalgaard Ebbesen Jepsen
- & Ebbe Sloth Andersen
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| Open AccessGlycaemic control boosts glucosylated nanocarrier crossing the BBB into the brain
There are only a few examples of nanocarriers that can transport bioactive substances across the blood-brain barrier. Here the authors show that by rapid glycaemic increase the accumulation of a glucosylated nanocarrier in the brain can be controlled.
- Y. Anraku
- , H. Kuwahara
- & K. Kataoka
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| Open AccessProtein-driven RNA nanostructured devices that function in vitro and control mammalian cell fate
Nucleic acid nanotechnology has great potential for future therapeutic applications. Here the authors build protein-driven RNA nanostructures that can function within mammalian cells and regulate the cell fate.
- Tomonori Shibata
- , Yoshihiko Fujita
- & Hirohide Saito
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| Open AccessOligolysine-based coating protects DNA nanostructures from low-salt denaturation and nuclease degradation
The instability of DNA nanostructures in physiological environments has hampered their use as therapeutics and diagnostic agents inin vivoapplications. Here, the authors show that coating DNA origami with oligolysine-PEG moieties improves their pharmacokinetic properties in mouse models.
- Nandhini Ponnuswamy
- , Maartje M. C. Bastings
- & William M. Shih
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| Open AccessInterface confined hydrogen evolution reaction in zero valent metal nanoparticles-intercalated molybdenum disulfide
Interface confined reactions are a viable strategy for achieving stable and selective catalysts. Here, the authors demonstrate that 1T'-enriched lithiated MoS2 can reduce metal ions in situ, forming zero valent platinum nanoparticle-intercalated MoS2, with enhanced hydrogen evolution activity.
- Zhongxin Chen
- , Kai Leng
- & Kian Ping Loh
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| Open AccessTailored protein encapsulation into a DNA host using geometrically organized supramolecular interactions
Current strategies for protein encapsulation in DNA vessels for controlled enzymatic catalysis or therapeutic delivery rely on formation of covalent complexes. Here, the authors design a system that mimics natural reversible non-covalent host–guest interactions between a DNA host and the protein DegP.
- Andreas Sprengel
- , Pascal Lill
- & Barbara Saccà
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| Open AccessWafer-scale integration of sacrificial nanofluidic chips for detecting and manipulating single DNA molecules
The wide use of microfluidics for biological analysis demands scalable preparation methods, yet in practice it is very challenging. Here, Wanget al. show a wafer-scale fabrication of nanofluidic chips with single-digit nanometre dimension, which is compatible with standard semiconductor processing.
- Chao Wang
- , Sung-Wook Nam
- & Qinghuang Lin
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| Open AccessCarbon nanotube dry adhesives with temperature-enhanced adhesion over a large temperature range
Adhesives typically lose adhesion strength at high temperatures. Here, the authors design a carbon nanotube dry adhesive that becomes stronger with rising temperature, and ascribe this counterintuitive behavior to a thermally-induced nanoscale interlocking mechanism.
- Ming Xu
- , Feng Du
- & Liming Dai
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| Open AccessIn situ characterization of nanoparticle biomolecular interactions in complex biological media by flow cytometry
The protein corona on nanoparticle surfaces leads to presentation of receptor-binding motifs and defines the cellular interactions. Here, the authors use antibody mapping fluorescent quantum dot reporters, and flow cytometry to measure the availability of these recognition motifs in biological media.
- Maria Cristina Lo Giudice
- , Luciana M. Herda
- & Kenneth A. Dawson
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| Open AccessA modular platform for one-step assembly of multi-component membrane systems by fusion of charged proteoliposomes
Assembling multiple biological components into synthetic lipid vesicles is a limiting step in the manufacture of biomimetic cell-like structures. Here the authors use fusogenic proteoliposomes of opposite charge for fast assembly of a minimal electron transport chain consisting of F1F0 ATP-synthase and the proton pump bo3-oxidase.
- Robert R. Ishmukhametov
- , Aidan N. Russell
- & Richard M. Berry
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Article
| Open AccessCollapsed polymer-directed synthesis of multicomponent coaxial-like nanostructures
Multicomponent colloidal nanostructures have topologically dependent chemical and physical properties, but are difficult to synthesise with high order complexity. Here, Nie and co-workers show a general and scalable route to synthesise such structures with unique coaxial-like construction.
- Zhiqi Huang
- , Yijing Liu
- & Zhihong Nie
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| Open AccessNanodiamond-based nanostructures for coupling nitrogen-vacancy centres to metal nanoparticles and semiconductor quantum dots
The coupling of nitrogen-vacancy centres with plasmonic and photonic nanostructures is usually studied by top-down preparation. Here, Gong et al. use a bottom-up approach to grow metallic and semiconducting nanoparticles on nanodiamonds, controlling the nanoparticle coverage, size and composition.
- Jianxiao Gong
- , Nat Steinsultz
- & Min Ouyang
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| Open Access111 oriented gold nanoplatelets on multilayer graphene as visible light photocatalyst for overall water splitting
A plethora of photocatalysts have been investigated in order to obtain solar fuels but the photon-to-hydrogen molecule conversion is generally remains low. Here the authors show that 111 facet oriented gold nanoplatelets on multilayer graphene films is an active photocatalyst for overall water splitting.
- Diego Mateo
- , Iván Esteve-Adell
- & Hermenegildo Garcia
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| Open AccessPhotoelectrochemical water splitting enhanced by self-assembled metal nanopillars embedded in an oxide semiconductor photoelectrode
Nanoscale designs are known to increase the energy conversion efficiency of photoelectrochemical water splitting. Here, the authors report a self-organized nanocomposite formed by embedding self-assembled metal nanopillars in a semiconductor thin film, for enhanced photocarrier separation efficiency.
- Seiji Kawasaki
- , Ryota Takahashi
- & Mikk Lippmaa
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| Open AccessFreestanding three-dimensional core–shell nanoarrays for lithium-ion battery anodes
Degradation and low conductivity of transition metal oxide anodes cause capacity fading in lithium ion batteries. Here the authors make freestanding 3D copper oxide/carbon nitride core-shell nanoarrays which accommodate volume change, provide electro-active zones and facilitate rapid charge transport.
- Guoqiang Tan
- , Feng Wu
- & Khalil Amine
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| Open AccessRegulation at a distance of biomolecular interactions using a DNA origami nanoactuator
The construction of nano-machines requires building nano-scale structures with controllable functions. Here the authors use DNA origami to construct an allosteric actuator which can act as signal propagator and an environmental sensor.
- Yonggang Ke
- , Travis Meyer
- & Gaetan Bellot
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| Open AccessIn vivo covalent cross-linking of photon-converted rare-earth nanostructures for tumour localization and theranostics
Directing nanomedicines to desired locations - such as tumour sites - is difficult to achieve selectively. Here, the authors develop a method to covalently crosslink peptide-modified upconversion nanocrystals into tumour sites for photodynamic therapy and show in vivotumour inhibition in mice.
- Xiangzhao Ai
- , Chris Jun Hui Ho
- & Bengang Xing
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| Open AccessTwo-dimensional honeycomb network through sequence-controlled self-assembly of oligopeptides
Peptide nanostructures are currently arousing interest thanks to their potential applications in medicine, electronics and coatings. Here, through experiment and theory, the authors demonstrate exquisite control over surface peptide assembly behaviour through manipulation of amino acid sequence.
- Sabine Abb
- , Ludger Harnau
- & Klaus Kern
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| Open AccessUltrahigh sensitivity and layer-dependent sensing performance of phosphorene-based gas sensors
Phosphorene is one of a growing number of 2D materials with high potential for device applications. Here, the authors report a sensor composed of phosphorene nanosheets, showing a high sensitivity to NO2in dry air and also demonstrate that the sensitivity depends on the nanosheet thickness.
- Shumao Cui
- , Haihui Pu
- & Junhong Chen
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| Open AccessAqueous multiphoton lithography with multifunctional silk-centred bio-resists
Scientists are increasingly realising the potential for natural materials in micro- and nanofabrication. Here, the authors employ silk-based resists for aqueous multiphoton lithography towards generating intricate structures by femtosecond direct writing.
- Yun-Lu Sun
- , Qi Li
- & Hong-Bo Sun
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| Open AccessFormation of functional super-helical assemblies by constrained single heptad repeat
Advances in bionanotechnology demand an increased portfolio of assemblies beyond those currently available. Here, the authors design a crystallographically characterized super-helical sequence composed of single heptad repeats which, through derivatisation, offers vast potential applications.
- Sudipta Mondal
- , Lihi Adler-Abramovich
- & Ehud Gazit
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| Open AccessFlexible transition metal dichalcogenide nanosheets for band-selective photodetection
Transition metal dichalgogenide sheets prepared by liquid phase exfoliation can be limited in terms of scalability. Here, Velusamy et al. use a scalable liquid phase exfoliation process to fabricate micrometre thick composite nanosheets with amine-terminated polymers, which exhibit photo-detective properties.
- Dhinesh Babu Velusamy
- , Richard Hahnkee Kim
- & Cheolmin Park
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| Open AccessGram-scale synthesis of coordination polymer nanodots with renal clearance properties for cancer theranostic applications
Coordination polymers are promising drug delivery nanomaterials as their structural properties can be easily controlled. Here, Wang et al. prepare coordination nanodots that integrate cancer imaging and therapeutic functions with beneficial renal clearance.
- Fuyao Liu
- , Xiuxia He
- & Zhenxin Wang
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| Open AccessKinetics and fracture resistance of lithiated silicon nanostructure pairs controlled by their mechanical interaction
It is imperative to understand how individual Si nanostructures interact in battery operations. Here, the authors design well-defined crystalline Si nanopillars and show how mechanical interactions of neighbouring Si structures affect their reaction kinetics and fracture resistance during electrochemical lithiation.
- Seok Woo Lee
- , Hyun-Wook Lee
- & Yi Cui
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Tuning the acoustic frequency of a gold nanodisk through its adhesion layer
The mechanical properties of metal nanostructures depend on nature of the adhesion layer attaching it to a substrate. Chang et al.find that the properties of phonons in gold nanodisks vary with adhesion layer thickness, and that this response can act as a probe of the metallic composition of the disk.
- Wei-Shun Chang
- , Fangfang Wen
- & Stephan Link
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| Open AccessMetallic glass nanostructures of tunable shape and composition
The nanoscale manipulation of the shape and composition of metallic glasses is challenging. Here, the authors employ a multitarget carousel oblique angle deposition strategy to synthesize metallic glass nanoarchitectures, and demonstrate applicability to a range of glass-forming alloys.
- Yanhui Liu
- , Jingbei Liu
- & Jan Schroers
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The role of random nanostructures for the omnidirectional anti-reflection properties of the glasswing butterfly
The transparent wings of the glasswing butterfly have a low reflectance over the visible spectrum thanks to the nanopillars distributed across them. Siddique et al. show that this behaviour still works at high angles of incidence because of the random height distribution of the pillars.
- Radwanul Hasan Siddique
- , Guillaume Gomard
- & Hendrik Hölscher
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| Open AccessAccelerated sintering in phase-separating nanostructured alloys
In sintering, powders of small grains are packed together to form shapes or grain structures that cannot be achieved by melt casting. Here, the authors demonstrate the fast sintering of a nanostructured alloy at low temperatures, preserving its nanoscale grain structure.
- Mansoo Park
- & Christopher A. Schuh
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Formation of nickel cobalt sulfide ball-in-ball hollow spheres with enhanced electrochemical pseudocapacitive properties
While the synthesis of hollow structures of transition metal oxides is well established, the related sulfide chemistry remains challenging. Here, the authors report the synthesis of nickel cobalt sulfide ball-in-ball hollow spheres, via anion exchange, and evaluate their pseudocapacitive behaviour.
- Laifa Shen
- , Le Yu
- & Xiong Wen (David) Lou
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| Open AccessReversed oxygen sensing using colloidal quantum wells towards highly emissive photoresponsive varnishes
Colloidal quantum wells have great potential as solution-processed light sources. Here, Lorenzon et al. demonstrate that such colloidal quantum wells can also be exploited as luminescent-sensing varnishes capable of detecting chemical agents through their reversible emission response.
- Monica Lorenzon
- , Sotirios Christodoulou
- & Sergio Brovelli
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Mesoporous bismuth ferrite with amplified magnetoelectric coupling and electric field-induced ferrimagnetism
Bismuth ferrite is an important room temperature multiferroic material where magnetism and ferroelectricity are coupled. Here, the authors utilize a wet chemical synthesis method to create strained nanoporous bismuth ferrite with enhanced magnetoelectric coupling and elevated magnetic moments.
- Thomas E. Quickel
- , Laura T. Schelhas
- & Sarah H. Tolbert
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A surface curvature oscillation model for vapour–liquid–solid growth of periodic one-dimensional nanostructures
Vapour-liquid-solid process is widely used to prepare a variety of one-dimensional nanostructures, but a quantitative understanding of the growth mechanism is missing. Here, Wang et al. show that the surface curvature oscillation of the liquid tip determines the growing process and thus the morphology.
- Hui Wang
- , Jian-Tao Wang
- & Xiao-Hong Zhang
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Direct growth of large-area graphene and boron nitride heterostructures by a co-segregation method
Direct growth of graphene on h-BN is desired to improve device performance. Here, the authors demonstrate the direct growth of large-area and continuous graphene/h-BN vertical heterostructures via a co-segregation approach.
- Chaohua Zhang
- , Shuli Zhao
- & Zhongfan Liu
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Strong interactive growth behaviours in solution-phase synthesis of three-dimensional metal oxide nanostructures
It has been suggested that the growth rate of nanocrystals is affected by the size and density of surrounding crystals. Here, the authors study the anisotropic growth of zinc oxide nanorod arrays, and show that rod diameter and height are interdependent, and may be affected by local interactions.
- Jung Min Lee
- , You-Shin No
- & Won Il Park
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Room-temperature exciton coherence and dephasing in two-dimensional nanostructures
Evidence for exciton coherence in photosynthetic complexes raises questions about whether quantum processes can play a role in biological environments, which are warm and wet. Cassette et al. now demonstrate long-lived electronic coherence in colloidal nanoplatelets in solution and at room temperature.
- Elsa Cassette
- , Ryan D. Pensack
- & Gregory D. Scholes
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| Open AccessPromotion of water-mediated carbon removal by nanostructured barium oxide/nickel interfaces in solid oxide fuel cells
Anodes composed of nickel/yttria-stabilized zirconia in solid oxide fuel cells are known to suffer from coking, which reduces their performance. Here, Yang and colleagues report a new barium oxide/nickel anode, which efficiently oxidizes fuel with minimum carbon buildup.
- Lei Yang
- , YongMan Choi
- & Meilin Liu
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Nanostructural hierarchy increases the strength of aluminium alloys
Improving the properties of metallic alloys is important to develop new lightweight materials. In this paper, we show that an aluminium (Al) alloy containing a hierarchy of nanostructures in a solid solution with a high density of dislocations is capable of beating strength records for Al alloys while maintaining good ductility.
- Peter V. Liddicoat
- , Xiao-Zhou Liao
- & Simon P. Ringer
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Fluidic supramolecular nano- and microfibres as molecular rails for regulated movement of nanosubstances
Microtubules act as molecular tracks for the transport of substances within cells, and have inspired the construction of artificial supramolecular fibres. Here, self-assembled glycol–lipid fibres are shown to be sufficiently fluid to allow directional movement of attached molecules, proteins and nanobeads.
- Shun-ichi Tamaru
- , Masato Ikeda
- & Itaru Hamachi