Nanoscience and technology

The adoption of photonic synapses with biosimilarity to realize analog signal transmission is of significance in realizing artificial illuminance modulation responses. Here, the authors report a biomimetic ocular prosthesis system based on quantum dots embedded photonic synapses with improved depression properties through mid-gap trap.

Here, the authors attribute the ambient surface contamination of van der Waals materials to a self-organized molecular layer of normal alkanes with lengths of 20-26 carbon atoms. The alkane adlayer displaces the manifold other airborne contaminant species, capping the surface of graphene, graphite, hBN and MoS₂.

High-speed flexible circuits are essential in flexible systems for real-time information analysis and wireless communication. Here, flexible circuits are reported with a 281 ps stage delay based on scaled carbon nanotube thin film transistors.

Interlayer spacing and termination are important for controlling the physical and chemical properties of MXenes, largely affecting their potential applications. Here authors present a general approach for simultaneously tuning the interlayer spacing and termination of MXenes using Lewis-basic halides.

Perovskite nanomaterials may suffer degradation during conventional photolithography. Here, the authors report a non-destructive method for patterning perovskite quantum dots based on direct photopolymerization catalyzed by lead bromide complexes.

Improving fuel cell technologies based on Pt-based alloys is important for efficient fuel cells. Here, the authors report a hybrid PtCo alloy electrocatalyst for acidic oxygen reduction at high current densities and H₂/air fuel cell power densities.

By carefully structuring and patterning a material, it is possible to introduce emergent properties that would otherwise not exist. These metamaterials have allowed the development of a wide variety of new optical properties. Here, Matsubara et al present a magnetic metamaterial, where spin-currents can be directed by tuning the polarization of the incident light.

Understanding water transport through nanochannels is central to biology, separations and clean water. Here, the authors show transport of water vapor through Angstrom-scale pores (~2.8–6.6 Å in diameter) in atomically thin graphene membranes is orders of magnitude faster than liquid water, due to permeation occurring in different flow regimes.

Exsolution of transition metal cations from non-stoichiometric perovskites offer a route for the formation of stable nanoparticles on the surface. Here authors present an anti-phase boundaries-accelerated exsolution and two-step crystallisation of nanoparticles in non-stoichiometric perovskite thin films.

While cobalt-based electrocatalysts demonstrate promising performances for oxygen evolution, active site identification is complicated by concurrent structural changes. Here, authors examine crystalline, well-defined cobalt oxyhydroxide nanomaterials and identify the geometric active sites.

Displaying the correct surface functionality at the right time is important for efficient drug delivery. Here, the authors report on the pH-responsive, sequential presentation of cell-penetrating peptide and liver-targeting moiety designed to improve intestinal absorption and liver targeting and demonstrate this with insulin delivery in vivo.

The authors demonstrate a label-free superresolution imaging method by using a hyperbolic material as a substrate for tailored light-matter interactions. The hyperbolic material enhanced scattering, combined with dark-field detection, result in 5.5-fold resolution improvement beyond the diffraction limit.

The authors report high-efficiency emission depletion through a surface migration emission depletion mechanism, which takes advantage of the effects of surface quenching and energy migration in nanocrystals. They demonstrate super-resolution microscopy with very low depletion saturation intensities.

Many complex devices rely on epitaxial growth with high crystallinity and accurate composition. Here authors report epitaxial growth of Ge on deep etched porous Si pillars to provide a fully compliant substrate enabling elastic relaxation of defect free Ge microcrystals.

The application of electric fields >1 V/nm in solid state devices could provide access to unexplored phenomena, but it is currently difficult to implement. Here, the authors develop a double-sided ionic liquid gating technique to generate electric fields as large as 4 V/nm across few-layer WSe₂, leading to field-induced semiconductor-to-metal transitions.

Coherently interfacing microwave and optical radiation at the single photon level is an outstanding challenge in quantum technologies. Here, the authors show bi-directional on-chip conversion between MW and optical frequencies exploiting piezoelectric actuation of a gallium phosphide optomechanical resonator.

While the combination of synthetic and biological systems offers an appealing strategy for solar-to-fuel conversion, such hybrid systems typically suffer from low selectivity. Here, authors integrate a bimetallic alloy with a CdS-containing methanogen for selective CO₂ reduction to methane.

The optoelectronic performance of lead halide perovskite in highfluence applications are hindered by heterogeneous multi-polaron interactions in the nanoscale. Here, Nishda et al. spatially resolve sub-ns relaxation dynamics on the nanometer scale by ultrafast infrared pumpprobe nanoimaging.

Analysis of the protein corona formed around nanoparticles is important for multiple applications in nanomedicine, the methods used at core facilities used for analysis can impact the results. Here, the authors report on a study into the variability of the results obtained from 17 different core facilities and the implications of this.

Natural buffer molecules ensure the controlled and precise delivery of specific molecules in biology. Here, the authors replicate the natural buffer systems using aptamers with controlled binding efficiency to control and maintain the levels of free drugs both in vitro and in vivo.

Understanding the behaviors of droplets at nanoscales is crucial to many applications, yet it remains experimentally challenging to track them in real time. Here, Sbarra et al. use a miniature optomechanical resonator to probe the evaporation dynamics of attoliter droplets with millisecond resolution.

The authors design double shelled hollow superstructures from self-assembled CdSe/CdS nanorods in covalent organic frameworks for CO2 photo-reduction at a gas/solid interface.

The authors developed a pristine hyperspectral SPR microscopy that enables monochromatic and polychromatic SPR imaging with flexible field-of-view option, single-pixel spectral SPR sensing and 2D quantification of thin films with resonant wavelength images.

THz imaging and spectroscopy always request even more efficient components. Here the authors, thanks to a modified photoconductive switch that includes a graphene layer, demonstrate a high-speed photoconductive switch without sacrificing the generated power.

Yu-Shiba-Rusinov (YSR) states result from the exchange coupling between a localized magnetic moment and a superconductor. Traditionally, the YSR states have been studied for magnetic atoms. For molecular magnets with extended ligand spin, the entanglement of spin and ligand orbital gives rise to new forms of YSR excitations. Here, Xia et al uncovered spin-orbital YSR states in an unpaired ligand spin in the molecular magnet Tb2Pc3 on Pb.

The motion of a vibrating object is set by the way it is held. Here, the authors show a nanomechanical resonator reversibly slides on its supporting substrate as it vibrates and exploit this unconventional dynamics to quantify friction at the nanoscale.

Stable electrodes which operate at large current density are essential for industrial water electrolysis. Here, a highly active Chevrel phase electrode is reported to achieve 2500 mA/cm⁻² current density for 300 hours at small overpotentials.

Rare-earth elements are vital to advanced technological applications ranging from spintronic devices to quantum information science. Here, the authors formed charged rare-earth complexes on a material surface and demonstrated atomically precise control on their rotational dynamics.

We show frequency domain mirrors that provide reflections of optical mode propagation in the frequency domain. We theoretically investigated the mirror properties and experimentally demonstrate it using polarization and coupled-resonator-based coupling on thin film Lithium Niobate.

PVA is a hydrogel that has attractive swelling properties for use in tunable photonic applications. Here, the authors exploit PVA with nanoimprint lithography to realize multiplexed optical encryption metasurfaces to display, hide, and destroy encrypted information.

Interfacial ferroelectricity may emerge in moiré superlattices. Here, the authors find that the polarized charge is much larger than the capacity of the moiré miniband and the associated anomalous screening exists outside the band.

Memory augmented neural network for lifelong on-device learning is bottlenecked by limited bandwidth in conventional hardware. Here, the authors demonstrate its efficient in-memristor realization with a close-software accuracy, supported by hashing and similarity search in crossbars.

Cost-effective methods for long-term storage of DNA are desired. Here the authors present a method for in situ cryosilicification of whole blood cells, allowing long-term and room temperature preservation of genomic information for only approximately $0.5 per sample.

Excitonic states govern the optical response of low-dimensional nanomaterials and are key for a wide range of applications. Here, the authors investigate the exciton decay dynamics in single carbon nanotubes with few-exciton detection sensitivity.

Slow light effects are interesting for telecommunications and quantum photonics applications. Here, the authors use coupled exciton-surface plasmon polaritons (SPPs) in a hybrid monolayer WSe₂-metallic waveguide structure to demonstrate a 1300-fold reduction of the SPP group velocity.

Here, the authors fabricate large area and highly aligned polymer semiconductor sub-microwires arrays via coaxial focused electrohydrodynamic jet printing technology, achieving high on/off ratio and average mobility that is 5x higher than that of thin film based organic field effect transistors.

While photoelectrochemical water splitting produces fuel from solar energy, a large fraction of photoanode photoexcited charge carriers cannot be extracted efficiently at low bias voltages. Here, authors improve the charge transport in P-doped BiVO₄ by mediating polaron hopping and trap states.

Topological superconductivity (TSC) is predicted to exist in nanowires with strong spin-orbit coupling (SOC) when they are in proximity to superconductors, with a key signature being zero-energy states in conductance measurements. Here, using weak-SOC carbon nanotubes as the nanowires, the authors show that similar looking zero-energy states can appear even in nanowires which cannot, in principle, host TSC.

Atomic-scale insights into how a nanoparticle surface reconstructs under reaction conditions and the impact of the reconstruction on catalytic activity are still lacking. Here the authors reveal that Pd nanocatalysts display oscillatory changes in both their structure and activity during CO oxidation using operando TEM.

Surface modification of nanoparticles by cell membrane (CM) coating to improve their bio-interface properties often results in partial coating. Here the authors show that partial coating is an intermediate state due to the absorption of CM fragments or vesicles and can be resolved by increasing CM fluidity with external phospholipids.

The simple and scalable fabrication of high aspect ratio encapsulated flexible nanowire arrays with controlled size and periodicity is demonstrated and modelled, enabling nanophotonics applications requiring long-range order over several meters.

Experimental studies of the Casimir effect have involved only interactions between two bodies so far. Here, the authors observe a micrometer-thick cantilever under the Casimir force exerted by microspheres from two sides simultaneously.

While metal-organic frameworks offer a diverse array of structural motifs for electrocatalysis, poor conductivity and mass permeability limit performances. Here, authors confine low-conductivity metal-organic frameworks between graphene multilayers to enhance oxygen evolution performances.

2D multiferroic materials have garnered broad interests due to their magnetoelectric properties and multifunctional applications. Here, the authors discover a multiferroic feature in physical vapor deposition synthesized 2D metallic p-doped SnSe.

Multi-chambered structures have attracted great attention due to their ability to create multifunctional partitions in different chambers. Here, the authors prepared mesoporous silica nanoreactors with hierarchical chambers for catalytic cascades.

While water-splitting electrolysis offers a potential renewable means to store energy, the oxygen evolution half-reaction’s sluggish kinetics limits performances. Here, authors incorporation boron into nickel-iron hydroxide catalysts to promote electrocatalytic water oxidation activities

The potential energy efficiency of impact ionization field-effect transistors (I²FETs) is usually limited by stringent operational conditions. Here, the authors report I²FETs based on 2D WSe₂, showing average subthreshold slopes down to 2.3 mV/dec and on/off ratios of ~10⁶ at room temperature and bias voltages <1 V.

Skyrmion bubbles consist of a centre magnetization pointing up or down, and a swirling vortex magnetic texture, either clockwise or anticlockwise around this. Here, Yao et al use a three-dimensional imaging approach to study this magnetic texture, and show that while the in-plane vortex-like texture changes easily, the centre magnetic direction, the polarity, is retained, leading to a reversed chirality.

Topological materials hold great promise for dissipationless information transmission. Here, the authors create Chern insulator junctions between domains with different Chern numbers in MnBi₂Te₄ to realize the basic operation of a topological circuit.