Focus
Wetting properties of graphene
- Focus issue:
- October 2013 Volume 12, No 10
The intrinsic hydrophobicity of graphitic surfaces and the recent claim of wetting transparency of supported graphene are being questioned. In this focus issue we highlight the latest developments aimed at increasing our understanding of how graphene and graphitic surfaces interact with water.
Editorial
Not so transparent - p865
doi:10.1038/nmat3773
As with the ongoing debate on the degree of wetting transparency of supported graphene, transparency in both pre- and post-publication peer review is a contentious concept.
Full text - Not so transparent | PDF (112 KB) - Not so transparent
Commentary
Wetting translucency of graphene - pp866–869
Chih-Jen Shih, Michael S. Strano and Daniel Blankschtein
doi:10.1038/nmat3760
For the case of water on supported graphene, about 30% of the van der Waals interactions between the water and the substrate are transmitted through the one-atom-thick layer.
Full text - Wetting translucency of graphene | PDF (615 KB) - Wetting translucency of graphene
News & Views
Wetting: Contact with what? - pp872–873
Ke Xu and James R. Heath
doi:10.1038/nmat3763
Pristine graphitic surfaces seem to be more hydrophilic than previously assumed because of the unexpected influence of the quick adsorption of hydrocarbons from air.
Full text - Wetting: Contact with what? | PDF (142 KB) - Wetting: Contact with what?
Article
Effect of airborne contaminants on the wettability of supported graphene and graphite - pp925–932
Zhiting Li, Yongjin Wang, Andrew Kozbial, Ganesh Shenoy, Feng Zhou, Rebecca McGinley, Patrick Ireland, Brittni Morganstein, Alyssa Kunkel, Sumedh P. Surwade, Lei Li and Haitao Liu
doi:10.1038/nmat3709
Contact-angle and spectroscopy experiments on clean supported graphene and graphite show that these surfaces become more hydrophobic as they adsorb airborne hydrocarbons. Furthermore, the water contact angle on these graphitic surfaces decreases if these contaminants are partially removed by both thermal annealing and controlled ultraviolet–ozone treatments, suggesting that graphitic surfaces are more hydrophilic than previously believed.
Full text - Effect of airborne contaminants on the wettability of supported graphene and graphite | PDF (585 KB) - Effect of airborne contaminants on the wettability of supported graphene and graphite | Supplementary information