Focus

Wetting properties of graphene

The intrinsic hydrophobicity of graphitic surfaces and the recent claim of wetting transparency of supported graphene are being questioned. In this focus issue we highlight the latest developments aimed at increasing our understanding of how graphene and graphitic surfaces interact with water.

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Editorial

Not so transparent p865

doi:10.1038/nmat3773

As with the ongoing debate on the degree of wetting transparency of supported graphene, transparency in both pre- and post-publication peer review is a contentious concept.


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Commentary

Wetting translucency of graphene pp866–869

Chih-Jen Shih, Michael S. Strano and Daniel Blankschtein

doi:10.1038/nmat3760

For the case of water on supported graphene, about 30% of the van der Waals interactions between the water and the substrate are transmitted through the one-atom-thick layer.


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News & Views

Wetting: Contact with what? pp872–873

Ke Xu and James R. Heath

doi:10.1038/nmat3763

Pristine graphitic surfaces seem to be more hydrophilic than previously assumed because of the unexpected influence of the quick adsorption of hydrocarbons from air.


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Article

Effect of airborne contaminants on the wettability of supported graphene and graphite pp925–932

Zhiting Li, Yongjin Wang, Andrew Kozbial, Ganesh Shenoy, Feng Zhou, Rebecca McGinley, Patrick Ireland, Brittni Morganstein, Alyssa Kunkel, Sumedh P. Surwade, Lei Li and Haitao Liu

doi:10.1038/nmat3709

Contact-angle and spectroscopy experiments on clean supported graphene and graphite show that these surfaces become more hydrophobic as they adsorb airborne hydrocarbons. Furthermore, the water contact angle on these graphitic surfaces decreases if these contaminants are partially removed by both thermal annealing and controlled ultraviolet–ozone treatments, suggesting that graphitic surfaces are more hydrophilic than previously believed.


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