Identifying and tuning the coordination environment to improve the oxygen evolution reaction kinetics of coordination complexes is important, yet challenging. Here, the authors report a series of coordination complexes as catalytic models and reveal the unique reaction behavior of coordinated water.

CO₂ can be captured in mesoporous alkaline waste materials. Here the authors provide atomistic insight for CO₂ adsorption in calcium hydroxide to identify optimal relative humidity conditions for maximum CO₂ intake.

Secondary nucleation is an approach to synthesizing higher-order supramolecular polymers with exciting topologies, but a detailed understanding of growth processes is needed. Here, the authors report the non-covalent synthesis and high chiro-optical photoresponse of dendritic homochiral superstructures via a secondary nucleation elongation process.

The activation of C-C bond of benzocyclobutenones under mild reaction conditions remains a challenge. Herein, the authors report a photoinduced catalyst-free regio-specific bond cleavage of benzocyclobutenones, enabling the generation of ortho-quinoid ketene methides for aza-[4 + 2]-cycloaddition with imines. Catalytic asymmetric version is also realized with Ni catalysis.

Metastable supramolecular polymerization under kinetic control is a closer way to biosystem than thermodynamic process but the library of available non-covalent driving modes is small. Here, the authors propose a coopetition-driven metastability strategy for parallel/perpendicular aromatic stacking to construct metastable supramolecular polymers.

The 2.71-2.17 Ma apparent polar wander paths of Wyoming and Superior provide indicated relative horizontal motion during the Neoarchean. Together with other tectonic proxies, the data support plate mobilisation in operation prior to 2.5 Ga.

Here, particulate matter metrics are assessed and associated with sand and dust storm health risks. The oxidative potential and the environmentally persistent free radicals of particulate matter could be used to develop effective sand and dust risk prevention in dust-prone countries.

Using a high-resolution model forced under a high emission scenario, the authors find an increase in subsurface marine heatwaves, and in concurrent surface and subsurface marine heatwaves, which can restrict refuge options of marine organisms.

This study finds that vegetation greening is expected to exacerbate compound soil drought-heat extreme events, as enhanced transpiration during the early growing season depletes soil moisture leading to deficits in the subsequent warm season.

Historical emissions of polychlorinated naphthalenes from production and use (1912-1987), unintentional emissions (2000-2020), and projected future emissions (2020-2050) are estimated.

Here, the authors show that vaginal lactobacilli associated with optimal health interact selectively with a restricted subset of anti-inflammatory receptors through their Surface Layer Proteins, both in vitro and in cervicovaginal fluids, correlating with lower maternal inflammation.

Efficiency of Hi-C methods is restrained by usage of enzymes irrelevant to TF mediated chromatin interactions. Here, the authors present Footprint-C for constructing chromatin contact maps upon genuine TF footprints and reveal a regulatory lexicon of TF local residence and long-range interactions.

Detecting FGFR3-mutant muscle-invasive and metastatic urothelial cancers (MIBC/mUC) for targeted therapy remains challenging, but clinically important. Here, the authors develop a deep-learning model to detect FGFR3 mutations in MIBC/mUC from routine histopathology slides, allowing for highly sensitive, rapid, and cost-effective pre-screening.

How intracellular iron homeostasis is controlled and regulated is not well understood. Here, the authors show that SLC39A13 promotes iron transport from the cytosol to the ER/Golgi and affects iron metabolism in several compartments.

Threshold-like relationships between fitness & phenotype are ubiquitous in nature. Erdoğan et al. use experimental & simulated evolution of an antibiotic resistance enzyme to show how such relationships allow the emergence of standing phenotypic variation under static environmental conditions.

Fine particulate matter has been linked to acute coronary syndrome, but the key constituents remain unclear. Here, the authors show that organic matter and black carbon have the largest effects on acute coronary syndrome onset, and contributed most to the joint impacts.

Using clinico-genomic data from 78,287 cancer patients, this study identifies genomic alterations linked to survival outcomes, advancing precision oncology by predicting responses to immunotherapy, chemotherapy, and targeted therapies across 20 cancers.

Neuropathy leads to sensory loss and increased risk of fall. Here, the authors design a wearable non-invasive neuroprosthesis that restores lost sensations and improves gait.

Higher mitochondrial oxidative phosphorylation assessed in skeletal muscle through non-invasive MR spectroscopy predicts less brain atrophy and microstructural deterioration in community-dwelling adults.

Dog-mediated rabies is endemic in parts of Asia and Africa including the Philippines. Here, the authors report investigation of an outbreak of rabies in Romblon, a previously rabies-free island province in the Philippines, using a One Health approach.

Success is being increasingly studied as a collective phenomenon. Here the authors review how this perspective has deepened our understanding of success, uncovering regularities and predictive signals across diverse domains, as well as biases that challenge meritocratic views of success.

The tourism carbon footprint grew 2.3 times faster than the rest of the economy, reaching nearly 9% of global emissions by 2019. Rapid tourism demand growth (3.8% per year) has outpaced energy efficiency gains among businesses (0.3% per year).

For control systems, blockchain usually exhibits a trade-off between security and real-time performance. Here, authors propose a new mechanism that utilizes multi-party computation and verification with prediction, specifically tailored for real-time security control of renewable energy power systems.

33% of the world’s sandy coastlines are hardened by human-made structures, hindering natural retreat as sea levels rise. By 2100, up to 26% may face severe beach loss, while emission reductions could lower this to 21%.

By analyzing 187,926 Norwegian first-time parents, researchers found that partners are more similar in mental than physical health, with mental health similarity increasing over time. Educational similarity partially explained health similarity.