Abstract
In this work boehmite nanoparticles (BNPs) were prepared through addition of aqueous solution of NaOH to solution of Al(NO3)3·9H2O. Then, the surface of BNPs was modified by (3-chloropropyl)trimethoxysilane (CPTMS) and further tetradentate ligand (MP-bis(AMP)) was anchored on its surface. At final step, a tetradentate organometallic complex of copper was stabilized on the surface of modified BNPs (Cu(II)-MP-bis(AMP)@boehmite). These obtained nanoparticles were characterized using SEM imaging, WDX, EDS, AAS and TGA analysis, BET method, FT-IR spectroscopy, and XRD pattern. In continue, the catalytic activity of Cu(II)-MP-bis(AMP)@boehmite has been used as a much efficient, reusable and hybrid of organic–inorganic nanocatalyst in the synthesis of ether derivatives through C–O coupling reaction under palladium-free and phosphine-free conditions. Cu(II)-MP-bis(AMP)@boehmite catalyst has been recovered and reused again for several times in the synthesis of ether derivatives.
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Introduction
The field of nanoparticles solid-state nanoparticles have been grown strong consideration in green chemistry, biological applications and scientific research due to their inimitable properties such as excellent particular surface area, high stability, non-toxicity and high environmental friendly1,2,3,4,5. For example, polymers6, carbon nanotubes7, MCM-418,9, ionic liquids10, boehmite11,12, zeolite13, biochar14,15, graphene oxide16, magnetic nanoparticles17,18,19,20, and etc. were demonstrated in variant fields especially in catalysis knowledge. Amongst them, BNPs encompass variant usages such as the vaccine adjuvants, optical material, photoluminescent substance, flame retardant, plastics reinforcing, coatings, composite material amplification in ceramics, support for catalysts, starting substance in the alumina synthesis and so on12,21,22,23,24,25,26,27,28. BNPs are one of the polymorph of aluminum oxide hydroxide (γ‐AlOOH) that are form twice sheet construction and composed just aluminum and oxygen29,30. The surface of BNPs encompass high aggregation of OH groups, which makes possible its surface modification with various functional groups to stabilization of catalysts31. Therefore recently, BNPs were synthesized by variant procedure and peculiarly used as support for catalysts12. BNPs were generally formed by hydrolysis of Al-salts such as NaAlO2, Al2(SO4)3, AlCl3, Al(NO3)3, or aluminum alkoxide32,33,34,35,36,37. Herein, variant processes have been introduced for synthesis of BNPs such as hydrothermal38, solvothermal30, sol–gel39, coprecipitation40 reactions and hydrolysis of aluminum41. Stability, availability and environmentally of BNPs are significant benefits for usage in industrial and academic research42,43.
Carbon–oxygen coupling reaction as powerful tools for the synthesis of ether derivatives is generally offered with Pd-catalysts containing phosphine ligands44,45,46,47. The use of palladium catalyst and phosphine ligands led to expensive, toxic and also air or moisture sensitive of procedure. More addition, instability and non‐recoverability are major drawback of homogeneous catalysts and phosphine materials16. Meanwhile, copper catalyst without phosphine ligands is non-toxic and inexpensive than palladium catalyst and high environmentally friendly and moisture- or air-stability16,48. Therefore, to make pace principles of green chemistry, we investigated Cu-catalyst on BNPs as a stable and recyclable nanocatalyst for the C–O coupling reaction.
Result and discussion
Surface modification of BNPs by CPTMS was performed matching to last reported method15. Then, MP-bis(AMP) ligand was substituted with Cl of CPTMS. Subsequently copper catalyst was fixated on the surface. The schematic preparation procedure of this catalyst (Cu(II)-MP-bis(AMP)@boehmite) is outlined in Fig. 1.
Synthesis of Cu(II)-MP-bis(AMP)@boehmite.
Cu(II)-MP-bis(AMP)@boehmite was characterized by scanning electron microscopy (SEM) imaging, wavelength dispersive X-ray spectroscopy (WDX), energy-dispersive X-ray spectroscopy (EDS), atomic absorption spectroscopy (AAS) and thermogravimetric analysis (TGA) analysis, X-ray diffraction (XRD) pattern, Fourier transform infrared spectroscopy (FT-IR) spectroscopy, N2 adsorption–desorption isotherms method. SEM images of Cu(II)-MP-bis(AMP)@boehmite and MP-bis(AMP)@boehmite are shown in Fig. 2a,b respectively which indicate that Cu(II)-MP-bis(AMP)@boehmite has particle size in nanometer scale. As shown in Fig. 2, the SEM images of the material before the addition of Cu are similar to after the addition of Cu in term of size and morphology which shows the stability of these nanoparticles after stabilization of the copper complex.
SEM image of (a) Cu(II)-MP-bis(AMP)@boehmite and (b) MP-bis(AMP)@boehmite.
In order to illustrate the elemental combination and distributions of catalyst, the energy-dispersive X-ray spectroscopy (EDS) and wavelength-dispersive X-ray mapping (WDX) analysis of Cu(II)-MP-bis(AMP)@boehmite have been examined, the EDS (Fig. 3) and WDX (Fig. 4) analysis of this catalyst shown the attendance of aluminum, oxygen, silica, carbon, sulfur, nitrogen, and in addition copper species in catalyst with homogeneous dispensations of all elements in the structure of Cu(II)-MP-bis(AMP)@boehmite. Also, the exact amount of copper was found to be 0.4 × 10−3 mol g−1 by AAS analysis.
EDS diagram of Cu(II)-MP-bis(AMP)@boehmite.
Elemental mapping of (a) aluminum, (b) oxygen, (c) silica, (d) carbon, (e) sulfur, (f) nitrogen, (g) copper and combine elements for Cu(II)-MP-bis(AMP)@boehmite.
In order to determine content of organic species, which were immobilized on the surface of BNPs, TGA/DTA analysis of Cu(II)-MP-bis(AMP)@boehmite was performed (Fig. 5). The miniature weight loss within 9% at downward temperature is related to vaporization of adsorbed solvents49. The organic substance including CPTMS and ligand which fixed on BNPs was decomposed at 200–500 °C that is 32% of catalyst. Last weight dissipation which is lesser than 2% a may be related to transformation of thermal crystal phase of boehmite nanoparticles11.
TGA/DTA diagrams of Cu(II)-MP-bis(AMP)@boehmite.
Powder XRD analysis is a great technique to determine the crystal structure of materials. Therefore, the powder XRD analysis was performed to shown the crystalline phase of Cu(II)-MP-bis(AMP)@boehmite. The experimentally obtained XRD patterns were compared to the Inorganic Crystal Structure Database (ICSD) provided which shows two series of crystal structure. The obtained results analysis from powder XRD analysis of Cu(II)-MP-bis(AMP)@boehmite is shown in Fig. 6. Also, phases list from XRD results are summarized in Table 1. As shown in Fig. 5 and Table 1, X-ray diffraction analysis of this catalyst shows two series of materials. The first of them is related to the boehmite (Aluminum Oxide Hydroxide) crystal phase, which matched with the standard pattern 01-083-1506 code of ICSD database. This pattern correspond to 2θ value positions at 14.8° (0 2 0), 28.48° (1 2 0), 38.27° (0 3 1), 46.45° (1 3 1), 49.24° (0 5 1), 51.94° (2 0 0), 55.49° (1 5 1), 59.35° (0 8 0), 64.91° (2 3 1), 65.56° (0 0 2), 67.23° (1 7 1), and 72.65° (2 5 1), which are consistent with the orthorhombic unit cell of standard pattern of boehmite nanoparticles50. Therefore, the initial boehmite phase is stable during the boehmite modification and copper stabilization on its surface. The second pattern is related to the sodium nitrate as impurity (which matched with the standard pattern 00-036-1474 code of ICSD database). This pattern corresponds to 2θ value positions at 29.43°, 32.04°, 35.39°, 39.04°, 62.63°, 47.94°, 55.49°, 67.23° and 72.65°. This sodium nitrate impurity is also commonly seen in the IR spectrum in region 1650 cm−1. As shown, some peaks of the sodium nitrate crystal phase pattern overlap with the boehmite crystal phase peaks at 2θ value positions 32.04°, 39.04°, 47.94°, 55.49°, 67.23° and 72.65°.
XRD pattern of Cu(II)-MP-bis(AMP)@boehmite (a), standard pattern 01-083-1506 code of boehmite (b) and standard pattern 00-036-1474 code of sodium nitrate (c).
The N2 adsorption–desorption isotherms and BJH-Plot diagram of Cu(II)-MP-bis(AMP)@boehmite are shown in Fig. 7 and textural properties of Cu(II)-MP-bis(AMP)@boehmite are summarized in Table 2. As shown in Table 2, surface area, pore volumes and pore diameters of this catalyst are 101.66 m2 g−1, 0.375 cm3 g−1 and 4.62 nm respectively. Decreasing of surface area of Cu(II)-MP-bis(AMP)@boehmite than boehmite nanoparticles (128.8 m2 g−1, Ref.29) is due to the linking of organic substance and copper complex.
(a) N2 adsorption–desorption isotherm and (b) BJH-Plot of Cu(II)-MP-bis(AMP)@boehmite.
The FT-IR spectrum of Cu(II)-MP-bis(AMP)@boehmite is illustrated in Fig. 8. Also, FT-IR characteristic absorptions of Cu(II)-MP-bis(AMP)@boehmite are summarized in Table 3. The FT-IR spectrum of Cu(II)-MP-bis(AMP)@boehmite is demonstrated a strong peak at 1634 cm−1, which are related to the C=N vibrations in the structure of the fabricated ligand15. The several peaks which are shown in region < 3000 cm−1 related to the vibrations of the C–H bonds of immobilized organic groups on the surface of boehmite nanoparticles51. The stretching vibration of Si–O is observed at 1073 cm−151. The stretching vibration of hydroxyl groups in FT-IR spectrum of Cu(II)-MP-bis(AMP)@boehmite is appeared at 3318 cm−151. The vibrations of hydrogen bands of OH⋯OH is indicated at 1164 cm−152. Also, the bending vibration of hydroxyl groups is appeared at 1385 cm−115. The three bands at 478, 623 and 741 cm−1 are referred to the vibration of the Al–O bonds in boehmite nanoparticles52. The characteristic of the NaNO3 impurity was emerged at 1650 cm−152 which overlap with the vibrations of the other bonds. This impurity is also observed in the XRD analysis.
FT-IR spectrum of Cu(II)-MP-bis(AMP)@boehmite.
Catalytic study of Cu(II)-MP-bis(AMP)@boehmite
The catalytic activity of Cu(II)-MP-bis(AMP)@boehmite has been investigated in the C-O coupling reaction toward the formation of diaryl ether derivatives. In the synthesis of diaryl ethers, the coupling of phenol (Ph-OH) with iodobenzene (Ph-I) using catalytic value of Cu(II)-MP-bis(AMP)@boehmite as catalyst has been chosen as a pattern reaction to found the optimize conditions. At first, the pattern reaction has been tested without Cu(II)-MP-bis(AMP)@boehmite (Table 4, entry 1) which the pattern reaction was not go proceed. Then, the pattern reaction was carried out in using variant value of catalyst which it was completed with 98% of yield when 30 mg of Cu(II)-MP-bis(AMP)@boehmite was used (Table 4, entry 2). At second, the effect of various solvents (Table 4, entries 4–7) and bases (Table 4, entries 8–11) were studied in the pattern reaction under wide range of temperature. As shown, DMSO solvent and KOH base at 130 ºC offered the best results for the synthesis of diaryl ether (Scheme 1).
Synthesis of diaryl ether derivatives using Cu(II)-MP-bis(AMP)@boehmite.
In order to show the role of Cu(II)-MP-bis(AMP)@boehmite, the catalytic activity of Cu(II)-MP-bis(AMP)@boehmite was compared with alone boehmite and MP-bis(AMP)@boehmite in the coupling of phenol with iodobenzene under optimized conditions (Table 5). As shown, diphenyl ether was formed in the presence of Cu(II)-MP-bis(AMP)@boehmite with 98% of yield. While, almost no products were formed in the presence of alone boehmite or MP-bis(AMP)@boehmite.
The mentioned optimizing condition were investigated to the various aryl halide derivatives to extend catalytic scope of Cu(II)-MP-bis(AMP)@boehmite (Table 6). All aryl halide derivatives having other functional groups with electron-withdrawing or electron-donating nature were successfully coupled with phenol in superior yields in the presence of this catalyst. As shown in Table 6, aryl iodides have great reaction rate than aryl bromides, while aryl chlorides have lowest reaction rate under coupling of phenol using Cu(II)-MP-bis(AMP)@boehmite catalyst. This indicates that the C–Cl bond is stronger than the C–I bond because the carbon and chlorine orbitals are similar in size, energy, and symmetry, but the iodine and carbon orbitals have different sizes and energies. In addition, the C–I bond is longer and weaker than the C–Cl bond, which C–I bond requires less energy to break and has a faster coupling rate than the short C–Cl bond. For example, the coupling of phenol with 4-nitrobromobenzene is greater than 4-nitrochlorobenzene. This ordered was also observed at coupling of phenol with iodobenzene, bromobenzene and chlorobenzene using Cu(II)-MP-bis(AMP)@boehmite catalyst.
Comparison of the catalyst
The activity and practicality of Cu(II)-MP-bis(AMP)@boehmite catalyst in comparison with reported catalysts in the literatures are listed in Table 6 for coupling of Ph-OH with Ph-I. As monitored in Table 7, biphenyl ether was synthesized in superior yields when Cu(II)-MP-bis(AMP)@boehmite employed as catalyst than other catalysts. Therefore, Cu(II)-MP-bis(AMP)@boehmite catalyst is more effective than alternative catalysts in terms of practicality, reaction rate and isolated yield. Also, in some cases, non-recoverable homogeneous catalysts have been introduced for the formation of aromatic ethers (Table 7, entry 7). While, Cu(II)-MP-bis(AMP)@boehmite catalyst can be recycled over and over again.
Recycling ability and leaching study of the catalyst
Cu(II)-MP-bis(AMP)@boehmite catalyst can be isolated easily by centrifugation and recycled again for multifold times. For this issue, recoverability of Cu(II)-MP-bis(AMP)@boehmite was investigated in the coupling of Ph-O with Ph-I. At first, coupling of Ph-O with Ph-I was started under optimized conditions and after termination of the reaction, the residue catalyst was separated via centrifugation. Then, the divided catalyst was washed and then it was employed again in the next run for 6 cycles. As shown in Fig. 9, Cu(II)-MP-bis(AMP)@boehmite catalyst can be recycled frequently at minimum to 6 times in synthesis of biphenyl ether.
Recyclability of Cu(II)-MP-bis(AMP)@boehmite in the coupling of phenol with iodobenzen.
The copper leaching from Cu(II)-MP-bis(AMP)@boehmite in the reaction mixture was studied by AAS analysis. In order to this issue, the coupling reaction of Ph-O with Ph-I in the presence of Cu(II)-MP-bis(AMP)@boehmite was repeated and the catalyst was recovered and collected after completion of the reaction. Then, the amount of copper in the recovered catalyst (0.32 × 10−3 mol g−1) was compared with the unused catalyst (0.4 × 10−3 mol g−1) by AAS analysis which indicated that copper leaching of this catalyst is negligible (less than 0.01%).
The SEM images of Cu(II)-MP-bis(AMP)@boehmite after recovered and reused are shown in Fig. 10. The particle sizes and morphology of Cu(II)-MP-bis(AMP)@boehmite were compared to the fresh catalyst. As shown, the size and morphology of recovered and reused catalyst indicated an excellent similarly to the fresh catalyst.
SEM images of Cu(II)-MP-bis(AMP)@boehmite after recovery.
The heterogeneity of Cu(II)-MP-bis(AMP)@boehmite was authenticated by the hot filtration experiment. In order to this issue, the coupling reaction of Ph-O with Ph-I using Cu(II)-MP-bis(AMP)@boehmite catalyst was started and it was stopped after 30 min. In this step, 48% of biphenyl ether was formed. Then, the selected reaction was repeated and the catalyst was pick up after 30 min and the solution was permitted to proceed for 30 min again without catalyst. In this step, 51% of biphenyl ether product was obtained. it means that Cu(II)-MP-bis(AMP)@boehmite catalyst have heterogeneous nature and C–O coupling reactions are take place following heterogeneous conditions.
Experimental
Preparation of catalyst
Modified BNPs with (3-chloropropyl)trimethoxysilane (CPTMS@boehmite) was prepared matching to last reported method15. Also, MP-bis(AMP) was synthesized from condensation of 2-hydroxy benzaldehyde with 4,6-diaminopyrimidine-2-thiol14. Then, CPTMS@boehmite (1.0 g) was blended with MP-bis(AMP) (3 mmol) and stirred in reflux conditions of toluene for 72 h and MP-bis(AMP) ligand was attached on modified BNPs. The outcome solid (MP-bis(AMP)@boehmite) was centrifuged, washed via EtOH and dried at room temperature. Finally, for the preparation of the catalyst (Cu(II)-MP-bis(AMP)@boehmite), the MP-bis(AMP)@boehmite (0.5 g) was diffused in EtOH and blended with 1.0 mmol of Cu(NO3)2·9H2O. Then, the afforded mixture was stirred at 80 °C for 20 h.
Aromatic ethers formation catalyzed by Cu(II)-MP-bis(AMP)@boehmite
Aryl halide (1 mmol), phenol (1 mmol), KOH (5 mmol), and Cu(II)-MP-bis(AMP)@boehmite (30 mg, containing 2.12 mol% of Cu) were stirred in DMSO at 130 °C and the progression of the reaction was seen by TLC. After performing of the reaction, the reaction mix was make cold to room temperature. Then, the mixture was dilute with water, the remaining catalyst was cleared by ordinary filtration and washout with ethyl acetate. The filtered solution was extracted with ethyl acetate and water. The solution was dried upon Na2SO4 (2 g). Then the solvent was vaporized and pure ether derivatives were afforded.
Conclusion
In summary, boehmite NPs have been prepared in aqueous media and then a new Schiff base Cu-complex has been stabilized on the surface of BNPs (Cu(II)-MP-bis(AMP)@boehmite). This catalyst was evidenced using SEM imaging, WDX, EDS, AAS and TGA analysis, BET method, FT-IR spectroscopy, and XRD pattern. The yields of the obtained ethers were authenticated the good performance of Cu(II)-MP-bis(AMP)@boehmite in the C–O coupling reaction toward formation of diaryl ethers. Present method is practicable for an unlimited range of aryl halide derivatives of I, Br and Cl containing other functional groups with electron-withdrawing or electron-donating nature. Excellent stability and heterogeneous nature of Cu(II)-MP-bis(AMP)@boehmite were certified by hot filtration examination.
Data availability
Data available in article Supplementary Materiall; the data that supports the findings of this study are available in the Supplementary Material of this article.
References
Yang, Z., Wang, D., Ji, D., Li, G. & Zhao, X. Solvent-free synthesis of FeAPO-44 molecular sieves with CHA structures. Solid State Sci. 119, 106698 (2021).
Goyal, C. P. et al. Surface modification of ZnO nanowires with CuO: A tool to realize highly-sensitive H2S sensor. Phys. Solid State 63, 460–467 (2021).
Nikoorazm, M., Rezaei, Z. & Tahmasbi, B. Two Schiff-base complexes of copper and zirconium oxide supported on mesoporous MCM-41 as an organic–inorganic hybrid catalysts in the chemo and homoselective oxidation of sulfides and synthesis of tetrazoles. J. Porous Mater. 27, 671–689 (2020).
Toda, F. Solid state organic chemistry: Efficient reactions, remarkable yields, and stereoselectivity. Acc. Chem. Res. 28(12), 480–486 (1995).
Seo, T., Toyoshima, N., Kobota, K. & Lto, H. Tackling solubility issues in organic synthesis: Solid-state cross-coupling of insoluble aryl halides. J. Am. Chem. Soc. 143(16), 6165–6175 (2021).
Zhang, Y. & Riduan, S. N. Functional porous organic polymers for heterogeneous catalysis. Chem. Soc. Rev. 41, 2083–2094 (2012).
Balasubramanian, K. & Burghard, M. Chemically functionalized carbon nanotubes. Small 1(2), 180–192 (2005).
Nikoorazm, M., Moradi, P. & Noori, N. L-cysteine complex of palladium onto mesoporous channels of MCM-41 as reusable, homoselective and organic-inorganic hybrid nanocatalyst for the synthesis of tetrazoles. J. Porous Mater. 27, 1159–1169 (2020).
Nikoorazm, M., Noori, N., Tahmasbi, B. & Faryadi, S. A palladium complex immobilized onto mesoporous silica: A highly efficient and reusable catalytic system for carbon–carbon bond formation and anilines synthesis. Transit. Met. Chem. 42, 469–481 (2017).
Yarie, M., Zolfigol, M. A. & Saeidi-Rad, M. Tributyl(3-sulfopropyl)phosphonium hydrogen sulfate (TBSPHS) as a novel task-specific phosphonium ionic liquid: A robust catalyst for the synthesis of 1,5-dihydro-2H-pyrrol-2-ones. J. Mol. Liq. 249, 144–152 (2018).
Ghorbani-Choghamarani, A., Moradi, P. & Tahmasbi, B. Modification of boehmite nanoparticles with Adenine for the immobilization of Cu(II): Organic-inorganic hybrid nanocatalyst in organic reactions. Polyhedron 163, 98–107 (2019).
Mohammadi, M., Khodamorady, M., Tahmasbi, B., Bahrami, K. & Ghorbani-Choghamarani, A. Boehmite nanoparticles as versatile support for organic-inorganic hybrid materials: Synthesis, functionalization, and applications in eco-friendly catalysis. J. Ind. Eng. Chem. 97, 1–78 (2021).
Martausová, I. et al. Catalytic activity of advanced titanosilicate zeolites in hydrogen peroxide S-oxidation of methyl(phenyl)sulfide. Catal. Today 324, 144–153 (2019).
Moradi, P. & Hajjami, M. Magnetization of biochar nanoparticles as a novel support for fabrication of organo nickel as a selective, reusable and magnetic nanocatalyst in organic reactions. New J. Chem. 45, 2981–2994 (2021).
Moradi, P., Hajjami, M. & Tahmasbi, B. Fabricated copper catalyst on biochar nanoparticles for the synthesis of tetrazoles as antimicrobial agents. Polyhedron 175, 114169 (2020).
Moradi, P. & Hajjami, M. Magnetization of graphene oxide nanosheets using nickel magnetic nanoparticles as a novel support for the fabrication of copper as a practical, selective, and reusable nanocatalyst in C-C and C–O coupling reactions. RSC Adv. 11, 25867–25879 (2021).
Polshettiwar, V. et al. Magnetically recoverable nanocatalysts. Chem. Rev. 111, 3036–3075 (2011).
Nikoorazm, M., Moradi, P., Noori, N. & Azadi, G. L-arginine complex of copper on modified core–shell magnetic nanoparticles as reusable and organic–inorganic hybrid nanocatalyst for the chemoselective oxidation of organosulfur compounds. J. Iran. Chem. Soc. 467–478, 18 (2021).
Atashkar, B., Rostami, A., Gholami, H. & Tahmasbi, B. Magnetic nanoparticles Fe3O4-supported guanidine as an efficient nanocatalyst for the synthesis of 2H-indazolo[2,1-b]phthalazine-triones under solvent-free conditions. Res. Chem. Intermed. 3675–3681, 41 (2015).
Lim, C. W. & Lee, I. S. Magnetically recyclable nanocatalyst systems for the organic reactions. Nano Today 5, 412–434 (2010).
Qing, Yu. Z., Xia, W. C., Tian, Gu. X. & Li, C. Photoluminescent properties of boehmite whisker prepared by sol-gel process. J. Lumin. 106, 153–157 (2004).
Miri, A. & Ghorbani, F. Syntheses of Ag[Cu@Ag]\APTMS\boehmite as a photocatalyst for methylene blue degradation in batch and continuous flow systems under visible light. Environ. Nanotechnol. Monit. Manage. 16, 100493 (2021).
Khare, T. et al. Nano-boehmite induced oxidative and nitrosative stress responses in Vigna radiata L.. J. Plant Growth Regul. https://doi.org/10.1007/s00344-021-10303-8 (2021).
Hu, L., Fu, Z., Gu, X., Wang, H. & Li, Y. Strengthened interface as flame retarding belt: Compatibilized PLLA/PP blends by reactive boehmite nanorods. Polymer 228, 123879 (2021).
Kausar, A. A review of current knowledge and future trends in polymer/boehmite nanocomposites. J. Plast. Film Sheet. https://doi.org/10.1177/87560879211043558 (2021).
Abram, A. & Dražić, G. Structural and photocatalytic properties of hydrothermally-prepared boehmite/TiO2 coatings. Open Ceram. 7, 100153 (2021).
Ramírez, C., Belmonte, M., Miranzo, P. & Osendi, M. I. Reinforced 3D composite structures of γ-, α-Al2O3 with carbon nanotubes and reduced GO ribbons printed from boehmite gels. Materials 14, 2111 (2021).
Abdelkader, A., Hussien, B. M., Fawzy, E. M. & Ibrahim, A. A. Boehmite nanopowder recovered from aluminum cans waste as a potential adsorbent for the treatment of oilfield produced water. Appl. Petrochem. Res. 11, 137–146 (2021).
Tahmasbi, B., Ghorbani-Choghamarani, A. & Moradi, P. Palladium fabricated on boehmite as an organic-inorganic hybrid nanocatalyst for the C-C cross coupling and homoselective cycloaddition reactions. New J. Chem. 44, 3717–3727 (2020).
Ohta, Y., Hayakawa, T., Inomata, T., Ozawa, T. & Masuda, H. Novel nano boehmite prepared by solvothermal reaction of aluminum hydroxide gel in monoethanolamine. J. Nanopart. Res. 19, 232 (2017).
Bakherad, M. et al. Palladium-free and phosphine-free Sonogashira coupling reaction of aryl halides with terminal alkynes catalyzed by boehmite nanoparticle-anchored Cu(I) diethylenetriamine complex. Res. Chem. Intermed. 43, 7347–7363 (2017).
Zhao, Y., Frost, R. L., Martens, W. N. & Zhu, H. Y. Growth and surface properties of boehmite nanofibers and nanotubes at low temperatures using a hydrothermal synthesis route. Langmuir 23, 9850–9859 (2007).
He, T., Xiang, L. & Zhu, S. Different nanostructures of boehmite fabricated by hydrothermal process: Effects of pH and anions. Cryst. Eng. Commun. 11, 1338–1342 (2009).
Shen, S. C. et al. Steam-assisted solid wet-gel synthesis of high-quality nanorods of boehmite and alumina. J. Phys. Chem. C. 111, 700–707 (2007).
Hochepied, J. F., Ilioukhina, O. & Berger, M. H. Effect of the mixing procedure on aluminium (oxide)-hydroxide obtained by precipitation of aluminium nitrate with soda. Mater. Lett. 57, 2817–2822 (2003).
Chen, X. Y., Zhang, Z. J., Li, X. L. & Lee, S. W. Controlled hydrothermal synthesis of colloidal boehmite (γ-AlOOH) nanorods and nanoflakes and their conversion into γ-Al2O3 nanocrystals. Solid State Commun. 14, 368–373 (2008).
Jabbari, A., Tahmasbi, B., Nikoorazm, M. & Ghorbani-Choghamarani, A. A new Pd-Schiff-base complex on boehmite nanoparticles: Its application in Suzuki reaction and synthesis of tetrazoles. Appl. Organometal. Chem. 32, e4295 (2018).
Zhou, J. et al. N, N-dimethylformamide assisted facile hydrothermal synthesis of boehmite microspheres for highly effective removal of Congo red from water. J. Colloid Interface Sci. 583, 128–138 (2021).
Kim, S. M., Lee, Y. J., Jun, K. W., Park, J. Y. & Potdar, H. S. Synthesis of thermo-stable high surface area alumina powder from sol–gel derived boehmite. Mater. Chem. Phys. 104, 56–61 (2007).
Hou, H., Xie, Y., Yang, Q., Guo, Q. & Tan, C. Preparation and characterization of γ-AlOOH nanotubes and nanorods. Nanotechnology 16, 741–745 (2005).
Thiruchitrambalam, M., Palkar, V. R. & Gopinathan, V. Hydrolysis of aluminium metal and sol–gel processing of nano alumina. Mater. Lett. 58, 3063–3066 (2004).
Ghalkhani, M. & Salehi, M. Electrochemical sensor based on multi-walled carbon nanotubes–boehmite nanoparticle composite modified electrode. J. Mater. Sci. 52, 12390–12400 (2017).
Van Garderen, N., Clemens, F. J., Aneziris, C. G. & Graule, T. Improved γ-alumina support based pseudo-boehmite shaped by micro-extrusion process for oxygen carrier support application. Ceram. Int. 38, 5481–5492 (2012).
Huu Phan, T. N., Lee, J., Shin, H. & Sohn, J. H. Oxidative dehydrosulfurative carbon–oxygen cross-coupling of 3,4-dihydropyrimidine-2-thiones with aryl alcohols. J. Org. Chem. 86, 5423–5430 (2021).
Szpera, R. et al. Synthesis of fluorinated alkyl aryl ethers by palladium-catalyzed C-O cross-coupling. Org. Lett. 22(16), 6573–6577 (2020).
Chen, G., Chan, A. S. C. & Kwong, F. Y. Palladium-catalyzed C-O bond formation: Direct synthesis of phenols and aryl/alkyl ethers from activated aryl halides. Tetrahedron Lett. 48(3), 473–476 (2007).
Al-Masum, M. & Alalwan, H. A. Microwave irradiated palladium-catalyzed cascade type cross coupling of phenols and halides for the synthesis of polyphenolic ethers. Int. J. Org. Chem. 10, 135–143 (2020).
Nejati, K., Ahmadi, S., Nikpassand, M., Kheirollahi Nezhad, P. D. & Vessally, E. Diaryl ethers synthesis: Nano-catalysts in carbon-oxygen cross-coupling reactions. RSC Adv. 8, 19125–19143 (2018).
Tahmasbi, B. & Ghorbani-Choghamarani, A. Magnetic MCM-41 nanoparticles as support for the immobilization of organometallic catalyst of palladium and its application in C-C coupling reactions. New J. Chem. 43, 14485–14501 (2019).
Tahmasbi, B. & Ghorbani-Choghamarani, A. The first report on the direct supporting of Pd-arginine complex on boehmite nanoparticles and its application in the synthesis of 5-substituted tetrazoles. Appl. Organometal. Chem. 31, e3644 (2017).
Nikoorazm, M., Tahmasbi, B., Gholami, S. & Moradi, P. Copper and nickel immobilized on cytosine@MCM-41: As highly efficient, reusable and organic–inorganic hybrid nanocatalysts for the homoselective synthesis of tetrazoles and pyranopyrazoles. Appl. Organomet. Chem. 34, e5919 (2020).
Tahmasbi, B. & Ghorbani-Choghamarani, A. Pd(0)-Arg-boehmite: As reusable and efficient nanocatalyst in Suzuki and Heck reactions. Catal. Lett. 147, 649–662 (2017).
Zhang, C., Li, C., Bai, J. & Li, H. A Cu nanoparticle embedded in electrospundoped carbon nanofibers as efficient catalysts for Ullmann O-arylation of aryl halides with various phenols. Catal. Lett. 145, 1764–1770 (2015).
Jammi, S. et al. CuO nanoparticles catalyzed C-N, C-O, and C-S cross-coupling reactions: Scope and mechanism. J. Org. Chem. 74, 1971–1976 (2009).
Kidwai, M., Mishra, N. K., Bansal, V., Kumar, A. & Mozumdar, S. Cu-nanoparticle catalyzed O-arylation of phenols with aryl halides via Ullmann coupling. Tetrahedron Lett. 48, 8883–8887 (2007).
Mousavi, M. S. A., Kassaee, M. Z. & Eidi, E. Magnetically recyclable nano copper/chitosan in O-arylation of phenols with aryl halides. Appl. Organometal. Chem. 33, e5042 (2019).
Nasrollahzadeh, M., Maham, M., Rostami, A., Bagherzadeh, M. & Sajadi, S. M. Barberry fruit extract assisted in situ green synthesis of Cu nanoparticles supported on a reduced graphene oxide–Fe3O4 nanocomposite as a magnetically separable and reusable catalyst for the O-arylation of phenols with aryl halides under ligand-free conditions. RSC Adv. 5, 64769–64780 (2015).
Wang, Y. et al. Cu2O/SiC as efficient catalyst for Ullmann coupling of phenols with aryl halides. Chin. J. Catal. 38, 658–664 (2017).
Chang, J. W. W. et al. Copper-catalyzed Ullmann coupling under ligand- and additive-free conditions. Part 1: O-arylation of phenols with aryl halides. Tetrahedron Lett. 49, 2018–2022 (2008).
Arundhathi, R., Sreedhar, B. & Parthasarathy, G. Highly efficient heterogenous catalyst for O-arylation of phenols with aryl halides using natural ferrous chamosite. Appl. Clay Sci. 51, 131–137 (2011).
Acknowledgements
Pecuniary support for this work by the research affairs of Islamic Azad University, Qeshm Branch, Qeshm, Iran is gratefully acknowledged. Also, authors appreciate Ilam University and Bu-Ali Sina University for pecuniary support of this research project.
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A.J.: Funding acquisition, Supervision, Project administration, Conceptualization, Resources. P.M.: Methodology, Validation, Investigation. M.H.: Supervision, Writing-review & editing. B.T.: Validation, Writing—original draft.
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Jabbari, A., Moradi, P., Hajjami, M. et al. Tetradentate copper complex supported on boehmite nanoparticles as an efficient and heterogeneous reusable nanocatalyst for the synthesis of diaryl ethers. Sci Rep 12, 11660 (2022). https://doi.org/10.1038/s41598-022-15921-0
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DOI: https://doi.org/10.1038/s41598-022-15921-0
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