Abstract
The occurrence of phlogopite and amphibole in mantle ultramafic rocks is widely accepted as the modal effect of metasomatism in the upper mantle. However, their simultaneous formation during metasomatic events and the related sub-solidus equilibrium with the peridotite has not been extensively studied. In this work, we discuss the geochemical conditions at which the pargasite-phlogopite assemblage becomes stable, through the investigation of two mantle xenoliths from Mount Leura (Victoria State, Australia) that bear phlogopite and the phlogopite + amphibole (pargasite) pair disseminated in a harzburgite matrix. Combining a mineralogical study and thermodynamic modelling, we predict that the P–T locus of the equilibrium reaction pargasite + forsterite = Na-phlogopite + 2 diopside + spinel, over the range 1.3–3.0 GPa/540–1500 K, yields a negative Clapeyron slope of -0.003 GPa K–1 (on average). The intersection of the P–T locus of supposed equilibrium with the new mantle geotherm calculated in this work allowed us to state that the Mount Leura xenoliths achieved equilibrium at 2.3 GPa /1190 K, that represents a plausible depth of ~ 70 km. Metasomatic K-Na-OH rich fluids stabilize hydrous phases. This has been modelled by the following equilibrium equation: 2 (K,Na)-phlogopite + forsterite = 7/2 enstatite + spinel + fluid (components: Na2O,K2O,H2O). Using quantum-mechanics, semi-empirical potentials, lattice dynamics and observed thermo-elastic data, we concluded that K-Na-OH rich fluids are not effective metasomatic agents to convey alkali species across the upper mantle, as the fluids are highly reactive with the ultramafic system and favour the rapid formation of phlogopite and amphibole. In addition, oxygen fugacity estimates of the Mount Leura mantle xenoliths [Δ(FMQ) = –1.97 ± 0.35; –1.83 ± 0.36] indicate a more reducing mantle environment than what is expected from the occurrence of phlogopite and amphibole in spinel-bearing peridotites. This is accounted for by our model of full molecular dissociation of the fluid and incorporation of the O-H-K-Na species into (OH)-K-Na-bearing mineral phases (phlogopite and amphibole), that leads to a peridotite metasomatized ambient characterized by reduced oxygen fugacity.
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Introduction
Phlogopite [KMg3AlSi3O10(OH)2] is a common hydrous mineral that occurs in ultramafic-alkaline igneous rocks, including kimberlites, aillikites, orangeites, and carbonatites1,2,3,4. This mineral is frequently observed in cratonic mantle (garnet- and spinel- bearing) xenoliths hosted in rocks of the diatremic association, such as kimberlites, and occurs mainly along with amphibole, another hydrous mineral, in ultramafic rocks formed by cumulate processes5,6, in peridotite massifs7 and in off-craton mantle spinel-bearing xenoliths8,9,10. In particular, phlogopite in lherzolites and harzburgites from off-craton mantle xenoliths that achieved equilibrium in the spinel stability field is scarce (rarely > 1%9), whereas it becomes modally relevant in pyroxenite and wehrlite lithotypes6,11. The presence of phlogopite and/or amphibole in an anhydrous-dominated ultramafic system is widely accepted to mark the occurrence of “modal mantle metasomatism”12, as phlogopite and amphibole crystallization is mainly due to the interaction between metasomatic K(Na)-OH rich “fluids/melts” (e.g., alkaline mafic melts) and variously depleted peridotites, in a porous flow regime13,14,15. Such metasomatic reactions have extensively modified the sub-continental lithospheric mantle (SCLM) since the Archean16,17,18,19,20,21,22.
The metasomatic processes take place even though K-Na-OH are chemical species showing modest compatibility or even incompatibility with the peridotite minerals (i.e., olivine, orthopyroxene, clinopyroxene, spinel or garnet) in geochemical reactions. In the petrological system of the upper mantle consisting of a source-melt-residuum, the mineral/melt partitioning of K(Na)-OH shifts towards the melt, i.e., D = Cmineral/Cmelt < 0.1 (where D = distribution coefficient; C = concentration). Only Na is considered a mildly incompatible element in pyroxenes, yielding a D of ~ 0.1 at < 1.5 GPa, which increases with higher pressure conditions23.
Phlogopite (and amphibole) melting is often invoked to account for a high potassium content in mantle-derived melts24,25,26. For instance, PIC (Phlogopite-Ilmenite-Clinopyroxene) and MARID (Mica-Amphibole-Rutile-Ilmenite-Diopside) mantle assemblages are supposed to account for the origin of alkali rich mafic–ultramafic magmas20,27. Conversely, the preservation of phlogopite and amphibole during low degree partial melting induces significant depletion of potassium in the derived melts28.
Many experimental studies on natural peridotite deal with either phlogopite15 or amphibole29 stability and ascribe the occurrence of these two minerals to a recent metasomatism6. Such studies are generally focused on understanding the relationship between minerals and magma source region24,29,30, as well as unravelling the nature of the metasomatic fluids/melts in the upper mantle6,7,13,21,31. Although the stability of the hydrous phases affects both mantle solidus and magma genesis24,30, the sub-solidus equilibrium of the phlogopite + amphibole system with the anhydrous peridotite minerals has attracted moderate attention and the experimental confirmation of this paragenesis in ultramafic systems is only provided by solidus reactions involving fluids (see Safonov et al.15 for a review).
In this work, we explored the physical–chemical mantle conditions (P, T, ƒO2) at which the phlogopite + amphibole system stabilized. In particular, we investigated two mantle xenoliths from Mount Leura (Victoria State, southeast Australia) in which phlogopite (LE7[phl]) and phlogopite + amphibole (LE5[phl+amph]) occur. They are thought to be products of an early metasomatism, which subsequently underwent textural (re) equilibration with primary anhydrous minerals. We used laboratory characterizations complemented by theoretical modelling to determine: (i) the P–T conditions at the formation of the peridotite + phlogopite + amphibole assemblage; (ii) the stability conditions of potential metasomatic fluids in a K-Na-OH peridotite ambient; (iii) the related redox conditions driving the reactions.
Sample description and petrography
The two samples were collected in Cenozoic basanites from Mount Leura, one of the richest xenolith sites of the Newer Volcanic Province (4.5 Ma-5000 B.P), in western Victoria state, southeast Australia32,33. Peridotite are the predominant lithotype of xenoliths in the Newer Volcanic Province. In particular, spinel lherzolites can be found in 28 localities (e.g., Mounts Porndon, Leura, Noorat, etc.32,34). These xenoliths are fragments from the shallow portion of the continental lithospheric mantle, carried to the surface by a relatively recent activity of the Newer Volcanic Province32, as a late effect of the continental extension related to the breakup of Gondwana and opening of the Tasman Sea32,34.
Both xenoliths (LE7[phl] and LE5[phl+amph]) are sub-rounded in shape, ~ 7 cm in diameter, apparently free of host magma infiltrations, though infiltrations of exotic (e.g., magmatic) fluids/melts cannot be excluded.
Their mineral phase proportions were estimated by mass balance calculations between bulk rock and mineral phase compositions, using a non-weighted least-squares regression of the major element oxides (Table 1).
Given that the xenoliths under study contain a spinel peridotite assemblage (olivine + clinopyroxene + orthopyroxene + spinel) with less than 5% clinopyroxene (Table 1), they are classified as harzburgites (according to the IUGS scheme35). Both harzburgites bear observable amounts of phlogopite: 1.9% in LE7[phl] and 1.2% in LE5[phl+amph], whereas amphibole (1.4%) occurs only in LE5[phl+amph] (Table 1).
Following the Mercier and Nicolas41 nomenclature, both samples exhibit protogranular texture with large olivine (2–3 mm in size) characterized by kink-bands, and coarse orthopyroxene (1–2 mm in size) with lobate grain boundaries (Fig. 1). Primary spinel and clinopyroxene are smaller (~ 0.1–0.3 mm in size), and anhedral in shape (Fig. 1). LE7[phl] harzburgite is devoid of small-grained reaction patches and of any clear evidence of host magma infiltrations. In LE7[phl], phlogopite crystals (~ 0.1–0.5 mm in size) occur either as disseminated grains in olivine rich domains, or aligned along former fractures and grain boundaries of olivine and orthopyroxene (Fig. 1a-f). In back-scattered electron (BSE) images, phlogopite show a homogeneous brightness, indicating lack of zoning with respect to major elements (Fig. 1c, e). In LE5[phl+amph], phlogopite occurs as large lobate grains (~ 0.1–0.3 mm in size) in harzburgite matrix (Fig. 1g-j) and as small crystals associated with spinel, clinopyroxene and amphibole (Fig. 1k, l). Amphibole crystals are larger than phlogopite (~ 0.5–1.5 mm in size), anhedral/lobated in shape, like the coexisting peridotite minerals and phlogopite (Fig. 1k-n). In LE5[phl+amph] some amphibole crystals are locally surrounded by fine-grained clinopyroxene, olivine, spinel and glass (Fig. 1k, l).
In both xenoliths, BSE images of phlogopite and amphibole grains, even those close to or embedded in fine-grained reaction zones, show a quasi-homogeneous degree of brightness, thus suggesting a modest chemical zoning (Fig. 1l, n).
Results
Xenolith bulk composition
LE5[phl+amph] has a higher FeO/MgO ratio and is slightly richer in CaO, Na2O, K2O and Al2O3 than LE7[phl], in keeping with the formation of amphibole, in addition to phlogopite (Table 1), and their abundance. The reaction zones did not significantly modify the xenolith’s bulk chemistry. Both samples show large contents of compatible/moderately incompatible minor elements (Ni: 2191–2529 ppm; Cr2O3: 2051- 2900 ppm; and Mn: 0.11–014 wt% MnO) and are highly depleted of incompatible major element oxides (Al2O3: 0.21–0.69 wt%; TiO2: 0.02–0.06 wt%). Modal and chemical compositions of the two samples agree with harzburgite residues’, as proven by 22–25% of anhydrous, or hydrous (1 wt% H2O), melting of fertile lherzolites (PM-DMM-like) at ~ 2 GPa in various experimental studies42,43,44,45,46.
Mineral composition
Major element compositions of peridotite minerals, phlogopite and amphibole are set out in Supplementary Tables 1–6.
The composition of the primary minerals in both samples is homogenous at grain scale, but with an increasing variability at thin-section scale.
Forsterite content [Fo = Mg/(Mg + Fe)mol × 100] in olivine ranges from 89.8 to 91.4 in LE7[phl], and from 89.1 to 93.0 in LE5[phl+amph]; the latter larger range may be attributable to a more pervasive late stage metasomatism47,48. NiO content lies in the interval 0.33–0.45 wt%.
In both samples, orthopyroxene far from the reaction zones show larger Mg# [Mg/(Mg + Fe) × 100, cations per formula unit; 90.7–93.6] than coexisting olivine. Such a figure agrees with those predicted by the equilibrium partitioning of Mg and Fe between these phases36. Al2O3 and Cr2O3 vary from 1.08 to 2.90 wt% and from 0.33 to 0.88 wt%, respectively. Ti and Na are negligible. The reported compositional ranges are consistent with a residual character of the rock46.
In both samples, clinopyroxene abundance is ≤ 4% (Table 1), with Mg# from 90.4 to 92.9. The TiO2 content is lower than 0.40 wt%, whereas Al2O3 and Cr2O3 lie in the range of 3.08–4.99 wt% and 1.20–2.40 wt%, respectively. The iron-magnesium partitioning between clinopyroxene and orthopyroxene is close to its equilibrium value36 (D = 1.09 ± 0.14).
Spinel have compositions on the (Mg,Fe)Al2O4-(Mg,Fe)Cr2O4 join, with Mg > Fe2+, Cr > Al and a negligible Ti content. Despite their textural position, the large spinel crystals in LE5[phl+amph] (Fig. 1e) share similar compositions, with Cr#Sp [Cr#Sp = Cr/(Cr + Al) × 100] of 48.3–59.0. In addition, the combination of Cr#Sp with the Fo content of primary olivine points to a high-degree mantle melting (LE7[phl]: ~ 22–25%; LE5[phl+amph]: ~ 25–28%; Fig. 2), in agreement with the inferences from the bulk rock42,43,44,45,46.
The Cr content in spinel, orthopyroxene and clinopyroxene is such that Cr#Sp > Cr#Cpx > Cr#Opx (Supplementary Tables 2–4). This suggests that the compositional evolution of spinel results from a Cr-Al exchange with coexisting pyroxenes during mantle melting49,50,51, thus promoting an increase of the Cr/Al ratio in spinel and the formation of Al-bearing coexisting pyroxene52.
Phlogopite, as the only hydrous mineral species (LE7[phl]) or coexisting with amphibole (LE5[phl+amph]), displays minor oscillations of its major element contents. In particular: Mg# 90.7–92.8; TiO2 > 1.5 wt%; Cr2O3 > 0.8 wt%. Phlogopite in LE5[phl+amph] exhibit slightly higher contents of TiO2 and Na2O (Supplementary Table 5) than LE7[phl]. Phlogopite in LE7[phl] is richer in F (0.119–0.394 wt%), but poorer in Cl (0.020–0.056 wt%) with respect to LE5[phl+amph] (F: 0.110–0.210 wt%; Cl: 0.048–0.073 wt%).
Large amphibole crystals in LE5[phl+amph] (Fig. 1g, i) exhibit (i) Mg# (89.5–90.7), i.e., in the range of the values recorded for the co-existing olivine, orthopyroxene and clinopyroxene, (ii) FeOtot, TiO2 and Cr2O3 3.35–3.82, 1.48–3.12 and 1.50–2.39 wt%, respectively. F and Cl are observed in the intervals 0.100–0.300 and 0.040–0.068 wt%, respectively. Amphibole crystals, without evidences of reaction rims, were extracted for in-situ Mössbauer spectroscopy (SMS) and single crystal diffraction experiments. Many amphibole grains show reaction rims with evidence of late stage trasformation32,34; the Mg# values range from 86.9 to 90.1, with large zoning in FeOtot (3.37–4.62 wt%) and TiO2 (1.76–3.47 wt%) (Supplementary Table 6). Trace element abundances in clinopyroxene, amphibole and phlogopite, determined by LA-ICP-MS (see “Methods”), are set out in Supplementary Table 7. The chondrite-normalized53 Rare Earth Element (REE) signatures of clinopyroxenes in both samples are very similar to each other and to the ones of large amphibole grains of LE5[amph+phl] (Fig. 3). They all exhibit enriched patterns with a weakly positive slope between LaN and NdN, followed by a quasi-flat trend of Middle Rare Earth Elements (MREE)N, and then by a steady decrease of Heavy Rare Earth Elements (HREE)N.
Like amphibole, phlogopite in both samples incorporate Nb (and Ta) more efficaciously than the coexisting clinopyroxene. In contrast, REE abundances are very small, and LREE lie below the detection limit (0.1 ppm; Supplementary Table 7). Phlogopite are observed to host also Cs, Rb, Ba, Ni and Cr.
Fe3+/Fetot determination
Phlogopite and amphibole contain both ferric and ferrous iron, whose proportions are related to the oxygen fugacity conditions54,55. The Mössbauer spectroscopy provides measurements of the Fe3+ and Fe2+ proportions, but there are some limitations due to the amount of sample required. In our case, amphibole and phlogopite were not sufficient for conventional Mössbauer measurements (even using a micro-source), but amphibole crystals exhibited a size suitable for synchrotron Mössbauer spectroscopy (SMS). Unfortunately, the thinness of the phlogopite crystals did not allow reliable measurements even with the latter.
Figure 4 shows the SMS absorption spectrum of an amphibole crystal extracted from the LE5[phl+amph] xenolith. The observed Mössbauer absorption pattern is typical of a paramagnetic silicate without impurities and can be satisfactorily modelled by three quadrupole doublets. Two quadrupole doublets (assigned to Fe2+) were modelled with an isomer shift (IS) value of 1.1 mm/s, and quadrupole splitting (QS) values of 1.6 mm/s and 2.8 mm/s. The third one, with IS of 0.39 mm/s and QS of 0.93 mm/s, was ascribed to Fe3+. Such assignments agree with the vast literature on amphiboles55,56,57,58. The Fe3+ proportion determined from direct measurement of the absorption area is ~ 51% Fetot, which becomes ~ 46% if the corrective strategy of Dyar et al.56 is adopted, with an estimated 2σ-uncertainty of about ± 6%.
With reference to the octahedrally coordinated M(1), M(2), M(3) sites and the distorted eight-coordinated M(4) site of the amphibole structure, Fe3+ was ascribed to M(2), in agreement with literature59,60. The site attribution of Fe2+ is more controversial because several different partitioning schemes have been proposed so far. For instance, in the case of the calcic tremolite-actinolite series, Burns and Greaves55 ascribed the Fe2+ doublets with QS of 1.7–1.9 mm/s and 2.8–2.9 mm/s to the occurrence of Fe2+ at M(2) and M(1), respectively. Other authors agreed to assign the doublet with the lowest QS to Fe2+ in M(2), but indicated other assignments for the doublet with the highest QS, suggesting an irresolvable combination of Fe2+ at [M(1),M(3)] (e.g., Gunter et al.59).
As to tremolite, fibrous cummingtonite, grunerite (namely amosite) and anthophyllite, Bancroft et al.61,62, Hafner and Ghose63, Goldman and Rossman64, and Stroink et al.65 attributed the Fe2+ doublets with QS of 1.5–1.8 mm/s to M(4), and those with QS of 2.6–2.8 mm/s to an irresolvable combination of [M(1),M(2),M(3)].
In our case, the Mössbauer results, complemented by chemical and structural data, confirm that Fe3+ is located at the M(2) site and suggest that Fe2+ is distributed over M(1) and M(4), with preference for the former (Fig. 4). Accordingly, the Fe2+ doublet with QS of 1.6 mm/s (19% Fetot) is assigned to M(4), and Fe2+ with QS of 2.8 mm/s (30% Fetot) to M(1).
Single crystal structure characterization
Both xenoliths contain texturally equilibrated amphibole and/or phlogopite crystals of suitable size for single crystal X-ray diffraction experiments.
Amphibole and phlogopite structures’ details from structure refinements are reported in Supplementary Tables 8–10. The crystal-chemical formulae of the hydrous phases were calculated by combining structure information with the chemical compositions resulting from the average of 8, 5 and 12 wavelength dispersive X-ray spectroscopy analysis points on LE7[phl]-phlogopite, LE5[phl+amph]-phlogopite and LE5[phl+amph]-amphibole specimens, respectively.
In amphibole, hydroxyl groups can be partially replaced by oxygen atoms (Oxo component), thus affecting the distance between the octahedral sites M(1) and M(2). Following Oberti et al.66, who correlated the M(1)-M(2) bond length to the degree of OH ↔ O substitution, we measured the M(1)-M(2) distances in the range 3.121–3.127 Å, corresponding to 0.83–0.94 Oxo per formula unit (a.p.f.u.), i.e. about 42–47% of O replacing OH per site. Taking into account the total content of the iron oxide, the Fe2+ and Fe3+ proportions determined by SMS, and the Oxo replacement, we propose the following average crystal-chemical formula for the LE5[phl+amph]-amphibole:
which, on the basis of the current nomenclature of the amphibole super-group67, corresponds to pargasite.
As to phlogopite crystals, we were not able to carry out experimental determinations of the Fe3+/Fetot ratio. We chose to overcome this difficulty using the ratio obtained from amphibole. In our opinion such an approximation is acceptable because:
(i) the structural differences between these two minerals are not expected to have any relevant influence on the Fe oxidation state;
(ii) phlogopite and amphibole, which coexist, are assumed to have formed under the same equilibrium conditions;
(iii) mica crystals from the two xenoliths share very similar compositions.
The results obtained from structure refinements of phlogopite were compared with earlier determinations for mica of similar compositions (see the compilation of Brigatti et al.68). This led us to conclude that the phlogopite crystals under investigation do not show any evidence of vacancy occurrence in the octahedrally- and tetrahedrally-coordinated sites.
The crystal-chemical formulae of LE7[phl]/LE5[phl+amph]-phlogopite crystals were calculated by setting the sum of the octahedrally- and tetrahedrally-coordinated cations equal to 7 and fulfilling electroneutrality by the replacement of OH- with O2-. In doing so, both phlogopite samples exhibit a degree of de-hydroxylation of ~ 20% per site, corresponding to ~ 0.40 a.p.f.u., as shown by the following crystal-chemical formulae:
LE7[phl]-phlogopite:
LE5[phl+amph]-phlogopite:
Discussion
In many mantle xenolith suites, phlogopite and amphibole occur separately in time and space, and are associated with two distinct types of metasomatism (e.g., silicate versus carbonatite melts: West Eifel, Germany6; Ichinomegata, Japan69).
On the contrary, the two hydrous phases in Mount Leura’s samples are supposed to have formed simultaneously during the same metasomatic event. They might have achieved equilibrium with the primary anhydrous minerals (i.e., olivine, orthopyroxene and clinopyroxene) prior to the last-stage metasomatic event occurrence, which is likely related to host basalt infiltration that locally perturbed the original chemical and textural features (Supplementary Table 1–6; Table 1; Fig. 1).
Inter-mineral trace element equilibrium
Once equilibrium is achieved (simultaneous crystallization and sub-solidus re-arrangement), the observable inter-mineral trace element is expected to approximately follow the ideal coefficients (Di = Ci mineral1/Ci mineral2). Clinopyroxene, which in both xenoliths share the same chondrite normalized REE profile and LREE zoning, and coexisting amphibole yield MREE and HREE partitioning coefficients in agreement with those measured at equilibrium (Fig. 3; amphibole/clinopyroxene DREE: MREE ~ 1.3; HREE ~ 1.1 in silicate ultramafic system70). Equilibrium between amphibole and phlogopite (and clinopyroxene) was assessed using elements of different geochemical affinities: Zr-Ti (High Field Strength Elements-HFSE), Sr (Large Lithophile Element-LILE) and F-Cl (halogens). Zr is an element ranging from mildly incompatible to compatible and is preferentially hosted by amphibole rather than clinopyroxene and phlogopite (Table 2). The Zr partitioning coefficient of the phlogopite/clinopyroxene pair from Mount Leura xenoliths is in the narrow range of 0.22–0.51, close to the upper limit experimentally observed, but in agreement with those measured on natural samples (Table 2). The amphibole/phlogopite DZr values, obtained for the samples under investigation, approach those from experiments at equilibrium on a mineral/basaltic melt system (Table 2) and overlap those observed in amphibole-phlogopite bearing mantle xenoliths (Table 2).
In the case of Ti, amphibole/phlogopite DTi is measured in the range 0.46–0.89, in agreement with experimental data by Adam and Green70 and Moine et al.71 (Table 2). Therefore, even if the coexistence of amphibole and phlogopite in the LE5[phl+amph] sample is texturally affected by last stage metasomatism, the inter-mineral partition coefficients confirm that Zr and Ti attained the equilibrium conditions in the coexisting hydrous minerals and Mount Leura harzburgite matrix (Table 2).
As to Sr, our samples yield amphibole/clinopyroxene DSr and amphibole/phlogopite DSr larger than earlier experimental determinations, whereas phlogopite /clinopyroxene DSr is close to equilibrium measurements (Table 2). This suggests a mobilization and re-distribution of Sr during last stage metasomatism, and the amphibole seem to be more affected than phlogopite.
The halogen concentration in coexisting amphibole and phlogopites is a marker of the nature of the metasomatic melt/fluid that, reacting with peridotite, led to the hydrous phases. Experiments on F and Cl partitioning between amphibole, phlogopite and basanite melts in equilibrium with peridotite72,73 show that fluorine is highly incompatible with peridotite minerals, but compatible with amphibole and phlogopite, the latter being the preferred host (amphibole/phlogopite DF ~ 0.5–0.66; Table 2). Chlorine, in turn, is incompatible in peridotite phases but mildly incompatible with amphibole and phlogopites (Table 2). In our samples, amphibole core and phlogopite (both core and rim) have F and Cl contents whose partitioning coefficients (observed: amphibole/phlogopite DF: 0.49–0.90; amphibole/phlogopite DCl: 0.42–0.93) approach those expected at equilibrium (Table 2), whereas amphibole rim seems to record the last metasomatic event, through a remarkable mobility of both F and Cl (observed: amphibole/phlogopite DF ~ 2.2–2.5; amphibole/phlogopite DCl ~ 1.5–3.5). Altogether, the trace element partitioning may be compatible with the following scenery:
(i) phlogopite and amphibole crystals formed through the same metasomatic reaction, and equilibrated with the peridotite mineral assemblage and (ii) the interaction of the xenoliths with the host basalt mainly affected amphibole.
Therefore, the occurrence of phlogopite and phlogopite + amphibole in the harzburgitic mineral assemblage of the Mount Leura xenoliths was also studied to track the geothermal state and redox conditions of the peridotite system, and to formulate the fundamental reactions that may account for such a phase composition.
Geothermal state and redox conditions
Estimates of oxygen fugacity (fO2) are important to predict stable phase assemblages in the mantle, in particular OH-bearing phases (amphibole and phlogopite).
The redox conditions of phlogopite + amphibole-bearing peridotite of this mantle domain were assessed through a fO2 marker calculated from the olivine + orthopyroxene + spinel assemblage, according to the end-member reaction: 6 Fe2SiO4 (fayalite) + O2 = 3 Fe2Si2O6 (orthopyroxene) + 2 Fe3O4 (spinel), at given P–T conditions37,78,79.
The equilibrium temperature of this peridotite mineral assemblage was determined using the two-pyroxene geothermometer by Brey and Köhler36, and the olivine-spinel geothermometers by Ballhaus et al.37 and Jianping et al.39. For such an estimate, the equilibrium pressure was set to 1.5 GPa, which lies in the pressure range of the spinel stability. Both samples were equilibrated at similar thermal conditions with an average temperature of ~ 1230 K, though LE7[phl] recorded slightly higher T-values (TOpx-Cpx: 1313 ± 15 K; TOl-Sp 1280 ± 100 K), with respect to LE5[phl+amph] (TOpx-Cpx: 1175 ± 32 K; TOl-Sp 1151 ± 83 K) (Table 1).
Several studies calibrated the O2-fugacity buffered by the olivine-orthopyroxene-spinel mineral equilibrium39,79,80 as a function of spinel composition and P–T conditions. Oxygen fugacity estimates refer to the fayalite-magnetite-quartz (FMQ) buffer (calibration of Frost40) and are reported in terms of Δ(FMQ), where Δ(FMQ) = log(fO2)rock–log(fO2)FMQ.
Here, we chose the formulation by Wood39 and applied the Wood and Virgo81 correction to determine the Fe3+/Fetot ratio in spinel, using data from electron microprobe analyses.
The Wood and Virgo81 correction (validated by Davis et al.54), substantially improves both accuracy and precision of the Fe3+/Fetot ratio in spinel from EMPA determinations. In particular, such a correction is very effective whenever Fe3+/Fetot is required at the grain scale, and provided that secondary oxidation did not occur during the spinel thermal history subsequent to its crystallization. In fact, if spinel crystals undergo oxidation (i.e., increasing environmental oxygen fugacity), they become non- stoichiometric82,83. In our case, no evidence of oxidation was observed, neither in spinel nor in other coexisting phases, and the Δ(FMQ) values from the spinel composition, using EMPA data and adopting the Wood and Virgo81 correction, coherently point to a homogeneous and reducing environment.
Uncertainties in calculated fO2 were estimated as ~ 0.4 log units, at fO2 lower than about FMQ-1 (see Davis et al.54). Notably, LE7[phl] and LE5[phl+amph] harzburgites recorded almost identical fugacity conditions [–1.83 ± 0.36 and –1.97 ± 0.35, in terms of Δ(FMQ); Table 1], which reflects similar and reducing conditions, well in the graphite stability field if compared with typical mantle spinel peridotite83. As a consequence, we conclude that LE7[phl] and LE5[phl+amph] shared the same mantle conditions, further reflected by the chemical similarity of the mica crystals in both samples (Supplementary Tables 5–6).
Phlogopite-amphibole stability model
The stability of phlogopite and phlogopite + amphibole in the peridotite system is governed by the key-equation of equilibrium, i.e.:
where ν and G are stoichiometric coefficients and molar Gibbs energy of the involved phases, respectively. Under the constraints of (1), the occurrence of pargasite, phlogopite, spinel, clinopyroxene and olivine in the LE5[phl+amph] harzburgite was modelled by the following approximate equation:
where we simplified the mineral phases by means of their end members:
pargasite [NaCa2(Mg4Al) (Si6Al2)O22(OH)2], forsterite [Mg2SiO4], spinel [MgAl2O4], diopside [CaMgSi2O6] and aspidolite [NaMg3(AlSi3)O10(OH)2].
This allowed us to estimate the P–T equilibrium-like conditions of LE5[phl+amph] (hereafter: equilibrium conditions tout court). The calculations related to (2) were carried out under the constraint provided by Eq. (1), splitting the Gibbs energy into two contributions: an integration along an isotherm and an integration along an isobar, as discussed by Curetti et al.84. We chose to develop our calculations following two general principles: (i) using as few phases as possible to model Eq. (2), in order to limit the uncertainty due to the experimental error on the observables involved in the calculations; (ii) selecting literature data, for which the experimental uncertainties are comparatively small. Calorimetric and thermo-elastic data of the involved mineral phases are set out in Supplementary Table 11. In particular, thermo-elastic data were chosen paying special care to their uncertainties, to minimize the error that propagates on the energy deformation calculated along the related isobar (Supplementary Table 11). ΔG, i.e., the Gibbs energy difference between the left-hand side member and right-hand side member of (2), was split into two parts: (i) ΔGs-t, which accounts for all contributions (static and thermal components) except for configuration entropy; (ii) ΔGconf, which expresses the configuration entropy contribution. Preliminary tests were performed using 5 × 5 × 5 supercells, semi-empirical potentials and lattice dynamics via the GULP code85 to model the effects induced by cation order–disorder in the minerals under investigation. We estimated that ΔGs-t changes comparatively little (~ 5–7%) with respect to the end-members, if the mineral compositions observed in the present investigation are used. ΔGconf, in turn, affects ΔG by 35–50%, in the range from 800 to 1400 K. For this reason, we chose to determine ΔGs-t from end-members, and ΔGconf from the crystal-chemical results obtained by structure refinements and Mössbauer spectroscopy. For olivine, clinopyroxene and spinel we used the chemical compositions (Supplementary Tables 1, 3–4) from EMPA, and assumed in each crystal structure the cation partitioning that maximizes configuration entropy.
The physically sound P–T locus fulfilling Eqs. (1–2) stretches over the interval 1.3–6.1 GPa/540–1500 K (Fig. 5). The resulting equilibrium P–T curve can be approximated by the following equation:
T(K) = −4.6966 P3 + 86.63 P2 − 619.83 P + 2160.5 (P in GPa), which yields a negative Clapeyron slope, (∂P/∂T)equilibrium. The presence of Cr-Al spinel in the xenoliths, in combination with detailed geological and petrological studies of the xenolith-bearing volcanic region27,32,34, allowed us to restrict the pressure interval to the more realistic range of 1.3–3.0 GPa. In this interval the negative Clapeyron slope of the P–T curve has an average value in the range 1.3–3.0 GPa of –0.003 GPa K–1. The modelled P–T locus crosses the Australian geotherms’ field, calculated by heat-flow measurements and xenolith samples86,87, in the lower end at ~ 2.2 GPa /1210 K and in the upper end at ~ 1.4 GPa /1400 K (Fig. 5). The Australian mantle domain that stabilized the Mount Leura xenolith mineral assemblages under study is placed in this region. Using the recent thermal model of the crust and upper mantle of the Australian continent, obtained from the analysis of surface heat flow data and combining seismic tomography and gravity data88,89, it was possible to calculate the geotherm of this mantle column down to 200 km of depth in the proximity of the xenolith location (38°14′41.0"S; 143°09′27.5"E). The new proposed geotherm (Fig. 5) takes into account the mantle xenolith’s petrological evidence (part of this study) of the extensive re-fertilization that occurred during the Proterozoic tectonic events88,89. The resulting geotherm, specifically related to the mantle column of the Mount Leura xenoliths, is slightly “cooler” than the Australian mantle geotherms’ field (2.3 GPa /1290 K) and intersects the modelled P–T locus of the amphibole-phlogopite equilibrium at ~ 2.3 GPa/1190 K. This P–T point represents the plausible thermal-baric conditions of the mantle region (~ 70 km depth) related to the Mount Leura xenolith provenance.
On the basis of these data, the south-eastern Australian geotherm shows a sub-linear trend up to 4 GPa (~ 150 km depth), in agreement with the previous thermal models, and then it becomes convection-driven, well before the previous estimates (Fig. 5). This probably implies that beneath the Newer Volcanic Province there is an increasing efficiency of thermal perturbations in the deeper mantle region.
Metasomatic fluid stability conditions
We used the equilibrium P–T curve to constrain the geothermobarometric conditions at which circulating fluids/volatile rich melts led to hydrous phases. Phase and chemical compositions along with textural observations suggest the following equation:
The fluid composition is designed to guarantee a mass balance between the left- and right-hand side members of the equation above.
Let us consider a virtual reference fluid (VRF; GFluid,0) of composition H2O + 1/2 (K0.85Na0.15)2O, which represents an ideal fluid-like system (see “Experimental Methods and modelling”), whose GFluid,0 (i.e. molar Gibbs energy) is formally modelled as follows:
EH2O, EK2O and ENa2O are the quantum energies of H2O, K2O and Na2O (crystals);
SFluid,Mixing is the mixing entropy of an ideal gas, composed of K, Na, H and O independent atoms;
{H(T)-T × S}Fluid,Thermal is calculated by a CP set equal to 3 k per atom, for T ≥ 273 K. At lower T, CP is taken linear, with CP(T = 0 K) = 0;
GFluid,Exc is modelled using the activity coefficients for K+, Na+ and OH- in aqueous solution.
We would like to underline that it is not our aim to develop any physically consistent VRF, but to set up a fictitiously “over-stable” fluid-like virtual system.
Equation (3) can be expressed in a general form assuming that (i) all members undergo forward–backward transformations and behave as if they were components, and (ii) the Gibbs energy of each phase is treated like the composition independent part of the chemical potential of a component (γs are set to unity, initially). The resulting chemical equilibrium constant, Keq, is written as
where \(\Delta G_{j}^{k}\) is the Gibbs energy difference in (3) between left-hand side member and right-hand side member, the latter containing VRF formulated via Eq. (4); Keq coincides with the concentration quotient, in the present case. Equation (3) virtually shifts leftwards, if Keq > 1, and rightwards, if Keq < 1. We chose to describe a deviation of Keq from 1 by introducing a fictitious activity coefficient that is arbitrarily attributed to the fluid-component, namely 2RT ln(γFluid) = \(\Delta {G}_{j}^{k}\). Eventually, for bare convenience of notation, we set γFluid = fFluid/fFluid,0, and thence Δlog(fFluid) = log(fFluid)–log(fFluid,0). Note that, on an alternative viewpoint, \(\Delta {G}_{j}^{k}\) can be seen as the “additional” excess Gibbs energy required for VRF to ideally achieve equilibrium according to Eq. (3). Altogether, Δlog(fFluid) < < 0 implies that Eq. (3) is shifted leftwards, namely a very small amount of “over-stable” VRF is expected.
Calculations were performed by a combination of:
(i) quantum-mechanics (CRYSTAL code90), for static energy contributions;
(ii) semi-empirical potentials, for phonons related energy terms via lattice dynamics (GULP code85), such as zero-point energy and calorimetric contributions below room temperature;
(iii) thermo-elastic data are set out in Supplementary Table 11.
We chose to follow such an approach to guarantee the highest comparability between Gibbs energy values, which play an important role in the determination of Δlog(fFluid).
The Δlog(fFluid) as a function of pressure and along isotherms (300–1500 K) is reported in Fig. 6. Notably, over the P–T range of petrological interest, i.e., 900–1500 K and 1.5–3.0 GPa, the mean value of Δlog(fFluid) (< Δlog(fFluid) >) is ~ –9.6. This large negative value shows, as stated above, that a hypothetical metasomatic fluid tends to occur in a very small amount, if at all. Therefore, the coexistence of fluid at equilibrium with phlogopite is unlikely, in keeping with petrographic observations, which do not show any evidence of residual fluids in association with phlogopite crystals.
It follows that Na–K aqueous fluids (or Na–K hydrous melt) cannot flow over long distances throughout the mantle as they are highly reactive with the ultramafic system.
All this is in keeping with the observations of Huang et al.91, who claim an increase of wettability of H2O because of the addition of NaCl, in an ultramafic environment. In our case, owing to the absence of saline brine in the fluid inclusions of the mineral samples, we conclude that the K-Na aqueous fluids, originated in the same “harzburgitic system” as the Mount Leura mantle fragments and immediately promoted the formation of phlogopite and amphibole, and these minerals achieved equilibrium with the ultramafic system.
According to the comparatively low fO2 values [–1.83 ÷ –1.97 Δ(FMQ)] of LE7[phl] and LE5[phl+amph] harzburgites, such an environment is more reducing than it would be expected from the occurrence of phlogopite and amphibole in spinel bearing peridotites. In fact, this mineral assemblage is commonly associated with an average Δ(FMQ) of ~ ± 1, and several studies ascribe the role of O2 buffers to hydrous phases6,92,93.
The relatively reducing conditions of LE7[phl] and LE5[phl+amph] harzburgites may indicate (i) that peridotite lacks a sufficient amount of phases (amphibole/phlogopite, but also spinel) capable of buffering O2 (which is not our case, as phlogopite and amphibole are estimated to be about 2.5 wt%, in total), and/or (ii) that full molecular dissociation of the fluid takes place, followed by incorporation of the O-H-K-Na species into (OH)-K-Na-bearing mineral phases (phlogopite and amphibole). The modelled metasomatic fluid, having Δlog(fFluid) < < 0 points to this second situation, thus leading to a peridotite metasomatized ambient, characterized by reducing conditions58,92,93.
It is worth noting that near Mount Leura there are Bullen-Merri and Gnotuk maars, two volcanic crater-lakes probably formed by diatremes, which host spinel lherzolites with coexisting amphibole and phlogopite, containing F and Cl31,94. Waters of Lake Bullen-Merri are “brackish” and those of Lake Gnotuk are even hyper-saline (twice as salty as seawater). Among the various hypotheses about the origin of hyper-saline waters of the hydrologically closed maar crater lakes95, we venture upon that of a mantle source with amphibole and phlogopite (F and Cl bearing) for the local magmatism. On the basis of the experimental results, 5% partial melting of a metasomatized mantle sources (amph:phl = 2:4), produce primary magmas with fluorine contents of ~ 8500 ppm (using ampbibole-phlogopite/melt DF < 1) and F/Cl between 5 and 10 73. All this suggests that magmas may have reached the surface with their halogen budgets, which could be preserved and concentrated in the subsequent shallow geological structures95.
In conclusion, a novel perspective is applied to the mineral assemblage of olivine + clinopyroxene + orthopyroxene + spinel + phlogopite + amphibole in mantle xenoliths and it can provide further restraints about the effective reducing/oxidizing state of the lithospheric mantle. In addition, this petrological study provides a new finding for a potential geotherm in the southeast Australian upper mantle, which is fully consistent with the results of previous thermal models86,87,88,89.
Experimental methods and modelling
Bulk rock major element compositions were determined by wavelength dispersive X-ray fluorescence spectroscopy (WDXRF) on pressed powder pellets at the Department of Physics and Earth Sciences of the University of Ferrara (Italy), using an ARL Advant-XP spectrometer, following the full matrix correction method proposed by Lachance and Traill96. Accuracy is generally lower than 2% for major oxides and 5% for trace elements; the detection limit for the latter ranges from 1 to 2 ppm. Volatile contents were determined by loss on ignition (LOI) at 1000 °C.
Polished petrographic thin sections were prepared for optical microscopy observations and in-situ chemical analyses. The statistical significance of the petrographic and crystal-chemical analyses was guaranteed by cutting two different slices of the same xenolith, so that two thin sections per sample were obtained and analyzed.
Backscattered electron (BSE) images were recorded by a ZEISS EVO MA 15 scanning electron microscope (SEM) at the Department of Physics and Earth Sciences of the University of Ferrara (Italy). This instrument is equipped with an SDD detector, and employs a LaB6 filament as an electron source. The thin sections were studied at 20 kV and 8.5 mm working distance, at high vacuum conditions. Major element compositions of cores and rims of the primary minerals were determined using a JEOL JXA-8900 wavelength dispersive X-ray spectroscopy (WDS) electron microprobe, at the Earth Sciences Department of the University of Milan (Italy). The system was operated with an accelerating voltage of 15 kV, a beam current of 5 nA, a counting time of 30 s on the peaks and 10 s on the backgrounds, and a beam spot size of 10 µm, the latter to avoid sample sublimation. The following standards were used: graftonite for P, Fe, and Mn; grossular for Si, Al, and Ca; K-feldspar for K; forsterite for Mg; niccolite for Ni; and omphacite for Na. The halogen contents in amphibole and phlogopite were measured using natural topaz as reference material and following the analytical protocol of Zhang et al.97. The EMPA detection limits for F and Cl are ~ 0.07 and ~ 0.015 wt%, respectively.
Trace element analyses of clinopyroxene, amphibole and mica were performed by LA-ICP-MS, at the Istituto di Geoscienze e Georisorse, C.N.R., Pavia (Italy), using PerkinElmer SCIEX ELAN DRC-e quadrupole mass spectrometer. Helium was used as carrier gas and mixed with Ar downstream of the ablation cell. NIST SRM 610 was used as external standard, while Ca was the internal standard for clinopyroxene and amphibole and Si was the internal standard for phlogopite. Data reduction was performed using the Glitter software. Precision and accuracy were assessed from repeated analyses of the BCR-2 g reference material and usually resulted in being better than 10%. The laser was operated at a repetition rate of 10 Hz, with a pulse energy of ~ 35 mJ. Spot diameter was typically 40–50 μm. Single crystals of phlogopite and amphibole were extracted for X-ray diffraction experiments (XSC) and in-situ synchrotron Mössbauer spectroscopy (SMS).
XSC experiments were carried out on single crystals of mica (LE7-MICA 1/8/15) from LE7[phl], and of amphibole (LE5-AMPH 2/3/4/5) and mica (LE5-MICA 1/3/5) from LE5[phl+amph]. The diffraction intensities of the crystals were collected using the Gemini R Ultra X-ray diffractometer at the CrisDi Interdepartmental Centre of the University of Torino (Italy), equipped with a Ruby CCD detector, using a monochromatic MoKα radiation and X-ray tube operating at 50 kV and 40 mA. The 171.37.35 version of CrysAlysPro software (Agilent Technologies) was used for data reduction (integration of the intensity spots, absorption and Lorentz-polarization corrections). Structure refinements were performed by the codes Schelx-TL and Jana2006, starting from the atomic coordinates reported in literature for phlogopite68 and pargasite98. The atomic positions were refined without restraints, save the symmetry constraints; electron occupancies and anisotropic thermal factors of the crystallographic sites were refined using the ionic scattering factors of the more abundant atomic species, in particular: Si4+ for T-site, Mg2+ for M(1)-M(2)-M(3)-sites, Ca2+ for M(4)-site, and Na+ for A-site. The “large” A-site of amphibole was filled by cations with a partially disordered arrangement, characterized by three different positions99.
Energy-domain in-situ SMS measurements were performed on amphibole single crystals, LE5-AMPH, at the Nuclear Resonance beamline ID18100 of the European Synchrotron Radiation Facility (ESRF), Grenoble (France), in multi-bunch (7/8 + 1) mode. The SMS instrument is equipped with a nuclear resonant monochromator and employs pure nuclear reflections of an iron borate (57FeBO3) single crystal101. The source provides 57Fe resonant radiation at 14.4 keV within a bandwidth of 6 μeV, which is tuneable over an energy range of ± 0.6 μeV101. The X-rays beam emitted by the SMS was focused onto a 16-vertical × 15-horizontal μm2 spot size, at the full width half maximum. Before and after each sample measurement, the SMS linewidth was determined using a K2Mg57Fe(CN)6 reference single line absorber. The velocity scale (± 5 mm/s) was calibrated by a 25 μm-thick natural α-Fe foil. The small cross section, high brilliance and the fully resonant and polarized nature of the beam allowed rapid data collections (approximately 2 h).
The spectra were fitted with a full transmission integral and pseudo-Voigt line shape using the software package MossA102. The single line spectra were modelled by a normalized Lorentzian-squared source line shape. A linear function was used for background.
Equation (4) was developed considering a virtual fluid system of composition H2O + 1/2 (K0.85Na0.15)2O, with a Gibbs energy lower than that expected for a physical fluid sharing the same composition. We start from (i) solid oxides K2O, Na2O and H2O, having at 0 K a total energy E0-ΔE, where E0 and -ΔE (ΔE > 0) are the free atoms’ energy and crystal formation energy, respectively. Such a system is (ii) heated up to T0 = 273 K, assuming a specific heat per atom at constant pressure given by
that is an overestimate of CP for a solid mixture with the phase composition of H2O + 0.425 K2O + 0.075 Na2O 103,104.
At 273 K, (iii) the atoms are split apart by an external work equal to ΔE. This leads to a mixture of non-interacting monoatomic gases, with P → ε, T1 > T0 in keeping with the energy equipartition theorem, and V ∝ 1/ε, following the gas EoS. We neglect T1, and start considering the gas mixture from T0, for the reason below. For T > T0 (iv) we set CP as large as 3 k per atom, which is an overestimate for an ideal monoatomic gas. The developed model relies upon a general overestimation of CP. Given that
then the use of an overestimated CP yields an underestimated thermal contribution to the Gibbs energy, thus fictitiously boosting stability of the related system. Mixing entropy due to the gas mixture is taken into account (SFluid,Mixing). We then proceed to compress (v) the monoatomic gas mixture, at T. The isothermal compression of the system, changes its Gibbs energy in terms of
whose positive contribution (P2 > P1) is neglected here. Possible condensation processes upon compression cannot lead to an exothermic energy exchange larger than -ΔE. Eventually, we complete this modelling of a virtual “over-stable” fluid introducing an additional, though uninfluential, excess contribution (GFluid,Exc) from an aqueous solution using the following equilibrium chemical equations:
according to Ferse105 and taking the lowest activity coefficients reported there.
(K,Na)-phlogopite, in turn, was modelled as a linear combination of the phlogopite and aspidolite Gibbs energy values. The excess Gibbs energy of the isomorphic replacement involving K and Na in phlogopite, given the composition of (3), was estimated to be ~ 0.01–0.03 kJ/mol in terms of lattice contribution106 and therefore neglected.
Calculations were carried out using both quantum mechanics and semi-empirical modelling. Quantum mechanics was employed to calculate the lattice energy of the involved phases, adding the vibrational contributions determined by semi-empirical potentials and lattice dynamics in quasi-harmonic approximation. In the case of lattice dynamics modelling (GULP code85), semi-empirical potentials were taken from Catlow107, available from the repository www.ucl.ac.uk/klmc/Potentials/Library/catlow.lib. Quantum mechanics calculations rely upon an ab-initio Hartree–Fock (16%)-DFT (84%) hybrid approach (CRYSTAL code90), adopting a Hamiltonian based on the SOGGA (Second Order GGA) functional in combination with the PBE correlation functional108. Computational details are reported in Merli and Pavese109. Gaussian basis set (name as recorded in the repository of the CRYSTAL site www.crystal.unito.it/Basis_Sets) are: H_pob_TZVP_2012 for H, O_8-411d1_bredow_2006 for O, Na_8-511(1d)G_baranek_2013_NaNbO3 for Na, Mg_8-511d1G_valenzano_2006 for Mg, Al_85-11G*_catti_1994 for Al, Si_88-31G*_nada_1996 for Si, K_pob_TZVP_2012 for K.
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Acknowledgements
The present study was granted by the “PRIN2017-2017L83S77” project of the Italian Ministry for Education, University and Research (MIUR) (AP; CB). V.B and B.P were supported by University of Ferrara Research Fund 2020 (FAR2088483). G.B.A. and V.S. acknowledge financial support from “Fondi di Ateneo Sapienza Università di Roma 2017 and 2018”. We acknowledge the European Synchrotron Radiation Facility for the provision of beam time at ID18 Nuclear Resonance Beamline and beam scientists V. Cerantola and A. Chumakov for their technical assistance. N. Eftekhari (University of Ferrara) and Alberto Zanetti (CNR-IGG Pavia) are also thanked for SEM and ICP-MS technical assistance, respectively. The authors are grateful to Dr. B. Galassi (Brighton, UK) for the linguistic revision of the text. The authors would like to thank three anonymous reviewers for their constructive criticism that greatly improved an earlier version of the manuscript.
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C.B. and A.P. conceived the study and wrote the main text. C.B collected the samples. V.B, B.P provided the geological setting, the petrography, carried out chemical analyses, processed and discussed the data. N.C and P.B made single crystal X-ray diffraction experiments, processed and discussed the data. M.T. modelled the geotherm and discussed the data. G.B.A and V.S provided in-situ synchrotron Mössbauer spectroscopy experiments, processed and discussed the data. A.P and M.M designed the modelling strategy, made calculations and discussed the data. C.B, B.F and M.C provided a preliminary geochemical study. All authors discussed the results, edited and commented on the manuscript.
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Bonadiman, C., Brombin, V., Andreozzi, G.B. et al. Phlogopite-pargasite coexistence in an oxygen reduced spinel-peridotite ambient. Sci Rep 11, 11829 (2021). https://doi.org/10.1038/s41598-021-90844-w
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DOI: https://doi.org/10.1038/s41598-021-90844-w
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