Abstract
Cotton cellulose was independently oxidized with sodium metaperiodate, potassium dichromate–sulfuric acid, and potassium dichromate–oxalic acid. The various modified celluloses so-obtained were grafted with methyl methacrylate using peroxydiphosphate as the initiator. It was found that the initiation characteristics of the cellulose samples vary widely with the oxidizing agent used. The various factors which affect the graft uptake, such as the substrate, [peroxydiphosphate], [methyl methacrylate], [H2SO4], temperature, and solvent were studied. Also a determination of the molecular weight and elucidation of the reactions involved in initiation of grafting were undertaken.
Similar content being viewed by others
Article PDF
References
J. W. Vanderhoff, in “Vinyl Polymerization,” Part II, G. E. Ham, Ed., Dekker, N.Y., 1969, Chapter 1.
M. Negishi, K. Arai, and S. Okada, J. Appl. Polym. Sci., 11, 115 (1967).
M. Negishi, K. Arai, and S. Okada, J. Appl. Polym. Sci., 12, 2585 (1968).
K. Arai, M. Negishi, T. Suda, and K. Doi, J. Polym. Sci., A-1, 9, 1879 (1971).
D. A. House, Chem. Rev., 62, 185 (1962).
W. K. Wilmarth and A. Him, “Peroxide Reaction”, 1962, p 175.
Y. Ikada, Y. Nishizaki, and I. Sakurada, J. Polym. Sci., Polym. Chem. Ed., 12, 1829 (1974).
A. A. Green, J. O. Edwards, and P. Jones, Inorg. Chem. 5, 1858 (1966).
M. Anderson, J. O. Edwards, A. A. Green, and M. D. Wiswell, Inorg. Chem. Acta, 3, 655 (1969).
R. J. Lussier, W. M. Risen, and J. O. Edwards, J. Phys. Chem., 74, 4039 (1970).
E. Chaffee, I.I. Creaser, and J. O. Edwards, Inorg. Nucl. Chem. Lett., 7, 1 (1971).
J. O. Edwards, Coord. Chem. Rev., 8, 87 (1972).
S. S. Hariharan and A. Meenakshi, J. Polym. Sci., Polym. Lett. Ed., 15, 1 (1977).
K. Dimov and P. Pavlov, J. Polym. Sci., A-1, 7, 2775 (1969).
D. H. Gallagher, Text. Res. J., 40, 621 (1970).
R. J. Dement, J. C. Arther, Jr., and W. F. McSherry, Text. Res. J., 31, 821 (1961).
A. Kantouch, A. Hebeish, and M. H. El-Rafie, Eur. Polym. J., 6, 1575 (1970)
A. Hebeish, A. Kantouch, and M. H. El-Rafie, J. Appl. Polym. Sci., 15, 1921 (1971).
A. Hebeish, A. Kantouch, and M. H. El-Rafie, J. Appl. Polym. Sci., 15, 11 (1971).
A. Kantouch, A. Hebeish, and M. H. El-Rafie, Text. Res. J., 42, 10 (1972).
Y. Ogiwara and H. Kubota, J. Appl. Polym. Sci., 17, 2427 (1973).
M. Kamel, A. Hebeish, and A. Al-Aref, J. Appl. Polym. Sci., 18, 3463 (1974).
A. Hebeish, M. H. El-Rafie, M. I. Khalil, and A. Bendak, J. Appl. Polym. Sci., 21, 1901 (1977).
P. L. Nayak, S. Lenka, and M. K. Mishra, J. Appl. Polym. Sci., 25, 63 (1980).
P. L. Nayak, S. Lenka, and M. K. Mishra, to be published in Angew. Makromol. Chem., No. 1371.
S. Lenka, P. L. Nayak, and M. K. Mishra, Angew. Makromol. Chem., 84, 183 (1980).
P. L. Nayak, S. Lenka, and M. K. Mishra, to be published in J. Polym. Sci.
R. J. Valles, M. C. Otizinger, and D. W. Lewis, J. Appl. Polym. Sci., 4, 92 (1960).
S. Chinai, A. Resnik,and T. Matlack, J. Polym. Sci., 17, 391 (1955).
Y. Iwakura, T. Kurosaki, and Y. Imai, J. Polym. Sci., A, 3, 1185 (1965).
Y. Ogiwara, Y. Ogiwara, and H. Kubota, J. Polym. Sci., A-1, 5, 2791 (1967).
P. Maruthamuthu and M. Santappa, J. Inorg. Nucl. Chem., 37, 1305 (1975).
J. O. Edwards, J. Chem. Educ., 31, 270 (1954).
J. O. Edwards, Chem. Rev., 50, 455 (1952).
J. J. Siglla, J. Chem. Phys., 788 (1958).
M. N. Crutchfield, “Peroxide Reaction Mechanisms,” J. O. Edwards, Ed., Interscience, N.Y., 1962, p41.
P. Maruthamuthu and M. Santappa, Indian J. Chem., 14A, 35 (1976).
Rights and permissions
About this article
Cite this article
Mishra, M., Lenka, S. & Tripathy, A. Grafting Vinyl Monomers onto Modified Cellulose: Potassium Peroxydiphosphate-Induced Graft Copolymerization of Methyl Methacrylate onto Oxidized Cellulose. Polym J 13, 305–311 (1981). https://doi.org/10.1295/polymj.13.305
Issue Date:
DOI: https://doi.org/10.1295/polymj.13.305