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Graft polymerization of methyl methacrylate on the surface of poly(vinylidene fluoride) using tributylborane as an initiator

Polymer Journal volume 56, pages 79–85 (2024)Cite this article

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Abstract

Tributylborane-initiated graft polymerization of methyl methacrylate on a poly(vinylidene fluoride) film was successfully achieved. The reaction was affected by the temperature and concentration of tributylborane, and a 41% graft yield was obtained under the optimized conditions. This value was higher than those obtained with other methods. This method facilitated modifications of only the surface of the poly(vinylidene fluoride) film, which was confirmed by IR spectroscopy and cross-section observations. New physical properties were added to the surface, such as hydrophilicity, which was confirmed by a decrease in the water contact angle from 82.5° to 68.6° after graft polymerization.

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Authors and Affiliations

  1. School of Engineering Science, Kochi University of Technology, Tosayamada, Kami, 782-8502, Kochi, Japan

    Yusuke Mizuta, Kazuya Kobiro, Nagatoshi Nishiwaki & Ryuichi Sugimoto

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  1. Yusuke Mizuta
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Correspondence to Ryuichi Sugimoto.

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Mizuta, Y., Kobiro, K., Nishiwaki, N. et al. Graft polymerization of methyl methacrylate on the surface of poly(vinylidene fluoride) using tributylborane as an initiator. Polym J 56, 79–85 (2024). https://doi.org/10.1038/s41428-023-00853-x

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