Abstract
RECENT work on absorption spectra and lattice spacings in the Al2O3–Cr2O3 solid solution1–6 has been in sufficient agreement to warrant a fitting of the optical results to the crystal field-splitting diagram7. The relevant terms are shown in Fig. 1, which also shows the transitions involved in the yellow and blue absorption bands.
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References
Graham, J., J. Phys. Chem. Solids, 17 (1/2), 18 (1960).
Schultz, G., Conf. Physics and Chemistry of Crystal Phosphors (Greifswald, 1959), 219 (Akademie-Verlag, Berlin, 1960).
Schmitz-Dumont, O., and Reinen, D., Z. Elektrochem., 68 (8), 978 (1959).
Mandarino, J. A., Amer. Mineralogist, 44 (9/10); 961 (1959).
Jan, J. P., Steinemann, S., and Dinichert, P., Helv. Phys. Acta, 33 (2), 123 (1960).
Neuhaus, A., Z. Krist., 113, 195 (1960) (includes spectra by W. Schilly).
Tanabe, Y., and Sugano, S., J. Phys. Soc., Japan, 9, 766 (1954).
Tsuchida, R., see ref. 6, 775.
Schäffer, C. E., and Jorgensen, C. K., J. Inorg. Nuclear Chem., 8, 143 (1958).
Dunn, T. M., J. Chem. Soc., (2) 623 (1959).
Schultz, G., Annalen der Phys., 6 (7/8), 345 (1960).
Goodenough, J. B., J. App. Phys., 31, 3595 (1960).
Schäffer, C. E., J. Inorg. Nuclear Chem., 8, 149 (1958).
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GRAHAM, J., SCAIFE, D. Ligand Field for Chromic Ions in the Corundum Lattice. Nature 192, 161–163 (1961). https://doi.org/10.1038/192161b0
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DOI: https://doi.org/10.1038/192161b0
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