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| Open AccessThree-dimensional crossbar arrays of self-rectifying Si/SiO2/Si memristors
Memristors are key structural units of complex memory and computing systems, yet most currently available memristors are based on materials that are not compatible with silicon technology. Here, the authors demonstrate a CMOS-compatible, self-rectifying memristor and arrays entirely based on p-Si/SiO2/n-Si.
- Can Li
- , Lili Han
- & Qiangfei Xia
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Article
| Open AccessThermal annihilation of photo-induced radicals following dynamic nuclear polarization to produce transportable frozen hyperpolarized 13C-substrates
Hyperpolarized molecules provide unique contrast for MRI but due to their short relaxation time need to be prepared shortly before injection. Here the authors report a method for eliminating the main source of relaxation and producing frozen polarized substances that can be stored and transported.
- Andrea Capozzi
- , Tian Cheng
- & Arnaud Comment
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Article
| Open AccessHot excited state management for long-lived blue phosphorescent organic light-emitting diodes
Large-scale commercialization of organic light-emitting diodes is impeded by the short operational lifetime of blue emitting materials. Leeet al. show a strategy to manage the energy dissipation on molecular dissociation using dopants with high triplet exciton energy that improves device stability.
- Jaesang Lee
- , Changyeong Jeong
- & Stephen R. Forrest
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Article
| Open AccessNeuromorphic device architectures with global connectivity through electrolyte gating
Global regulation of synaptic strengths in neural systems is known as homeoplasticity. Here, Gkoupideniset al. use an electrolyte to connect and control an array of organic electrochemical devices, in order to demonstrate behaviour that resembles homeoplasticity phenomena in the brain.
- Paschalis Gkoupidenis
- , Dimitrios A. Koutsouras
- & George G. Malliaras
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Article
| Open AccessNanogenerator-based dual-functional and self-powered thin patch loudspeaker or microphone for flexible electronics
Self-powered nanogenerators by harvesting energy from the environment are desirable for future portable and wearable electronics. Liet al. show the use of ferroelectret nanogenerators to build microphone or loudspeaker, which convert electrical signals to mechanical motions in a reversible manner.
- Wei Li
- , David Torres
- & Nelson SepĂșlveda
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| Open AccessFace classification using electronic synapses
Using chips that mimic the human brain to perform cognitive tasks, namely neuromorphic computing, calls for low power and high efficiency hardware. Here, Yaoet al. show on-chip analogue weight storage by integrating non-volatile resistive memory into a CMOS platform and test it in facial recognition.
- Peng Yao
- , Huaqiang Wu
- & He Qian
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Article
| Open AccessLipoprotein-biomimetic nanostructure enables efficient targeting delivery of siRNA to Ras-activated glioblastoma cells via macropinocytosis
Drug delivery in brain tumours is still a significant clinical concern. In this study, the authors develop a biomimetic lipoprotein nanoparticle for the efficient delivery of ATF5 siRNA inRas-activated brain cancer cells, where the nanoparticle is internalized by macropinocytosis in a Ras-dependent manner.
- Jia-Lin Huang
- , Gan Jiang
- & Xiao-Ling Gao
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Article
| Open AccessMembraneless water filtration using CO2
Water treatment processes mostly rely on the use of membranes and filters, which have high pumping costs and require periodic replacement. Here, the authors describe an efficient membraneless method that induces directed motion of suspended colloidal particles by exposing the suspension to CO2.
- Sangwoo Shin
- , Orest Shardt
- & Howard A. Stone
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Article
| Open AccessAn extra-uterine system to physiologically support the extreme premature lamb
The ability to support the development of a premature fetus in the form of an extracorporeal system has had limited success. Here, the authors show that an extra-uterine device that mimics the intra-uterine environment can provide physiologic support for the extreme premature lamb fetus for four weeks.
- Emily A. Partridge
- , Marcus G. Davey
- & Alan W. Flake
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Article
| Open AccessElectrochemical generation of sulfur vacancies in the basal plane of MoS2 for hydrogen evolution
In order to fully utilize sulfur vacancies in MoS2 catalysts for industrial applications, a facile and general route for making sulfur vacancies in MoS2 is needed. Here, the authors introduce a scalable route towards generating sulfur vacancies on the MoS2basal plane using electrochemical desulfurization.
- Charlie Tsai
- , Hong Li
- & Frank Abild-Pedersen
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Article
| Open AccessImplantable batteryless device for on-demand and pulsatile insulin administration
Implantable insulin delivery devices can make a significant difference in the lives of patients although they are limited by the duration of their battery life, often requiring replacement. Here, the authors developed an implantable battery-less insulin delivery device with noninvasive actuation.
- Seung Ho Lee
- , Young Bin Lee
- & Young Bin Choy
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Article
| Open AccessCharge carrier mobility in thin films of organic semiconductors by the gated van der Pauw method
Charge carrier mobility is one of the key parameters that are used to evaluate the electrical quality of thin film semiconductors, whilst it is easily overestimated. Here, Rolinet al. use the gated van der Pauw method to extract charge mobility independent of contact resistance and device dimensions.
- Cedric Rolin
- , Enpu Kang
- & Jan Genoe
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Article
| Open AccessMechano-regulated surface for manipulating liquid droplets
Droplet manipulation is an essential task for designing microfluidic platforms such as lab-on-chip devices. Here Tanget al. develop a non-wettable mesh with reversible liquid adhesion controlled by mechanically inserting wettable pillars which allows for effective and rapid droplet manoeuvring.
- Xin Tang
- , Pingan Zhu
- & Liqiu Wang
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Article
| Open AccessStable and solubilized active Au atom clusters for selective epoxidation of cis-cyclooctene with molecular oxygen
Gold catalysts have previously been reported for the epoxidation of alkenes with molecular oxygen. Here the authors show that, rather than the gold nanoparticles, the active species for this reaction are actually small, soluble gold species stabilized by the oxidised organic products.
- Linping Qian
- , Zhen Wang
- & Harold H. Kung
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Article
| Open AccessMolecular level detection and localization of mechanical damage in collagen enabled by collagen hybridizing peptides
Collagen denaturation is thought to occur during tissue mechanical damage, but its role in damage initiation is still unclear. Here, the authors use a collagen hybridizing peptide to provide insights into the molecular mechanisms leading to collagen unfolding during tendon mechanical stretch.
- Jared L. Zitnay
- , Yang Li
- & Jeffrey A. Weiss
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Article
| Open AccessThe best features of diamond nanothread for nanofibre applications
Carbon fibres are emerging as a promising material for multifunctional nanotextiles. Here, the authors show that diamond nanothread possesses excellent torsional deformation capability and interfacial load transfer efficiency, ideal for constructing next generation carbon fibres.
- Haifei Zhan
- , Gang Zhang
- & Yuantong Gu
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Article
| Open AccessDemonstrating the potential of yttrium-doped barium zirconate electrolyte for high-performance fuel cells
Protonic ceramic fuel cells are promising for energy applications, but maintaining high performance with long-term stability is an issue. Here the authors use a stable yttrium-doped barium zirconate electrolyte, achieving a power output one order of magnitude higher than existing protonic ceramic fuel cells.
- Kiho Bae
- , Dong Young Jang
- & Joon Hyung Shim
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Article
| Open AccessLimited options for low-global-warming-potential refrigerants
With societies phasing down the use of hydrofluorocarbons (HFCs), alternative environmentally-friendly refrigerants are required. Here the authors screen a large chemical database for replacements, performing simulations to show there are only a few candidate single-component fluids that can realistically replace HFCs.
- Mark O. McLinden
- , J. Steven Brown
- & Piotr A. Domanski
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| Open AccessHarnessing catalytic pumps for directional delivery of microparticles in microchambers
Targeted delivery of microparticles is desirable for rapid, sensitive biological assays or self-assembly process. Here Daset al. use catalytic reactions on the surface of microfluidic chambers to generate unidirectional flows that carry and deposit microparticles to selective regions of the chamber.
- Sambeeta Das
- , Oleg E. Shklyaev
- & Ayusman Sen
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| Open AccessClimbing favours the tripod gait over alternative faster insect gaits
Numerous selective forces shape animal locomotion patterns and as a result, different animals evolved to use different gaits. Here, Ramdyaet al. use live and in silicoDrosophila, as well as an insect-model robot, to gain insights into the conditions that promote the ubiquitous tripod gait observed in most insects.
- Pavan Ramdya
- , Robin Thandiackal
- & Dario Floreano
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| Open AccessReversed thermo-switchable molecular sieving membranes composed of two-dimensional metal-organic nanosheets for gas separation
Reducing membrane thickness to nanometre scale should increase the throughput of gas separation sieves. Here, the authors report a sieving membrane composed of two-dimensional metal-organic framework nanosheets, exhibiting both high permeation flux and thermally switchable behaviour.
- Xuerui Wang
- , Chenglong Chi
- & Dan Zhao
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| Open AccessRobust microscale superlubricity under high contact pressure enabled by graphene-coated microsphere
Superlubricity can be unstable in graphene systems, especially under high applied loads. Here the authors use microspheres uniformly coated by graphene to measure friction between 2D materials and show that superlow friction is preserved for long periods of time under high loads and various atmospheres.
- Shu-Wei Liu
- , Hua-Ping Wang
- & Jianbin Luo
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Article
| Open AccessHydraulic hydrogel actuators and robots optically and sonically camouflaged in water
Hydrogel actuators have been widely developed to be osmotic-driven but many are in fact only capable of producing low forces. Here, the authors developed high speed and high force hydrogel actuators capable of camouflage optically and sonically with low fatigue over multiple cycles.
- Hyunwoo Yuk
- , Shaoting Lin
- & Xuanhe Zhao
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Article
| Open AccessMultiplexed single-mode wavelength-to-time mapping of multimode light
Photonic lanterns are made by merging several single-mode cores into one multimode core. Here, the authors show this type of structure can both perform wavelength-to-time mapping of multimode states of light and couple such light to an array of single-photon avalanche detectors.
- Harikumar K Chandrasekharan
- , Frauke Izdebski
- & Robert R. Thomson
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Article
| Open AccessThe shape of telephone cord blisters
Telephone cord blisters constitute a well-known example of patterns generated following buckling in thin films. Here the authors develop an analytical approach that can model the sectional height profiles along the blisters that they measure experimentally and simulate numerically.
- Yong Ni
- , Senjiang Yu
- & Linghui He
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Article
| Open AccessRapid control and feedback rates enhance neuroprosthetic control
Brain machine interfaces (BMI) enable sensorimotor control of movement yet the parameters that may affect these pathways are not known. Here the authors show systematically that increasing the rate of control from brain as well as feedback rates to the subject results in better performance on a BMI task in monkeys.
- Maryam M. Shanechi
- , Amy L. Orsborn
- & Jose M. Carmena
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Article
| Open AccessA stable lithiated siliconâchalcogen battery via synergetic chemical coupling between silicon and selenium
Lithium-based batteries employing silicon anodes and sulfur cathodes are promising for combining low cost and high capacity, but have been limited in terms of cycling stability. Here authors present cycling and characterization data supporting beneficial synergies between a selenium disulfide cathode and a silicon anode.
- KwangSup Eom
- , Jung Tae Lee
- & Thomas F. Fuller
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| Open AccessMeasurement of transverse emittance and coherence of double-gate field emitter array cathodes
Field emitter arrays are key components for X-ray sources, microwave generators, RF communication and advanced light sources. Tsujinoet al., report double-gate field emitter arrays with competitive beam qualities to the state of the art UV photoexcited cathodes.
- Soichiro Tsujino
- , Prat Das Kanungo
- & R.J. Dwayne Miller
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Article
| Open AccessBio-inspired self-shaping ceramics
Shaping ceramics into complex forms is a formidable goal. Here, the authors present an approach to self-shaping ceramics, inspired by self-folding processes in plants, in which the ceramic microstructure is embedded with aligned platelets that control the orientation of heat-induced shrinkage.
- Fabio L. Bargardi
- , Hortense Le Ferrand
- & André R. Studart
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Article
| Open AccessGrain neighbour effects on twin transmission in hexagonal close-packed materials
Twin transmission across grain boundaries has important influence on deformation and fracture in hexagonal close-packed metals. Here, experimental and computational statistical analyses show that whether twins cross grain boundaries depends not only on crystal misorientation but also strongly on anisotropy in crystallographic slip.
- M. Arul Kumar
- , I. J. Beyerlein
- & C. N. Tomé
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Article
| Open AccessImprovement of system capacitance via weavable superelastic biscrolled yarn supercapacitors
Carbon nanotube yarns with high loadings of pseudocapacitive material are desirable, e.g., for emerging wearable technologies. Here authors make biscrolled yarns with high loadings of MnO2nanoparticles confined in carbon nanotube galleries, demonstrating very high linear and areal capacitances.
- Changsoon Choi
- , Kang Min Kim
- & Seon Jeong Kim
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Article
| Open AccessSpray printing of organic semiconducting single crystals
The development of organic electronics calls for low-cost printing techniques that can prepare high quality, large-area organic single crystals. Here, Rigaset al. achieve this goal by combining spray printing and antisolvent crystallization and test the method on various materials and substrates.
- Grigorios-Panagiotis Rigas
- , Marcia M. Payne
- & Maxim Shkunov
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Article
| Open AccessPolarization bandgaps and fluid-like elasticity in fully solid elastic metamaterials
Controlling elastic waves in medium is essential to many applications in mechanical to earthquake engineering. Ma et al. demonstrate selective suppression of different vibrational modes in a three-dimensional rod-shape structure, which shows fluid-like elasticity with only longitudinal waves propagating.
- Guancong Ma
- , Caixing Fu
- & Ping Sheng
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Article
| Open AccessA two-dimensional spin field-effect switch
By forming heterostructures of different layered two-dimensional materials, functional spintronic devices may be built by exploiting the materialsâ different spin-orbit coupling and spin transport properties. Here, the authors demonstrate a spin switch in a gated structure of graphene and MoS2.
- Wenjing Yan
- , Oihana Txoperena
- & FĂšlix Casanova
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| Open AccessPhosphorene/rhenium disulfide heterojunction-based negative differential resistance device for multi-valued logic
Electronic devices based on negative differential resistance hold promise for multi-valued logic applications. Here, the authors implement such functionalities using an atomically thin phosphorene/rhenium disulfide van der Waals heterostructure, and further demonstrate the implementation of a ternary inverter.
- Jaewoo Shim
- , Seyong Oh
- & Jin-Hong Park
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| Open AccessPhotoemission-based microelectronic devices
Most microelectronic devices today exploit the electronic properties of semiconductors. Here, the authors demonstrate a microelectronic device for free-space electrons by using the enhanced fields in a microstructured metal surface to induce effective photoemission.
- Ebrahim Forati
- , Tyler J. Dill
- & Dan Sievenpiper
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Article
| Open AccessThe flux qubit revisited to enhance coherence and reproducibility
Scalable quantum information processing requires controllable high-coherence qubits. Here, the authors present superconducting flux qubits with broad frequency tunability, strong anharmonicity and high reproducibility, identifying photon shot noise as the main source of dephasing for further improvements.
- Fei Yan
- , Simon Gustavsson
- & William D. Oliver
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Article
| Open AccessGraphene-coated meshes for electroactive flow control devices utilizing two antagonistic functions of repellency and permeability
The wettability properties of graphene hold promise for the realisation of flow control devices. Here, the authors demonstrate that the degree of water penetration through a nickel mesh coated with graphene can be controlled electrically, enabling dynamic locomotion of water droplets.
- Rassoul Tabassian
- , Jung-Hwan Oh
- & Il-Kwon Oh
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Article
| Open AccessBioengineering of injectable encapsulated aggregates of pluripotent stem cells for therapy of myocardial infarction
Stem cell therapy of myocardial infarction is hampered by poor survival of injected cells. Here the authors develop injectable aggregates of stem cells differentiated to an early cardiac stage and encapsulated in a biodegradable micromatrix, and show their enhanced therapeutic efficacy in a heart infarction mouse model.
- Shuting Zhao
- , Zhaobin Xu
- & Xiaoming He
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Article
| Open AccessPlatinum recycling going green via induced surface potential alteration enabling fast and efficient dissolution
Given the scarcity and cost of platinum, it is important to develop sustainable processes for its recycling. Here, the authors report the dissolution of metallic platinum using reductive and oxidative gases to repetitively change its surface oxidation state, in the absence of an external electric current.
- Nejc Hodnik
- , Claudio Baldizzone
- & Karl J. J. Mayrhofer
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Article
| Open AccessAge and structure of a model vapour-deposited glass
Vapour-deposited glasses show high stability compared to that of aged glasses, but a structural understanding remains elusive. Here, Reid et al. find that vapour deposited and liquid-cooled glasses show identical structures, suggesting these two classes of films lie on the same path to equilibrium.
- Daniel R. Reid
- , Ivan Lyubimov
- & Juan J. de Pablo
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Article
| Open AccessLarge-scale microfluidics providing high-resolution and high-throughput screening of Caenorhabditis elegans poly-glutamine aggregation model
Large-scale screens on whole animals could facilitate drug discovery, but are technically challenging. Here, Mondal et al. develop a microfluidic chip combined with an automated imaging platform that enables high-throughput, high-resolution screening of Caenorhabditis elegansdisease models.
- Sudip Mondal
- , Evan Hegarty
- & Adela Ben-Yakar
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Article
| Open AccessFabrication of fibrillosomes from droplets stabilized by protein nanofibrils at all-aqueous interfaces
All-aqueous emulsions are useful for delivering and processing biomolecules, but their stability is constrained by low interfacial adsorption energy. Song et al. solve this problem using protein nanofibrils that form a crosslinked network, whose stability is superior to conventional colloidal capsules.
- Yang Song
- , Ulyana Shimanovich
- & Ho Cheung Shum
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Article
| Open AccessTuning the catalytic CO hydrogenation to straight- and long-chain aldehydes/alcohols and olefins/paraffins
The catalytic CO hydrogenation traditionally produces mainly methanol and long-chain hydrocarbons. Here, the authors show that the same reaction can be tuned to produce long-chain n-aldehydes, 1-alcohols and olefins, as well as n-paraffins over potassium-promoted CoMn catalysts.
- Yizhi Xiang
- & Norbert Kruse
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Article
| Open AccessMicrofluidic cantilever detects bacteria and measures their susceptibility to antibiotics in small confined volumes
Analysis of bacteria and their response to antibiotics in real time is challenging. Here the authors report a microcantilever based system that can detect and discriminate between bacteria species and, due to the ability to discriminate between alive and dead samples, measure response to antibiotics.
- Hashem Etayash
- , M. F. Khan
- & Thomas Thundat
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| Open AccessA 17âGHz molecular rectifier
Molecular electronics holds promise to overcome scaling limits of conventional technologies, but is currently limited to low frequency operation. Here, Trasobares et al. show radio frequencies of up to 17.8âGHz in a molecular diode based on ferrocenyl undecanethiol self-assembled monolayers on gold nanodots.
- J. Trasobares
- , D. Vuillaume
- & N. Clément
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| Open AccessInterplay between hydrophilicity and surface barriers on water transport in zeolite membranes
Zeolite crystal with porous structure is predicted to be a good membrane material for water purification, but experiments show water uptake orders of magnitude smaller than the theory. Here, Fasano et al. attribute this disagreement to the additional diffusion resistance induced by surface defects.
- Matteo Fasano
- , Thomas Humplik
- & Pietro Asinari
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Article
| Open AccessIntercalated water layers promote thermal dissipation at bioânano interfaces
Thermal management is important for designing bio-nano interfaces for biosensing and thermotherapic applications. Here the authors perform simulations showing that nm-thick water layers between graphene and cell membranes display layered ordering, promoting interfacial thermal coupling and thermal dissipation.
- Yanlei Wang
- , Zhao Qin
- & Zhiping Xu
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| Open AccessCrystal nuclei templated nanostructured membranes prepared by solvent crystallization and polymer migration
Conventionally porous polymeric membranes for filtration are produced by phase-separation techniques, but this process has reached saturation. Here, Li and co-workers developed a manufacturing process involving oriented green solvent crystallization and polymer migration to form high-performance membranes.
- Bo Wang
- , Jing Ji
- & Kang Li