Article | Open | Published:

Underestimated risks of recurrent long-range ash dispersal from northern Pacific Arc volcanoes

Scientific Reports volume 6, Article number: 29837 (2016) | Download Citation


Widespread ash dispersal poses a significant natural hazard to society, particularly in relation to disruption to aviation. Assessing the extent of the threat of far-travelled ash clouds on flight paths is substantially hindered by an incomplete volcanic history and an underestimation of the potential reach of distant eruptive centres. The risk of extensive ash clouds to aviation is thus poorly quantified. New evidence is presented of explosive Late Pleistocene eruptions in the Pacific Arc, currently undocumented in the proximal geological record, which dispersed ash up to 8000 km from source. Twelve microscopic ash deposits or cryptotephra, invisible to the naked eye, discovered within Greenland ice-cores, and ranging in age between 11.1 and 83.7 ka b2k, are compositionally matched to northern Pacific Arc sources including Japan, Kamchatka, Cascades and Alaska. Only two cryptotephra deposits are correlated to known high-magnitude eruptions (Towada-H, Japan, ca 15 ka BP and Mount St Helens Set M, ca 28 ka BP). For the remaining 10 deposits, there is no evidence of age- and compositionally-equivalent eruptive events in regional volcanic stratigraphies. This highlights the inherent problem of under-reporting eruptions and the dangers of underestimating the long-term risk of widespread ash dispersal for trans-Pacific and trans-Atlantic flight routes.


Predicting the hazards and risk to society of widespread volcanic ash dispersal is compromised by the lack of a complete record of global volcanism with well-constrained evidence of eruptive magnitude, tephra fall volume and dispersal extent1,2. Extensive ash dispersal is recognised as the foremost volcanic hazard that can disrupt a substantial proportion of the population3. The risks to aviation are particularly significant, as exemplified by recent narrowly avoided air accidents (e.g. Redoubt 1989)4 and the substantial economic losses (US$5 billion) suffered due to the enforced airspace closure during the Eyjafjallajökull 2010 eruption5. Assessing the extent of the threat from future events depends entirely on a thorough understanding and compilation of volcanic histories and ash-fall distribution patterns6,7. Given the fragmentary and poorly preserved nature of the geological records, global volcanic databases6,8 are inherently affected by the under-reporting of events and spatial and temporal biases2,9. Some volcanoes are very poorly studied and under-reporting of events becomes more apparent as one goes back in time and is particularly notable for medium-scale events2. Recent findings and observations have highlighted that even moderate-sized events (such as the White River Ash)10 with short-recurrence intervals can distribute ash over much wider geographical areas than previously anticipated10 (Fig. 1a). Low frequency but high-magnitude events are also under-represented in the geological record and a focus on the short and most recent Holocene period may well bias any risk analysis11. Assessing the ash-related risk to the aviation industry with an incomplete history is thus compromised.

Figure 1
Figure 1

(a) Map showing the location of Greenland deep ice-cores investigated in this study and the main Northern Hemisphere volcanic centres active during the Quaternary. In addition, the distribution of the widespread White River Ash tephra deposit10 is shown as an example of a moderate-sized eruption with widespread tephra deposition (see text in main paper), along with major cross polar flight routes36. Map was modified from a base map in the public domain37. (b) Stratigraphic position of the 12 far-travelled cryptotephra deposits (red lines) against the NGRIP δ18O record38. Areas of the ice-cores sampled for cryptotephra content are shown in grey.

We present new evidence of repeated explosive Late Pleistocene eruptions in the Pacific Arc, that are hitherto undocumented in the proximal geological record and dispersed ash up to 8000 km distance from volcanic source.


A search of the Greenland ice-cores has revealed volcanic glass particles that can be traced back to distant eruptive centres in the northern Pacific. Although, the ash-fall record preserved within the ice is swamped by recurrent local Icelandic basaltic eruptions12, twelve cryptotephra deposits (glass-shard concentrations insufficiently numerous to be visible to the naked eye), ranging in age between 11.1 and 83.7 ka b2k, reveal major and trace-element signatures that are inconsistent with an Icelandic anorogenic magmatic setting (Figs 1b and 2, Table 1). These cryptotephra deposits are only able to be detected by melting the ice and exploring the residual particulate material with light microscopy. The cryptotephra deposits are present throughout the last glacial period ranging in stratigraphic position from GI-21e to GS-1/Holocene transition (Fig. 1b) and are deposited during stadial and interstadial events. The glass-shard concentrations range over two orders of magnitude, with half the deposits yielding more than 95 shards, and the other half containing fewer than 36 (Table 1). This overall range in shard abundance, along with the small size of the particles (average 15–41.2 μm) is similar to the abundance and size of shards for tephras from Icelandic sources preserved in the Greenland ice (Table 1)12. We obtained geochemical data for each cryptotephra deposit from single-grain analyses by electron microprobe and laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) (Table 1). Recent technical advances allow small individual glass shards extracted from ice-core material to be analysed for their trace element signatures13. Given the nature and availability of geochemical datasets for proximal deposits, both major and trace elements are used for determining tectonic setting whilst only the major elements (together with chronostratigraphic data) are used for assessing correlations to specific eruptions.

Figure 2
Figure 2

(a) FeO vs. CaO biplot showing the compositions of glass-shard analyses from the 12 ice-core deposits in relation to the Icelandic volcanic field (comprised of glass analyses of dacitic and rhyolitic tephra deposits from Iceland stored in the RESET database)39. (b) AFM ternary diagram showing the magma series and volcanic environment affinities of the cryptotephra deposits analysed in this study. The dashed lines show the various divisions between the calc-alkaline and the tholeiitic fields. The Thingmuli trend would be consistent with Icelandic origin whereas the ice-core cryptotephra deposits exhibit calc-alkaline composition (adapted from)14. (c) Primitive Mantle-normalised40 trace element profile for the ice-core cryptotephra deposits compared to tephras originating from the Icelandic field41. All data are normalised.

Table 1: Northern Pacific cryptotephra deposits present in the Greenland ice-core.

Volcanic Setting

With the exception of NEEM 1400.15 m and NEEM 1603.45 m (sample nomenclature is defined in the methods), all deposits reveal high CaO relative to FeOt values, which distinguishes them from Icelandic eruptives of dacitic and rhyolitic composition (Fig. 2a). The same ten deposits are also calc-alkaline in composition and do not fall on the Thingmuli trend (Fig. 2b) as expected of Icelandic tephras14. Mantle-normalised trace-element profiles for all deposits are characterised by enrichments in the large ion lithophile elements (LILE e.g. Rb, Ba) relative to the high field strength elements (HFSE e.g. Nb, Ta, Ti) and the rare-earth elements (REE La to Lu)15. This feature, along with pronounced depletions in Nb, Ta and Ti, provides diagnostic fingerprints of ash generated in a subduction-tectonic setting and contrasts markedly from expected profiles for anorogenic-derived Icelandic volcanism (Fig. 2c)15. Despite showing major element affinity to Icelandic sources, trace-element data for NEEM 1400.15 m and NEEM 1603.45 m also point towards a subduction-tectonic setting. The closest active subduction zone settings to Greenland are the northern Pacific volcanic arcs and the compositional signatures reported here are consistent with those of the products from the Cascadian, Alaska-Aleutian, Kamchatka-Kurile and Japanese arcs (Fig. 1). The prevailing wind direction and abundant East Asian dust transport to Greenland during the last glacial period support this tephra transport pathway16.

Correlation of Cryptotephra Deposits

Glass shards from the cryptotephra deposits range from dacitic in composition with SiO2 values of 63.52–66.22 wt% (NEEM 1400.15 m) to rhyolitic with SiO2 values of 76.68–77.61 wt% (NGRIP 2441.28 m) (Table 1, Fig. 3a). The potassium values of the twelve deposits also show significant variation, with NEEM 1603.45 m (K2O = 0.62–0.86 wt%) and NEEM 1502.60 m (K2O = 1.12–1.28 wt%) classified in the Low-K series and NEEM 1633.15 m (K2O = 3.05–3.73 wt%) and NEEM 2049.30 m (K2O = 2.70–3.11 wt%) classified in the High-K series with the remaining eight deposits classified in the calc-alkaline series (Table 1, Fig. 3b).

Figure 3
Figure 3

(a) Total alkali vs. silica diagram42. (b) SiO2-K2O plot43. (c) Comparison of glass shard analyses from samples NEEM 1502.60 m/NGRIP1628.25 m with those for glass of the Towada-H46 deposits from Honshu, Japan, and NGRIP 1884.50 m with Mount St. Helens Set M47. (d) Comparison of glass shard analyses from the ice-core cryptotephra deposits with those of potential volcanic sources, Kurile Islands (Tephra N), Kutcharo caldera (Kc-2/3)46, Ata caldera (Ata and SG06-5353)20 and the Eastern Aleutian Arc (VT)48. All data have been normalised.

Although the compositional data point towards northern Pacific Arc sources, matching the ash deposits to reported eruptions of similar age and composition is difficult and could be compounded by differences in compositional ranges between typically more heterogeneous proximal deposits and the more restricted ranges of distal deposits17,18. We draw on the eruptive data compiled in the database of large magnitude explosive volcanic eruptions (LaMEVE)6 and are only able to find two potential matches for our ice-core cryptotephra deposits. The major element signature for NEEM 1502.60 m (which is correlated to NGRIP 1628.25 m)19 overlaps with that for the Towada-H eruption, associated with a magnitude 6.9, VEI 6 event on north-eastern Honshu Island, Japan (Fig. 3c). The NEEM age of 15.7 ± 0.2 ka b2k is consistent with the proximal age of this deposit (10.19–18.55 cal ka BP)20. Geochemical and age similarities are also observed between NGRIP 1884.50 m (28.8 ± 0.8 ka b2k) and the Mount St Helens Set M complex (magnitude 5.3, VEI 5) constrained in age to between 28 and 18 ka BP21 (Fig. 3c).

Where possible, potential sources are suggested for the remainder of the tephras (Table 1), but no correlations can be made to specific eruptions reported in the literature due to age discrepancies, in some cases up to 30,000 years. Some of our suggested sources based on comparisons of available major element data include the Ata and Kutcharo (Japan) calderas to NEEM 2033.75 m and NGRIP 2441.28 m, respectively, but the ice-core ages for these events are mismatched with the local eruption stratigraphy and the proposed ages for the formation of these calderas (Fig. 3d). We argue therefore that these could represent new, previously undocumented eruptions from these sources but we do not rule out other more distal Pacific rim sources such as Indonesia and the Philippines. However, no compositional matches of similar age are identified22.

Chemical Records of Volcanism

Although the discovery of these cryptotephra deposits demonstrates the significant dispersal of ash from non-Icelandic eruptions, only three of these deposits are marked by any concurrent volcanic aerosol deposition preserved in polar ice-cores, in these cases represented as chemical matchpoints between ice-cores23. The remaining nine ash deposits have been dispersed over 8000 km to Greenland but have no associated volcanic aerosol signal preserved in the ice. All of these nine cryptotephra horizons were deposited during cold stadial events (Table 1), which are characterised by high background levels of sulphate deposition and suppressed Electrical Conductivity Measurements (ECM) and Di-electrical Profiling (DEP) levels due to alkaline dust deposition. Therefore, volcanic aerosol indicators for these eruptions may be hidden or have been subdued because of the timing of deposition. Long and unbroken records of ice acidity and sulphate aerosol deposition preserved within the ice typically provide the focus for global volcanism indices24. Our results thus demonstrate that many significant and widespread eruptives will be overlooked during the glacial period if the focus remains solely on aerosol deposition.


The discovery of several far-travelled volcanic ash clouds highlight the inherent problem of under-reporting eruptions and the under-representation of events from volcanoes with long repose times2,9. It is clear that many more eruptions in the past have deposited ash over much larger geographical areas than previously anticipated. Given that our ice-core data-set is in a distal location and with only partial matches to near-source volcanic deposits, the magnitude and explosivity of the eruptive events that generated the ash clouds are unknown. We do not believe that ash dispersal is enhanced by intensified atmospheric circulation during stadial periods25 because some of the tephras are also deposited during interstadial periods (Fig. 1b). However, we argue that the dacitic to rhyolitic chemical compositions and the extent of ash dispersal point towards explosive and voluminous eruptions that characterise these Si-rich (acidic) magmas26. We postulate that they are probably of medium magnitude as these are the ones most likely to be under-reported and undocumented2. However, it is also conceivable that these are large-magnitude events with long return intervals that have been missed in the geological records due to ice removal of proximal deposits, for example. Recent mathematical and modelling analysis of the Japanese eruptions reported in the LaMEVE database6 suggests that a high percentage of high-magnitude eruptions are under-reported over the full Quaternary period27. Whilst not all of the Greenland ice-cores between 11 and 85 ka has been sampled (Fig. 1b), the recurrent interval is approximately every 6000 years over the whole period and every 3000 years if only the 10–30 ka period is considered. Volcanic risk assessments are frequently based on the Holocene period due to the more complete nature of the record3,11, but our results from the last glacial reinforce the urgency to consider longer-term assessments and extra-regional spatial scales to fully capture the impact of these far-reaching ash clouds. Based solely on Holocene data, Kamchatka and Japan are two of the volcanic systems in the Asian-Pacific region showing increased volcanic ash hazards at longer repose periods11.

During the last 100,000 years the most widespread ash deposits include the Younger Toba Tuff (YTT) from Sumatra, Indonesia, found over 7000 km west of the source volcano in Lake Malawi (magnitude 8.8, VEI 8)6,28, the White River Ash dispersed approximately 7000 km east from Mt Churchill, Alaska (magnitude 6.1, VEI 6)6,10 (Fig. 1a), the Vedde Ash dispersed from the Katla Volcano in Iceland to Slovenia and western Russia (magnitude 5.8, VEI 6)6,29 and ash from the Campanian Ignimbrite (CI) eruption of Campi Flegrei, Italy, was dispersed more than 2200 km east to Russia and over 1000 km southward to the north African coast (magnitude 7.1, VEI 7)6,30 (Fig. 1a). Whilst two of these far-travelled eruptions, the YTT and CI, are both classified as super-eruptions, the White River Ash and Vedde Ash are one to two orders of magnitude lower volume in comparison. In addition, the Pacific Arc tephras identified in Greenland, do not correlate with some of the most explosive and high-magnitude eruptions from this region (e.g. the Japanese VEI 8 eruptions, AT and Aso-4 eruptions)6,20. Our discoveries of potential gaps in the Japanese volcanic stratigraphy support previous findings27 and highlight the importance of distal tephra studies for building complete eruptive histories. These eruptions were probably of medium magnitude, capable of generating widespread ash clouds, but we cannot rule out the possibility that these are as yet undiscovered large-magnitude eruptions27. Such far-travelled ash clouds are reported to have caused damage to aircraft in the past31. Ash probability maps based on historical eruptions in the North Pacific do not predict ash leaving the region32. The risk of disruption to trans-Pacific and trans-Atlantic flight routes by recurrent ash dispersal from the Pacific Arc is therefore greater than previously thought.


The 12 deposits presented here have been identified as part of continued efforts to establish a tephrochronological framework for the Greenland ice-cores12. Long and continuous time-intervals have been sampled throughout the last glacial period rather than targeted sampling intervals dictated by the ages of known high-magnitude eruptions. The ice-core samples were processed for tephra investigations according to the procedures outlined in12. Cryptotephra deposits identified in the ice have been given unique labels based on the name of the ice-core and the basal depth of the sample containing the ash-sized glass shards e.g. the cryptotephra found in NGRIP sample 1399.95–1400.15 m will be NGRIP 1400.15 m.

Both major and trace elements were used to determine the tectonic setting of the volcanoes that generated the tephra deposits found in the cores. Identification of potential correlative tephra deposits was undertaken by compiling a list of dacitic and rhyolitic eruptions from northern Pacific Arc volcanoes with a VEI of ≥5 aged between 10 and 80 ka BP from the LaMEVE database6. Due to the limited availability of proximal geochemical datasets, only major element data are used for the attempted correlation to specific eruptions.

Major element results on single-glass shards were obtained by electron-probe microanalysis (EPMA) during seven analytical periods at the Tephra Analytical Unit at the University of Edinburgh, UK. A Cameca SX-100 electron microprobe with five vertical wavelength dispersive spectrometers was employed to analyse 10 major and minor elements within individual glass shards. Both 3- and 5- μm beam diameters were used, according to the grain-size of the glass shards making up the samples, and the operating conditions followed those outlined in33. Secondary standard analyses of Lipari obsidian and BCR-2 G basalt were analysed at the beginning and end of each day, as well as at regular intervals between analyses of samples to monitor the accuracy and precision of the instrument and data. The major oxide data are normalised to an anhydrous basis and raw geochemical results, including the operating conditions, beam diameter employed for each sample, and standard data are provided in the Supplementary information.

LA-ICP-MS analyses were performed at Aberystwyth University to analyse the trace element composition of single glass shards from each deposit. A Coherent GeoLas 193 nm Excimer laser system was coupled to a Thermo Finnegan Element 2 high-resolution sector field ICP-MS13. Analyses were performed with a 10 μm laser beam diameter, the laser was pulsed at 5 Hz with a fluence of 10 J/cm2, and had a flash duration of ~20 ns. Each acquisition took 24 s, with Ar as the carrier gas. The internal standard used was 29Si (determined by EPMA analysis). Geochemically distinct MPI-DING34 reference glasses were used to monitor the analytical accuracy and can be found in the Supplementary data. Analyses using a 10 μm laser beam diameter are at the limit of instrumental sensitivity for many elements13, and while analytical accuracy remains consistent between sessions, slight variations in operating conditions (instrument sensitivity, tuning, analytical blanks) can lead to differences in signal/noise, (and thus detection limits) and analytical precision. Given the small number of glass-shard analyses available from these cryptotephras deposits, these methodological challenges should be considered if these data are utilised in future comparisons.

Ages are assigned to each tephra according to the NGRIP GICC05 annual-layer counted chronology that has also been transferred to all deep ice-cores in Greenland23,35. This timescale delimits age errors based on the concept of maximum counting errors (MCE), which are considered to represent 2σ uncertainties35.

Additional Information

How to cite this article: Bourne, A. J. et al. Underestimated risks of recurrent long-range ash dispersal from northern Pacific Arc volcanoes. Sci. Rep. 6, 29837; doi: 10.1038/srep29837 (2016).


  1. 1.

    & Tying down eruption risk. Nature Geosci 8, 248–250, 10.1038/ngeo2403 (2015).

  2. 2.

    et al. Characterisation of the Quaternary eruption record: analysis of the Large Magnitude Explosive Volcanic Eruptions (LaMEVE) database. Journal of Applied Volcanology 3, 5 (2014).

  3. 3.

    , , & Regional ash fall hazard II: Asia-Pacific modelling results and implications. Bulletin of Volcanology 74, 1713–1727, 10.1007/s00445-012-0628-7 (2012).

  4. 4.

    & In Volcanic Hazards, Risks and Disasters (ed ShroderPaolo Papale) 87–108 (Elsevier, 2015).

  5. 5.

    , & In Governing Disasters The Challenges of Emergency Risk Regulation (ed ) 27–49 (Edward Elgar Publishing, Inc, 2011).

  6. 6.

    et al. Global database on large magnitude explosive volcanic eruptions (LaMEVE). J Appl Volcanol 1, 1–13 (2012).

  7. 7.

    , , , & A 7000 yr perspective on volcanic ash clouds affecting northern Europe. Geology, 10.1130/g32146.1 (2011).

  8. 8.

    (ed.) Global Volcanism Program, Volcanoes of the World, v. 4.4.3. Smithsonian Institution (Date of Access: 12/03/2016) (2013).

  9. 9.

    , & Recurrence rates of large explosive volcanic eruptions. J Geophys Res 115, B06203 (2010).

  10. 10.

    et al. Transatlantic distribution of the Alaskan White River Ash. Geology 42, 875–878, 10.1130/g35945.1 (2014).

  11. 11.

    , , , & Emulating volcanic ash fall for multi-scale analysis: Development of the VAPAHR tool and application to the Asia-Pacific region for the United Nations Global Assessment Report 2015. 1–75 (2014).

  12. 12.

    et al. A tephra lattice for Greenland and a reconstruction of volcanic events spanning 25–45 ka b2k. Quaternary Science Reviews 118, 122–141, doi: (2015).

  13. 13.

    , & Microbeam methods for the analysis of glass in fine-grained tephra deposits: a SMART perspective on current and future trends. Geological Society, London, Special Publications 398, 29–46, 10.1144/sp398.1 (2014).

  14. 14.

    et al. Holocene tephra from Iceland and Alaska in SE Greenland Shelf Sediments. Geological Society, London, Special Publications 398, 157–193, 10.1144/sp398.6 (2014).

  15. 15.

    et al. The major and trace element glass compositions of the productive Mediterranean volcanic sources: tools for correlating distal tephra layers in and around Europe. Quaternary Science Reviews 118, 48–66, doi: (2015).

  16. 16.

    , & Two distinct seasonal Asian source regions for mineral dust deposited in Greenland (NorthGRIP). Geophysical Research Letters 30, n/a–n/a, 10.1029/2002GL016446 (2003).

  17. 17.

    & Tephrochronology. In Encyclopaedia of Scientific Dating Methods (ed , (editors)) pp. 783–799. (Springer, 2015).

  18. 18.

    , , & Compositional heterogeneity in tephra deposits resulting from the eruption of multiple magma bodies: implications for tephrochronology. Quaternary International 178, 44–53 (2008).

  19. 19.

    , , , & Volcanic ash layers from the Last Glacial Termination in the NGRIP ice core. Journal of Quaternary Science 20, 209–219, 10.1002/Jqs.908 (2005).

  20. 20.

    et al. Identification and correlation of visible tephras in the Lake Suigetsu SG06 sedimentary archive, Japan: chronostratigraphic markers for synchronising of east Asian/west Pacific palaeoclimatic records across the last 150 ka. Quaternary Science Reviews 67, 121–137, 10.1016/j.quascirev.2013.01.026 (2013).

  21. 21.

    et al. The Pleistocene eruptive history of Mount St. Helens, Washington, from 300,000 to 12,800 years before present: Chapter 28 in A volcano rekindled: the renewed eruption of Mount St. Helens, 2004–2006. Report No. 1750–28, 593–627 (Reston, VA, 2008).

  22. 22.

    , , , & Global Volcanic Hazards and Risk. (Cambridge University Press, Cambridge, 2015).

  23. 23.

    et al. A stratigraphic framework for abrupt climatic changes during the Last Glacial period based on three synchronized Greenland ice-core records: refining and extending the INTIMATE event stratigraphy. Quaternary Science Reviews 106, 14–28, doi: (2014).

  24. 24.

    , & Bipolar correlation of volcanism with millennial climate change. Proceedings of the National Academy of Sciences of the United States of America 101, 6341–6345, 10.1073/pnas.0400323101 (2004).

  25. 25.

    et al. Major features and forcing of high-latitude northern hemisphere atmospheric circulation using a 110,000-year-long glaciochemical series. Journal of Geophysical Research: Oceans 102, 26345–26366, 10.1029/96JC03365 (1997).

  26. 26.

    et al. The largest volcanic eruptions on Earth. Earth Sci Rev 102, 207–229 (2010).

  27. 27.

    et al. How many explosive eruptions are missing from the geologic record?Analysis of the quaternary record of large magnitude explosive eruptions in Japan. Journal of Applied Volcanology 4, 1–15, 10.1186/s13617-015-0035-9 (2015).

  28. 28.

    , & Ash from the Toba supereruption in Lake Malawi shows no volcanic winter in East Africa at 75 ka. Proceedings of the National Academy of Sciences 110, 8025–8029, 10.1073/pnas.1301474110 (2013).

  29. 29.

    et al. Widespread dispersal of Icelandic tephra: how does the Eyjafjoll eruption of 2010 compare to past Icelandic events? Journal of Quaternary Science 25, 605–611, 10.1002/Jqs.1421 (2010).

  30. 30.

    , , & The Campanian Ignimbrite Eruption: New Data on Volcanic Ash Dispersal and Its Potential Impact on Human Evolution. Plos One 8, e65839, 10.1371/journal.pone.0065839 (2013).

  31. 31.

    The 1989–1990 eruption of Redoubt Volcano, Alaska: impacts on aircraft operations. Journal of Volcanology and Geothermal Research 62, 301–316, doi: (1994).

  32. 32.

    , & Predicting regions susceptible to high concentrations of airborne volcanic ash in the North Pacific region. Journal of Volcanology and Geothermal Research 148, 295–314, doi: (2005).

  33. 33.

    High spatial resolution electron probe microanalysis of tephras and melt inclusions without beam-induced chemical modification. Holocene 22, 119–125, 10.1177/0959683611409777 (2012).

  34. 34.

    & Reference materials in geoanalytical research - Review for 2004 and 2005. Geostand Geoanal Res 30, 143–156, 10.1111/j.1751-908X.2006.tb01057.x (2006).

  35. 35.

    et al. A 60 000 year Greenland stratigraphic ice core chronology. Climate of the Past 4, 47–57, 10.5194/Cp-4-47-2008 (2008).

  36. 36.

    OpenFlights, (Date of access: 27/11/2015) (2015).

  37. 37.

    WikiCommons. North Pole Blank Map, (2015).

  38. 38.

    NGRIP Members. High-resolution record of Northern Hemisphere climate extending into the last interglacial period. Nature, 147–151 (2004).

  39. 39.

    , , , & The RESET tephra database and associated analytical tools. Quaternary Science Reviews 118, 33–47, doi: (2015).

  40. 40.

    Sun, S. S. & McDonough, W. F. Chemical and isotopic systematics of oceanic basalts: implications for mantle composition and processes. Geological Society, London, Special Publications 42, 313–345, 10.1144/gsl.sp.1989.042.01.19 (1989).

  41. 41.

    et al. Re-evaluation and extension of the Marine Isotope Stage 5 tephrostratigraphy of the Faroe Islands region: The cryptotephra record. Palaeogeography, Palaeoclimatology, Palaeoecology 409, 153–168, doi: (2014).

  42. 42.

    , , & A chemical classification of volcanic rocks based on the Total Alkali-Silica diagram. Journal of Petrology 27, 745–750 (1986).

  43. 43.

    & Geochemistry of Eocene calc-alkaline volcanic rocks from the Alban Hills (Roman comagmatic region) as inferred from trace element geochemistry. Contrib. Mineral. Petrol 58 (1976).

  44. 44.

    et al. Consistently dated records from the Greenland GRIP, GISP2 and NGRIP ice cores for the past 104 ka reveal regional millennial-scale δ18O gradients with possible Heinrich event imprint. Quaternary Science Reviews 106, 29–46, doi: (2014).

  45. 45.

    et al. A first chronology for the North Greenland Eemian Ice Drilling (NEEM) ice core. Climate of the Past 9, 2713–2730, 10.5194/cp-9-2713-2013 (2013).

  46. 46.

    & element composition of volcanic glass shards in the late Quaternary widespread tephras in Japan - distinction of tephras using K2O-TiO2 diagrams. Bulletin of the Geological Survey of Japan 57, 239–258 (2006).

  47. 47.

    & A 250 k.y. record of Cascade arc pyroclastic volcanism from late Pleistocene lacustrine sediments near Summer Lake, Oregon, USA. Geosphere 6, 397–429, 10.1130/ges00515.1 (2010).

  48. 48.

    , , , & A catalogue of late Cenozoic tephra beds in the Klondike goldfields and adjacent areas, Yukon Territory1Yukon Geological Survey Contribution 010. Canadian Journal of Earth Sciences 48, 1386–1418, 10.1139/e10-110 (2011).

Download references


AJB, PMA and SMD are financially supported by the European Research Council (TRACE project) under the European Union’s Seventh Framework Programme (FP7/2007-2013) / ERC grant agreement no. [259253]. SMD and PGA acknowledge support from the Leverhulme Trust (Philip Leverhulme Prize 2011). EC was financially supported by STSM funding from EU-COST INTIMATE action (ES0907). VP acknowledges support from the Russian Science Foundation grant #16-17-10035. We would like to thank Drs Chris Hayward and David Steele for their assistance with the use of the electron microprobe at the Tephrochronology Analytical Unit, University of Edinburgh. Thanks are due also to Gareth James, Gwydion Jones, Kathryn Lacey, Rhian Meara and Adam Griggs (Swansea University) for help with the ice-core sampling and slide preparation. We are grateful to David Lowe and an anonymous reviewer for their comments on an earlier draft of the manuscript. This paper is a contribution to the Climate Change Consortium of Wales (C3W). It contributes to the EXTRAS project (EXTending TephRAS as a global geoscientific research tool stratigraphically, spatially, analytical, and temporally within the Quaternary), an INTAV-led project (International Focus Group on Tephrochronology and Volcanism) within the Stratigraphy and Chronology Commission (SACCOM) of the International Union for Quaternary research (INQUA).

Author information

Author notes

    • A. J. Bourne

    Present address: School of Geography, Queen Mary University of London, London, UK.

    • P. G. Albert

    Present address: Research Laboratory for Archaeology and the History of Art, University of Oxford, Oxford, UK.


  1. Department of Geography, College of Science, Swansea University, Swansea, UK

    • A. J. Bourne
    • , P. M. Abbott
    • , P. G. Albert
    • , E. Cook
    •  & S. M. Davies
  2. Centre for Ice and Climate, Niels Bohr Institute, University of Copenhagen, Denmark

    • E. Cook
    •  & A. Svensson
  3. Department of Geography and Earth Sciences, Aberystwyth University, Aberystwyth, UK

    • N. J. G. Pearce
  4. Inst. of Volcanology and Seismology, Petropavlovsk-Kamchatsky, Russia

    • V. Ponomareva


  1. Search for A. J. Bourne in:

  2. Search for P. M. Abbott in:

  3. Search for P. G. Albert in:

  4. Search for E. Cook in:

  5. Search for N. J. G. Pearce in:

  6. Search for V. Ponomareva in:

  7. Search for A. Svensson in:

  8. Search for S. M. Davies in:


S.M.D. obtained financial support for the project. A.J.B., P.M.A., P.G.A. and E.C. carried out laboratory, geochemical and data analysis. N.J.G.P., A.S. and V.P. provided assistance with data analysis. The manuscript was written by A.J.B. and S.M.D. with contributions from all other authors.

Competing interests

The authors declare no competing financial interests.

Corresponding author

Correspondence to A. J. Bourne.

Supplementary information

About this article

Publication history






By submitting a comment you agree to abide by our Terms and Community Guidelines. If you find something abusive or that does not comply with our terms or guidelines please flag it as inappropriate.