Single-crystal black phosphorus nanoribbons have been grown through chemical vapour transport, using black phosphorus nanoparticles as seeds. The nanoribbons orient exclusively along the zigzag direction and have good semiconductor properties that render them suitable for use as channel material in field-effect transistors.
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References
Li, L. et al. Black phosphorus field-effect transistors. Nat. Nanotechnol. 9, 372–377 (2014). This paper reports the exfoliation of BP and fabrication of BP field-effect transistors.
Bridgman, P. W. Two new modifications of phosphorus. J. Am. Chem. Soc. 36, 1344–1363 (1914). This paper reports the synthesis of bulk BP.
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Watts, M. C. et al. Production of phosphorene nanoribbons. Nature 568, 216–220 (2019). This paper reports the top-down synthesis of phosphorene nanoribbons.
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This is a summary of: Wang, H. et al. Seeded growth of single-crystal black phosphorus nanoribbons. Nat. Mater. https://doi.org/10.1038/s41563-024-01830-2 (2024).
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Semiconducting black phosphorus nanoribbons grown on insulating substrates. Nat. Mater. 23, 458–459 (2024). https://doi.org/10.1038/s41563-024-01844-w
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DOI: https://doi.org/10.1038/s41563-024-01844-w
