Understanding and controlling anionic redox processes is pivotal for the design of new Li-ion battery and water-splitting materials.
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References
T. Ohzuku, Y. M. Chem. Lett. 7, 642–643 (2001).
Thackeray, M. M. et al. J. Mater. Chem. 17, 3112 (2007).
Lu, Z., Beaulieu, L. Y., Donaberger, R. A., Thomas, C. L. & Dahn, J. R. J. Electrochem. Soc. 149, A778 (2002).
Thackeray, M. M., Johnson, C. S., Vaughey, J. T., Ha, N. & Hackney, S. A. J. Mater. Chem. 15, 2257 (2005).
Sathiya, M. et al. Nature Mater. 12, 827–835 (2013).
Sathiya, M. et al. Nature Commun. 6, 6276 (2015).
Tarascon, J. M. et al. J. Electrochem. Soc. 420, 410–420 (1999).
Rivadulla, F., Zhou, J.-S. & Goodenough, J. B. Phys. Rev. B 68, 075108 (2003).
Foix, D., Mariyappan, S., McCalla, E., Tarascon, J.-M. & Gonbeau, D. J. Phys. Chem. C (in the press).
McCalla, E. et al. Science 350, 1516–1521 (2015).
Yabuuchi, N. et al. Proc. Natl Acad. Sci. USA 112, 7650–7655 (2015).
Rozier, P. et al. Electrochem. Commun. 53, 29–32 (2015).
Nørskov, J. K. et al. J. Phys. Chem. B 108, 17886–17892 (2004).
Man, I. C. et al. ChemCatChem 3, 1159–1165 (2011).
Suntivich, J., May, K. J., Gasteiger, H. A., Goodenough, J. B. & Shao-Horn, Y. Science 334, 1383–1385 (2011).
Suntivich, J. et al. Nature Chem. 3, 546–550 (2011).
Surendranath, Y., Kanan, M. W. & Nocera, D. G. J. Am. Chem. Soc. 132, 16501–16509 (2010).
Mavros, M. G. et al. Inorg. Chem. 53, 6386–6397 (2014).
De Faria, L. A., Boodts, J. F. C. & Trasatti, S. J. Appl. Electrochem. 26, 1195–1199 (1996).
May, K. J. et al. J. Phys. Chem. Lett. 3, 3264–3270 (2012).
Risch, M. et al. J. Phys. Chem. C 117, 8628–8635 (2013).
Grimaud, A. et al. Nature Commun. 4, 2439 (2013).
Hong, W. T. et al. J. Phys. Chem. C 119, 2063–2072 (2015).
Lee, Y.-L., Kleis, J., Rossmeisl, J., Shao-Horn, Y. & Morgan, D. Energy Environ. Sci. 4, 3966–3970 (2011).
Mueller, D. N., Machala, M. L., Bluhm, H. & Chueh, W. C. Nature Commun. 6, 6097 (2015).
Goodenough, J. B. & Kim, Y. Chem. Mater. 22, 587–603 (2010).
Rouxel, J. Chem. Eur. J. 2, 1053–1059 (1996).
Blandeau, L., Ouvrard, G., Calage, Y., Brec, R. & Rouxel, J. J. Phys. C 4271, 4271–4281 (1987).
Nücker, N., Fink, J., Fuggle, J., Durham, P. & Temmerman, W. Phys. Rev. B 37, 5158–5163 (1988).
Saubanère, M., McCalla, E., Tarascon, J.-M. & Doublet, M.-L. Energy Environ. Sci. http://dx.doi.org/10.1039/C5EE03048J (2015).
Koga, H., Croguennec, L. & Me, M. J. Phys. Chem. C 118, 5700–5709 (2014).
Sathiya, M. et al. Chem. Commun. 49, 11376–11378 (2013).
McCalla, E. et al. J. Electrochem. Soc. 162, A1341–A1351 (2015).
McCalla, E. et al. J. Am. Chem. Soc. 137, 4804–4814 (2015).
Sathiya, M. et al. Nature Mater. 14, 230–238 (2015).
Wattiaux, A. J. Electrochem. Soc. 134, 1714 (1987).
Bockris, J. O. & Otagawa, T. J. Phys. Chem. 87, 2960–2971 (1983).
Bockris, J. O. & Otagawa, T. J. Electrochem Soc. 131, 290–302 (1984).
Grimaud, A. et al. J. Phys. Chem. C 117, 25926–25932 (2013).
Suntivich, J., May, K. J., Gasteiger, H. A., Goodenough, J. B. & Shao-Horn, Y. Science 334, 1383–1385 (2011).
Hong, W. et al. Energy Environ. Sci. 8, 1404–1427 (2015).
Suntivich, J. et al. J. Phys. Chem. C 118, 1856–1863 (2014).
Wohlfahrt-Mehrens, M. & Heitbaum, J. J. Electroanal. Chem. 237, 251–260 (1987).
Surendranath, Y., Kanan, M. W. & Nocera, D. G. J. Am. Chem. Soc. 132, 16501–16509 (2010).
Wang, H. et al. Nature Commun. 6, 7261 (2015).
Maiyalagan, T., Jarvis, K. A., Therese, S., Ferreira, P. J. & Manthiram, A. Nature Commun. 5, 3949 (2014).
Lee, S. W. et al. J. Am. Chem. Soc. 134, 16959–16962 (2012).
Ebbinghaus, S. G., Erztoument, C. & Marozau, I. J. Solid State Chem. 180, 3393–3400 (2007).
Götzfried, T., Reller, A. & Ebbinghaus, S. G. Inorg. Chem. 44, 6550–6557 (2005).
Grasset, F., Dussarrat, C. & Darriet, J. J. Mater. Chem. 7, 1911–1915 (1997).
Demourgues, A. et al. J. Solid State Chem. 105, 458–468 (1993).
Mefford, J. T., Hardin, W. G., Dai, S., Johnston, K. P. & Stevenson, K. J. Nature Mater. 13, 726–732 (2014).
Hinnemann, B. et al. J. Am. Chem. Soc. 127, 5308–5309 (2005).
Voiry, D. et al. Nature Mater. 12, 850–855 (2013).
Jaramillo, T. F. et al. Science 317, 100–102 (2007).
Popczun, E. J. et al. J. Am. Chem. Soc. 135, 9267–9270 (2013).
Vrubel, H. & Hu, X. Angew. Chem. Int. Ed. 51, 12703–12706 (2012).
Chen, W. et al. Angew. Chem. Int. Ed. 51, 6131–6135 (2012).
Pralong, V., Souza, D. C. S., Leung, K. T. & Nazar, L. F. Electrochem. Commun. 4, 516–520 (2002).
Bichat, M.-P. et al. Chem. Mater. 16, 1002–1013 (2004).
Trześniewski, B. J. et al. J. Am. Chem. Soc. 137, 15112–15121 (2015).
Fierro, S., Nagel, T., Baltruschat, H. & Comninellis, C. Electrochem. Commun. 9, 1969–1974 (2007).
Diaz-Morales, O., Calle-Vallejo, F., de Munck, C. & Koper, M. T. M. Chem. Sci. 4, 2334 (2013).
Acknowledgements
We thank M. Gauthier, K. A. Stoerzinger and L. Giordano at MIT, M. Saubanère and M.-L. Doublet at the Institut Charles Gerhardt in Montpellier, and E. McCalla at Collège de France for discussion. J.-M.T. and A.G. acknowledges funding from the European Research Council (ERC) (FP/2014)/ERC Grant-Project 670116-ARPEMA.
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Grimaud, A., Hong, W., Shao-Horn, Y. et al. Anionic redox processes for electrochemical devices. Nature Mater 15, 121–126 (2016). https://doi.org/10.1038/nmat4551
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DOI: https://doi.org/10.1038/nmat4551
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