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Nanorings and rods interconnected by self-assembly mimicking an artificial network of neurons
Molecularly interconnected networks are the building blocks for molecular circuits in nanoelectronic devices, but a mass production with tunable properties is difficult. Escárcega–Bobadilla et al.develop an approach to form interconnected self-assembled nano-rings, which resemble a network of neurons.
- Martha V. Escárcega-Bobadilla
- , Gustavo A. Zelada-Guillén
- & Arjan W. Kleij
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Tumour-on-a-chip provides an optical window into nanoparticle tissue transport
The interaction of nanoparticles with target tissues is important in the design of nanoparticle-based therapies. Here, the authors develop a microfluidic chip to assess the interaction of nanoparticles with tumour tissues and demonstrate its capacity to predict in vivonanoparticle behaviour.
- Alexandre Albanese
- , Alan K. Lam
- & Warren C.W. Chan
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Stochastic switching of cantilever motion
Microcantilevers made from flexible materials exhibit nonlinear dynamic behaviour such as bistability. Venstra et al.describe how noise induces transitions between the states in a strongly nonlinear vibrating cantilever and exploit the noisy environment to improve the signal transduction.
- Warner J. Venstra
- , Hidde J. R. Westra
- & Herre S. J. van der Zant
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| Open AccessGreen chemistry and nanofabrication in a levitated Leidenfrost drop
Droplets of water on very hot surfaces form levitating droplets, according to the Leidenfrost effect. Here, the authors show that green chemistry can be performed in these charged droplets, demonstrated by the synthesis of a range of nanoparticles, nanoscale coatings and porous metallic materials.
- Ramzy Abdelaziz
- , Duygu Disci-Zayed
- & Mady Elbahri
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| Open AccessAttomolar DNA detection with chiral nanorod assemblies
Nanoscale plasmonic assemblies are known to display exceptionally strong chiral optical activity. Here, the authors assemble gold nanorods into DNA-bridged chiral systems, and demonstrate their high efficiency for DNA detection at very low concentrations.
- Wei Ma
- , Hua Kuang
- & Nicholas A. Kotov
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Large modulation of zero-dimensional electronic states in quantum dots by electric-double-layer gating
The manipulation of electronic states in quantum dots is important to control their properties for applications in electronics and spintronics. Shibata and colleagues achieve a large modulation of the energy level spacing in InAs quantum dots by using a liquid-gating technique.
- Kenji Shibata
- , Hongtao Yuan
- & Kazuhiko Hirakawa
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Deterministic quasi-random nanostructures for photon control
The control of propagating light is a crucial aspect in photonics. Here Martins et al.demonstrate that by a careful design of their Fourier spectra, quasi-random nanostructures can achieve such control very efficiently.
- Emiliano R. Martins
- , Juntao Li
- & Thomas F. Krauss
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Tailoring the chirality of magnetic domain walls by interface engineering
Current-driven domain wall propagation in ferromagnetic layers adjacent to normal metals can be very fast, which could recently be explained by their chirality. Here, the authors show means of controlling the magnetic chirality, which opens the possibility to tune the dynamics of domain walls.
- Gong Chen
- , Tianping Ma
- & Andreas K. Schmid
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Molecular actuators driven by cooperative spin-state switching
Molecular actuators hold potential in a number of sensing applications but require careful design to ensure specific functionality. Shepherdet al.report a new platform for molecular actuators based on spin crossover materials, whose response can be controlled by various stimuli or chemical modification.
- Helena J. Shepherd
- , Il’ya A. Gural’skiy
- & Azzedine Bousseksou
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| Open AccessFlash freezing route to mesoporous polymer nanofibre networks
Mesoporous polymeric materials are good candidates for advanced separation materials, though their low-cost production remains challenging. Here, the authors report a microphase separation technique for the fabrication of nanoporous networks from frozen solutions of common polymers.
- Sadaki Samitsu
- , Rui Zhang
- & Izumi Ichinose
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Formation of nanodiamonds at near-ambient conditions via microplasma dissociation of ethanol vapour
Nanodiamonds are small clusters of carbon that are of use in various nanotechnology applications such as spintronics, but are difficult to synthesize. Here Kumar et al. achieve the fabrication of nanodiamonds 2–5 nm in size at near-ambient conditions by a microplasma process.
- Ajay Kumar
- , Pin Ann Lin
- & R. Mohan Sankaran
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Plasmon-induced photonic and energy-transfer enhancement of solar water splitting by a hematite nanorod array
Plasmonic nanostructures may enhance solar energy collection. Here, the authors exploit both plasmon-induced resonant energy transfer and surface plasmon polaritons in a hematite–gold nano-array, leading to a tenfold increase in the photocurrent at a bias of 0.23 V in a photoelectrochemical cell.
- Jiangtian Li
- , Scott K. Cushing
- & Nianqiang Wu
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A plasma-treated chalcogenide switch device for stackable scalable 3D nanoscale memory
To reach terabit density in random access memory devices, the select switching and storage components need to be improved. Here, the authors fabricate a fully stackable switching device based on chalcogenides, which reaches an exceptional performance following reactive nitrogen and nitrogen plasma treatments.
- Myoung-Jae Lee
- , Dongsoo Lee
- & In-Kyeong Yoo
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Tailoring the hydrophobicity of graphene for its use as nanopores for DNA translocation
Graphene nanopores hold great potential for single-molecule DNA screening; however, pore clogging due to hydrophobic interactions is a severe problem. Schneider et al. show that this can be prevented by non-covalently coating graphene with an ultrathin hydrophilic self-assembled monolayer.
- Grégory F. Schneider
- , Qiang Xu
- & Cees Dekker
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| Open AccessMultiplexed biomimetic lipid membranes on graphene by dip-pen nanolithography
The sensitivity and selectivity of graphene-based biosensors depends on attaching various functional groups to graphene. Hirtz et al. use dip-pen nanolithography to directly write phospholipid membranes on graphene, which enables multiplexed and heterogeneous non-covalent functionalization.
- Michael Hirtz
- , Antonios Oikonomou
- & Aravind Vijayaraghavan
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Tip-enhanced nano-Raman analytical imaging of locally induced strain distribution in carbon nanotubes
Tip-enhanced Raman scattering microscopy gives high-resolution information on nanostructures, yet measurements on more intrinsic properties have been elusive. Yano et al. develop a tip-enhanced method to induce strain in carbon nanotubes and image its distribution along the tube length.
- Taka-aki Yano
- , Taro Ichimura
- & Satoshi Kawata
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| Open AccessGrowth of carbon nanotubes via twisted graphene nanoribbons
Carbon nanotubes can be considered as rolled-up small sheets of graphene. Here Lim and colleagues demonstrate this process, by fabricating carbon nanotubes through a thermally induced process of self-intertwining of graphene nanoribbons.
- Hong En Lim
- , Yasumitsu Miyata
- & Hisanori Shinohara
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Pair distribution function computed tomography
Determining the nanostructure within complex composites may lead to greater understanding of their properties. Here, the authors demonstrate the application of X-ray atomic pair distribution function computed tomography to resolve the physicochemical properties of palladium nanoparticles on an alumina catalyst.
- Simon D. M. Jacques
- , Marco Di Michiel
- & Simon J. L. Billinge
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Direct measurement of the absolute absorption spectrum of individual semiconducting single-wall carbon nanotubes
A detailed knowledge of the properties of carbon nanotubes is required for their utilization in practical devices. Here the measurement of the absorption spectra of individual carbon nanotubes by Blancon et al.provides an important feedback to the modelling of their intrinsic properties.
- Jean-Christophe Blancon
- , Matthieu Paillet
- & Fabrice Vallée
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| Open AccessStrong Casimir force reduction through metallic surface nanostructuring
The Casimir force between two objects in close distance to each other can be an important yet undesirable force for nanoscale devices. Here, Intravaia et al. observe that nanostructured metal surfaces show a Casimir force that is reduced even further than suggested by existing theoretical models.
- Francesco Intravaia
- , Stephan Koev
- & Daniel López
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Stable platinum nanoparticles on specific MgAl2O4 spinel facets at high temperatures in oxidizing atmospheres
Supported platinum nanoparticles are highly active catalysts, but often gradually degrade under standard reaction conditions. Here, a well-defined spinel material is used as a support, resulting in a catalyst capable of maintaining performance even after severe thermal aging in oxidizing atmospheres.
- Wei-Zhen Li
- , Libor Kovarik
- & Charles H. F. Peden
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Complete gate control of supercurrent in graphene p–n junctions
Josephson junctions composed of graphene are limited by incomplete gate control of the supercurrent, impeding their development for superconducting quantum devices. Here, the authors fabricate bipolar Josephson junctions of graphene, allowing supercurrent on/off switching through electrostatic gating.
- Jae-Hyun Choi
- , Gil-Ho Lee
- & Hu-Jong Lee
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Tailoring deposition and morphology of discharge products towards high-rate and long-life lithium-oxygen batteries
Poor rate capability and low cycle stability are common problems in lithium-oxygen batteries. Xuet al.present a free-standing palladium-modified carbon-based cathode with a tailored porous honeycomb-like structure, which is capable of high-rate and long-term battery operation.
- Ji-Jing Xu
- , Zhong-Li Wang
- & Xin-Bo Zhang
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Ordered bilayer ruthenium–platinum core-shell nanoparticles as carbon monoxide-tolerant fuel cell catalysts
Ruthenium can alleviate poisoning effects of carbon monoxide on platinum catalysts, but is prone to dissolution in fuel cells. Hsieh et al.synthesize ordered ruthenium–platinum nanoparticles with well-defined platinum bilayer shells, leading to high carbon monoxide tolerance and superior durability.
- Yu-Chi Hsieh
- , Yu Zhang
- & Jia X Wang
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| Open AccessGraphene-based in-plane micro-supercapacitors with high power and energy densities
Micro-supercapacitors offer the advantage of high power density over lithium batteries and high energy density over electric capacitors, but integration of these advantages is yet to be achieved. Wu et al. develop a graphene-based in-plane micro-supercapacitor with ultrahigh power and energy densities.
- Zhong–Shuai Wu
- , Khaled Parvez
- & Klaus Müllen
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Two-dimensional vanadyl phosphate ultrathin nanosheets for high energy density and flexible pseudocapacitors
Graphene-like materials with pseudocapacitive characteristics are desirable for flexible solid-state pseudocapacitors. Here Wu et al. report such a graphene analogue, vanadyl phosphate ultrathin nanosheets, which exhibits excellent pseudocapacitive properties, leading to a high energy density.
- Changzheng Wu
- , Xiuli Lu
- & Yi Xie
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Diameter-dependent ion transport through the interior of isolated single-walled carbon nanotubes
Calculations suggest that ion transport through nanochannels is significantly modified as the diameter approaches molecular dimensions. Choi et al.introduce a single-nanotube platform to demonstrate this effect and find a maximum ion transport rate at a diameter of approximately 1.6 nm.
- Wonjoon Choi
- , Zachary W. Ulissi
- & Michael S. Strano
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Free-decay and resonant methods for investigating the fundamental limit of superhydrophobicity
Knowing how moving droplets dissipate energy is important for designing superhydrophobic surfaces, but measuring such small energy losses is challenging. Timonen et al.develop a technique to do this, which monitors freely decaying and resonant oscillations of moving magnetic droplets.
- Jaakko V. I. Timonen
- , Mika Latikka
- & Robin H. A. Ras
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| Open AccessCarbon nanotubes on a spider silk scaffold
The use of spider silk in electronic devices is dependent on its compatibility with electrically conductive materials. Here the authors modify spider silk with carbon nanotubes to produce a strong, flexible and electrically conductive thread.
- Eden Steven
- , Wasan R. Saleh
- & James S. Brooks
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DNA-directed self-assembly of shape-controlled hydrogels
The development of a series of orthogonal binding interactions to direct the controlled self-assembly of mesoscale objects is desirable. Here, the authors use DNA as a sequence-specific glue to assemble hydrogel cuboids into a diverse series of structures in the micro- to millimeter length scale.
- Hao Qi
- , Majid Ghodousi
- & Ali Khademhosseini
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In situ observation of filamentary conducting channels in an asymmetric Ta2O5−x/TaO2−x bilayer structure
Despite its importance for non-volatile memory, the origin of resistive switching in a metal insulator-metal structure is unclear. Park et al.fabricate such a structure inside a transmission electron microscope to show that switching occurs via oxygen-vacancy migration, which changes the conduction channels.
- Gyeong-Su Park
- , Young Bae Kim
- & Kinam Kim
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All-thiol-stabilized Ag44 and Au12Ag32 nanoparticles with single-crystal structures
Noble metal nanoparticles are used for applications in optics, catalysis, sensing and others. Here the authors study the crystal structures of silver and gold-silver intermetallic nanoparticles stabilized by thiol ligand layers, helping to understand the relationship between their structure and properties.
- Huayan Yang
- , Yu Wang
- & Nanfeng Zheng
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Atomic layer lithography of wafer-scale nanogap arrays for extreme confinement of electromagnetic waves
Electromagnetic waves passing through nanogaps can be strongly enhanced, leading to novel physical phenomena. Chen et al. present a new method of atomic layer lithography for patterning uniform arrays of subnanometre gaps in metal films using adhesive tape and show unprecedented field enhancements.
- Xiaoshu Chen
- , Hyeong-Ryeol Park
- & Sang-Hyun Oh
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Direct growth of aligned graphitic nanoribbons from a DNA template by chemical vapour deposition
Graphene nanoribbons display many advantageous properties compared with large-area graphene, such as possessing a bandgap. Here a technique is presented for the production of graphene nanoribbons via the use of a DNA template, enabling replication of template shape with ribbon widths reaching <10 nm.
- Anatoliy N. Sokolov
- , Fung Ling Yap
- & Zhenan Bao
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Manipulation and coherence of ultra-cold atoms on a superconducting atom chip
Superconducting qubits are promising for quantum information processing, yet maintaining their coherence for long periods is hard. Bernon et al.characterize the coherence of cold atom superposition states trapped on superconducting atom chips and show that such long-lived ensembles are a viable alternative.
- Simon Bernon
- , Helge Hattermann
- & József Fortágh
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A nanostructured cathode architecture for low charge overpotential in lithium-oxygen batteries
Lithium-oxygen batteries can deliver high-energy densities, but their performance suffers from large charge-discharge overpotential. Lu et al.design a cathode by integrating electrode coating and electrocatalyst in a nanostructured architecture, whereby the overpotential is reduced to 0.2 V.
- Jun Lu
- , Yu Lei
- & Khalil Amine
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Electronically stabilized nanowire growth
Nanowires show unique physical properties owing to their one-dimensional nature. Here Mocking and colleagues demonstrate that the length of nanowires is electronically stabilized such that the length distribution shows a preference for integer multiples of half of the electron Fermi wavelength.
- Tijs F. Mocking
- , Pantelis Bampoulis
- & Harold J. W. Zandvliet
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| Open AccessCorrelation between spin structure oscillations and domain wall velocities
A prerequisite for using domain walls in logic or sensing devices is a thorough knowledge of the properties and precise control. Here the authors monitor the domain wall motion in curved nanowires by stroboscopic imaging and find a regime of oscillating velocity and spin structure below the Walker breakdown.
- André Bisig
- , Martin Stärk
- & Mathias Kläui
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| Open AccessHigh charge-carrier mobility enables exploitation of carrier multiplication in quantum-dot films
Carrier multiplication effects are of promise for enhancement of solar cells, but have been difficult to exploit in such devices. Here, the authors demonstrate how carrier multiplication in quantum-dot films can be considerably enhanced by appropriate tuning of the charge-carrier mobility.
- C. S. Suchand Sandeep
- , Sybren ten Cate
- & Laurens D. A. Siebbeles
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| Open AccessSingle-mode tunable laser emission in the single-exciton regime from colloidal nanocrystals
Semiconductor nanocrystals are of interest for microlasers that, for example, can be used for integrated photonics applications. Here, Grivas et al.demonstrate single-mode lasing in the single-exciton regime from core/shell CdSe/CdS quantum rods deposited on a single silica microsphere.
- Christos Grivas
- , Chunyong Li
- & Pavlos Lagoudakis
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| Open AccessScaling laws for van der Waals interactions in nanostructured materials
Van der Waals interactions have a large influence on phenomena that occur at short-length scales. Gobre et al.demonstrate that van der Waals interactions in low-dimensional materials act at very large distances, and can significantly influence the self-assembly of nanostructured systems.
- Vivekanand V. Gobre
- & Alexandre Tkatchenko
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Nanoconfinement effects on hydrated excess protons in layered materials
An understanding of excess protons in nanoconfined water is highly relevant to technological applications such as fuel cell membranes. Here, ab initiosimulation reveals almost barrier-free proton transfer even in the limit of molecularly thin water films confined by mineral sheets.
- Daniel Muñoz-Santiburcio
- , Carsten Wittekindt
- & Dominik Marx
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Ballistic interferences in suspended graphene
Exploiting the optics-like dynamics of low-energy electronic excitations in graphene requires the challenging combination of ballistic transport and complex gating. Here the fabrication and characterization of suspended graphene p–njunctions is reported, paving the way for future electron optics experiments.
- Peter Rickhaus
- , Romain Maurand
- & Christian Schönenberger
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Depinning probability of a magnetic domain wall in nanowires by spin-polarized currents
The ability to move magnetic domain walls within magnetic nanowires is a potentially useful means of manipulating and storing digital information. Fukami et al.report a systematic study of the conditions under which these walls can be depinned from a pinning site in a magnetic nanowire.
- S. Fukami
- , M. Yamanouchi
- & H. Ohno
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Formation of nitrogen-doped graphene nanoscrolls by adsorption of magnetic γ-Fe2O3 nanoparticles
Graphene nanoscrolls are known to display interesting electronic structures and properties. Sharifi et al. demonstrate a 100% efficient process for their reversible formation, based on decorating nitrogen-doped graphene with magnetic iron oxide particles.
- Tiva Sharifi
- , Eduardo Gracia-Espino
- & Thomas Wågberg
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Carbon nanotube membranes with ultrahigh specific adsorption capacity for water desalination and purification
Absorption-based water purification technologies are simple to use but can be hindered by their low salt removal capacity. Here, the authors report ultralong carbon nanotubes modified by plasma treatment, capable of salt adsorption two orders of magnitude higher than state-of-the-art carbon-based systems.
- Hui Ying Yang
- , Zhao Jun Han
- & Rohit Karnik
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In vivo time-gated fluorescence imaging with biodegradable luminescent porous silicon nanoparticles
Tissue autofluorescence can lead to considerable noise in fluorescence imaging of biological tissues. Here Gu et al.demonstrate that the use of photoluminescent silicon nanoparticles with long emission lifetimes enable a late time-gated imaging technique where autofluorescence effects are avoided.
- Luo Gu
- , David J. Hall
- & Michael J. Sailor
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Disk-cylinder and disk-sphere nanoparticles via a block copolymer blend solution construction
Compositionally and geometrically complex nano-objects are an important goal in medicinal, photonic and electronic materials research. Here, the authors fabricate disk-sphere and disk-cylinder nanoparticles with defined multicompartments from binary mixtures of block copolymers.
- Jiahua Zhu
- , Shiyi Zhang
- & Darrin J. Pochan
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| Open AccessA chiral-based magnetic memory device without a permanent magnet
Most new device concepts for random-access memory are based on inorganic spin filters, which need a permanent magnet to operate. Here, the authors exploit the chiral-induced spin selectivity effect in an organic spin filter to construct a novel type of memory device, which works without a permanent magnet.
- Oren Ben Dor
- , Shira Yochelis
- & Yossi Paltiel