Featured
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Oriented nucleation in formamidinium perovskite for photovoltaics
The black phase of formamidinium lead iodide perovskite is used to make highly efficient solar cells, and a technique to improve its purity and stability by controlling crystal nucleation could make them even better.
- Pengju Shi
- , Yong Ding
- & Rui Wang
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Article
| Open AccessEntropic repulsion of cholesterol-containing layers counteracts bioadhesion
Entropic repulsion caused by interfacial orientational fluctuations of cholesterol layers restricts protein adsorption and bacterial adhesion, providing a conceptually new physicochemical perspective on biointerfaces that may guide future material design in regulation of adhesion.
- Jens Friedrichs
- , Ralf Helbig
- & Carsten Werner
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Article |
Liquid metal for high-entropy alloy nanoparticles synthesis
We discovered that liquid metal endowing negative mixing enthalpy with other elements could provide a stable thermodynamic condition and act as a desirable dynamic mixing reservoir, realizing the synthesis of high-entropy alloy nanoparticles.
- Guanghui Cao
- , Jingjing Liang
- & Lei Fu
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Article |
All-perovskite tandem solar cells with 3D/3D bilayer perovskite heterojunction
All-perovskite tandem solar cells with an immiscible 3D/3D bilayer heterojunction demonstrate a record-high PCE of 28%, as well as the ability to retain more than 90% of their initial performance after 600 h of continuous operation.
- Renxing Lin
- , Yurui Wang
- & Hairen Tan
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Research Highlight |
Joyous ode by Beethoven flows from a robot’s fingers
Digits made of soft materials tap out a melody from the composer’s Ninth Symphony on a keyboard.
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News & Views |
Lithium filaments wedge open cracks in solid-state batteries
The development of a promising type of battery has been plagued by an issue that causes these devices to fail — lithium filaments grow in the electrolyte. An investigation of this failure mechanism could help to solve the problem.
- Kelsey B. Hatzell
- & Maha Yusuf
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Research Briefing |
Elastic ceramic plastic made using molecules with organic and inorganic parts
Hybrid molecules containing organic and inorganic components were assembled through bottom-up synthesis into a continuous network of interpenetrating molecular-scale organic and inorganic ionic domains. The resulting material, called elastic ceramic plastic, shows ceramic-like hardness and strength, rubber-like deformability and resilience, and plastic-like mouldability.
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Article
| Open AccessChiral phonons in quartz probed by X-rays
Our experimental proof of chiral phonons demonstrates a degree of freedom in condensed matter that is of fundamental importance and opens the door to exploration of emergent phenomena based on chiral bosons.
- Hiroki Ueda
- , Mirian García-Fernández
- & Urs Staub
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Article |
Organic–inorganic covalent–ionic molecules for elastic ceramic plastic
Covalent organic molecules can be combined with ionic inorganic molecules to create a hybrid material demonstrating paradoxical mechanical properties in a bottom-up manner, enabling the manufacture of an ‘elastic ceramic plastic’.
- Weifeng Fang
- , Zhao Mu
- & Zhaoming Liu
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Article |
Hydration solids
A study shows that water can control macroscopic properties of biological materials through the hydration force, giving rise to a distinct class of solid matter with unusual properties.
- Steven G. Harrellson
- , Michael S. DeLay
- & Ozgur Sahin
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Article |
Dendrite initiation and propagation in lithium metal solid-state batteries
Analysis of dendrite initiation, owing to filling of pores with lithium by means of microcracks, and propagation, caused by wedge opening, shows that there are two separate processes during dendrite failure of lithium metal solid-state batteries.
- Ziyang Ning
- , Guanchen Li
- & Peter G. Bruce
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Research Briefing |
Designer titanium alloys created using 3D printing
An original class of strong, ductile titanium alloy containing the inexpensive and abundant oxygen and iron as principal alloying elements has been created using 3D printing. The research findings offer promise for turning low‑quality titanium sponge — a waste product of the energy-intensive production of titanium — into high‑performance titanium alloys, and for innovative alloy engineering.
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Article
| Open AccessStrong and ductile titanium–oxygen–iron alloys by additive manufacturing
Combining alloy design with additive manufacturing process design creates α–β titanium–oxygen–iron alloys that are both strong and ductile, with the potential to revitalize off-grade sponge titanium and thereby reduce the carbon footprint of the titanium industry.
- Tingting Song
- , Zibin Chen
- & Ma Qian
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Article |
Attosecond electron microscopy of sub-cycle optical dynamics
The cycles of laser light have been used to advance transmission electron microscopy to attosecond time resolution, revealing the interactions between light and matter in terms of their fundamental dimensions in space and time.
- David Nabben
- , Joel Kuttruff
- & Peter Baum
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Article |
Indefinite and bidirectional near-infrared nanocrystal photoswitching
This study reports unlimited near-infrared photoswitching in inorganic avalanching nanoparticles via a discrete shift of threshold intensity mediated by internal defect-based colour centres.
- Changhwan Lee
- , Emma Z. Xu
- & P. James Schuck
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Outlook |
Bioglue breakthrough
A nature-inspired adhesive offers hope for wound healing and haemorrhage control.
- Elie Dolgin
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Outlook |
Better batteries built using existing technology
Advances in materials yield safer, cheaper and denser energy storage.
- Neil Savage
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Research Briefing |
Flexible solar cells made with crystalline silicon
Although crystalline silicon (c-Si) solar cells were developed nearly 70 years ago, their use is still limited. Tailoring the structural symmetry on the edges of textured c-Si wafers changes their fracture mechanism such that they can be used to fabricate flexible solar cells with a bending radius of about 8 millimetres.
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Perspective |
Lead immobilization for environmentally sustainable perovskite solar cells
An analysis of chemical processes to immobilize lead from perovskite solar cells is presented, highlighting the need for a standard lead-leakage test and mathematical model to reliably evaluate the potential environmental risk of perovskite optoelectronics.
- Hui Zhang
- , Jin-Wook Lee
- & Nam-Gyu Park
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Article |
Inverted perovskite solar cells using dimethylacridine-based dopants
A dimethylacridine-based molecular doping process is used to construct a well-matched p-perovskite/indium tin oxide contact, along with all-round passivation of grain boundaries, achieving a certified power conversion efficiency of 25.39%.
- Qin Tan
- , Zhaoning Li
- & Zhubing He
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Article
| Open AccessFlexible solar cells based on foldable silicon wafers with blunted edges
Modules of foldable crystalline silicon solar cells retain their power-conversion efficiency after being subjected to bending stress or exposure to air-flow simulations of a violent storm.
- Wenzhu Liu
- , Yujing Liu
- & Zhengxin Liu
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News |
Soft ‘electronic skin’ mimics our sense of touch
A flexible, conductive membrane that can pass sensory information to the brain and muscles is a step towards artificial skin.
- Katharine Sanderson
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News & Views |
Ink that mimics the colour of incoming light
Light-sensitive particles have been shown to stratify in solution in a way that changes the colour of the whole suspension. The system forms a colour-changing ink that could make electronic paper a viable technology.
- Hector Lopez-Rios
- & Monica Olvera de la Cruz
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Article |
CO2-mediated organocatalytic chlorine evolution under industrial conditions
A study shows that an organocatalyst with an amide functional group, and carbon dioxide, can efficiently and selectively produce chlorine, potentially offering a low-cost and less energy intensive alternative to the chlor-alkali process.
- Jiarui Yang
- , Wen-Hao Li
- & Yadong Li
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Article
| Open AccessPhotochromism from wavelength-selective colloidal phase segregation
A simple spectral selective active colloidal system is designed in which TiO2 colloidal species are coded with dyes to form a photochromic swarm that adapts the appearance of incident light due to layered phase segregation.
- Jing Zheng
- , Jingyuan Chen
- & Jinyao Tang
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Article
| Open AccessAbsence of near-ambient superconductivity in LuH2±xNy
Nitrogen-doped lutetium hydrides LuH2±xNy synthesized using a high-pressure and high-temperature synthesis technique did not show near-ambient superconductivity at pressures below 40.1 GPa.
- Xue Ming
- , Ying-Jie Zhang
- & Hai-Hu Wen
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Article
| Open AccessX-ray-to-visible light-field detection through pixelated colour conversion
Lithographically patterned perovskite nanocrystal arrays were used to determine radiation vectors from X-rays to visible light and the emission colours of the nanoparticles was used to create images of three-dimensional objects and for phase-contrast imaging.
- Luying Yi
- , Bo Hou
- & Xiaogang Liu
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Article
| Open AccessHigh-throughput printing of combinatorial materials from aerosols
The authors report a high-throughput combinatorial printing method capable of fabricating materials with compositional gradients at microscale spatial resolution, demonstrating a variety of high-throughput printing strategies and applications in combinatorial doping, functional grading and chemical reaction.
- Minxiang Zeng
- , Yipu Du
- & Yanliang Zhang
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Where I Work |
Mimicking of human skin to build wearable sensors
Yichen Cai creates thin, flexible devices that could have myriad uses, from wearable blood-pressure monitors to touch sensors for robots.
- Linda Nordling
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Research Highlight |
Wearable sensor gives a glimpse of ‘invisible’ light
A device that transforms infrared light into a visible image could be used for anti-surveillance purposes.
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Article |
Constrained C2 adsorbate orientation enables CO-to-acetate electroreduction
A study using a copper-in-silver dilute alloy catalyst in a high-pressure gas flow reactor reports highly selective electrosynthesis of acetate from carbon monoxide.
- Jian Jin
- , Joshua Wicks
- & Yuanjie Pang
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Article |
Helical polymers for dissymmetric circularly polarized light imaging
We report a simple method to fabricate chiroptical flexible layers via supramolecular helical ordering of conjugated polymer chains, providing direct, scalable realization of on-chip detection of the spin degree of freedom of photons.
- Inho Song
- , Jaeyong Ahn
- & Joon Hak Oh
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Nature Video |
Wind turbines are tough to recycle – this new chemistry could help
A method for breaking down epoxies could stop wind turbine blades ending up in landfill.
- Shamini Bundell
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News & Views |
Mixed plastics upcycled dynamically
Waste plastics contain immiscible polymers, making recycling challenging. A new additive enables the thermal reprocessing of mixed plastics into recyclable, high-performance materials.
- Mathieu L. Lepage
- & Jeremy E. Wulff
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Article |
Near-frictionless ion transport within triazine framework membranes
The authors develop a strategy that allows the diffusion limit of ions in water to be approached for large-area, free-standing, synthetic membranes using covalently bonded polymer frameworks with rigidity-confined ion channels.
- Peipei Zuo
- , Chunchun Ye
- & Tongwen Xu
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Article |
Tunable electron–flexural phonon interaction in graphene heterostructures
Experimental observation and calculations show that broken reflection symmetry in graphene heterostructures allows tunable electron–flexural phonon coupling, providing a way to control quantum matter at the atomic scale.
- Mir Mohammad Sadeghi
- , Yajie Huang
- & Li Shi
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Article |
Dynamic crosslinking compatibilizes immiscible mixed plastics
A new compatibilization strategy installs dynamic crosslinkers into several classes of binary, ternary and postconsumer immiscible polymer mixtures in situ, with the resulting compatibilized dynamic thermosets exhibiting intrinsic reprocessability and enhanced tensile strength and creep resistance.
- Ryan W. Clarke
- , Tobias Sandmeier
- & Eugene Y.-X. Chen
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Article
| Open AccessA 3D printable alloy designed for extreme environments
The authors develop a new oxide-dispersion-strengthened NiCoCr-based alloy using a model-driven alloy design approach and laser-based additive manufacturing, showing how such designs can provide superior compositions using far fewer resources than previous methods.
- Timothy M. Smith
- , Christopher A. Kantzos
- & John W. Lawson
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Research Briefing |
Plastic polymers split into reusable monomers using an electrical heating method
An innovative approach has been developed to break down plastic polymers into their monomer building blocks. It uses a continuous melting, wicking, vaporization and reaction process in a porous carbon-bilayer structure, and can convert two model plastic polymers to their monomers at high yields without a catalyst.
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Article |
Depolymerization of plastics by means of electrified spatiotemporal heating
A depolymerization method is described that uses electrified spatiotemporal heating to selectively generate monomers from the commodity plastics polypropylene and poly(ethylene terephthalate), allowing control over the pyrolysis of plastic waste and reducing the formation of side products.
- Qi Dong
- , Aditya Dilip Lele
- & Liangbing Hu
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Article |
pH-dependent water permeability switching and its memory in MoS2 membranes
We demonstrate the memory effects and stimuli-regulated transport of molecules through an intelligent, phase-changing MoS2 membrane in response to external pH, a phenomenon unique to the 1T′ phase of MoS2.
- C. Y. Hu
- , A. Achari
- & R. R. Nair
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Research Briefing |
Quantization observed for ‘heavy’ electrons
Quantum materials can host exotic phases of matter in which electrons form unusual collective states. Scientists have struggled to observe the quantization that these electronic states are expected to show, but this phenomenon has now been detected in heavy states at the surface of a superconducting quantum material.
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News & Views |
Elusive excited states identified from cutting-edge molecular movies
A molecular process called singlet fission might boost solar-cell efficiency, but the mechanism must first be determined. A technique that probes molecules undergoing this process finally reveals the excited states involved.
- Andrew J. Musser
- & Hannah Stern
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Article
| Open AccessOrbital-resolved observation of singlet fission
Time- and angle-resolved photoemission spectroscopy is used to observe the primary step of singlet fission with orbital resolution indicating a charge-transfer mediated mechanism with a hybridization of states in the lowest bright singlet exciton.
- Alexander Neef
- , Samuel Beaulieu
- & Ralph Ernstorfer
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Article
| Open AccessDehydration of a crystal hydrate at subglacial temperatures
A porous organic crystal readily and reversibly adsorbs water, with dehydration occurring well below the freezing point of water, which could be seen by a change in colour.
- Alan C. Eaby
- , Dirkie C. Myburgh
- & Leonard J. Barbour
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Article
| Open AccessGiant magnetoresistance of Dirac plasma in high-mobility graphene
A Dirac plasma in high-mobility graphene shows anomalous magnetotransport and giant magnetoresistance that reaches more than 100 per cent in a low magnetic field at room temperature.
- Na Xin
- , James Lourembam
- & Alexey I. Berdyugin
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Article
| Open AccessTwo-dimensional ferroelectricity in a single-element bismuth monolayer
A single-element ferroelectric state is observed in a black phosphorus-like bismuth layer, in which the ordered charge transfer and the regular atom distortion between sublattices happen simultaneously and ferroelectric switching is further visualized experimentally.
- Jian Gou
- , Hua Bai
- & Andrew Thye Shen Wee
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Article |
Deforming lanthanum trihydride for superionic conduction
By creating nanosized grains and defects in lanthanum trihydride, its electronic conductivity can be suppressed, transforming it into a superionic conductor at −40 °C with a record high H− conductivity.
- Weijin Zhang
- , Jirong Cui
- & Ping Chen
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Article |
Self-powered perovskite photon-counting detectors
Suppression of shallow traps responsible for dark count rates in polycrystalline methylammonium lead triiodide using diphenyl sulfide enables the production of metal-halide perovskite photon-counting detectors that allow sensitive detection of γ-ray spectra.
- Ying Zhou
- , Chengbin Fei
- & Jinsong Huang