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| Open AccessObservation of intervalley quantum interference in epitaxial monolayer tungsten diselenide
Monolayers of transition metal dichalcogenides have many of the properties required for applications in spintronics and valleytronics. Here, the authors experimentally observe intervalley quantum interference involving conduction band Q-valleys in tungsten diselenide.
- Hongjun Liu
- , Jinglei Chen
- & Maohai Xie
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Article
| Open AccessVisualizing nanoscale 3D compositional fluctuation of lithium in advanced lithium-ion battery cathodes
It is challenging to quantitatively diagnose the lithium-ion distribution in batteries. Here, the authors use laser-assisted atom probe tomography to probe the nanoscale compositional fluctuations of lithium ions in two popular lithium-ion battery cathodes before and after electrochemical cycling.
- A. Devaraj
- , M. Gu
- & S. Thevuthasan
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Article
| Open AccessPressure-driven dome-shaped superconductivity and electronic structural evolution in tungsten ditelluride
Tungsten ditelluride has been recently discovered to possess very large and unsaturated magnetoresistance, up to 60 T. Here the authors apply high pressure on this material and observe a dome-shaped superconducting phase transition.
- Xing-Chen Pan
- , Xuliang Chen
- & Yuheng Zhang
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Article
| Open AccessDetermination of band alignment in the single-layer MoS2/WSe2 heterojunction
The alignment of the bandgap of adjacent materials in a heterostructure largely determines the electronic properties of a device. Here, the authors measure the conduction and valance band offsets at the interface between two two-dimensional materials: molybdenum disulphide and tungsten diselenide.
- Ming-Hui Chiu
- , Chendong Zhang
- & Lain-Jong Li
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Article
| Open AccessSubcycle-resolved probe retardation in strong-field pumped dielectrics
At the ultrafast timescale the propagation of light pulses through a dielectric material is not only determined by the envelope, but also by nonlinear interactions that evolve within one optical cycle. Here, the authors demonstrate a method to determine the subcycle-resolved delay to a probe pulse in ultrafast, high-field pump–probe experiments.
- Aseem Prakash Pati
- , Imam Setiawan Wahyutama
- & Adrian Nikolaus Pfeiffer
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Article
| Open AccessElectrical probing of field-driven cascading quantized transitions of skyrmion cluster states in MnSi nanowires
Future magnetic memory technologies may be based on the manipulation of skyrmions, nanoscale topologically stable circulating magnetization textures arising in chiral magnets. Here, the authors explore the behaviour of skyrmion clusters in nanowires with widths comparable to the single-skyrmion scale.
- Haifeng Du
- , Dong Liang
- & Mingliang Tian
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Article
| Open AccessPrintable elastic conductors with a high conductivity for electronic textile applications
Printable electronics is highly desirable for high throughput device manufacture. Here, Matsuhisa et al. report an electric ink, made of a self-assembled network of sliver flakes on the surface of a fluorine rubber matrix, which exhibits high conductivity and mechanical durability to achieve this goal.
- Naoji Matsuhisa
- , Martin Kaltenbrunner
- & Takao Someya
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Article
| Open AccessOrbital reconstruction in nonpolar tetravalent transition-metal oxide layers
The iridate compounds display interesting physical properties, including quasi-two-dimensional behaviour similar to cuprates. Bogdanov et al. explore the d-level structure of Sr2IrO4using electron spin resonance measurements and detailed calculations and find it is inverted compared to its normal ordering
- Nikolay A. Bogdanov
- , Vamshi M. Katukuri
- & Liviu Hozoi
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Article
| Open AccessThe optoelectronic role of chlorine in CH3NH3PbI3(Cl)-based perovskite solar cells
Chlorine incorporation into CH3NH3PbI3improves solar cell performance, but its optoelectronic role is still unclear. Here the authors present a strategy that decouples the morphological impact, to reveal that chlorine incorporation affects carrier transport across the heterojunction interface rather than within the perovskite crystal.
- Qi Chen
- , Huanping Zhou
- & Yang Yang
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Article
| Open AccessDirect characterization of photoinduced lattice dynamics in BaFe2As2
In BaFe2As2, the lattice couples strongly to the magnetic and electronic degrees of freedom, providing a way to control them. Here, by means of time-resolved X-ray scattering, the authors measure rapid lattice oscillations, which can induce changes in the material’s electronic and magnetic properties.
- S. Gerber
- , K. W. Kim
- & W.-S. Lee
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Article
| Open AccessHigh-performance green flexible electronics based on biodegradable cellulose nanofibril paper
The rapid evolution of consumer electronics means that out-of-date devices quickly end up in the scrap heap. Here, the authors fabricate electrical components using biodegradable and flexible cellulose nanofibril paper—a natural sustainable resource derived from wood.
- Yei Hwan Jung
- , Tzu-Hsuan Chang
- & Zhenqiang Ma
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Article
| Open AccessAn incompressible state of a photo-excited electron gas
Two-dimensional phases of electrons exhibit interesting phenomena under magnetic fields. Chepelianskii et al.show that electrons on liquid helium exhibit an incompressible state when they are excited by a microwave field at particular frequencies related with the Landau level spacing.
- Alexei D. Chepelianskii
- , Masamitsu Watanabe
- & Denis Konstantinov
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Article
| Open AccessRevealing the role of organic cations in hybrid halide perovskite CH3NH3PbI3
Hybrid halide perovskite solar cells are studied as easy to fabricate compounds for efficient solar cell devices. Here, the authors use density functional theory calculations to show that the orientation of the organic molecules in these materials is crucial for their electronic and solar conversion properties.
- Carlo Motta
- , Fedwa El-Mellouhi
- & Stefano Sanvito
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Article
| Open AccessPatterning two-dimensional chalcogenide crystals of Bi2Se3 and In2Se3 and efficient photodetectors
Two-dimensional chalcogenides offer great potential in electronics, but accurate control of their growth is difficult. Here, the authors combine microintaglio printing and van der Waals epitaxy to pattern various large-area arrays of single-crystal chalcogenides with remarkable properties.
- Wenshan Zheng
- , Tian Xie
- & Hailin Peng
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Article
| Open AccessNanoscale determination of the mass enhancement factor in the lightly doped bulk insulator lead selenide
Electron–phonon coupling influences the thermal and electronic properties of many solid materials. Zeljkovic et al. now combine Landau level spectroscopy and scanning tunnelling microscopy to extract quantitative information on electron–phonon coupling in the insulator lead selenide.
- Ilija Zeljkovic
- , Kane L. Scipioni
- & Vidya Madhavan
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Semiconductor/relaxor 0–3 type composites without thermal depolarization in Bi0.5Na0.5TiO3-based lead-free piezoceramics
Piezoelectric materials are used as sensors or actuators in many devices. Here, the authors demonstrate that semiconducting ZnO particles embedded into a Bi0.5Na0.5TiO3-based matrix improve its piezoelectric properties, promising an alternative to presently used lead-based materials.
- Ji Zhang
- , Zhao Pan
- & Yan-Feng Chen
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Evidence for a nematic component to the hidden-order parameter in URu2Si2 from differential elastoresistance measurements
The heavy fermion material URu2Si2 exhibits a hidden-order phase transition that remains poorly understood. Using differential elastoresistance measurements, Riggs et al. show that this phase has a nematic component and that it spontaneously breaks fourfold lattice symmetry.
- Scott C. Riggs
- , M.C. Shapiro
- & I.R. Fisher
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Article
| Open AccessPolaron pair mediated triplet generation in polymer/fullerene blends
The spin dynamics at organic donor–acceptor junctions is critical in determining charge generation and recombination in devices, but the detail is still unclear. Here, Dimitrov et al. observe singlet–triplet spin mixing at nanosecond timescales, which competes directly with free charge separation.
- Stoichko D. Dimitrov
- , Scot Wheeler
- & James R. Durrant
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Visualization of a ferromagnetic metallic edge state in manganite strips
Boundary effects play a strong role in the electronic properties of structured manganites. Here, Du et al. demonstrate the existence of ferromagnetic metallic edge states and an enhanced metal–insulator transition temperature in patterned strips of manganite which emerge because of broken symmetry effects.
- Kai Du
- , Kai Zhang
- & Jian Shen
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Massive band gap variation in layered oxides through cation ordering
Understanding and controlling the electronic band gap of a material is vital for many electronic and optoelectronic applications. Towards this aim, this study shows how huge band gap variations can arise by manipulating the electrostatic interactions via cation ordering in correlated oxide materials.
- Prasanna V. Balachandran
- & James M. Rondinelli
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Probing the electron states and metal-insulator transition mechanisms in molybdenum disulphide vertical heterostructures
The mechanism that drives the metal to insulator transition in the two-dimensional material molybdenum disulphide is unknown. Here, the authors identify a percolation-type transition by studying the transport and capacitance properties of a metal-insulator-MoS2heterostructure.
- Xiaolong Chen
- , Zefei Wu
- & Ning Wang
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Article
| Open AccessThe evolution of cyclopropenium ions into functional polyelectrolytes
Cationic polyelectrolytes have a broad range of applications, including membranes for fuel cells. Here, the authors report a family of cationic polyelectrolytes based on the highly modular cyclopropenium ion building block, which show high ionic conductivity and tunable physical properties.
- Yivan Jiang
- , Jessica L. Freyer
- & Luis M. Campos
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Large resistivity modulation in mixed-phase metallic systems
The control of magnetization by an electric field can offer new magnetic data devices. Here, controlling magnetic phases in FeRh, the authors achieve a large electroresistance response in FeRh/PMN-PT heterostructures by applying an electric field, which could be used for non-volatile memory applications.
- Yeonbae Lee
- , Z. Q. Liu
- & R. Ramesh
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Observation of the intrinsic bandgap behaviour in as-grown epitaxial twisted graphene
Stacking graphene in such a way that each layer is rotated relative to the one below provides a way of controlling the properties of this useful material. Park et al. now demonstrate a technique for fabricating this twisted graphene in such a way that it has an intrinsic electronic bandgap.
- Jeongho Park
- , William C. Mitchel
- & Jonghoon Lee
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Article
| Open AccessControlling coherence via tuning of the population imbalance in a bipartite optical lattice
Ultracold atoms in optical lattices are a versatile platform for modelling simplified physical systems. By tuning structural deformations in bipartite optical lattices, Di Liberto et al. induce superfluid-to-Mott-insulator phase transitions that may shed light on condensed-matter systems such as the cuprates.
- M. Di Liberto
- , T. Comparin
- & C. Morais Smith
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Carbon nanotube network-silicon oxide non-volatile switches
The integration of carbon nanotubes with silicon is important for their incorporation into next-generation nano-electronics. Here, the authors demonstrate a non-volatile switch that utilizes carbon nanotube networks to electrically contact a conductive nano-crystal silicon filament in silica.
- Albert D. Liao
- , Paulo T. Araujo
- & Mildred S. Dresselhaus
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Article |
Optical freezing of charge motion in an organic conductor
In strongly correlated systems, the material properties can be drastically altered through subtle external perturbations. Here, the authors show that photoexcitation of the organic conductor α-(ET)2I3with ultrashort pulses leads to a counter-intuitive freezing of the electron motion.
- Takahiro Ishikawa
- , Yuto Sagae
- & Shinichiro Iwai
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Visible-light-enhanced gating effect at the LaAlO3/SrTiO3 interface
The interface between LaAlO3 and SrTiO3 is host to exotic phenomena that can be controlled by light or electric fields. Lei et al. show that combining the two controls leads to a dramatic decrease, not increase, of carrier density at the heterointerface, beyond what can be done with only one of them.
- Y. Lei
- , Y. Li
- & J. R. Sun
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Femtosecond electrons probing currents and atomic structure in nanomaterials
Femtosecond low-energy electron pulses allow probing ultrafast processes in nanoscale systems with high spatial and temporal resolution. Here, the authors develop a hybrid approach for studying ultrafast electric currents and structural dynamics in low-dimensional systems.
- Melanie Müller
- , Alexander Paarmann
- & Ralph Ernstorfer
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The missing boundary in the phase diagram of PbZr1−xTixO3
PbZr1−xTixO3is a widely used piezoelectric material. Here, the authors clarify the long-standing issue of the monoclinic crystal phase evolution across the morphotropic phase boundary in the compound’s phase diagram, contributing also to the understanding of its piezoelectric properties.
- N. Zhang
- , H. Yokota
- & Z.-G. Ye
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A polarity-induced defect mechanism for conductivity and magnetism at polar–nonpolar oxide interfaces
The interface between LaAlO3 and SrTiO3shows unusual phenomena such as a two-dimensional electron gas as well as magnetism. Here, Yu and Zunger show how the formation of defects contributes to the properties of this system.
- Liping Yu
- & Alex Zunger
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Few-layer molybdenum disulfide transistors and circuits for high-speed flexible electronics
Molybdenum disulfide holds great potential for advanced flexible electronic devices. Here, using a transferred gate technique, the authors fabricate molybdenum disulfide-based transistors with optimized device geometry and contact, improving device speed and demonstrating gigahertz circuits with voltage gain.
- Rui Cheng
- , Shan Jiang
- & Xiangfeng Duan
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Article
| Open AccessGigahertz single-trap electron pumps in silicon
Devices that generate single electrons are crucial for a precise definition of the ampere—the SI unit for electrical current. Yamahata et al. now demonstrate a silicon-based transistor that can accurately emit lone electrons at a rate of over 3 billion per second.
- Gento Yamahata
- , Katsuhiko Nishiguchi
- & Akira Fujiwara
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Bottom-up approach for the low-cost synthesis of graphene-alumina nanosheet interfaces using bimetallic alloys
Graphene-dielectric interfaces play a crucial role in many electronic devices, but electronic properties of graphene are inevitably degraded when the interfaces are produced. Omiciuolo et al.solve this problem using a low-cost approach based on epitaxial growth of graphene on dielectric alloys.
- Luca Omiciuolo
- , Eduardo R. Hernández
- & Alessandro Baraldi
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Spin–orbit proximity effect in graphene
Spin–orbit coupling in graphene is small, which makes controlling spin currents in this otherwise useful spintronic material difficult. Avsar et al.now demonstrate that combining graphene with few-layer tungsten disulphide increases its spin–orbit coupling by three orders of magnitude
- A. Avsar
- , J. Y. Tan
- & B. Özyilmaz
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Tenfold increase in the lifetime of blue phosphorescent organic light-emitting diodes
Short device lifetime of blue phosphorescent organic light-emitting diodes currently prevents their use. Here, Zhang et al. prove that the triplet-polaron annihilation mechanism is responsible for the degraded blue emitters and show how this finding can be used to improve the device lifetime.
- Yifan Zhang
- , Jaesang Lee
- & Stephen R. Forrest
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Article |
Flutter-driven triboelectrification for harvesting wind energy
The harvesting of electrical energy from renewable sources remains an ongoing scientific focus. Here, the authors report a triboelectric generator that is capable of harnessing energy from the wind via a flutter motion, with the output of the device dependent on the precise motion caused by the wind.
- Jihyun Bae
- , Jeongsu Lee
- & U-In Chung
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Rational design of all organic polymer dielectrics
The selection of polymeric dielectric materials for energy storage applications is not trivial, as several criteria must be satisfied simultaneously. Here, Sharma et al.present a high-throughput hierarchical strategy using the band gap and dielectric constant to screen and identify good candidates.
- Vinit Sharma
- , Chenchen Wang
- & Rampi Ramprasad
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Critical speeding-up in the magnetoelectric response of spin-ice near its monopole liquid–gas transition
The competing magnetic interaction in the spin-ice oxide compounds lead to emergent magnetic monopole excitations. Here, the authors study the critical dynamics near the monopole liquid-gas transition, and confirm predictions that these monopoles are also accompanied by an electric dipole.
- Christoph P. Grams
- , Martin Valldor
- & Joachim Hemberger
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Enhancing 2D growth of organic semiconductor thin films with macroporous structures via a small-molecule heterointerface
High-performance organic electronics require minimal grain boundaries in an organic semiconductor active layer. Here, Kang et al.report the growth of pentacene thin films in a macroporous structure with improved crystallinity, which is guided by a chemically heterogeneous, rubber-like substrate.
- Boseok Kang
- , Moonjeong Jang
- & Kilwon Cho
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Article |
Reversible control of spin-polarized supercurrents in ferromagnetic Josephson junctions
The ability to manipulate spin-polarized supercurrents could enable the development of superconducting spintronic devices whose performance exceeds that of conventional spintronics. Banerjee et al.demonstrate a superconducting analogue of the archetypical spintronic device, the spin valve.
- N. Banerjee
- , J.W.A. Robinson
- & M. G. Blamire
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Article |
Reversible nano-structuring of SrCrO3-δ through oxidation and reduction at low temperature
Oxygen vacancies can significantly influence the electronic and structural properties of complex oxides. Here, the authors find that by controlling the concentration of oxygen vacancy defects in SrCrO3thin films, the crystal structure, oxygen diffusivity and electronic properties can be reversibly switched.
- K. H. L. Zhang
- , P. V. Sushko
- & S. A. Chambers
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Article |
Magneto-tunable photocurrent in manganite-based heterojunctions
Correlated oxide materials are of interest for solar cell applications that, in combination with properties such as magnetism, could offer novel functionalities. Here, the authors find that by applying strain or magnetic fields the photocurrent in La0.7Sr0.3MnO3 thin films can be significantly enhanced.
- Z. G. Sheng
- , M. Nakamura
- & M. Kawasaki
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Article |
Ionic field effect and memristive phenomena in single-point ferroelectric domain switching
The switching of ferroelectric domains can be used for applications such as information storage. Here, the authors demonstrate that a broad range of domain morphologies can be induced by the tip of a scanning probe microscope, which can be explained by the dynamics of surface charge screening.
- Anton V. Ievlev
- , Anna N. Morozovska
- & Sergei V. Kalinin
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Article
| Open AccessGiant dielectric and magnetoelectric responses in insulating nanogranular films at room temperature
The electric and magnetic responses of matter are of interest for their use in electronic applications. Here, the authors find a large dielectric and magnetoelectric response in FeCo-MgF nanogranular films, caused by quantum mechanical tunnelling oscillation between magnetic granules.
- Nobukiyo Kobayashi
- , Hiroshi Masumoto
- & Sadamichi Maekawa
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Article
| Open AccessTurning a band insulator into an exotic superconductor
Most superconductors that exhibit exotic pairing symmetries are derived from host materials that are Mott insulators. Xiangang Wan and Sergey Savrasov show that it may be possible to realize an exotic p-wave superconductor in doped Bi2Se3, which is a topological band insulator.
- Xiangang Wan
- & Sergey Y. Savrasov
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Suppression of the critical thickness threshold for conductivity at the LaAlO3/SrTiO3 interface
The thin highly conducting electron layer at the interface of LaAlO3 grown on SrTiO3 is of promise for nanoscale electronics. Here, the authors show that, by depositing a thin cobalt film on top of LaAlO3, the minimum thickness of LaAlO3needed for this conducting layer to form can be reduced to one unit cell.
- E. Lesne
- , N. Reyren
- & M. Bibes
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Article |
Functional ferroic heterostructures with tunable integral symmetry
Crystal symmetries play an important role in the properties of materials, but allow little dynamic control once the materials have been grown. Here, the authors show that conducting oxides sandwiched between independently switchable ferroelectric films achieve tunable symmetry for controllable properties.
- C. Becher
- , M. Trassin
- & D. Meier
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Article |
Approaching the limits of transparency and conductivity in graphitic materials through lithium intercalation
Graphene-based materials have potential as transparent electrodes, but still fall short of desired performance goals. Here, Bao et al.report that upon intercalation of lithium into few-layer graphene, desired sheet resistance and optical transmittance may be achieved.
- Wenzhong Bao
- , Jiayu Wan
- & Liangbing Hu