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After over a quarter of a century, the doors of the world's first synchrotron radiation source have closed. Its contribution to materials science in the past and the future should not be underestimated.
Understanding the corrosion mechanism of aqueous silicate glass is crucial for the long-term durability of nuclear waste glasses. This mechanism is generally thought to be associated with chemical affinity, but it is now demonstrated that morphological transformations also have an important role in the leaching kinetics of these glasses.
According to a neutron-scattering study of the structural and magnetic properties of the pnictide CeFeAsO1−xFx, the phase diagram of this material shows considerable similarities with the high-Tc cuprate superconductors. These results are an important addition to the effort to find out where superconductivity in these iron–arsenic alloys arises.
Zeolite nanocrystals with three-dimensionally ordered mesoporous structures are important for designing molecularly accessible and selective catalysts. With a single zeolite synthesis procedure, uniform nanocrystals and crystal zeolites with ordered imprinted mesoporosity can now be obtained.
How do entangled polymer rings relax? Linear polymers can ease their stress because their chains have ends, but cyclic polymers do not. Even trace amounts of linear chains dominate the mechanical properties if present as impurities. Investigation of carefully purified ring polymers reveals they exhibit self-similar dynamics and a power-law stress relaxation.
To enable the development of devices based on the electrical manipulation of magnetic molecules, their magnetic state needs to be conserved when electrical contacts are applied. N@C60 molecules have now been integrated as part of single-molecule transistors, and their spin states retained. This achievement may lead towards their use in high-density information storage and quantum-state control.
Defects can significantly alter the physical properties of materials. A detailed experimental analysis of defects in carbon nanotubes enables the relationship between the atomic response and the broadly available macrosopic behaviour to be captured.
Flexible electronics require that all parts can be printed on plastic substrates, but finding materials that can act as high-capacitance dielectrics is a priority. An emerging class of polymer electrolytes, ion gels, can do the job—with high capacitance and at low voltage.
Nanocrystalline materials usually exhibit high strength and their deformation caused by stress is limited. Nanocrystalline CdS with spherical and hierarchical shell geometry is shown not only to withstand extreme stresses, but also to deform considerably before failure.
A new polymer is investigated as a drug-delivery vehicle for the treatment of inflammatory diseases, such as cardiac dysfunction. The biocompatibility, neutral degradation products and controlled-release properties of the polyketal microparticles indicate the material’s promising future in inflammation inhibition.
Conversion electrodes for lithium-ion batteries are capable of high capacity but low energy efficiency and low voltages are problematic. The electrochemical reactivity of MgH2 with Li shows promise in using metal-hydride electrodes for both lithium-ion-battery and hydrogen storage applications.
Increasing the carrier density of a material to the limit at which superconductivity can be induced has been a long-standing challenge. This is now realized in an insulator by using an electric-double-layer gate in an organic electrolyte.
The trapping of electrons by grain boundaries in semiconducting and insulating materials is important for a wide range of devices such as sensors, and solar and fuel cells. First-principles calculations on MgO, LiF and NaCl reveal a novel type of electron trapping at grain boundaries associated with the negative electron affinity of these materials.
Characterizing medium-range order in disordered solids and liquids is crucial for elucidating their structure and transport properties, but it has so far proved difficult. Using a combination of X-ray diffraction and Raman scattering, the pressure-dependent and atomic-void structure of amorphous red phosphorous is determined.
A universal feature of disordered glasses is the appearance of the so-called boson peak in neutron-scattering experiments. A universal link between this boson peak and transverse phonons has now been discovered, and linked to locally favoured structures in the glass.
In a device design that brings mechanical flexibility to silicon photovoltaics, Jongseung Yoon, Alfred J. Baca and colleagues demonstrate how transfer-printing of ultrathin silicon films onto flexible substrates leads to semitransparent and large-scale arrays of integrated solar microcells with high solar-energy conversion efficiencies of 6–8%.
Philips has recently changed its focus from electronic components to healthcare innovations. Nature Materials talked to Hans Hofstraat about the reasons behind this choice and how it affected Philips Research scientists.
