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Volume 8 Issue 3, March 2023

Crack-initiated failure

Lithium penetrating electrolytes is a common cause of short-circuiting in batteries but its mechanism is elusive. This study conducts scanning electron microscopy experiments where tungsten microprobes are brought into contact with the solid electrolyte surface revealing that nanoscale cracks can initiate the lithium propagation inside the electrolyte.

See McConohy et al. and Research Briefing

Image: Image: Geoff McConohy, Xin Xu, Teng Cui & William Chueh, Stanford University and Younghee Lee, Cube3D. Cover Design: Thomas Phillips.

Comment & Opinion

  • Today’s sodium-ion batteries can not only be used in stationary energy storage applications, but also in 160–280 mile driving-range five-passenger electric vehicles. This technology will alleviate some of the supply-chain issues arising from limited resources of materials used in the ubiquitous lithium-ion batteries.

    • Ashish Rudola
    • Ruth Sayers
    • Jerry Barker
    Comment

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Research Highlights

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News & Views

  • The limited durability of perovskite photovoltaics has held back the technology. New research unveils a class of low-dimensionality perovskites based on metals such as zinc, cobalt or copper that protects the 3D perovskite solar absorber from degradation while affording high efficiency.

    • Wanyi Nie
    News & Views
  • Capping a three-dimensional metal halide perovskite with a layered, two-dimensional perovskite prevents ions from diffusing out of the perovskite keeping out oxygen and water as well as contributing to solar cell stability. New research shows that a thin cross-linked polymer layer can ensure that the boundary between the 3D and 2D materials remains sharp, further improving stability.

    • Michael D. McGehee
    News & Views
  • Conventional and emerging refrigeration technologies either use refrigerants with high-global warming potential (GWP) or require application of strong fields. Now, researchers demonstrate ionocaloric refrigeration based on the electrochemical tuning of the melting behaviour of zero-GWP materials under low applied field strength.

    • Si Wu
    • Tingxian Li
    News & Views
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Research Briefings

  • The performance of solid electrolytes is hindered by instabilities caused by the formation of lithium intrusions. The mechanism responsible for these intrusions is not well understood. Experiments with a scanning electron microscopy setup revealed that applied stresses can control the probability of intrusion formation and influence the propagation behaviour.

    Research Briefing
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Reviews

  • Solid-state batteries are widely regarded as one of the next promising energy storage technologies. Here, Wolfgang Zeier and Juergen Janek review recent research directions and advances in the development of solid-state batteries and discuss ways to tackle the remaining challenges for commercialization.

    • Jürgen Janek
    • Wolfgang G. Zeier
    Review Article
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