Abstract
Recent observations of macroscopic quantum condensation using electron-hole (e-h) bilayers have activated the research of its application to electronics. However, to the best of our knowledge, no attempts have been made to observe the condensation in silicon, the major material in electronics, due to the lack of technology to form closely-packed and uniform bilayers. Here, we propose a method to meet such requirements. Our method uses the transient response of carriers to a rapid gate-voltage change, permitting the self-organized bilayer formation at the metal-oxide-semiconductor interface with an e-h distance as small as the exciton Bohr radius. Recombination lifetime measurements show that the fast process is followed by a slow process, strongly suggesting that the e-h system changes its configuration depending on carrier density. This method could thus enable controlling the phase of the e-h system, paving the way for condensation and, ultimately, for low-power cryogenic silicon metal-oxide-semiconductor devices.
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Introduction
Electron-hole (e-h) coexisting systems form in semiconductors in various phases: plasma, liquid, and gas (excitons), depending on the temperature and density, due to the Coulomb interaction. These systems have attracted continuous attention from the viewpoint of many-body physics1,2,3,4,5,6.
In particular, the progressive development of the physics and technologies for the e-h bilayers in compound semiconductors7,8,9,10, and more recently, in the two-dimensional (2D) materials, such as transition-metal dichalcogenides11,12,13,14,15 and graphene16,17,18, has activated the research on the macroscopic quantum condensations, i.e., Bose-Einstein condensation (BEC), Bardeen-Cooper-Schrieffer states, and their crossover. Stimulated by these studies7,8,9,10,11,12,13,14,15,16,17,18, applications of the quantum condensation to optoelectronic and electronic devices have also been intensively considered19,20,21,22,23,24. One example is “bilayer pseudospin field-effect transistor (FET)”19,23, whose operation is based on the discovery that the recombination rate drastically increases when the e-h bilayer exhibits BEC8. Sun et al. recently showed that the condensation bilayer state can be used as a device that works like a Josephson junction, using a similar mechanism21. Another idea is to use the “perfect drag”, taking place under the BEC conditions, which could be used to develop a DC current transformer24.
Considering the application to electronics, especially to rapidly developing cryogenic electronics based on the complementary metal-oxide-semiconductor (CMOS) technologies25,26,27, research on these phenomena in silicon (Si) becomes critical. The e-h coexisting system in Si has been investigated from the viewpoint of clarifying the basic properties of the e-h system in semiconductors28,29,30,31,32,33,34. However, research aiming at the realization of the condensation is not active. Only a few papers35,36,37 have so far reported e-h bilayers in Si, in which adjacent electron and hole layers were formed at the front and back interfaces of thin silicon-on-insulator (SOI) layers for the purpose of observing frictional drag38.
The main cause of this stagnation is the concern that the thickness fluctuation of thin SOI layers causes inhomogeneous density profiles of electrons and holes, which could fatally block the condensation of excitons in the e-h bilayer39. The state-of-the-art fully-depleted (FD) SOI technology achieves a uniform Si film with the standard deviation of thickness fluctuation being about 0.4 nm40. This is remarkable, but still one order of magnitude lager than those of the 2D materials on boron nitride film41. On the other hand, for the silicon dioxide (SiO2)/Si interface itself, the effect of the roughness is recognized to be minor (if the charge density is low), and thus this interface has been the playground for the research of strongly interacting 2D electron systems, without the annoyance of the potential disorder caused by the interface roughness42,43,44. Therefore, in order to avoid the thickness-fluctuation problem of the SOIs, while still taking advantage of the high quality of the SiO2/Si interface, we propose here a method to form the e-h system at the single SiO2/Si interface of bulk (non-SOI) MOSFETs.
In this Article, we experimentally investigate the transient electrical formation of the e-h coexisting system in such bulk MOSFETs. The method uses the response of carriers to a rapid gate-voltage change under low temperature conditions; electrons are induced from the source/drain by a gate voltage pulse, while holes are confined in a potential well formed at the interface. We measured the e-h recombination current generated by repetitive pulses, and analyzed it as a function of the gate-pulse parameters. We demonstrate that the e-h system is formed at low temperatures, below about 30 K, and that the densities of the electrons and holes can be independently controlled by the amplitude and the base voltage of the pulse, respectively. Most importantly, we found that the introduced electrons are located in close proximity to the interface hole layer, at a distance on the order of nanometers, comparable to the Bohr radius of excitons in Si, revealing the self-organized formation of the e-h bilayer with a strong Coulomb coupling. In addition, the recombination lifetime measurements indicate that the fast process is followed by a slow process, suggesting that the introduced electrons change its configuration from plasma (Fermi gas) to the exciton.
Results
Method for e-h coexisting system formation
Figure 1 explains the method. Figure 1a shows the setup for n-channel MOSFETs. While the source/drain and the substrate terminals are grounded, we apply a pulse voltage to the gate with the base voltage Vbase and the amplitude Vamp, and measure the averaged current Irec flowing between the source/drain and the substrate. Figure 1b shows the energy band diagrams during the pulse sequence. As shown in the left diagram, we first set the Vbase to a negative value. The Fermi level of the gate EFGate then increases by (−e)Vbase, and holes are accumulated at the interface. We call this step “Pulse SET”. We next rapidly raise the gate voltage by Vamp so that the EFGate decreases by eVamp. We call this step “Pulse ON” (see the right diagram). If the temperature is low enough, the accumulated holes are expected to remain at the interface owing to the suppression of the thermal emission from the accumulation potential well. In such a case, with a sufficiently large value of Vamp, electrons can be introduced from the source/drain to the hole-accumulated interface, resulting in the coexistence of electrons and holes.
Figure 1b-right shows the expected potential profile when electrons are being introduced at the “Pulse ON” stage. Positive charges (of the holes) cause a steep downward-convex potential profile at the interface (Fig. 1b-left) like p-channel MOSFETs. On the other hand, negative charges (of the electrons) create an upward-convex potential profile like n-channel MOSFETs. Electrons are expected to be trapped at the potential pocket created by the combination of these two profiles, resulting in the bilayer-like charge profile.
The resultant e-h coexistence persists until the electrons and holes annihilate by recombination. Owing to the indirect-bandgap nature of Si, the recombination time is expected to be long, e.g., on the order of μs for the case of exciton recombination45. This time scale is much longer than the typical time constants important for e-h systems, such as the relaxation time due to the Coulomb interaction and exciton formation time, which are less than 1 ps46,47 and 1 ns47,48, respectively. Therefore, the present e-h system can be regarded as being under quasi-equilibrium, with the electron and hole densities well defined within the time scale of interest. Thus, it can be anticipated that it provides a good experimental host to investigate the properties and dynamics of the e-h system at Si MOS interfaces for future research.
Although, as we mentioned above, the recombination itself is the obstacle for the formation of a stable e-h system, we rather utilize it in this study for observing the e-h coexistence. We should mention here that similar transient experiments have been made focusing on the depletion-layer formation and on the possibility of the e-h plasma formation49,50,51. However, in these pioneering studies, the analysis ignored the e-h recombination process, and neither direct observation of the e-h coexistence, evaluation of the electron and hole densities, nor the estimation of the relative placement of electrons and holes have been done. We hereafter show that the recombination current conveys such important information about the e-h system. We should also mention that the present e-h coexistence due to the rapid voltage swing is relevant to the phenomenon called the “geometric effect”52,53 in the charge pumping (CP) process54, which is known as a limiting factor for the CP operating at high frequencies. The present method can be regarded as employing this phenomenon in a controlled way to form the closely-packed e-h bilayer.
The experiment we performed is the following. At “Pulse SET” stage, we wait a sufficiently long time, on the order of milliseconds, until the system reaches equilibrium, i.e., until the density of the accumulated holes Nh reaches the one determined by the accumulation gate-capacitance (per unit area) Cg,h for the hole layer, as Nh = Nh0 (≡ − Cg,h (Vbase – Vacc)/e), where e is the elementary charge and Vacc is the threshold voltage for the accumulation. We next made a rapid rising of the pulse voltage by Vamp, with the rising time on the order of 10 ns, resulting in the electron introduction. We then keep the voltage at Vbase + Vamp for a time interval tON. We repeat this process and measure the generated recombination current Irec flowing between the grounded source/drain and substrate (see Fig. 1a). With A and f being the channel area and pulse frequency, Irec is expressed by Irec = ANrecef, where Nrec is the density of the e-h pairs recombined in one cycle of the pulse. The period tON of the “Pulse ON” stage was set to be sufficiently long, on the order of milliseconds, so that all the recombination events are completed within one cycle of the gate pulse.
Exception is the measurement for the recombination lifetime, where tON was varied in the range between 10 ns to 100 μs in order to evaluate it. In addition, to support the data of the recombination lifetime, we also performed the real-time monitoring of the recombination current using a high-speed current amplifier.
The measurements were conducted at 8 K except for the measurements for temperature T dependence, where T was varied between 8 and 50 K.
For the measurements, n-channel MOSFETs fabricated on a Si (100) substrate were used. The channel length/width and gate-oxide thickness are, respectively, 50/500 μm and 30 nm. The substrate impurity (boron) concentration is on the order of 1015 cm−3. The basic characteristics of the MOSFET measured at 8 K can be found in the Supplementary Information. The field effect mobility exceeds 10,000 cm2V−1s−1 (see Supplementary Note 1), ensuring that the channel interface is of high quality. We also observed the metal-insulator transition with the critical electron density of 2 × 1011 cm−2 (see Supplementary Notes 2 and 3). This observation also ensures the high-quality of the interface, and it is expected that the potential disorder caused by the impurities is minor in the present measurements.
Measured characteristics
Figure 2 shows Irec (left axis) and Nrec (right axis) as a function of Vbase. The value of Vamp was fixed at 4 V. (The other parameters of the pulse are described in the caption of Fig. 2.) One can see that the characteristics are divided into three Vbase regions.
For Vbase ≳ −1.6 V, Irec and Nrec are negligibly small. This was ascribed to no hole accumulation layer being formed at the “Pulse SET” stage, i.e., Nh0 = 0. For the Vbase window, −4 V ≲ Vbase ≲ −1.6 V, Irec and Nrec increase nearly linearly with decreasing Vbase. The blue dashed line in the figure indicates the line Nrec = Nh0 (= − Cg,h (Vbase – Vacc)/e), with Vacc = –1.6 V. For this line, we used Cg,h (accumulation gate-capacitance) = 116 nFcm−2, which was obtained from CV measurements. One can see that the line traces well the experimental data. In addition, the value of Vacc (= –1.6 V) was found to be consistent with the expected value of the threshold voltage for the accumulation-layer formation. Therefore, we concluded that, in this Vbase range, the e-h recombination is dominated by Nh0 (Nh value set at the “Pulse SET” stage) so that Nrec = Nh0. (Note that the analysis of the slope and of Vacc was found to require careful consideration of the recombination of holes trapped at the interface defects, and the details of the analysis can be found in the Methods section.)
The above analysis suggests, in turn, that Ne > Nh0 (= Nrec), where Ne is the density of the introduced electrons (see the upper-right diagram in Fig. 2). That means that all the holes are recombined with the introduced electrons (and residual electrons are turned back to the source/drain at the next “Pulse SET” stage).
For Vbase smaller than about −4 V, on the other hand, Nrec saturates at a nearly constant value. We expect that this is because Ne did not reach Nh0 as Nh0 had a large value due to the negatively large Vbase. In such a case, Nrec should be limited by Ne, i.e., Nrec = Ne (see the upper-left diagram in Fig. 2). In order to confirm this expectation, we performed the same measurements using Vamp as a parameter. The results are shown in Fig. 3a. As expected, the saturation value of Nrec increases with increasing Vamp. This is because a larger Vamp causes larger Ne. In Fig. 3b, we plot the saturated Nrec at Vbase = −10 V as a function of Vamp. One can see that Nrec linearly increases with a distinct threshold at Vamp = 1.2 V, which is denoted by Vamp,th in the figure.
The linear dependence of the saturated Nrec on Vamp indicates that Ne can be well controlled by the capacitive coupling to the gate. The obtained eVamp,th (= 1.2 eV) is close to the band-gap energy of Si at low temperatures, 1.17 eV55. This agrees with our expectation. As represented by the blue dashed lines in Figs. 2 and 3a, Nrec equals to Nh0 (the initial value of Nh) in the linear region. This is the important manifestation that the emission (leakage) of holes from the accumulation potential well is negligibly small during the “Pulse ON” stage. This means that the accumulated holes can be regarded as fixed positive charges, which shift the threshold voltage for the electron channel in the negative gate-voltage direction. In such a case, the value of Vamp required for the electron channel formation should correspond to the bandgap energy irrespective of the value of Nh0 because, at the “Pulse SET” stage, the Fermi level lies (or is pinned) at around the valence-band edge due to the hole accumulation-layer formation.
We then discuss the slope in Fig. 3b. Different from the blue dashed lines in Figs. 2 and 3a, where the slope was fixed at Cg,h/e based on the accumulation-capacitance model, the red dashed line in Fig. 3b is the one obtained by fitting. The line is expressed by Nrec = Cg,e (Vamp – Vamp,th)/e and, in this case, Cg,e is the fitting parameter. We obtained Cg,e = 109 nFcm−2. The Cg,e can be expressed as Cg,e−1 = Cg,h−1 + ΔC−1, where ΔC is the additional capacitance (see Fig. 3c). Using Cg,h = 116 nFcm−2 and the dielectric constant of Si, εSi = 11.9ε0, where ε0 is the dielectric constant in vacuum, we obtained ΔC = 1.7 μFcm−2, corresponding to the length scale d = 6 nm, in the form of ΔC = εSi/d. This estimation suggests that the center of mass of the introduced electrons or the peak of the electron wave-function is positioned in close proximity to the hole layer, at a distance on the order of the Bohr radius rB (= 4 nm) of excitons in Si28.
We made the same analysis for various Vbase ranging from −4 V to −10 V. Figure 3d shows the estimated ΔC−1 (right axis) and corresponding d (left axis) as a function of Vbase (bottom axis) and corresponding Nh0 (top axis). As you can see, the value of d decreases with decreasing Vbase, i.e., with increasing Nh0, indicating that the placement of introduced electrons relative to the hole layer is dominated by the strength of the Coulomb interaction with the holes. Notice that the uncertainty of the results indicated by the error bars mostly arises from the process for determining Cg,h, i.e., the slope represented by the blue dashed line in Fig. 3a.
We next discuss the T dependence. Figure 4a shows the Nrec - Vbase characteristics for T ranging from 8 to 50 K. In Fig. 4b, we plot the saturated Nrec at Vbase = −10 V as a function of T. When T increases, the saturated Nrec starts to decrease at around T = 30 K. In accordance with this decrease, the slope of the Nrec - Vbase line in the Vbase range −4 V ≲ Vbase ≲ −1.6 V becomes gentler (Fig. 4a). These results indicate that holes are emitted from the accumulation layer during the “Pulse ON” stage, and the emission rate increases as T increases. T = 30 K corresponds to the energy broadening 3.5 kT of the Fermi-Dirac distribution of 9.1 meV, where k is the Boltzmann constant. This value is comparable to the barrier height of the ground subband level of the hole accumulation layer (a few tens of meV56,57). This is an implication that the leakage of the holes is caused by the thermal emission from the potential well of the accumulation layer (see potential diagram in Fig. 4b). We mention that at 50 K all the holes in the accumulation layer set at the “Pulse SET” stage were emitted before the electron introduction. Therefore, no Nrec was generated except for the additional component (the hatched region in the figure) originating from the recombination of holes trapped at the interface defects. (For the effects of the interface defects, see the Methods section).
We finally show the dependence of Irec on the hold time tON of the “pulse ON” stage. For the measurements discussed above, we set tON on the order of millisecond so that all the recombination events are completed within one cycle of the gate pulse. Here, we vary tON in the range of 10 ns to 100 μs to investigate the recombination lifetime. Figure 5a shows Irec and Nrec as a function of tON, measured at 8 K. For this measurement, the Vbase was set at –10 V, corresponding to the initial hole density Nh0 = 6.0 × 1012 cm−2, and Vamp was set at 6 V, corresponding to the density of the introduced electrons Ne = 3.25 × 1012 cm−2. (These Vbase and Vamp conditions are marked by the blue circle in Fig. 3a.)
One can see in Fig. 5a that Irec exhibits a two-step rise. The first rise of Irec can be fitted by a simple exponential form of I(1) = I0(1) (1− exp[−tON/τ1]) (red dashed line in the figure) with the time constant τ1 = 30 ns and the pre-factor I0(1) = 63.5 nA, which corresponds to 98% of the maximum value of Irec (= 64.9 nA). To evaluate the second rise part, we plot Irec − I(1) in Fig. 5b. One can see that Irec − I(1) can be fitted by the exponential form with the time constant τ2 = 0.7 μs (blue dashed line).
These results indicate that the present e-h system possesses two different recombination processes. The short (τ1 = 30 ns) and long (τ2 = 0.7 μs) recombination lifetimes respectively are the same order of the high-density unstable e-h plasma58,59 and exciton60 in Si. Noteworthy is that the second process starts to occur only after about 98% of the introduced electrons are recombined, i.e., only after the electron density is reduced down to about 0.7 × 1011 cm−2. The result suggests that the phase of the introduced electrons changes from the plasma (free Fermi gas) to the excitons (bound with a hole) as the recombination proceeds.
The behaviors of the above two (fast and slow) time-constants were also observed by a different measurement technique, the real-time monitoring of the recombination current using a high-speed current amplifier61,62,63. Figure 6a presents the experimental setup. The time constant for the current detection was set at 10 ns, which is the shortest available in our measurement system. The Vamp and Vbase were respectively set at 6 V and –10 V, which are the same conditions as those for Fig. 5. Figure 6b, c, respectively, show the pulse voltage and the resultant recombination current in time-domain irec(t), measured at 8 K. A sharp current spike is observed, which corresponds to the fast recombination process with the time constant of 30 ns in Fig. 5. Figure 6d displays the data of the micro-second range, where the vertical irec(t) axis is magnified. We observe a small current recovery followed by a slow decay, corresponding to the slow process with a time constant of 0.7 μs, agreeing with the data shown in Fig. 5.
It should be noted that the phase transition between the plasma and exciton gas in e-h bilayers has been theoretically analyzed using the Monte Carlo simulations64,65,66. The critical density nM for the transition (between the e-h plasma and the dipole exciton gas) is estimated by a simple form of nMae-h ≃ 0.02 (Eq. 3 of ref. 11), where ae-h is the Bohr radius of the dipole exciton. Assuming ae-h = d (≃ 6 nm), where d is the distance between electron and hole layers (Fig. 3d), nM comes to 0.6 × 1011 cm−2. This value is close to the boundary electron density of 0.7 × 1011 cm−2, observed in the measurement.
Although additional measurements, such as temperature dependence and electron- and hole-density dependence (i.e., Vamp and Vbase dependence) are called for to construct the phase diagram, the data reveal that the present e-h system could possess a rich set of configurations, and these can be analyzed by monitoring the recombination current.
Discussion
In the following, we discuss the features of the present method and the works to be performed in the future.
The drawback of SiO2/Si system is that there is no technology available for the hetero-epitaxy, which prevents us from forming uniform stacked layers of electrons and holes. The alternative solution might be the use of the FD-SOI technology. Using thin SOI films, we can form the electron and hole layers at each (top or bottom) side of the SOI interfaces with SiO235,36,37. However, the SOI film thinned down to nanometer-scale inevitably suffered from non-negligible thickness fluctuation. The state-of-the-art FD-SOI technology provides thin Si films whose thickness fluctuation is about 0.4 nm in standard deviation40. This is already remarkable, but will still be insufficient for the realization of the quantum condensation. In order for the quantum condensation to emerge, charge density fluctuation may have to be reduced to 1 × 1010 cm−2 or even smaller39 and, for this purpose, atomically flat layers are called for. In fact, the standard deviation of the roughness of the graphene sheet formed on the boron nitride film is 0.03 nm41, one order of magnitude smaller than that available in FD-SOI technology.
This is why we proposed the self-organized e-h bilayer formation at the single interface. We emphasize that the thickness fluctuation is due to the spatially uncorrelated interface roughness of the top and bottom interfaces, not the interface roughness itself. If we can make an e-h bilayer in a self-organized way at the single interface, then the electrons and holes are free from the thickness-fluctuation problem, and the spatial configuration of electrons and holes will be determined solely by the electronic correlation and the thermodynamic properties of the e-h system. We expect that our proposed method has the potential to offer such an ideal system.
In the future, we should critically evaluate the effect of the interface roughness itself on the charge density fluctuation. However, as long as we consider the experimental evidence reported in the research field of the strongly interacting electron systems in MOSFETs, the interface roughness does not cause any serious problems for investigating the properties of the system42,43,44.
We next discuss the importance of the bilayer formation in Si. From the viewpoint of the quantum condensation, Si e-h system has both advantage and disadvantage. The advantage is the long recombination time45 owing to the indirect bandgap nature, which gives the e-h system enough time to stabilize down to the ground state, as we have mentioned. (Note that most of the preceding materials used for the condensation experiments, e.g., GaAs and monolayer transition-metal dichalcogenides, have direct bandgap, and thus spatially separated electrons and holes (i.e., e-h bilayer) are indispensable in order to overcome the short recombination lifetime.) The disadvantage, on the other hand, arises from the multi-valley structure of the conduction band, causing the formation of e-h droplets3,6, which is the obstacle against the realization of the BEC of excitons. One way to avoid the droplet formation is the spatial separation of electrons and holes, which increases the strength of repulsive e-e and h-h interactions relative to the attractive e-h interaction, preventing the e-h system from agglomerating into droplets67. (Another way to avoid the droplet formation is the stress application68.) This means that the e-h bilayer formation is important in Si as well, but for a different reason from that of the preceding materials. As we have shown (in Fig. 3), the present method could provide the automatic formation of the bilayer-like e-h configuration at the MOS interface without the annoyance of the Si thickness fluctuation problem in SOIs.
We should emphasize here that the indirect bandgap of Si is critical for the self-organized e-h bilayer created by the present method using the transient response. In the preceding materials, such as graphene and MoS2, the electron and hole layers are separated by the boron nitride insulating spacer, which has a large potential barrier. Therefore, formation of the bilayer and the resultant indirect dipole excitons can be stable by avoiding the recombination (or tunneling) even with the direct bandgap nature. However, in the present method, the barrier separating the electrons and holes is induced by the electric field created in the Si layer, which is not strong enough to suppress the coupling (overlapping of the wave-functions). Therefore, the indirect bandgap and the resultant long recombination time are needed for the present method. In other words, the present transient technique to be performed at the single interface will not be applicable to the direct bandgap materials.
The most important issue to be further studied will be the phase diagram of this e-h coexistence system. For this purpose, the recombination lifetime measurements shown in Fig. 5 have to be extended for a wide range of electron and hole densities, and of the temperature. Based on references11,69, we roughly estimated the characteristic temperature Tc at which the excitons become degenerate. The result was a few Kelvin for the Si (100) interface. This is comparable to those for the GaAs and SiGe hetero e-h bilayers8,20. The recombination lifetime measurements in this temperature range will be particularly important.
With the present simple structure of MOSFETs, the hole current cannot be monitored. Therefore, a modified structure with p-type terminals (like the body contact of the MOSFET) should be prepared. By designing the time chart for the biasing of the drain terminals, the channel currents for both electron and hole layers can be monitored under the e-h bilayer configuration.
In summary, we investigated the electrical formation of the e-h coexisting system at the Si MOSFET interface. Measurements of the recombination current demonstrated that the transient e-h system can be formed at temperatures lower than about 30 K, and the electron and hole densities can be independently controlled by the amplitude and the base of the gate-voltage pulse, respectively. The measurements also indicated that the electrons are located at positions adjacent to the hole layer, at distances on the order of nanometers. In addition, we observed changes in the recombination lifetime as the recombination process proceeds, suggesting that the present e-h system possesses rich set of phases, depending on the electron and hole densities.
Methods
Analysis of V acc and slope in I rec-V base characteristic
In the Vbase range where Irec is nearly linearly varying, e.g., –4 V ≲ Vbase ≲ –1.6 V in Fig. 2, Irec was found to have an additional component originating from the recombination of electrons with holes trapped at the interface defects. Therefore, for the analysis, we have to carefully consider the effects of the interface defects. On the other hand, by using the properties of the interface-defect mediated recombination current, we can estimate the value of Vacc, the threshold voltage of the accumulation-layer formation. Here, we first describe in how to estimate Vacc, and in how the interface-defect mediated recombination currents contribute to Irec and how to compare the slope with the accumulation capacitance model.
Threshold voltage for accumulation-layer formation
Here, we estimate the threshold voltage Vacc for the accumulation-layer formation, and show that the estimated value is consistent with that (Vacc = –1.6 V) obtained in Figs. 2 and 3a.
The Vacc can be expressed as Vacc = VFB – ΔVg, where VFB is the flat-band voltage and ΔVg is the gate voltage, with respect to VFB, required for forming the lowest subband of the hole accumulation layer. In the following, we estimate VFB and ΔVg separately.
The VFB was estimated from the charge pumping (CP) measurements. The CP has been widely used for investigating the interface defects54,61,62,63. In the CP measurements54, a repetitive pulse voltage is applied to the gate so that holes and electrons are alternatively generated at the interface, similarly to the present method. The difference is the rising time tR. In the CP, the tR is set at a sufficiently large value so as to avoid the e-h coexistence. Then, the resultant e-h recombination current, called the CP current ICP, is generated, which flows only via the interface defects (see the potential diagram in Fig. 7a and the figure caption). The ICP is given by ICP = ANitef, where Nit is the density of the interface-defect states that can participate in the CP recombination process. Figure 7b shows the ICP of the present MOSFET taken as a function of Vbase at 8 K. (The Nit converted from ICP is shown on the right axis.) The tR was set at 1 ms. (As a reminder, it was set on the order of 10 ns for Figs. 2–6.) You can see that ICP flows only in a limited Vbase range (–3.4 V < Vbase < –1 V). This is because the lowest value (= Vbase) and the highest value (= Vbase + Vamp) of the gate pulse must be lower and higher than VFB and Vth (threshold voltage of the electron channel), respectively, in order to alternatively generate holes and electrons at the interface (see the inset of Fig. 7b). Therefore, the lower and higher thresholds of the ICP are respectively given by Vth – Vamp and VFB, as indicated by the arrows in Fig. 7b54. From the data, the VFB was estimated to be –1.2 ± 0.1 V. (Note that, from the value of ICP at the plateau, the maximum Nit was estimated to be 3 × 1010 cm–2.)
The ΔVg was estimated with the help of the theoretically derived values (from the literature) of the accumulation layer thickness tSi and the surface potential change from the flat-band condition Δφs for the lowest-subband formation (see Fig. 7c). According to the self-consistent calculations of the potential profile and the hole wave-function56,57, these were evaluated to be tSi ≃ 5 nm and Δφs ≃ 20 mV. The ΔVg can then be converted from Δφs as ΔVg = Δφs(Cox + CSi)/Cox, where the Cox = εox/tox and CSi = εSi/tSi with εox, εSi, and tox being the dielectric constants of the gate oxide and Si, and the gate-oxide thickness, respectively. Using εox = 3.9ε0, εSi = 11.9ε0 (ε0 is the dielectric constant in vacuum) and tox = 30 nm, the ΔVg was estimated to be 0.4 V.
In conclusion, we obtained Vacc = VFB – ΔVg = –1.6 ± 0.1 V, consistent with the value obtained in Figs. 2 and 3a.
Additional component of N rec
Here, we show that there is an additional component in Irec, and it originates from the CP recombination. We also show how to evaluate the slope of Nrec vs Vbase curve in order to compare it with the accumulation capacitance model.
In Fig. 8, we show with the black line the Irec - Vbase characteristics shown in Fig. 2 in the Vbase range from –4 V to –0.5 V. For comparison, ICP shown in Fig. 7b is replotted with the red line. Nrec and Nit converted from Irec and ICP are also shown on the right axis. These two (black and red) characteristics were taken with the same gate pulse conditions except for the rising time tR, which was 40 ns and 1 ms for the black and red lines, respectively.
One can see that Nrec (black line) has two features, a kink and tail, respectively, at Vbase = –3.4 V and –1.2 V, as indicated by the vertical arrows. One can also see that the values of Vbase at which the kink and the tail appear are coincident with the thresholds for Nit (red line). This indicates that the Nrec curve has an additional component originating from the recombination via the interface defects. This means that Nrec can be decomposed into two components. One is due to the e-h recombination dominated by the holes in the accumulation layer, which follows Nrec = – Cg,h (Vbase – Vacc)/e (indicated by the blue dashed line in Fig. 8). The other is due to the CP process where electrons are recombined with holes trapped at the interface defects (indicated by the hatching).
From the above analysis, one understands that only the limited range of Vbase, –4 V < Vbase < –3.4 V (= Vth – Vamp), gives us Nrec which is not influenced by the interface-defect mediated current (CP current). What we have found is that the slope in this Vbase region agrees with –Cg,h/e, where Cg,h is the hole accumulation-layer capacitance, and the resultant offset value of the Vbase, obtained by extrapolating the slope (blue dashed line), agrees with the hole accumulation-layer threshold Vacc (as explained in Methods section “Threshold voltage for accumulation-layer formation”). This means that the major Irec component, i.e., that not related to the CP process, is well described by the accumulation capacitance model.
Device fabrication
The n-channel MOSFETs were fabricated on a Si(100) substrate. The channel length, width and gate oxide thickness were, respectively, 50 μm, 500 μm and 30 nm, and the substrate doping (boron) concentration was of the order of 1015 cm−3. The gate oxide was formed in a dry oxygen ambient at 950 °C for 50 min. The gate was made of phosphorus-doped poly-Si and the fabrication was finalized with the forming gas (N2:H2 = 2:1) treatment at 450 °C for 30 min. The interface defect density was estimated to be 3 × 1010 cm−2 from the CP measurements described above.
Electrical measurements
The gate pulse was generated with the arbitrary function generator Tektronix AFG31102. The recombination current was measured in a low-temperature probing station with the source monitor units (SMUs) of the semiconductor parameter analyzer Keysight B1500A. Basically, the SMUs measure the charge Q originating from the current I to be measured with the long time period TP, and outputs the current I = Q/TP. Owing to this simple operation principle, it enables us to measure the (time-averaged) recombination current with a very high precision (at the cost of losing the information of the time domain).
For the real-time monitoring of irec(t), a high-speed current amplifier FEMTO DHPCA-100 was used. The time constant for the current detection was set at 10 ns, which is the shortest in the present measurement system.
The lattice temperature T of the device was measured and calibrated by using a commercially available Si diode thermometer.
Data availability
The data that support the findings of this study are available from the corresponding author upon reasonable request.
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Acknowledgements
The authors thank M. Tabe, T. Tsuchiya, and D. Moraru for their valuable comments. This work was partially supported by JSPS KAKENHI (JP16H06087, JP20H02203, JP20H00241, and JP22K18294).
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M.H. and J.K. measured the device; M.H. analyzed the data; M.H. and Y.O. wrote the manuscript; M.H., M.R. H.K., and Y.O. discussed the results; M.H. supervised the project.
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Hori, M., Kume, J., Razanoelina, M. et al. Electrical control of transient formation of electron-hole coexisting system at silicon metal-oxide-semiconductor interfaces. Commun Phys 6, 316 (2023). https://doi.org/10.1038/s42005-023-01428-1
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DOI: https://doi.org/10.1038/s42005-023-01428-1
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