Skip to main content

Thank you for visiting You are using a browser version with limited support for CSS. To obtain the best experience, we recommend you use a more up to date browser (or turn off compatibility mode in Internet Explorer). In the meantime, to ensure continued support, we are displaying the site without styles and JavaScript.

Heterobilayers of 2D materials as a platform for excitonic superfluidity


Excitonic condensate has been long-sought within bulk indirect-gap semiconductors, quantum wells, and 2D material layers, all tried as carrying media. Here, we propose intrinsically stable 2D semiconductor heterostructures with doubly-indirect overlapping bands as optimal platforms for excitonic condensation. After screening hundreds of 2D materials, we identify candidates where spontaneous excitonic condensation mediated by purely electronic interaction should occur, and hetero-pairs Sb2Te2Se/BiTeCl, Hf2N2I2/Zr2N2Cl2, and LiAlTe2/BiTeI emerge promising. Unlike monolayers, where excitonic condensation is hampered by Peierls instability, or other bilayers, where doping by applied voltage is required, rendering them essentially non-equilibrium systems, the chemically-specific heterostructures predicted here are lattice-matched, show no detrimental electronic instability, and display broken type-III gap, thus offering optimal carrier density without any gate voltages, in true-equilibrium. Predicted materials can be used to access different parts of electron-hole phase diagram, including BEC-BCS crossover, enabling tantalizing applications in superfluid transport, Josephson-like tunneling, and dissipationless charge counterflow.


Condensation to a macroscopic quantum state is a unique feature of bosonic particles that manifests in macroscopic quantum phenomena as remarkable as superfluidity and superconductivity. Experiments on these systems have affirmed our understanding of quantum theory, stimulated applications, and recent widespread interest in use for quantum computing1,2,3. Apart from the extraordinary transport properties4,5 of the condensate, the topological excitations in a superfluid are ideal hunting ground for exotic particles6 such as ‘t Hooft-Polyakov and Dirac monopoles, or skyrmions, useful for comprehending grand unified theory7 but also for applications in data storage and spintronics8,9. Excitons are composite bosons that are bound states of an electron and hole in a solid and were predicted to undergo condensation10,11 under appropriate conditions. Compared to commonly known bosonic systems such as atomic gases and liquid 4He, excitons have smaller mass and their condensate should remain stable12 up to higher temperatures13. Being created in solids by excitation with light, excitons have a short lifetime—a major obstacle to their condensation.

A fundamentally different possibility of an excitonic ground state was first discussed by Mott who noted14 that as valence and conduction bands of a semiconductor start overlapping (e.g., under external pressure) leading to a semi-metallic state (Fig. 1a), Coulomb attraction between the conduction band (CB) electrons and valence band (VB) holes should lead to the spontaneous formation of excitons, delaying the appearance of the metallic state. The semimetal transitions to an excitonic insulator phase, with a 2Δ gap15,16 in the excitation spectrum, as shown in Fig. 1b. The latter, also called the Bardeen-Cooper-Schrieffer (BCS) phase, corresponds to the weak coupling limit11 of composite boson condensate, and holds when na02 >> 1, where n is carrier or pair density and a0 is exciton radius. At low density, na02 << 1, the screening from carriers is reduced (strong coupling) and the Bose–Einstein condensate (BEC) phase forms. BEC and BCS are different limits11 of the same boson condensate state.

Fig. 1: Excitonic condensation in broken-gap 2D bilayer heterostructures.
figure 1

a Band alignment in a semi-metallic system with distinct electron and hole pockets necessary for exciton condensation. b For such a system with a negative gap (Eg) or when Eg < Eb (the exciton binding energy), the semi-metallic state becomes unstable and opens a gap for an arbitrarily weak electron-hole attraction. The semimetal now transitions to an excitonic insulator, with a gap of 2Δ in the excitation spectrum. c For a broken-gap band alignment, the electron is transferred to the conduction band of the acceptor layer B, with a hole remaining in the valence band on the donor layer A. In a staggered-gap alignment, band overlap can be tuned by external perturbation.

After early theoretical works on bulk semi-metallic crystals10,15,17,18, spatial separation has been proposed19,20,21 as a promising way to realize excitonic instability and inverted gap quantum-well bilayer systems were considered. Having electrons and holes spaced apart is deemed essential to reduce many-body interactions that lead to thermodynamic instability near the phase transition22. However, in quantum wells typically separated by dozens of Å, electron-hole interaction is weak. Moreover, surface roughness/disorder in quantum wells degrades the coherence of the excitonic state.

Recent interest in excitonic condensation has been renewed by the advent of two-dimensional (2D) materials, providing the advantage of reduced screening and atomically sharp interface. Bilayer graphene has been extensively investigated theoretically23,24,25,26 and even with some experimental evidence27, however inconclusive, since the phase sought is either not observed or has very low Tc; bilayer graphene low effective mass (0.03–0.05 me)28,29 results in weak exciton binding and requires intricate device design with electrostatic gating. Moreover, other 2D hetero-bilayers have also been theoretically predicted (ref. 30 and references therein) and recently experimentally demonstrated31 to exhibit exciton condensation. However, by necessity they require applied voltages for doping with inevitable leakage currents and energy dissipation, in other words all are fundamentally non-equilibrium systems. This is significant in preventing observation of zero-bias Josephson effect31, not to mention detrimental heating in any device. Recently there was a suggestion of true equilibrium excitonic condensate ground state in 1T-TiSe2, a layered 2D semimetal32,33. However, TiSe2 is also known to host phonon instability34,35, possibly making the excitonic phase ground state inaccessible36 due to lattice reconstruction. In a semimetal, a phonon with wave-vector QCDW = ΓM (Fig. 1a) could render the system unstable by creating a spontaneous crystal distortion (Peierls instability) driven by the electron-phonon interaction, preventing the appearance of the excitonic state22. Technically, the mean-field gap equations describing the excitonic insulator and Peierls instability are mathematically identical32,37,38 and give the same excitation spectrum16 as shown in Fig. 1b, with the only difference being in the nature of coupling (Coulomb attraction for the former and electron-phonon coupling for the latter), complicating the differentiation of the two phases. Thus, single-layer 2D systems are also potentially plagued by the same problems as bulk crystals - namely, strong interband tunneling transitions and thermodynamic instability, where excitons are mixed in into the ground state of the Peierls insulator38. To resolve this issue, both k-space and real space separations of the VB and CB are deemed essential for creation of the exciton condensate state.

This work identifies a realistic chemically-specific material system(s), 2D van der Waals (vdW) bilayer heterostructures, which are lattice-matched (prerequisite for exciton coherence), do not show detrimental electronic instability (like Peierls), and display broken type-III gap, thus offering the optimal carrier density without any voltage/gating, stable, in true equilibrium. The hetero-bilayers have spatially separated bands and the semimetallic state arises due to difference in the workfunctions of the layers and therefore not requring any electrostatic gating. The electrons and holes are located next to each other on different layers as well as on distinct valleys, their mutual interaction driving excitonic instability and, at lower temperatures, condensation. Since the electron and holes states are spatially separated, the electron-phonon interaction between the layers would be weak, thereby preventing any phonon-driven Peierls instability. Such bilayer heterostructure must be composed of a pair of lattice-matched monolayer 2D semiconductors with either a broken gap (type III) or staggered gap (type II) alignment. For a broken-gap band alignment shown in Fig. 1c, the electron is transferred to the conduction band of the acceptor layer, with a hole remaining in the valence band on the donor layer. Band overlap can also be tuned through external perturbation, as shown in Fig. 1c, starting from the staggered gap lineup.


Model Hamiltonian analysis of 2D bilayer heterostructure

In order to guide and accelerate such search of suitable material pairs based on their band alignment, we first perform a model Hamiltonian analysis (see “Methods”) for estimating the optimal effective mass and carrier density. In a bilayer heterostructure with carrier density n, embedded in vacuum and separated by distance d = 3 Å, the electron and hole states are on different layers and have distinct effective masses. To estimate the binding energies (Eb) of individual interlayer excitons in such vdW heterostructures, we adopt the RPA form of the screened potential suitable for bilayers19,25. The effective mass Hamiltonian for an electron-hole pair in parabolic bands was constructed and diagonalized using the Gaussian basis set (see “Methods” for details). Figure 2a shows the calculated room-temperature binding energies of interlayer excitons as a function of reduced mass μ, and carrier density. Although the potential is always attractive, the model predicts essentially no binding for n higher than ~1012 cm−2 as well as at carrier masses below μ ~ 0.03 me.

Fig. 2: Model of exciton condensation in 2D bilayer heterostructure.
figure 2

a Binding energies (lines labeled by meV) and exciton radius (color map) in a metallic bilayer with interlayer separation d = 3 Å as a function of reduced effective mass μ and carrier density n. Highlighted area shows the region with bound states. b Phase diagram for excitons in bilayer semimetal. BKT line for transition to quasi-condensate and BCS line for different reduced mass (0.125, 0.25, and 0.5) are shown (equal carrier masses are assumed). Outside of the condensate region, a degenerate exciton Bose gas (DEBG) exists on the low density side, and electron-hole plasma on the high density side. The estimated critical temperatures (Tc) for materials labeled (1, 2, and 3) in Fig. 3 are also shown.

Favorable conditions for strong interactions and a strongly coupled regime are in the upper left corner of Fig. 2a, i.e. at carrier masses μ ~ 0.5 me and densities n ~ 1011 cm−2. At low densities (na02 << 1) these individual excitons with high binding energy are known11,12 to condense into a BEC-like phase below a critical temperature. The two-dimensional analog of the three-dimensional BEC phase of excitons is the Berezinskii-Kosterlitz-Thouless (BKT)39 phase, which, unlike BEC, lacks long range phase coherence, but has local phase coherence and exhibits superfluidity. The temperature TBKT for the BKT superfluid phase transition in a noninteracting 2D Bose liquid is obtained from the universal relation39,40 kBTBKT = πn2/2 M, where M is the exciton mass, and is shown in Fig. 2b for different masses. One should note from Fig. 2a that the binding energies of individual excitons are greater than kBTBKT at corresponding masses and densities in Fig. 2b, justifying the use of the strongly coupled BKT limit. The dashed lines in Fig. 2b denote the crossover from the BKT phase to the BCS regime where the condensation is best described by the BCS mean field theory41. The BCS critical temperature is given by42 kBTc = 0.57Δ and is shown in Fig. 2b. The order parameter Δ was evaluated by solving the self-consistent excitonic gap equation for different masses and carrier densities (details in “Methods”). Overall, Fig. 2b represents a semi-quantitative phase diagram for excitonic particles and denotes optimal n to realize an excitonic condensate phase (see Supplementary Fig. 9 for all other phases). Apart from the phases shown in Fig. 2b, a gas of excitons can also transition to an electron-hole liquid (EHL) state, thereby preventing the realization of an excitonic condensation (BKT/BCS). However, in our bilayer case with electrons and holes spatially separated, the excitons act as oriented electric dipoles with a repulsive interaction between them. The repulsion is important because it prevents the occurrence of EHL state and excitonic BKT/BCS can be realized43 at low densities. However, at high densities, the EHL state might be more stable44.

Identifying optimal 2D bilayer heterostructures

The densities to realize excitonic condensation should be achievable with existing 2D materials. We search the 2D material database45 to identify optimal materials by first recalculating and comparing valence and conduction band positions with respect to the vacuum level. The database45 contains a list of 2D materials that can be exfoliated from experimentally known 3D compounds. Next, after pre-selecting candidate pairs, we calculate the band gaps of 23 heterostructures with broken and staggered band alignments, as shown in Fig. 3. The pairs were chosen so that their lattice mismatch Δε < 2%, and each layer has a band gap >0.3 eV. Band gaps in heterostructures range from −0.22 eV to 0.1 eV, with negative values indicating greater overlap. Assuming effective masses are same, higher band overlap corresponds to higher carrier density, and different heterostructures can be used to access distinct regions of the phase diagram. According to Fig. 2b, n ~ 1010–5 × 1012 cm−2 is an optimal range of carrier density for excitonic condensation, and the corresponding optimal initial band overlaps are 1 meV < W0 < 391 meV, assuming μ = 0.1 me, and d = 3 Å (see “Methods” for details). The final overlap in a heterostructure W is 1 meV<W < 120 meV. We select three materials pairs Sb2Te2Se/BiTeCl, Hf2N2I2/Zr2N2Cl2, and LiAlTe2/BiTeI marked in Fig. 3, in which final calculated band overlaps after forming heterostructures are 67 meV, 47 meV, and 38 meV, respectively. Materials with small band gaps can show excitonic instability provided that Eg < Eb and can also in principle exhibit condensation.

Fig. 3: Hetero-bilayers band alignments.
figure 3

Relative positions of valence (left upward columns) and conduction bands (right downward columns) in 2D heterostructures for Δε < 2%, −0.22 eV < ΔE < 0.1 eV, Eg > 0.3 eV. The five bilayers considered in detail in this work are highlighted with thicker outline, and the calculated BCS gaps Δ for heterostructures 1, 2, and 3 are shown.

We calculate the phonon spectra and band structure of Hf2N2I2/Zr2N2Cl2 (see Supplementary Fig. 3 for two other hetero-bilayers), which is instructive to compare with the monolayer 1T-TiSe2, well studied32,33,34,35 as a possible candidate for excitonic instability. In Fig. 4a, b the band structures of individual Hf2N2I2 and Zr2N2Cl2 layers are plotted. Both materials are semiconductors, with the VBM of freestanding Hf2N2I2 at −4.57 eV and the CBM of Zr2N2Cl2 at −4.88 eV, with respect to the same vacuum level. After a bilayer is formed, the energy overlap between the VBM and CBM decreases but remains, at ~0.05 eV, as seen in Fig. 4c of the Hf2N2I2/Zr2N2Cl2 band structure, which also shows that the electron-doped conduction band at the K point is located on the Zr2N2Cl2 layer, while hole-doped valence band on the Hf2N2I2 layer. As there is little interlayer mixing in either the valence or conduction bands, a bilayer becomes polar. The band structure of Hf2N2I2/Zr2N2Cl2 resembles in fact that of monolayer 1T-TiSe2 (Fig. 4d), both being indirect-gap semimetals with the VBM and CBM lying at different valleys in the Brillouin zone. Similar to 1T-TiSe2, the valence and conduction bands are mainly composed of p and d orbitals, with the VBM originating from iodine p states of Hf2N2I2 layer, and smaller contributions from nitrogen p states of Hf2N2I2, whereas the CBM originates from zirconium d states, with smaller contributions from p states of N and Cl of Zr2N2Cl2 (see Supplementary Fig. 7). Notably, the valence and conduction bands of 1T-TiSe2 are strongly coupled to phonons16,34,46, namely, the bands of TiSe2 are coupled to atomic displacements at modulation vector Q = ΓM, in Fig. 4e; resulting charge-density wave (CDW) is accompanied by lattice reconstruction. This resembles the Peierls instability which opens the band gap, debatably driving this material to a conventional insulator state34,35,36. In contrast, such instability is absent in Hf2N2I2/Zr2N2Cl2, where valence and conduction bands, located at different layers, are decoupled. The phonon spectrum of Hf2N2I2/Zr2N2Cl2 in Fig. 4f attests to its stable structure; electron-phonon coupling, largest at K and Γ points, is too weak to cause unstable modes. A CDW is expected due to the modulation vector Q = ΓK47, however, due to weak electron-phonon coupling, there will not be any lattice distortion. The spontaneous excitonic condensation in this material will be mediated by purely electronic interaction. Thus, excitonic condensation would not be hampered by the phonon instability in a Hf2N2I2/Zr2N2Cl2 bilayer or, for that matter, in other vdW bilayers (this was further affirmed by additional supercell calculations, see 3.2 in Supplementary Note 3).

Fig. 4: Band structures and phonon spectra of 2D Hf2N2I2, Zr2N2Cl2, Hf2N2I2/Zr2N2Cl2, and 1T TiSe2.
figure 4

Band alignment in a Hf2N2I2 and b Zr2N2Cl2. Projected LDA band structures of c Hf2N2I2/Zr2N2Cl2 heterostructure, and d 1T TiSe2. LDA phonon dispersions with electron-phonon couplings λ of e 1T TiSe2, and f Hf2N2I2/Zr2N2Cl2 heterostructure. The area of the gray and red circles is proportional to the coupling strength λ.


Hf2N2I2/Zr2N2Cl2 has a finite modulation vector Q = ΓK, however, Sb2Te2Se/BiTeCl, and LiAlTe2/BiTeI have a zero modulation vector (see Supplementary Fig. 3). This results in band crossing between electron and hole states and also hybridization in Sb2Te2Se/BiTeCl, and LiAlTe2/BiTeI (for details see 3.1 in Supplementary Note 3). Single-particle level band hybridization can lead to interband tunneling processes and may fix the phase of the order parameter and destroy superfluidity47. However, these tunneling processes can be suppressed by using suitable dielectrics such as hBN in between the two layers and superfluidity can be achieved.

From the band structures calculated using LDA functional, we further extract the effective masses (see Supplementary Table 1) and calculate the n in three hetero-bilayers, in order to estimate the critical temperatures for excitonic condensation, marked in Fig. 2b as circled 1, 2 and 3 (see 1.2 in Supplementary Note 1 for the value of n obtained with another functional). We find n to be >1012 cm−2, with Hf2N2I2/Zr2N2Cl2 highest Tc of ~31 K. While the method-dependent spread of n values as estimated by different functionals would yield different estimates for Tc, it should not affect the conclusion about the feasibility of excitonic condensation in these heterostructures. Building upon Mott’s early ideas14, external factors such as strain, and possibly gating or changing the interlayer distance (yet not to weaken binding interaction), can fine-tune the carrier density, to access different regions of the phase diagram, and increase the Tc (see Supplementary Note 2 for details). For example, a field of ~1 V/nm can change the carrier density by ~1012 cm−2, and can quite noticeably shift Tc of materials in Fig. 2b diagram. Similar perturbation can even be used to tune the band overlap in the hetero-bilayers lying on the flanks of Fig. 3, which were rendered above as suboptimal for excitonic condensation, if those are more readily synthesizable.

In summary, our quantitative analysis demonstrates that Sb2Te2Se/BiTeCl, Hf2N2I2/Zr2N2Cl2, LiAlTe2/BiTeI, Hf2N2I2/SnS2 and possibly other 2D hetero-bilayers can serve as a platform for realizing an excitonic ground state, in true equilibrium systems (with no need of light-excitation or even static applied voltages). The van der Waals spacing ensures that the lattice thermodynamic stability is preserved, with bands edges being decoupled from the atomic displacements, offering a better material-host for excitonic condensation as compared to recently considered monolayer 1T-TiSe2, likely prone to Peierls instability, which hamper exciton condensation. Moreover, the type-III broken gap ensures that no applied gate-voltage is required for doping, contrary to other studied hetero-bilayers. To map the electron-hole system behaviors in a hetero-bilayers, we construct a phase diagram, which for realistic materials suggests excitonic condensation at tens of K at densities 1011–1013 cm−2. Various parts of the phase diagram, and most importantly the BEC-BCS crossover can in principle be reached through further tuning by external electric field and strain. We expect the materials predicted here to show superfluid transport properties such as enhanced Josephson-like interlayer tunneling5, and dissipationless charge counterflow48, which have been experimentally observed in other bilayer designs and have potential for next-generation electronics and logic devices49. Excitons have spin degree of freedom and the spin polarization states of the excitons can also act as a qubit3. Moreover, excitonic ferromagnetism50 may arise from a mix of the singlet and triplet pairing states, which can be used to generate spin currents vital in spintronics. An interesting realization can be possible in nested cylindrical hetero-bilayers, where additional flexoelectric offset51 must be taken into account.


First principles DFT calculation

Band structures, phonon frequencies, and electron-phonon coupling coefficients were calculated from density functional theory using LDA functional, as implemented in the Quantum Espresso package52. Fully relativistic ultrasoft pseudopotentials were used to represent ionic cores and were obtained from the pslibrary53 (version 1.0.0, The pseudopotentials and 60 Ry kinetic energy cutoff was used for all materials except those with Li, Mg, La, Zn, Cu, and Na. For the latter few, we used the cutoffs above the recommended minima, all higher than 60 Ry. A k-grid of 81 × 81 × 1 was used for Brillouin zone sampling. BFGS algorithm was used for structural relaxation. The structure was relaxed until the Hellmann–Feynman forces on the atoms were less than 2.6 meV/Å. A vacuum of 20 Å was used along direction perpendicular to the 2D sheet to reduce the interaction between the periodic images. Spin-orbit coupling was included in all calculations. The response of the material to an external electric field (Supplementary Fig. 2) was calculated using the Vienna Ab Initio Simulation Package (VASP)54 implementation. A cutoff of 600 eV for the plane-wave basis was used. Ion-electron interactions were represented by all-electron projector augmented wave potentials. LDA functional is known to fortuitously capture well the interlayer van der Waals interactions55. Additionally, semiempirical Grimme’s DFT-D2 van der Waals correction to PBE functional was used to estimate the equilibrium interlayer distance and a good agreement with LDA functional was obtained.

We considered all 258 easily-exfoliable layers, with a small unit cell (≤6 atoms/unit cell) from the materials cloud database, as selected by its creators45. Among these, 135 were found to have hexagonal lattices, and their pairs-combinations were tested for lattice match. The lattice constant matching is important for excitonic condensation. In a heterostructure with a large difference in lattice constant, the materials are incommensurate, preventing zero-momentum excitons formation and excitonic condensation. This is analogous to the disappearance of excitonic condensation upon twisting the heterobilayers MoSe2/WSe2, observed recently31: upon twisting, the lattices become incommensurate with momentum mismatch between the hole and electron valleys in the materials, the interlayer excitons formed thus have a large momentum, which destroys condensation.

Model hamiltonian analysis - exciton binding energy

The model Hamiltonian within the effective mass approximation for an electron-hole pair in a bilayer semimetal is given by

$$H = - \hbar ^2/\left( {2\mu _x} \right)\partial ^2/\partial x^2 - \hbar ^2/\left( {2\mu _y} \right)\partial ^2/\partial y^2 + V_{{\mathrm{eh}}}\left( r \right)$$

Here, μx,y are the reduced masses in x and y directions, respectively, and Veh(r) is the effective 2D Coulomb potential in a bilayer metal. Unlike 2D single-layer56 and bilayer57 semiconductors, where intralayer and interlayer exciton binding energies are much larger compared to bulk due to weak screening, in semimetallic systems interactions are reduced significantly, leading to weaker binding. Here we adopt the random phase approximation (RPA) form of the screened potential suitable for metallic bilayers19,25, given by

$$V_{{\mathrm{eh}}}\left( q \right) = -(2\pi q/\kappa )[e^{ - qd}/((q + s)^2 - s^2e^{ - 2qd})]$$

Here, κ is the background dielectric constant assumed to be unity in this work, s is the 2D screening wave number and d is the distance between the bilayers. In the ideal case of a two-band metal, screening s is given by (gm*/κ)(1 − e−2πβn/gm*), where n is the carrier density, g is valley and spin degeneracy, β is 1/kBT and m* is the effective mass. In a two-dimensional metal with parabolic bands, the screening wave number is independent of density at zero temperature. However, at finite T, screening is both density- and temperature-dependent, with increasing temperature leading to reduced screening (for details see 1.1 in Supplementary Note 1); T = 300 K is assumed here. Veh(r) was obtained from Veh(q) using Fourier transform. The excitonic binding energies Eb and wavefunctions were obtained by finding the eigenvalues and eigenfunctions of the effective mass Hamiltonian (Eq. (1)). Gaussian basis set of size 6 was used to expand the ground-state excitonic wavefunction and calculate the matrix elements for the kinetic and potential energy of the Hamiltonian. The expansion was optimized using the downhill simplex algorithm. The parameters for model Hamiltonian analysis were extracted from the heterostructures, not the constituent layers.

BCS mean field gap equation

Analogous to the BCS algebra, the order parameter Δ is obtained by solving the below equations self-consistently21,44

$$\xi _k = \varepsilon _k -\bar \mu- \left( {1/2} \right)\Sigma _{k^\prime }V_{{\mathrm{ee}}}\left( {|k - k^\prime |} \right)\left( {1 - \xi _{k^\prime }/E_{k^\prime }} \right)$$
$$E_k^2 = \xi _k^2 + \Delta _k^2$$
$$\Delta _k = - \left( {1/2} \right)\Sigma _{k^\prime }V_{{\mathrm{eh}}}\left( {|k - k^\prime |} \right)\Delta _{k^\prime }/E_{k^\prime }$$

Here, Veh is the attractive Coulomb potential as given by Eq. (2), Vee(q) = (2π/κ)[(q + s − se−2qd)/((q + s)2 − s2e−2qd)]30, εk = 1/2(2k2/2me + 2k2/2mh), \(\bar \mu\)= 1/2(μex − e2nd0κ(1 + sd)), μex here is chemical potential for excitons, n = Σk ½ (1 − ξk/Ek) and q= |k − k′|. The order parameter (∆) in Eq. (5) is the gap function. It is zero in the normal state and non-zero in the excitonic insulating state. A value of 2∆ denotes the gap in the excitonic insulator ground state. The form of BCS Eq. (5) remains the same when the modulation vector Q is finite15, as Q does not enter the expression. This is because in εk (which depends on Ec(k) conduction band (electron) dispersion and Ev(k) valence band (hole) dispersion) k is referred to the respective band extrema15. We do not include spin degrees of freedom and thus neglect any spin-triplet excitonic order. All quantities in Eqs. (3)–(5) are assumed to be isotropic i.e. functions of magnitude of k, and these equations are solved self-consistently to determine Ek and ∆k. Subsequently, critical temperature is obtained from the maximum value of Δk. The mean field calculations give an approximate depiction of the excitonic condensate phase diagram and quantum Monte Carlo can be appropriate for a much higher accuracy58.

Charge transfer model

For an isolated pair of materials with parabolic bands and VBM-CBM overlap W0, the charge transfer can be estimated using a parallel-plate capacitor model as n = W0/e2(1/C + 1/Cq) where C = ε0/d and Cq = ge2μ/2π2 are the classical and quantum bilayer capacitances, respectively. One has n[1013 cm−2] = W0[eV]/(0.18d[Å] + 0.02/μ[me]) for numerical estimates. In a stacked heterostructure, with a new band overlap W, the density is expressed as n = W(C + Cq)/e2(1 + C/Cq), or n[1013cm−2] = W[eV](1 + 7.6μ[me]d[Å])/(0.18d[Å] + 0.02/μ[me]) for numerical estimates.

Data availability

The authors declare that the data supporting the findings of this study are available within the paper and its Supplementary information files. An archive with optimized geometries for heterostructures listed in Fig. 3 is provided as Supplementary dataset 1. The data in the dataset is deposited on the Zenodo database


  1. Friedman, J. R., Patel, V., Chen, W., Tolpygo, S. K. & Lukens, J. E. Quantum superposition of distinct macroscopic states. Nature 406, 43 (2000).

    ADS  CAS  PubMed  Article  Google Scholar 

  2. Dadras, S., Gresch, A., Groiseau, C., Wimberger, S. & Summy, G. S. Quantum Walk in Momentum Space with a Bose-Einstein Condensate. Phys. Rev. Lett. 121, 070402 (2018).

    ADS  CAS  PubMed  Article  Google Scholar 

  3. Byrnes, T., Wen, K. & Yamamoto, Y. Macroscopic quantum computation using Bose-Einstein condensates. Phys. Rev. A 85, 040306 (2012).

    ADS  Article  CAS  Google Scholar 

  4. Liu, X., Watanabe, K., Taniguchi, T., Halperin, B. I. & Kim, P. Quantum Hall drag of exciton condensate in graphene. Nat. Phys. 13, 746–750 (2017).

    CAS  Article  Google Scholar 

  5. Burg, G. W. et al. Strongly Enhanced Tunneling at Total Charge Neutrality in Double-Bilayer Graphene-WSe2 Heterostructures. Phys. Rev. Lett. 120, 177702 (2018).

    ADS  CAS  PubMed  Article  Google Scholar 

  6. Ueda, M. Fundamentals and New Frontiers of Bose-Einstein Condensation (World Scientific, 2010).

  7. Preskill, J. Magnetic Monopoles. Annu. Rev. Nucl. Part. Sci. 34, 461–530 (1984).

    ADS  CAS  Article  Google Scholar 

  8. Kiselev, N. S., Bogdanov, A. N., Schäfer, R. & Rößler, U. K. Chiral skyrmions in thin magnetic films: new objects for magnetic storage technologies? J. Phys. Appl. Phys. 44, 392001 (2011).

    Article  CAS  Google Scholar 

  9. Fert, A., Cros, V. & Sampaio, J. Skyrmions on the track. Nat. Nanotechnol. 8, 152–156 (2013).

    ADS  CAS  PubMed  Article  Google Scholar 

  10. Keldysh, L. & Kozlov, A. Collective properties of excitons in semiconductors. Sov. Phys. JETP 27, 521 (1968).

    ADS  Google Scholar 

  11. Nozières, P. & Schmitt-Rink, S. Bose condensation in an attractive fermion gas: From weak to strong coupling superconductivity. J. Low. Temp. Phys. 59, 195–211 (1985).

    ADS  Article  Google Scholar 

  12. Snoke, D. Spontaneous Bose coherence of excitons and polaritons. Science 298, 1368–1372 (2002).

    ADS  CAS  PubMed  Article  Google Scholar 

  13. Fogler, M. M., Butov, L. V. & Novoselov, K. S. High-temperature superfluidity with indirect excitons in van der Waals heterostructures. Nat. Commun. 5, 4555 (2014).

    ADS  CAS  PubMed  Article  Google Scholar 

  14. Mott, N. F. The transition to the metallic state. Philos. Mag. J. Theor. Exp. Appl. Phys. 6, 287–309 (1961).

    CAS  Google Scholar 

  15. Jérome, D., Rice, T. M. & Kohn, W. Excitonic Insulator. Phys. Rev. 158, 462–475 (1967).

    ADS  Article  Google Scholar 

  16. Rossnagel, K. On the origin of charge-density waves in select layered transition-metal dichalcogenides. J. Phys. Condens. Matter 23, 213001 (2011).

    ADS  CAS  PubMed  Article  Google Scholar 

  17. Kozlov, A. & Maksimov, L. The metal-dielectric divalent crystal phase transition. Sov. Phys. JETP 2, 790 (1965).

    ADS  Google Scholar 

  18. Halperin, B. I. & Rice, T. M. Possible anomalies at a semimetal-semiconductor transition. Rev. Mod. Phys. 40, 755–766 (1968).

    ADS  CAS  Article  Google Scholar 

  19. Lozovik, Y. E. & Yudson, V. Feasibility of superfluidity of paired spatially separated electrons and holes; a new superconductivity mechanism. JETP Lett. 22, 274–276 (1975).

    ADS  Google Scholar 

  20. Datta, S., Melloch, M. R. & Gunshor, R. L. Possibility of an excitonic ground state in quantum wells. Phys. Rev. B 32, 2607–2609 (1985).

    ADS  CAS  Article  Google Scholar 

  21. Zhu, X., Littlewood, P. B., Hybertsen, M. S. & Rice, T. M. Exciton condensate in semiconductor quantum well structures. Phys. Rev. Lett. 74, 1633–1636 (1995).

    ADS  CAS  PubMed  Article  Google Scholar 

  22. Guseinov, R. & Keldysh, L. Nature of the phase transition under the conditions of an ‘excitonic’ instability in the electronic spectrum of a crystal. Sov. Phys. JETP 36, 1193 (1973).

    ADS  Google Scholar 

  23. Min, H., Bistritzer, R., Su, J.-J. & MacDonald, A. H. Room-temperature superfluidity in graphene bilayers. Phys. Rev. B 78, 121401 (2008).

    ADS  Article  CAS  Google Scholar 

  24. Kharitonov, M. Y. U. & Efetov, K. B. Electron screening and excitonic condensation in double-layer graphene systems. Phys. Rev. B 78, 241401 (2008).

    ADS  Article  CAS  Google Scholar 

  25. Lozovik, Y. U. E., Ogarkov, S. L. & Sokolik, A. A. Condensation of electron-hole pairs in a two-layer graphene system: Correlation effects. Phys. Rev. B 86, 045429 (2012).

    ADS  Article  CAS  Google Scholar 

  26. Perali, A., Neilson, D. & Hamilton, A. R. High-temperature superfluidity in double-bilayer graphene. Phys. Rev. Lett. 110, 146803 (2013).

    ADS  CAS  PubMed  Article  Google Scholar 

  27. Li, J. I. A., Taniguchi, T., Watanabe, K., Hone, J. & Dean, C. R. Excitonic superfluid phase in double bilayer graphene. Nat. Phys. 13, 751 (2017).

    CAS  Article  Google Scholar 

  28. McCann, E. & Fal’ko, V. I. Landau-level degeneracy and quantum hall effect in a graphite bilayer. Phys. Rev. Lett. 96, 086805 (2006).

    ADS  PubMed  Article  CAS  Google Scholar 

  29. Kolomeisky, E. B., Straley, J. P. & Abrams, D. L. Space charge and screening in bilayer graphene. J. Phys. Condens. Matter 28, 47LT01 (2016).

    PubMed  Article  CAS  Google Scholar 

  30. Debnath, B., Barlas, Y., Wickramaratne, D., Neupane, M. R. & Lake, R. K. Exciton condensate in bilayer transition metal dichalcogenides: Strong coupling regime. Phys. Rev. B 96, 174504 (2017).

    ADS  Article  Google Scholar 

  31. Wang, Z. et al. Evidence of high-temperature exciton condensation in two-dimensional atomic double layers. Nature 574, 76–80 (2019).

    ADS  CAS  PubMed  Article  Google Scholar 

  32. Kogar, A. et al. Signatures of exciton condensation in a transition metal dichalcogenide. Science 358, 1314–1317 (2017).

    ADS  CAS  PubMed  Article  Google Scholar 

  33. Chen, C., Singh, B., Lin, H. & Pereira, V. M. Reproduction of the charge density wave phase diagram in 1T TiSe2 exposes its excitonic character. Phys. Rev. Lett. 121, 226602 (2018).

    ADS  CAS  PubMed  Article  Google Scholar 

  34. Bianco, R., Calandra, M. & Mauri, F. Electronic and vibrational properties of TiSe2 in the charge-density-wave phase from first principles. Phys. Rev. B 92, 094107 (2015).

    ADS  Article  CAS  Google Scholar 

  35. Pasquier, D. & Yazyev, O. V. Excitonic effects in two-dimensional TiSe2 from hybrid density functional theory. Phys. Rev. B 98, 235106 (2018).

    ADS  Article  Google Scholar 

  36. Zhu, Z., Cheng, Y. & Schwingenschlögl, U. Origin of the charge density wave in 1T-TiSe2. Phys. Rev. B 85, 245133 (2012).

    ADS  Article  CAS  Google Scholar 

  37. Gor’kov, L. P. & Grüner, G. in Charge Density Waves in Solids (eds. Gor’kov, L. P. & Grüner, G.) 25, 1–13 (Elsevier, 1989).

  38. Rice, M. J. & Gartstein, Y. N. The excitonic ground state of the half-filled Peierls insulator. J. Phys. Condens. Matter 17, 4615–4620 (2005).

    ADS  CAS  Article  Google Scholar 

  39. Kosterlitz, J. M. & Thouless, D. J. Ordering, metastability and phase transitions in two-dimensional systems. J. Phys. C. Solid State Phys. 6, 1181–1203 (1973).

    ADS  CAS  Article  Google Scholar 

  40. Nelson, D. R. & Kosterlitz, J. M. Universal jump in the superfluid density of two-dimensional superfluids. Phys. Rev. Lett. 39, 1201–1205 (1977).

    ADS  CAS  Article  Google Scholar 

  41. Lozovik, Y. E. & Yudson, V. A new mechanism for superconductivity: pairing between spatially separated electrons and holes. Zh. Eksp. Teor. Fiz. 71, 738–753 (1976).

    Google Scholar 

  42. Bardeen, J., Cooper, L. N. & Schrieffer, J. R. Theory of superconductivity. Phys. Rev. 108, 1175–1204 (1957).

    ADS  MathSciNet  CAS  MATH  Article  Google Scholar 

  43. Butov, L. V. Cold exciton gases in coupled quantum well structures. J. Phys. Condens. Matter 19, 295202 (2007).

    CAS  PubMed  Article  Google Scholar 

  44. Wu, F.-C., Xue, F. & MacDonald, A. H. Theory of two-dimensional spatially indirect equilibrium exciton condensates. Phys. Rev. B 92, 165121 (2015).

    ADS  Article  CAS  Google Scholar 

  45. Mounet, N. et al. Two-dimensional materials from high-throughput computational exfoliation of experimentally known compounds. Nat. Nanotechnol. 13, 246–252 (2018).

    ADS  CAS  PubMed  Article  Google Scholar 

  46. Hellgren, M. et al. Critical role of the exchange interaction for the electronic structure and charge-density-wave formation in TiSe2. Phys. Rev. Lett. 119, 176401 (2017).

    ADS  PubMed  Article  Google Scholar 

  47. Zenker, B., Fehske, H. & Beck, H. Fate of the excitonic insulator in the presence of phonons. Phys. Rev. B 90, 195118 (2014).

    ADS  Article  CAS  Google Scholar 

  48. Tutuc, E., Shayegan, M. & Huse, D. A. Counterflow measurements in strongly correlated GaAs hole bilayers: evidence for electron-hole pairing. Phys. Rev. Lett. 93, 036802 (2004).

    ADS  CAS  PubMed  Article  Google Scholar 

  49. Banerjee, S. K., Register, L. F., Tutuc, E., Reddy, D. & MacDonald, A. H. Bilayer pseudospin field-effect transistor (BiSFET): a proposed new logic device. IEEE Electron Device Lett. 30, 158–160 (2009).

    ADS  Article  Google Scholar 

  50. Volkov, B. A., Kopaev, Yu. V. & Rusinov, A. I. Theory of ‘excitonic’ ferromagnetism. Sov. Phys. JETP 41, 952 (1975).

    ADS  Google Scholar 

  51. Artyukhov, V. I., Gupta, S., Kutana, A. & Yakobson, B. I. Flexoelectricity and charge separation in carbon nanotubes. Nano Lett. 20, 3240–3246 (2020).

    CAS  PubMed  Article  ADS  Google Scholar 

  52. Giannozzi, P. et al. Advanced capabilities for materials modelling with quantum ESPRESSO. J. Phys. Condens. Matter. 29, 465901 (2017).

    CAS  PubMed  Article  Google Scholar 

  53. Dal Corso, A. Pseudopotentials periodic table: from H to Pu. Comput. Mater. Sci. 95, 337–350 (2014).

    CAS  Article  Google Scholar 

  54. Kresse, G. & Furthmüller, J. Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set. Comput. Mater. Sci. 6, 15–50 (1996).

    CAS  Article  Google Scholar 

  55. Mostaani, E., Drummond, N. D. & Fal’ko, V. I. Quantum Monte Carlo Calculation of the binding energy of bilayer graphene. Phys. Rev. Lett. 115, 115501 (2015).

    ADS  CAS  PubMed  Article  Google Scholar 

  56. Wang, L., Kutana, A. & Yakobson, B. I. Many-body and spin-orbit effects on direct-indirect band gap transition of strained monolayer MoS2 and WS2. Ann. Phys. 526, L7–L12 (2014).

    ADS  CAS  Article  Google Scholar 

  57. Okada, M. et al. Direct and indirect interlayer excitons in a van der Waals heterostructure of hBN/WS2/MoS2/hBN. ACS Nano 12, 2498–2505 (2018).

    CAS  PubMed  Article  Google Scholar 

  58. De Palo, S., Rapisarda, F. & Senatore, G. Excitonic condensation in a symmetric electron-hole bilayer. Phys. Rev. Lett. 88, 206401 (2002).

    ADS  PubMed  Article  CAS  Google Scholar 

Download references


This work was supported by the US Army Research Office, Electronics division (W911NF-16-1-0255), and by the Robert Welch Foundation (C-1590). The authors acknowledge the DoD HPCMP, DOE NERSC, and NSF XSEDE for computing resources, and Peter J. Reynolds for useful discussion.

Author information

Authors and Affiliations



S.G., A.K., and B.I.Y. conceived the project. S.G. and A.K. identified and refined the structures from the databases and performed all first-principles simulations. All authors contributed to the writing of the paper.

Corresponding author

Correspondence to Boris I. Yakobson.

Ethics declarations

Competing interests

The authors declare no competing interests.

Additional information

Peer review information Nature Communications thanks Oleg Yazyev and the other, anonymous reviewer(s), for their contribution to the peer review of this work.

Publisher’s note Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Supplementary information

Rights and permissions

Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit

Reprints and Permissions

About this article

Verify currency and authenticity via CrossMark

Cite this article

Gupta, S., Kutana, A. & Yakobson, B.I. Heterobilayers of 2D materials as a platform for excitonic superfluidity. Nat Commun 11, 2989 (2020).

Download citation

  • Received:

  • Accepted:

  • Published:

  • DOI:


By submitting a comment you agree to abide by our Terms and Community Guidelines. If you find something abusive or that does not comply with our terms or guidelines please flag it as inappropriate.


Quick links

Nature Briefing

Sign up for the Nature Briefing newsletter — what matters in science, free to your inbox daily.

Get the most important science stories of the day, free in your inbox. Sign up for Nature Briefing