Abstract
The ecological environment in Loess Plateau of Northern Shaanxi is fragile, so the soil pollution caused by the exploitation of coal resources cannot be ignored. With Shigetai Coal Mine in Loess Plateau of Northern Shaanxi as the object of study for field survey and sampling, the content of heavy metals in soil is analyzed, the environmental pollution in the research area is evaluated by the single factor pollution index method, comprehensive pollution index method and potential ecological risk index method, and the spatial distribution characteristics of heavy metals are discussed by the geostatistics method. According to the study results, the average contents of heavy metals Hg, Cd, Pb and Cr are 2.03, 1.36, 1.11 and 1.23 times of the soil background values in Shaanxi Province respectively and the average contents of other heavy metals are lower than the soil background values in Shaanxi Province; Hg and Cd show moderate variation while As, Pb, Cr, Zn, Ni and Cu show strong variation; the skewness coefficients and kurtosis coefficient of Cd, As and Cu in the soil within the research area are relatively high, and these elements are accumulated in large amounts. Single factor pollution index (Pi) and potential ecological risk index (E) indicate that heavy metal Hg is the main pollution factor and mainly distributed in the east and north of the research area. The comprehensive index of potential ecological risk (RI) of the research area is 1336.49, showing an extremely high ecological risk, and the distribution characteristics of potential ecological risk are consistent with that of potential ecological risk index (E) of Hg. The results of ecological risk warning show that Hg is in a slight warning status, while Cd, Pb and Cr are in a warning status. The areas with high ecological risk warning values are mainly distributed in the east and north, and the whole research area shows relatively obvious zonal distribution law. The soil is disturbed greatly during the coal mining, so the ecological governance of the mine area shall adapt to the local natural conditions and regional environmental characteristics and follow the principle of “adjusting governance measures based on specific local conditions and classifications”. An environmentally sustainable governance manner shall be adopted to realize the protection of the ecological environment and high-quality development of coal resources.
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Introduction
In recent years, the cultivated land area has been reduced and the natural environment has been seriously polluted due to the industrial revolution, rapid population growth, rural–urban migration and unplanned and uncontrolled urbanization1. With the high toxicity, long-term retention, persistent bioavailability and recalcitrance, pollutants such as heavy metals and metalloids (mercury, lead, zinc, copper, cadmium, chromium, nickel, arsenic) are considered to be the main harmful trace elements2,3,4. The sources of heavy metals in soil mainly include natural factors and human factors. The natural factor mainly refers to the rock weathering in the process of soil formation, and many studies showed that the concentration of the heavy metals formed by the natural factor is usually harmless to the ecological environment5. Human activities, such as exploitation of mineral resources, metal processing and smelting, chemical production, factory discharge and sewage irrigation, have been proved to be the main sources of heavy metal pollution6,7,8. According to statistics, the land area polluted by heavy metals in China is more than 10 million hectares, seriously threatening the agricultural development and quality and safety of ecological environment in China9,10. In addition, excessive heavy metals may enter the human body through the food chain, causing a variety of human diseases11. For example, excessive lead in the human body will damage their nervous and immune systems, and long-term exposure to cadmium will lead to potential risks of lung cancer and fracture, long-term intake of high concentrations of copper and zinc will damage human pancreas, liver and kidney and lower the HDL cholesterol level12, long-term consumption of crops and vegetables grown on the soil polluted by the arsenic will increase the risks of skin cancer, bladder cancer and lung cancer13,14. Therefore, in order to protect the ecosystem and human health, it is essential to evaluate the distribution, sources and potential environmental risks of heavy metals in soil.
Mining is one of the most polluted activities in the world. It is well-known that mining activities will lead to the loss of surrounding biodiversity15,16. In particular, mining activities will cause a wide range of landform disturbances, such as the destruction of geological continuity on the surface, soil pollution, hydrological impact on runoff capacity, and changes in landscape morphology. Excavation and overburden deposition aggravate the change of surface topography and cause the degeneration of the aquifers17. After the founding of new China, in order to vigorously develop the economy, China adopted an extensive economic development model, that is, treatment after pollution, which led to serious environmental problems. The open-pit coal mining is one of these models. No effective preventive and protective measures have been taken in the process of coal mining, resulting in serious environmental problems around the mine area. Heavy metal is one of the main pollutants in the coal mine area. According to statistics, about 3.2 million hectares of land in China were affected by mining activities prior to 1996, including cultivated land, woodland and pasture18. Many previous studies have shown that heavy metals are released into farmland soil, surface water and plant leaves around the mine area during coal mining and processing, endangering human health through the food chain19,20. In the process of coal mining, such as ore concentration, mineral extraction, topsoil stripping, tailings accumulation, wastewater treatment and transportation, a large amount of heavy metal dust and dusty wastewater are generated around the mine area21. After being mixed with soil, these refractory heavy metals migrate to the water environment through surface runoff, which amplifies their toxicity in the ecological environment22. In addition, long-term overexploitation causes land subsidence, soil erosion and deterioration of groundwater quality, seriously disturbing the local natural environment23. It is well-known that coal gangue and fly ash contain a variety of toxic heavy metal elements, which are released into the environment through coal transportation, smoke and dust discharging from coal-fired power plants, sewage discharging from mine areas and other coal-related industry activities. In addition, the long-term accumulation of coal gangue and fly ash is another way to release toxic elements into the soil24. Masto et al.25 and other26 researchers showed that the coal dust contains heavy metals such as iron, zinc, manganese, copper, lead, chromium, nickel, strontium, zirconium and arsenic, which are seeped into soil and even groundwater through surface runoff. According to statistics, the average concentrations of arsenic in bituminous coal and lignite in the world are 9.0 and 7.4 mg/kg, respectively27. Chen et al.28 found that the contents of arsenic, selenium, mercury and antimony discharged into the atmosphere from coal-fired power plants are 236, 637, 172 and 33 tons, respectively.
With rich coal, natural gas and oil resources, Northern Shaanxi is an important energy and chemical base in Shaanxi Province. Its ecosystem is very fragile and sensitive to environmental impact29. The geological tectonic unit of the mine area belongs to Ordos platform slope of North China platform and the north-central part of northern Shaanxi platform depression. No magmatic rock formation, magmatism and volcanic eruption occur and earthquakes are rare in this area. It borders the sandy grassland on the southern margin of Maowusu Desert in its north, and borders the hinterland of Loess Plateau in its south, with crisscrossed gullies and crisscross hills and ridges. At present, the study on heavy metals in mining industry mainly focuses on the evaluation, nature, mechanism, ecological improvement and biological effects of heavy metal pollution30. There are only sporadic research reports on Shenmu Mine Area, a super-large energy base located in water-wind erosion area and few reports on the spatial distribution and potential pollution evaluation of heavy metals in soil in this area. Geostatistics is used to predict the extent of soil and groundwater pollution as well as to calculate the risk in active or abandoned mining, waste disposal and urban sites, by accounting for the spatial distribution and uncertainty of the estimates. It facilitates quantification of the spatial characteristics of soil parameters and enables spatial interpolation31,32,33.
Therefore, with Shigetai Coal Mine in Shenmu as the research area, the pollution level of toxic substances is evaluated and their spatial distribution characteristics are discussed by using the single factor pollution index method, Nemerow pollution index method and potential ecological evaluation method based on GIS technology and geostatistical theory, in order to provide scientific support and basis for environmental management and standardization.
Materials and methods
Overview of the research area
The research area is located in Shigetai Coal Mine in the north of Loess Plateau of Northern Shaanxi on the southern margin of Maowusu Desert (Fig. 1). The coal field is bordered by Ulanmulun River in the west, Halagou coal field in the south, Battuta coal field in the north, Qigaigou and Shaanxi-Inner Mongolia border in the east. The geographical coordinates of the area are: 110° 09′ 41″ E–110° 18′ 35″ E and 39° 17′ 02″ N–39° 35′ 16″ N. The research area is dominated by a semi-arid continental climate in the mid-temperate zone, with cold winter and hot summer. The temperature difference between day and night is large, with the maximum value of about 20℃. The maximum frozen soil depth is 146 cm and the maximum snow depth is 12 cm from November to March of the following year. The monsoon period lasts from the beginning of January to the beginning of May and the prevailing wind direction is northwest wind. The annual average wind speed is 2.5 m/s and the maximum wind speed is 25 m/s. The annual average temperature is 8.5℃, the extreme maximum temperature is 38.9 ℃, the extreme minimum temperature is 28.5℃, and the annual average precipitation is 434.10 mm, which mainly occurs from July to September. The average annual evaporation is 1907.2–2122.7 mm, which is about 4–5 times of the precipitation.
Shigetai Coal Mine, one of the main production mines of Shendong Coal Group, was officially put into operation on January 15, 2006, with a geological reserve of 893 million tons and a recoverable reserve of 657 million tons. Characterized by low ash content, low sulfur content, low phosphorus content, medium to high calorific value in quality, the coal mined belongs to long flame coal with high volatile component and non-caking coal, which is the high-quality steam coal, chemical and metallurgical coal.
Sample collection
The sampling time is June 2020 and the soil sampling depth is 0–30 cm. One sample of about 0.5 kg is collected at the sampling point first, and then the 0.5 kg soil sample is collected at the other two sampling points within 2 m near this point respectively. Mix three soil samples evenly, take 500 g with quartering method to form one sample, and put it into a cloth bag. Put the collected samples into a cloth bag first to drain the most of the water before putting them into a polyethylene bag. Dry the sample in the air, and take some samples dried to be screened by 0.149 mm sieve, and then test Hg, Cd, As, Pb, Cr, Zn, Ni and Cu. See Fig. 1 for the location of the research area and the distribution of sampling points.
Test method
See Table 1 for test indexes of heavy metals. The parallel test is carried out on each sample for three times. During the test, the quality shall be controlled against the national standard soil reference substance (GSS-12) and duplicate samples. The test results show that the recovery rates of all elements are within the allowable range.
Evaluation methods
Nemerow pollution index method
With the soil background value in Shaanxi Province as a reference, the soil pollution status is evaluated by using the single factor pollution index method (\(P_{i}\)) and Nemerow pollution index method (NPI). The calculation equation is:
where, \(C_{i}\) is the measured content of heavy metal i (mg/kg); \(C_{n}^{i}\) is the background value of heavy metal i (mg/kg); \(P_{i}\) is the single factor pollution index of heavy metal i; \(NPI\) is Nemerow pollution index, \(P_{iave}\) is the average value of each single factor pollution index of heavy metals, and \(P_{i\max }\) is the maximum value of single factor pollution index of heavy metals. See Table 2 for pollution index classification standard.
Potential ecological risk index method
Potential ecological risk index method can reflect the pollution level of a single heavy metal element and the comprehensive effect of all heavy metal elements from the perspective of the biological toxicity of heavy metals. The calculation equation is:
where: \(RI_{j}\) is the comprehensive potential ecological risk index of multiple heavy metals from the sampling point j, \(E_{j}^{i}\) is the single potential ecological risk index of heavy metal i from the sampling point j, \(C_{j}^{i}\) is the pollution index of heavy metal i from the sampling point j, \(c_{j}^{i}\) is the measured concentration of heavy metal i from the sampling point j, \(c_{r}^{i}\) is the reference value of heavy metal i (the background value of soil environment in Shaanxi is taken as the reference value in this study), and \(T_{i}\) is the toxicity coefficient of heavy metal i34,35. See Table 3 for \(c_{r}^{i}\) and \(T_{i}\).
Ecological risk warning index method
In this research, the warning for the ecological risks of heavy metal pollution in open-pit coal mining areas is evaluated based on the ecological risk warning index (\(I_{ER}\)) proposed by Rapant and Kordik36. The calculation equation is:
where: \(I_{ER}\) is the ecological risk warning index, \(I_{{ER{\text{j}}}}\) is the ecological risk index of the ith heavy metal, and \(Pi\) is the pollution index of the heavy metal i. See Table 4 for classification of pollution risk levels of \(RI\) and \(I_{ER}\).
Geostatistics method
Geostatistics is an effective method to study the spatial distribution structure characteristics of regional variables. Its basic tool is a semivariate function that can be estimated by the following formula37:
where, γ(h) is the variation function, Z(x) is the value of the regionalised variable at the sampling point x, N(h) is the number of pairs with interval h and h is the interval, which is called the lag distance. Variograms can reflect and describe many properties of regionalised variables, and it is an important tool to analyze their spatial variation.
Data analysis
The data is summarized and processed by SPSS10.0 software, and the spatial distribution of single factor pollution index (Pi), Nemerow pollution index (NPI), potential ecological risk index (E), RI and ecological risk warning index (IER) is determined by ArcGIS 10.8 Kriging interpolation method.
Results and discussion
Analysis of contents of heavy metals in wasteland soil
The test results show (Table 5) that the contents of Hg, Cd, As, Pb, Cr, Zn, Ni and Cu in the surface soil within Shigetai Coal Mine vary from 0.043 to 0.255, 0.44 to 2.23, 2.66 to 18.40, 11.80 to 42.80, 40.50 to 118.60, 18.90 to 70.10, 4.31 to 28.10, 4.96 to 46.25 mg/kg, respectively; the average contents of Hg, Cd, As, Pb, Cr, Zn, Ni and Cu are 0.128, 1.03, 4.73, 23.08, 76.22, 46.94, 16.11 and 12.10 mg/kg, respectively. The average contents of Hg, Cd, Pb and Cr in soil within the research area are 2.03, 1.36, 1.11 and 1.23 times of the soil background values in Shaanxi Province, respectively. The average contents of As, Zn and Cu are lower than the soil background value in Shaanxi Province, but the maximum contents of these three elements are 1.65, 1.01 and 2.16 times of the soil background values in Shaanxi Province, respectively. It is reported that the average concentration of lead in agricultural soil affected by coal mines is relatively high (433 mg kg−1)38. Lead is usually related to minerals in coal and occurs mainly in the form of sulfide such as PbS and PbSe39. In addition, aluminosilicate and carbonate also contain lead40. Chromium is a non-volatile element, which is related to aluminosilicate minerals41. In the mining process, chromium may be accumulated in coal, gangue or other tailings, and then enter the soil or water body through rain leaching42.
The coefficient of variation (CV) of Hg and Cd contents in soil within the research area is 0.050 and 0.37, respectively, with moderate variation, indicating that the content of these two heavy metals is less affected by the external factors; the coefficient of variation (CV) of As, Pb, Cr, Zn, Ni and Cu contents is 2.81, 7.46, 18.00, 13.51, 5.44 and 5.64, respectively, with strong variation (CV > 0.50)43, indicating that the content of these eight heavy metals may be affected by some local pollution sources. The skewness coefficient (SK) ranges from − 3 to 3, and the larger its absolute value, the greater its skewness. When SK > 0, it is positive skewness; when SK < 0, it is negative skewness. Kurtosis coefficient is the characteristic value representing the peak value of probability density distribution curve at the average value44. The skewness coefficient and kurtosis coefficient of Cd, As and Cu elements in the soil within the research area are relatively high, indicating that these three elements are accumulated in the soil within the research area in large amounts.
Characteristics of heavy metal pollution in the research area
It can be seen from Table 6 that the average single factor pollution index (Pi) of heavy metals in the surface soil within the research area is Hg(2.03), Cr(1.22), Cd(1.14), Pb(1.11), Zn(0.68), As(0.59), Cu(0.57) and Ni(0.56) in descending order.
The average value of each element in the research area is at the mild pollution level or above, Hg is at a moderate pollution level, Cd, Pb and Cr are at the mild pollution level, and other heavy metals are at the clean level. Among them, the sampling points with the single pollution index of element Hg at moderate pollution level account for 21.52% of the total number of sampling points, and the sampling points with the single pollution index of Cd, Pb and Cr elements at the mild pollution level account for 43.04%, 55.70% and 77.22% of the total number of sampling points, respectively. NPI of eight heavy metal elements in the surface soil within the research area is between 0.80 and 3.20, with an average value of 1.64, so it is at the mild pollution level. The results show that the heavy metal elements in the surface soil within the research area are affected by human activities, and Hg is the most important pollution factor. This is consistent with the research result obtained by Li et al.45.
Spatial distribution pattern of heavy metal pollution in soil
The spatial distribution pattern of Pi and NPI values of eight heavy metals in the surface soil of Shigetai Coal Mine is drawn by ARCGIS 10.8 software based on GIS technology and geostatistical analysis (Fig. 2).
As can be seen from Fig. 2, the heavy metal Hg in the surface soil within the research area ranks top in the pollution degree and area. The heavy metal Hg is at the moderate pollution level in the east, south and north of the research area, while it is at the mild pollution level in the west and middle of the research area. The heavy metal Cr in the research area ranks second in the pollution area. The element Cr is at the clean level in the middle of the research area, but at the mild pollution level in other areas, with small clean area. The heavy metal Pb in the research area ranks third in the pollution area. The element Pb is at the clean level in the south and middle (with small clean area) of the research area, but at the mild pollution level in other areas, with large area of mild pollution. The heavy metal Cd in the research area ranks fourth in the pollution area. The element Cd is at the clean level in the northwest (with small clean area) and south of the research area, but at the mild pollution level in other areas. Other heavy metal elements in the research area are at the clean level. Relevant researches show that the heavy metal pollution in soil of the coal mine is mainly caused by various mining activities46. Compared with natural soils, the elevated concentrations of heavy metals in the mining-affected soils were also reported elsewhere, e.g., Bangladesh38and India47.
According to the study results of Sun and Li et al.48, in the process of coal mining, a large amount of coal gangue and fly ash is produced. During the process of rain leaching, many heavy metals, such as Pb, Hg, Crand Cd are released from coal gangue and fly ash. This is the most important sources of Pb, Hg, Cd, and Cr. In addition, traffic activities such as the wear of motor vehicle brake blocks and other parts, exhaust emissions, etc. are also one of the sources of heavy metal (Hg) pollution in soil49. Combined with the actual situation of the research area, the research area is adjacent to the Shaanxi-Inner Mongolia border in the east, so the exhaust emissions of motor vehicles may also be another cause of Hg pollution in the research area. Based on the spatial distribution pattern of NPI of heavy metal in the research area, its distribution status is basically consistent with the spatial distribution of Pi of heavy metal Hg.
Evaluation of potential ecological risks of heavy metal pollution in soil
By taking the soil background value of Shaanxi Province as the reference value, the single potential ecological risk index (E) and RI of heavy metals at each sampling point in Shigetai Coal Mine are calculated, and the ecological risk is evaluated according to the classification standard of potential ecological risks. It can be seen from Table 7 that the average value of E of the heavy metal in the surface soil within the research area is Hg(81.01), Cd(34.13), As(5.90), Pb(5.56), Cu(2.83), Ni(2.80), Cr(2.44) and Zn(0.68) in descending order. Except the heavy metal Hg, the average value of potential ecological risk index of other heavy metals in the surface soil within the research area is less than 40, so it is at a mild pollution level. The potential ecological risk of the element Hg ranges from 27.30 to 161.90, with an average value of 81.01, so it is in a relatively high ecological risk. It can be seen that Hg is the most important ecological risk factor in the research area. RI in the research area ranges from 53.44 to 6400.00 and the average value of comprehensive potential ecological risk index is 1336.49, so it is in an extremely high ecological risk.
Spatial distribution pattern of potential ecological risks of heavy metal pollution in soil
The spatial distribution pattern of E and RI of heavy metals in the surface soil of Shigetai Coal Mine is as shown in Fig. 3. It can be seen from Fig. 3 that the spatial distribution of E value of the element Hg is basically consistent with the spatial distribution of Pi, the distribution area of Hg is relatively large, and the potential ecological risk index is in the moderate risk, indicating that Hg is the main ecological risk factor in this mine area. The spatial distribution of E values of other heavy metals Cd, As, Pb, Cr, Zn, Ni and Cu is quite different. Among them, Ni, Zn and Pb are mainly distributed in the east and midwest of the mine area, Cr and As are mainly distributed in the east and southeast of the mine area, the heavy metal Cu is only distributed in the south of the mine area, and the heavy metal Cd is mainly distributed in the northwest and in the east (small area) of the mine area.
As can be seen from Fig. 4, the ecological risk index is high in the east and north of the research area from the spatial distribution pattern of RI in the research area, showing extremely strong risks, while it is in the slight risk in the middle and west, and moderate risk in other areas. On the whole, the spatial distribution pattern of RI values of heavy metals in the research area shows an obvious horizontal zonal distribution pattern, which is basically consistent with the distribution pattern of NPI.
Ecological risk warning of heavy metal pollution in soil
Based on the ecological risk evaluation, the ecological risk warning evaluation emphasizes the research on possible risk warning in ecosystem. The warnings for the ecological hazards caused by surface soil heavy metal pollution in the Shigetai Coal Mine in northern Shaanxi are evaluated based on the classification standard of ecological risks proposed by Rapant and Kordik36. It can be seen from Table 8 that the average values of IER of eight elements including Hg, Cd, As, Pb, Cr, Zn, Ni and Cu are 1.03, 0.14, -0.41, 0.11, 0.22, -0.32, -0.44 and -0.43, respectively. Among them, Hg is in the slight warning status, Cd, Pb and Cr are in the warning status, and As, Zn, Ni and Cu are in no warning status. IER values in the research area range from -34.80 to 81.00 and the average value is -1.13, so it is in no warning status.
Based on the spatial distribution of IER values (Fig. 5), the northern and eastern areas in the research area show serious warning, the transition area between the east and the north shows moderate warning to slight warning, the western and central areas show no warning, and other areas show warning to slight warning. The areas with high ecological risk warning values are mainly distributed in the east and north, with relatively serious pollution, showing relatively obvious zonal distribution law.
Conclusion
-
(1)
The contents of Hg, Cd, As, Pb, Cr, Zn, Ni and Cu in the soil within the research area vary from 0.043 to 0.255, 0.44 to 2.23, 2.66 to 18.40, 11.80 to 42.80, 40.50 to 118.60, 18.90 to 70.10, 4.31 to 28.10, 4.96 to 46.25 mg/kg, respectively. Among them, the average contents of heavy metals Hg, Cd, Pb and Cr are 2.03, 1.36, 1.11 and 1.23 times of the soil background values in Shaanxi Province respectively and the average contents of other heavy metals are lower than the soil background values in Shaanxi Province; based on the coefficient of variation, Hg and Cd show moderate variation while As, Pb, Cr, Zn, Ni and Cu show strong variation; the skewness coefficient and kurtosis coefficient of Cd, As and Cu in the soil within the research area are relatively high, and these elements are accumulated in large amounts.
-
(2)
The analysis of single factor pollution of heavy metals in the soil within the research area shows that the heavy metal Hg pollutes the soil seriously, so it is at the moderate pollution level, and it is mainly distributed in the east and north of the research area as well as a small area in the south, while three elements including Cd, Pb and Cr are at the mild pollution level. The analysis of Nemerow pollution index method shows that Nemerow pollution index in the research area reaches level III due to mining activities, and Hg is the most important pollution factor.
-
(3)
The average value of potential ecological risk index of heavy metals in soil within the research area is Hg(81.01), Cd(34.13), As(5.90), Pb(5.56), Cu(2.83), Ni(2.80), Cr(2.44) and Zn(0.68), respectively. The potential ecological risk of the heavy metal Hg ranges from 27.30 to 161.90, with an average value of 81.01, so it is in a relatively high ecological risk. Other heavy metals are in the low risk;.
-
(4)
From the perspective of spatial distribution, the eastern and northern ares in the research area are in the high risk, the central and western areas are in the low risk, and the other areas are in the medium risk; the areas with high ecological risk warning values are mainly distributed in the east and north, with relatively serious pollution, and the whole research area shows relatively obvious zonal distribution law. Due to the long-term human activities, the spatial heterogeneity of heavy metal pollution is obviously enhanced, and the potential risks may be increased beyond our expectations. Therefore, the ecological risks and human health risks of heavy metal pollution in this area shall be comprehensively evaluated in the future study, so as to provide a basis for the prevention and control strategies of heavy metal pollution in coal mine areas.
Data availability
The datasets analysed during the current study available from the corresponding author on reasonable request.
References
Ozturk, A. & Arici, O. K. Carcinogenic-potential ecological risk assessment of soils and wheat in the eastern region of Konya (Turkey). Environ. Sci. Pollut. R. 28(12), 15471–15484 (2021).
Dai, L. et al. Multivariate geostatistical analysis and source identification of heavy metals in the sediment of Poyang Lake in China. Sci. Total Environ. 621, 1433–1444 (2018).
Mazurek, R. et al. Assessment of heavy metals contamination in surface layers of Roztocze National Park forest soils (SE Poland) by indices of pollution. Chemosphere 168, 839–850 (2017).
Wang, Z. et al. Elucidating the differentiation of soil heavy metals under different land uses with geographically weighted regression and self-organizing map. Environ. Pollut. 260, 114065 (2020).
Javed, M. T., Saleem, M. H., & Aslam, S. et al. Elucidating silicon-mediated distinct morpho-physio-biochemical attributes and organic acid exudation patterns of cadmium stressed Ajwain (Trachyspermum ammi L.). Plant Physiol Bioch. 157, 23–37 (2020).
Sun, J. et al. Tracing of heavy metal sources and mobility in a soil depth profile via isotopic variation of Pb and Sr. CATENA 171, 440–449 (2018).
Wen, H. et al. Tracing sources of pollution in soils from the Jinding Pb–Zn mining district in China using cadmium and lead isotopes. Appl. Geochem. 52, 147–154 (2015).
Chakraborty, B. et al. Assessment of non-carcinogenic health risk of heavy metal pollution: Evidences from coal mining region of eastern India. Environ. Sci. Pollut. R. 28(34), 47275–47293 (2021).
Abdelhafez, A. A. & Li, J. Environmental monitoring of heavy metal status and human health risk assessment in the agricultural soils of the Jinxi River area, China. Hum. Ecol. Risk Assess. Int. J. 21(4), 952–971 (2015).
Zhou, M. et al. Pollution assessment and potential sources of heavy metals in agricultural soils around four Pb/Zn mines of Shaoguan city, China. Soil Sedim. Contam. Int. J. 24(1), 76–89 (2015).
Wei, L. et al. Transformation and speciation of typical heavy metals in soil aquifer treatment system during long time recharging with secondary effluent: Depth distribution and combination. Chemosphere 165, 100–109 (2016).
Shi, G. L. et al. Arsenic, copper, and zinc contamination in soil and wheat during coal mining, with assessment of health risks for the inhabitants of Huaibei China. Environ. Sci. Pollut. R. 20(12), 8435–8445 (2013).
Zhao, F. J. et al. Accumulation, distribution, and speciation of arsenic in wheat grain. Environ. Sci. Technol. 44(14), 5464–5468 (2010).
Melo, É. E. et al. Availability and accumulation of arsenic in oilseeds grown in contaminated soils. Water Air Soil Poll. 223(1), 233–240 (2012).
Horasan, B. Y., Ozturk, A. & Tugay, O. Nb–Sr–Pb isotope analysis in soils of abandoned mercury quarry in northwest Black Sea (Turkey), soil and plant geochemistry, evaluation of ecological risk and its ımpact on human health. Environ. Earth Sci. 80(15), 1–19 (2021).
Mammola, S. et al. Scientists’ warning on the conservation of subterranean ecosystems. Bioscience 69(8), 641–650 (2019).
Vatalis, K. I. & Kaliampakos, D. C. An overall index of environmental quality in coal mining areas and energy facilities. Environ. Manage. 38(6), 1031–1045 (2006).
Li, M. S. Ecological restoration of mineland with particular reference to the metalliferous mine wasteland in China: A review of research and practice. Sci. Total Environ. 357(1–3), 38–53 (2006).
Chen, Y. et al. Heavy metal pollution characteristics in the Kaili Coal mining region, Guizhou Province, China. J. Residuals Sci. Technol. 12, S123–S131 (2015).
Tozsin, G. Hazardous elements in soil and coal from the Oltu coal mine district Turkey. Int. J. Coal Geol. 131, 1–6 (2014).
Qiao, M. et al. Characterization of soil heavy metal contamination and potential health risk in metropolitan region of northern China. Environ. Monit. Assess. 172(1), 353–365 (2011).
Islam, A. R. M. T. et al. Quantifying source apportionment, co-occurrence, and ecotoxicological risk of metals from upstream, lower midstream, and downstream river segments Bangladesh. Environ. Toxicol. Chem. 39(10), 2041–2054 (2020).
Chen, Y., Yuan, L. & Xu, C. Accumulation behavior of toxic elements in the soil and plant from Xinzhuangzi reclaimed mining areas China. Environ. Earth Sci. 76(5), 1–8 (2017).
Candeias, C. et al. Assessment of soil contamination by potentially toxic elements in the Aljustrel mining area in order to implement soil reclamation strategies. Land Degrad. Dev. 22(6), 565–585 (2011).
Masto, R. E. et al. Assessment of environmental soil quality around Sonepur Bazari mine of Raniganj coalfield India. Solid Earth. 6(3), 811–821 (2015).
De, S. & Mitra, A. K. Mobilization of heavy metals from mine spoils in a part of Raniganj coalfield, India: Causes and effects. Environ. Geosci. 11(2), 65–76 (2004).
Yudovich, Y. E. & Ketris, M. P. Arsenic in coal: A review. Int. J. Coal Geol. 61(3–4), 141–196 (2005).
Chen, J. et al. Atmospheric emissions of F, As, Se, Hg, and Sb from coal-fired power and heat generation in China. Chemosphere 90(6), 1925–1932 (2013).
Wu, C., Deng, H., & Shu, S. The study on the land development process in the border area between Shaanxi and Inner Mongolia. Geogr. Res. 33(8), 1579–1592 (2014) in Chinese.
Solgun, E., Horasan, B. Y. & Ozturk, A. Heavy metal accumulation and potential ecological risk assessment in sediments from the southwestern Konya district (Turkey). Arab. J. Geosci. 14(8), 1–15 (2021).
Modis, K. & Komnitsas, K. Optimum sampling density for the prediction of acid mine drainage in an underground sulphide mine. Mine Water Environ. 26(4), 237–242 (2007).
Modis, K. et al. Uncertainty management of a hydrogeological data set in a greek lignite basin, using BME. Stoch. Environ. Res. Risk A. 24(1), 47–56 (2010).
Modis, K. & Vatalis, K. I. Assessing the risk of soil pollution around an industrialized mining region using a geostatistical approach. Soil Sedim. Contam. Int. J. 23(1), 63–75 (2014).
Suresh, G. et al. Assessment of spatial distribution and potential ecological risk of the heavy metals in relation to granulometric contents of Veeranam lake sediments India. Ecotox Environ. Safe. 84, 117–124 (2012).
Shen, F. et al. Spatial distribution and risk assessment of heavy metals in soil near a Pb/Zn smelter in Feng County China. Ecotox. Environ. Safe. 139, 254–262 (2017).
Rapant, S. & Kordík, J. An environmental risk assessment map of the Slovak Republic: Application of data from geochemical atlases. Environ. Geol. 44(4), 400–407 (2003).
Zhan, J., He, Y., & Zhao, G.et al. Quantitative evaluation of the spatial variation of surface soil properties in a typical alluvial plain of the lower yellow river using classical statistics, geostatistics and single fractal and multifractal methods. Appl. Sci. 10(17), 5796 (2020).
Bhuiyan, M. A. et al. Heavy metal pollution of coal mine-affected agricultural soils in the northern part of Bangladesh. J Hazard Mater. 173(1–3), 384–392 (2010).
Hower, J. C. & Robertson, J. D. Clausthalite in coal. Int. J. Coal Geol. 53(4), 219–225 (2003).
Wang, J., Sharma, A. & Tomita, A. Determination of the modes of occurrence of trace elements in coal by leaching coal and coal ashes. Energ Fuel. 17(1), 29–37 (2003).
Zhou, C. et al. The environmental characteristics of usage of coal gangue in bricking-making: A case study at Huainan China. Chemosphere 95, 274–280 (2014).
You, M., Huang, Y., Lu, J. & Li, C. Characterization of heavy metals in soil near coal mines and a power plant in Huainan China. Anal. Lett. 48(4), 726–737 (2015).
Eziz, M. et al. Assessment of heavy metal pollution and its potential ecological risks of farmland soils of oasis in Bosten Lake Basin. Acta Geogr. Sin. 72(9), 1680–1694 (2017).
Dong, Z., Wang, L. & Tian, F. The pollution status and spatial distribution of Cu and Pb in soil in Zhenjiang Region. Arid Environ. Monit. 28(4), 149–153 (2014).
Li, F., Li, X., Hou, L. & Shao, A. Impact of the coal mining on the spatial distribution of potentially toxic metals in farmland tillage soil. Sci. Rep. 8(1), 1–10 (2018).
Liu, X. et al. Heavy metal pollution of soils from coal mines in China. Nat. Hazards. 99(2), 1163–1177 (2019).
Mishra, V. K. et al. Heavy metal pollution induced due to coal mining effluent on surrounding aquatic ecosystem and its management through naturally occurring aquatic macrophytes. Bioresour. Technol. 99(5), 930–936 (2008).
Sun, X. B. & Li, Y. C. The spatial distribution of soil heavy metals and variation characteristics of Datong abandoned coal mine area in Huainan City. Sci. Geogr. Sin. 13(10), 1238–1244 (2013).
Apeagyei, E., Bank, M. S., & Spengler, J., D. Distribution of heavy metals in road dust along an urban-rural gradient in Massachusetts. Atmos Environ. 45(13), 2310–2323 (2011).
Acknowledgements
This research was supported by Natural Science Basic Research Plan in Shaanxi Province of China (2021JQ-958) and the Scientific Research Item of Shaanxi Provincial Land Engineering Construction Group (DJNY2022-20).
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N.W. designed the study and wrote the paper. Y. L performed the experiments and collected the data. Z. L. contributed the statistical analyses. Y.S. reviewed and edited the manuscript. All authors read and approved the final manuscript.
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Wang, N., Luo, Y., Liu, Z. et al. Spatial distribution characteristics and evaluation of soil pollution in coal mine areas in Loess Plateau of northern Shaanxi. Sci Rep 12, 16440 (2022). https://doi.org/10.1038/s41598-022-20865-6
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DOI: https://doi.org/10.1038/s41598-022-20865-6
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