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On-device lead sequestration for perovskite solar cells


Perovskite solar cells, as an emerging high-efficiency and low-cost photovoltaic technology1,2,3,4,5,6, face obstacles on their way towards commercialization. Substantial improvements have been made to device stability7,8,9,10, but potential issues with lead toxicity and leaching from devices remain relatively unexplored11,12,13,14,15,16. The potential for lead leakage could be perceived as an environmental and public health risk when using perovskite solar cells in building-integrated photovoltaics17,18,19,20,21,22,23. Here we present a chemical approach for on-device sequestration of more than 96 per cent of lead leakage caused by severe device damage. A coating of lead-absorbing material is applied to the front and back sides of the device stack. On the glass side of the front transparent conducting electrode, we use a transparent lead-absorbing molecular film containing phosphonic acid groups that bind strongly to lead. On the back (metal) electrode side, we place a polymer film blended with lead-chelating agents between the metal electrode and a standard photovoltaic packing film. The lead-absorbing films on both sides swell to absorb the lead, rather than dissolve, when subjected to water soaking, thus retaining structural integrity for easy collection of lead after damage.

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Fig. 1: Device schematic and Pb-absorbing material properties.
Fig. 2: On-device Pb-sequestration capability.
Fig. 3: Device performance.

Data availability

The data that support the findings of this study are available from the corresponding authors upon reasonable request.


  1. Best Research-Cell Efficiency Chart (National Renewable Energy Laboratory, 2019);

  2. Rong, Y. et al. Challenges for commercializing perovskite solar cells. Science 361, eaat8235 (2018).

    Article  Google Scholar 

  3. Park, N.-G., Grätzel, M., Miyasaka, T., Zhu, K. & Emery, K. Towards stable and commercially available perovskite solar cells. Nat. Energy 1, 16152 (2016).

    CAS  ADS  Article  Google Scholar 

  4. Jena, A. K., Kulkarni, A. & Miyasaka, T. Halide perovskite photovoltaics: background, status, and future prospects. Chem. Rev. 119, 3036–3103 (2019).

    CAS  Article  Google Scholar 

  5. Green, M. A., Ho-Baillie, A. & Snaith, H. J. The emergence of perovskite solar cells. Nat. Photon. 8, 506–514 (2014).

    CAS  ADS  Article  Google Scholar 

  6. Burschka, J. et al. Sequential deposition as a route to high-performance perovskite-sensitized solar cells. Nature 499, 316–319 (2013).

    CAS  ADS  Article  Google Scholar 

  7. Christians, J. A., Habisreutinger, S. N., Berry, J. J. & Luther, J. M. Stability in perovskite photovoltaics: a paradigm for newfangled technologies. ACS Energy Lett. 3, 2136–2143 (2018).

    CAS  Article  Google Scholar 

  8. Saparov, B. & Mitzi, D. B. Organic–inorganic perovskites: structural versatility for functional materials design. Chem. Rev. 116, 4558–4596 (2016).

    CAS  Article  Google Scholar 

  9. Correa-Baena, J.-P. et al. Promises and challenges of perovskite solar cells. Science 358, 739–744 (2017).

    CAS  ADS  Article  Google Scholar 

  10. Wang, R. et al. A review of perovskites solar cell stability. Adv. Funct. Mater. 29, 1808843 (2019).

    CAS  Article  Google Scholar 

  11. Bae, S.-Y. et al. Hazard potential of perovskite solar cell technology for potential implementation of “safe-by-design” approach. Sci. Rep. 9, 4242 (2019).

    ADS  Article  Google Scholar 

  12. Lyu, M., Yun, J.-H., Chen, P., Hao, M. & Wang, L. Addressing toxicity of lead: progress and applications of low-toxic metal halide perovskites and their derivatives. Adv. Energy Mater. 7, 1602512 (2017).

    Article  Google Scholar 

  13. Hailegnaw, B., Kirmayer, S., Edri, E., Hodes, G. & Cahen, D. Rain on methylammonium lead iodide based perovskites: possible environmental effects of perovskite solar cells. J. Phys. Chem. Lett. 6, 1543–1547 (2015).

    CAS  Article  Google Scholar 

  14. Fabini, D. Quantifying the potential for lead pollution from halide perovskite photovoltaics. J. Phys. Chem. Lett. 6, 3546–3548 (2015).

    CAS  Article  Google Scholar 

  15. Babayigit, A., Ethirajan, A., Muller, M. & Conings, B. Toxicity of organometal halide perovskite solar cells. Nat. Mater. 15, 247–251 (2016).

    CAS  ADS  Article  Google Scholar 

  16. Babayigit, A., Boyen, H.-G. & Conings, B. Environment versus sustainable energy: the case of lead halide perovskite-based solar cells. MRS Energy Sustain. 5, E1 (2018).

    Article  Google Scholar 

  17. Wei, M. et al. Ultrafast narrowband exciton routing within layered perovskite nanoplatelets enables low-loss luminescent solar concentrators. Nat. Energy 4, 197–205 (2019).

    CAS  ADS  Article  Google Scholar 

  18. Cannavale, A. et al. Perovskite photovoltachromic cells for building integration. Energy Environ. Sci. 8, 1578–1584 (2015).

    CAS  Article  Google Scholar 

  19. Wheeler, L. M. et al. Switchable photovoltaic windows enabled by reversible photothermal complex dissociation from methylammonium lead iodide. Nat. Commun. 8, 1722 (2017).

    ADS  Article  Google Scholar 

  20. Lin, J. et al. Thermochromic halide perovskite solar cells. Nat. Mater. 17, 261–267 (2018).

    CAS  ADS  Article  Google Scholar 

  21. Polman, A., Knight, M., Garnett, E. C., Ehrler, B. & Sinke, W. C. Photovoltaic materials: present efficiencies and future challenges. Science 352, aad4424 (2016).

    Article  Google Scholar 

  22. Ramírez Quiroz, C. O. et al. Pushing efficiency limits for semitransparent perovskite solar cells. J. Mater. Chem. A 3, 24071–24081 (2015).

    Article  Google Scholar 

  23. Meinardi, F., Bruni, F. & Brovelli, S. Luminescent solar concentrators for building-integrated photovoltaics. Nat. Rev. Mater. 2, 17072 (2017).

    CAS  ADS  Article  Google Scholar 

  24. Stoumpos, C. C., Malliakas, C. D. & Kanatzidis, M. G. Semiconducting tin and lead iodide perovskites with organic cations: phase transitions, high mobilities, and near-infrared photoluminescent properties. Inorg. Chem. 52, 9019–9038 (2013).

    CAS  Article  Google Scholar 

  25. van der Voet, E. et al. Environmental Challenges of Anthropogenic Metals Flows and Cycles (United Nations Environment Programme, 2013).

  26. Lead Laws and Regulations (Environmental Protection Agency, 2019).

  27. Jiang, Y. et al. Reduction of lead leakage from damaged lead halide perovskite solar modules using self-healing polymer-based encapsulation. Nat. Energy 4, 585–593 (2019).

    CAS  ADS  Article  Google Scholar 

  28. Conings, B., Babayigit, A. & Boyen, H.-G. Fire safety of lead halide perovskite photovoltaics. ACS Energy Lett. 4, 873–878 (2019).

    CAS  Article  Google Scholar 

  29. Current results weather and science facts: average annual precipitation by state. Current Results (2019).

  30. Bormann, B. T., Tarrant, R. F., McClellan, M. H. & Savage, T. Chemistry of rainwater and cloud water at remote sites in Alaska and Oregon. J. Environ. Qual. 18, 149–152 (1989).

    CAS  Article  Google Scholar 

  31. Zhang, F. et al. Self-seeding growth for perovskite solar cells with enhanced stability. Joule 3, 1452–1463 (2019).

    CAS  Article  Google Scholar 

  32. Lee, C., Yang, W. & Parr, R. G. Development of the Colle-Salvetti correlation-energy formula into a functional of the electron density. Phys. Rev. B 37, 785–789 (1988).

    CAS  ADS  Article  Google Scholar 

  33. Becke, A. D. Density-functional thermochemistry. III. The role of exact exchange. J. Chem. Phys. 98, 5648–5652 (1993).

    CAS  ADS  Article  Google Scholar 

  34. Frisch, M. J. et al. Gaussian09 revision D.01 (Gaussian, 2009).

  35. Grimme, S. Semiempirical GGA-type density functional constructed with a long-range dispersion correction. J. Comput. Chem. 27, 1787–1799 (2006).

    CAS  Article  Google Scholar 

  36. Tomasi, J., Mennucci, B. & Cammi, R. Quantum mechanical continuum solvation models. Chem. Rev. 105, 2999–3094 (2005).

    CAS  Article  Google Scholar 

  37. Sato, H., Yui, M. & Yoshikawa, H. Ionic diffusion coefficients of Cs+, Pb2+, Sm3+, Ni2+, SeO4 2− and TcO4 in free water determined from conductivity measurements. J. Nucl. Sci. Technol. 33, 950–955 (1996).

    CAS  Article  Google Scholar 

  38. Leyden, M. R. et al. Methylammonium lead bromide perovskite light-emitting diodes by chemical vapor deposition. J. Phys. Chem. Lett. 8, 3193–3198 (2017).

    CAS  ADS  Article  Google Scholar 

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T.X. acknowledges the support from the National Science Foundation (DMR 1806152). The work at the National Renewable Energy Laboratory was supported by the US Department of Energy under contract number DE-AC36-08GO28308 with Alliance for Sustainable Energy, Limited Liability Company (LLC), the Manager and Operator of the National Renewable Energy Laboratory. K.Z., F.Z. and J.J.B. acknowledge the support on perovskite synthesis and device fabrication and characterization from the De-risking Halide Perovskite Solar Cells programme of the National Center for Photovoltaics, funded by the US Department of Energy, Office of Energy Efficiency and Renewable Energy, Solar Energy Technologies Office. The views expressed in the article do not necessarily represent the views of the DOE or the US Government. The US Government retains and the publisher, by accepting the article for publication, acknowledges that the US Government retains a nonexclusive, paid-up, irrevocable, worldwide license to publish or reproduce the published form of this work, or allow others to do so, for US Government purposes.

Author information

Authors and Affiliations



T.X. and K.Z. designed and supervised the research. X.L. prepared the Pb-absorbing materials and conducted the Pb-leaking and -capture characterization in films and devices. F.Z. fabricated and characterized the perovskite thin films and devices. H.H. conducted the theoretical calculation and simulation. J.J.B. conducted Pb impact analysis and a life-cycle assessment literature review. All authors discussed the results and contributed to manuscript preparation.

Corresponding authors

Correspondence to Kai Zhu or Tao Xu.

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Competing interests

An application has been made for a provisional patent (US patent application number 62/853,951) related to the subject matter of this manuscript.

Additional information

Peer review information Nature thanks Bert Conings, Peng Gao and Antonio Urbina for their contribution to the peer review of this work.

Publisher’s note Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Extended data figures and tables

Extended Data Fig. 1 Optical transmittance of DMDP films coated on glass.

The DMDP film thickness was varied from 0.7 to 6.89 μm. The inset shows the magnified view of the transmittance spectra.

Extended Data Fig. 2 Pb2+ binding energy.

a, Calculation of both electronic binding energies (Eb) and Gibbs free-energy (ΔG) changes of adsorption of Pb2+ by neutral and deprotonated DMDP and EDTMP at room temperature (25 °C) and 50 °C. All energies are in units of kJ mol−1. b, Schematic of binding configurations of Pb2+ ions with deprotonated DMDP and EDTMP. Configurations were obtained based on density functional theory calculations.

Extended Data Fig. 3 Pb amount measurement verification.

a, Pb concentration leaked from two-side damaged devices without any Pb-sequestrating materials and EVA packaging layer after being soaked in 40 ml of water for 3 h. Six devices were tested. The concentrations of dissolved Pb from these pristine devices were also calculated based on the density and thickness of the perovskite layers. b, Typical cross-sectional scanning electron microscopy image of the devices used in a. c, A typical verification curve of nominal Pb concentrations of various PbI2 solutions and the measured concentrations by the flame atomic absorption spectrometer. The result shows excellent accuracy and precision of the measurement system.

Extended Data Fig. 4 Pb-sequestering performance of DMDP and EDTMP-blended films.

a, Pb-sequestering performance as a function of soaking time for DMDP films coated on glass substrates. The DMDP film thicknesses are indicated. All DMDP films are soaked in 50 ml of 1.93 × 10−5 M PbI2 aqueous solution (equivalent to 4 ppm of Pb2+) to test their Pb-absorbing capability. Five samples were measured for 2.36-μm-thick DMDP and three samples were measured for other DMDP film thickness, with the averages and standard deviations (error bars) indicated. b, Evaluation of Pb-sequestering capabilities of different EDTMP-blended films prepared by various methods. Three samples of each configuration type were measured with the averages and standard deviations (error bars) indicated. The films were soaked in 50 ml of aqueous PbI2 solution with a Pb concentration of 7 ppm. ‘5% PEO in water’ stands for the film prepared by dissolving 5 wt% PEO (viscosity-average molecular weight, about 2,000,000) in pure water as solvent, followed by adding a proper amount of EDTMP under stirring. Then the mixture was smeared into a thin film using a doctor-blade coating method with such an area that the concentration of EDTMP is 0.01 g cm−2. ACN was used as the test solvent. PVA, polyvinyl alcohol (molecular weight 86,000).

Extended Data Fig. 5 Pb-sequestration films assembly processes.

a, Schematic of integrating DMDP and EDTMP–PEO films into a PSC. b, Photos of a pristine device and a device treated with the DMDP solution showing that directly applying the DMDP in ethanol solution damaged the perovskite stack with evident yellowing associated with perovskite decomposition due to polar ethanol.

Extended Data Fig. 6 EVA coating effect on device performance.

JV curves of PSCs with and without the EVA coating on the metal-electrode side of the device. Both forward- and reverse-voltage scans are shown. No clear impact on cell efficiency is observed for the EVA coating.

Extended Data Fig. 7 Impact of device damage conditions on Pb sequestration in pure water.

a,b, Six types of devices with different Pb-absorber layer coating and device damage conditions were tested. All devices were sealed by EVA film on the back metal-electrode side. The details of Pb-absorber coating and device-damage conditions are given in the table on the right. Six devices for each type of sample were tested. The Pb-leakage tests were conducted at room temperature (a) and 50 °C (b) by soaking each damaged device in 40 ml of water. The error bars represent the standard deviations from six samples of each type of device. It is worth noting that the case with both sides coated and damaged outperforms the case with only one side (particularly the back side) coated and damaged. This effect can be attributed to the chemical Pb-sequestrating nature of the DMDP and EDTMP–PEO films, which yields a summed sequestration effect, namely any aqueous Pb chemically captured by the Pb-sequestrating layer on one side will no longer flow back to the other side, hence, reducing the leaked Pb via either side compared with the case where a coating layer is present on only one side.

Extended Data Fig. 8 Simulation of pristine and DMDP-coated devices on Pb sequestration at room temperature.

a,b, The two-dimensional geometry models for a pristine control device (only covered by EVA film on the metal side; a) and a device including one coated with DMDP film on the glass-side alone (and the metal side is covered with EVA; b). c,d, The simulated spatial Pb concentrations for a pristine device (c) and a DMDP-coated device after 180 min of damage by shattering the glass side and forming cracks in the glass/DMDP (d). The labelled dimensions are in mm, and the colour-scale numbers are in ppm. Note that the colour scale ranges are different in c and d.

Extended Data Fig. 9 Impact of acidic water, competitive ion (Ca2+) and flowing water on Pb sequestration.

a,b, Pb leakage of damaged PSCs in acidic water (pH = 4.2; 40 ml) at room temperature (a) and 50 °C (b). The samples with Pb absorbers have both sides of the device stack coated with the Pb-sequestrating films. All samples are covered by EVA film on the metal-electrode side. c,d, Effect of competitive ion Ca2+ (from CaCl2) on Pb sequestration by DMDP (c) and EDTMP–PEO (d) samples using 40 ml water containing 12 ppm Pb2+ and 0.1 ppm Ca2+ at room temperature. For the control tests, the water solution contains only Pb2+ ions. The error bars in a–d represent the standard deviations from three devices of each type of test condition. e, Photograph of homemade apparatus to study Pb leakage from damaged devices under flowing water to simulate rainfall conditions. The flowing water is continuously dripped on the damaged devices at a rate of 5 ml h−1 for 1.5 h facilitated by a syringe pump. The damaged devices are placed in the funnel with a tilt angle of 30° versus horizon. The rinsed water that contains Pb is collected in plastic tubes. f, Comparison of Pb-sequestration efficiency of devices under flowing water at room temperature. All devices are installed with Pb absorbers on both sides. Three devices for each type of test condition were measured.

Extended Data Fig. 10 Solar cell photovoltaic parameters.

a, Detailed device photovoltaic parameters (open-circuit voltage (Voc), short-circuit current density (Jsc), fill factor (FF) and power conversion efficiency (PCE)) from both reverse and forward JV curves shown in Fig. 3a. b, Statistics of photovoltaic parameters of devices with and without the Pb-sequestering layers. Twelve devices were used for each type of device configuration. Error bars show the mean value, maximum/minimum values, and 25–75% region of data, which are represented by the circle, top/bottom bars, and rectangle, respectively.

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Li, X., Zhang, F., He, H. et al. On-device lead sequestration for perovskite solar cells. Nature 578, 555–558 (2020).

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