Abstract
High-efficient heat dissipation plays critical role for high-power-density electronics. Experimental synthesis of ultrahigh thermal conductivity boron arsenide (BAs, 1300 W m−1K−1) cooling substrates into the wide-bandgap semiconductor of gallium nitride (GaN) devices has been realized. However, the lack of systematic analysis on the heat transfer across the GaN-BAs interface hampers the practical applications. In this study, by constructing the accurate and high-efficient machine learning interatomic potentials, we perform multiscale simulations of the GaN-BAs heterostructures. Ultrahigh interfacial thermal conductance of 260 MW m−2K−1 is achieved, which lies in the well-matched lattice vibrations of BAs and GaN. The strong temperature dependence of interfacial thermal conductance is found between 300 to 450 K. Moreover, the competition between grain size and boundary resistance is revealed with size increasing from 1 nm to 1000 μm. Such deep-potential equipped multiscale simulations not only promote the practical applications of BAs cooling substrates in electronics, but also offer approach for designing advanced thermal management systems.
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Introduction
Thermal management is critical for electronic devices1,2,3,4,5,6,7, such as high-electron-mobility transistors (HEMTs), high-power density field-effect transistors (FETs), and radiofrequency (RF) devices, where high temperature degrades the performance of the system. However, in modern semiconductor industries8, the high hot-spot temperature in growing miniaturized electronic devices leads to a significant challenge for heat dissipation9,10 as shown in Fig. 1a. Thus, there is a strong impetus to search for high thermal conductivity (HTC) substrate materials, which can be integrated with hot-spot units for efficient heat dissipation. Therein the emerging interfacial thermal resistance (ITR) at the interface of heterostructure11,12,13,14,15,16 plays a crucial role, which may hamper the heat transfer. From micro-/nanoscale perspective, some phonons carrying heat fail to cross the interface, resulting in the emerging interfacial thermal resistance as illustrated in Fig. 1d and the significant temperature jump as shown in Fig. 1e. Thus, both HTC and low ITR are essential to heat dissipation.
Significant efforts have been employed to search, design, and investigate HTC materials for efficiently cooling down electronic systems17,18,19,20,21,22,23,24,25,26,27,28. Recently, some HTC compounds have been predicted based on first principles calculations. For instance, binary boron compounds and ternary boron compounds are reported17,29,30, both with thermal conductivity (κ) higher than 500 W m−1K−1. Especially, a remarkably high κ of 1300 W m−1K−1 for boron arsenide (BAs) has been confirmed by both theoretical calculations31,32 and experimental measurements25,26,27. Recently, experimental studies show the high carrier mobility of BAs33,34, which indicates promising applications of BAs in high-power electronics and optoelectronics. Commonly, the high-power density electronic devices of HEMTs are composed of gallium nitride (GaN), silicon, and silicon carbide substrates, where the performance bottleneck generally exists due to the low thermal conductivity. Recently, Kang et al.35 successfully fabricated GaN devices on BAs cooling substrates in experiments. The crystal structures of BAs and GaN are presented in Fig. 1b and c, respectively. Excellent cooling efficiency compared with diamond-supported devices was observed, which is benefited from the low ITR in addition to the ultrahigh κ of BAs. In fact, boundaries and interfaces are inevitable for the practical applications of cooling substrates in microelectronics. The interfacial thermal transport across GaN and the neighboring BAs is important for a high-performance thermal management, especially for the near-junction region. However, limited by the accurate interatomic interaction potential, the lack of systematic analysis on the heat transfer across the GaN-BAs interface hampers the practical applications. The fundamental understanding on the heat transfer across the GaN-BAs interface can offer insight for the rational design of advanced thermal management systems, which demands for a systematic study of the ITR. We have pioneered to construct an innovative multiscale simulation framework that combines density functional theory (DFT) calculation, Molecular dynamics (MD) simulation, Monte Carlo (MC) simulation, and finite element (FE) simulation, with the aid of the state-of-the-art machine learning technique. The simulation framework enables deep understanding of the characteristics and principles of materials at different spatial and time scales.
MD simulations have been widely employed to study the thermal transport properties of interfaces in heterostructures11,36,37. Although it is robust and “automatic” to consider the effect of surface and interface, one apparent disadvantage of MD simulations is that it largely relies on an accurate interatomic potential. Unfortunately, the interatomic potentials of BAs are lacking up to now, which limits a detailed theoretical analysis on the interfacial thermal transport properties and thus hampers the potential applications of BAs as a competing cooling substrate for microelectronics. Previous studies used diffuse mismatch mode (DMM) and acoustic mismatch model (AMM) to calculate the interfacial thermal conductance (ITC). Both methods are empirical models that only consider the basic phonon scattering property of the two in-contact materials and assume the interface is perfect, while the detailed atomic structure at the interface does not play any role in the models. Compared to the traditional methods, direct MD simulations based on accurate machine learning (ML) potential are capable of studying the phonon thermal transport across the GaN-BAs interface with all order anharmonic phonon scattering involved and the simulation are much closer to the physical interfaces. Recently, it has been demonstrated that ML techniques can be utilized to construct accurate interatomic potentials38,39,40, where artificial neural networks (ANN) and neural network potentials (NNPs) are the most widely used methods41,42. Correspondingly, the resulting multiscale simulations based on NNPs combine the advantages of the accuracy of ab-initio calculations and the efficiency of analytically parameterized potentials. Thus, by empowering the multiscale study of the thermal transport properties of heterostructure with first principles accuracy43,44, the NNPs land the foundation to promote in-depth understanding and predictive design of efficient heat dissipation for engineering microelectronic devices.
In this study, we constructed the NNPs for GaN, BAs and their interfaces to systematically investigate the thermal transport properties of GaN-BAs heterostructure. The bulk thermal transport properties of GaN and BAs were firstly evaluated and validated with the existing reports. We then employed non-equilibrium MD (NEMD) and MC simulations to evaluate and analyze the interfacial thermal transport properties of the GaN-BAs heterostructure. The NEMD results reveal significant temperature-dependent ITC between 300 and 450 K in GaN-BAs, suggesting enhanced phonon transmission and inelastic phonon scattering. FM models (FEM) were further constructed to simulate GaN-BAs heterostructures, which is similar to the amorphous or polycrystalline layer near interface. Finally, we report the competition between grain size and boundary resistance in our polymer model expanding the size-scale from 1 nm to 1000 μm. The work is expected to shed light on practical thermal management engineering with interfaces.
Results
NNP training
To investigate the heat transfer across the GaN-BAs interfaces as shown in Fig. 1, we firstly construct the NNPs for BAs with 128 atoms, GaN with 144 atoms, and the GaN-BAs heterostructures with 128 atoms. For the atoms at the interfaces, we visualized the energy, force, and stress distribution as shown in Supplementary Figs. 3, 4, and 5, respectively. The selection of configurations used in NN training process is essential to construct reliable NNP models. More importantly, the interfacial structures in the GaN-BAs heterostructures can be complex. Therefore, the active learning strategy is utilized during the construction of NNPs, which shows high efficiency and low computation costs to collect relevant training configurations for pristine BAs, GaN, and GaN-BAs heterostructures. As shown in Fig. 2a, the NNP training workflow comprises three steps (see the section of Methods for more details). With the increasing iterations of the ab-initio calculations, we are able to collect diverse snapshots for the NNPs training. Finally, 2250, 2535, and 10350 training snapshots were collected for pristine BAs, GaN, and the GaN-BAs heterostructures, respectively.
The quality of the resulting NNP models is verified by performing a comparison for energies and forces (fx, fy, fz) between DFT calculations and NNPs predictions. The test configurations are composed of 2103, 2022 and 1990 snapshots for BAs, GaN and the GaN-BAs heterostructures, respectively, which are not included in the configurations for previous training. From Fig. 2d–i, it is obvious that NNPs are able to accurately reproduce the energies and forces obtained from DFT calculations. The force root mean square error (RMSE) are 18, 22, and 36 eV/Å for BAs, GaN, and GaN-BAs heterostructures, respectively. The small RMSE also implies the high quality of the NNP models. On the other hand, despite the successful description of the interfaces of the trained model, we have to say that the model is trained with limited data, and it surely fails in certain cases due to the native weakness of transferability from ML technologies, such as interfacial microstructures, doping elements, and disorder structures. With the NNP models, we calculate the phonon dispersions of BAs and GaN, and the results coincide with those from explicit DFT calculations, as comparably shown in Fig. 2b, c. Moreover, both BAs and GaN show obvious phonon gap, especially for BAs, which implies strong high order phonon scattering31.
Thermal transport in GaN and BAs
With the well-trained NNP models, we can evaluate the lattice thermal conductivities of GaN and BAs. The finite displacement method was adopted to calculate the second- and third-order constants that are required to solve the Boltzmann transport equation (BTE)45,46,47. And the force calculations are performed using the Large-scale Atomic/Molecular Massively Parallel Simulator (LAMMPS) software package48 coupled with our trained NNPs. Figure 3a shows the anisotropic κ of GaN considering four-phonon scattering and isotope effects, where the κ along the a and c axis are 217 and 229 W m−1K−1, respectively. These results are in excellent agreement with previously reported DFT calculations49 (a = 223 and c = 243 W m−1K−1) and experimental measurements50,51,52(a = 217 and c = 228, 195 W m−1K−1). Recent experimental measurements and theoretical calculations demonstrated that BAs has strong four-phonon scatterings25,27,53. Consequently, after considering four-phonon scatterings, the κ of BAs is calculated to be 1510 W m−1K−1 using NNP model of BAs at room temperature [Fig. 3b], which is consistent with the reported values (1400 W m−1K−1) in literature31. Note that we can obtain the calculation of the fourth force constants in a few minutes when using NNP model to evaluate atomic forces in supercells, which achieves a significant reduction of computational cost with similar precision compared to full first-principles calculations. The MD simulations of interfacial thermal transport across the GaN-BAs interfaces naturally includes all orders phonon transport, which is much closer to the physical interface compared to other methods. Different from the complex procedure of including four-phonon scatterings in BTE54, it is natural for MD simulations to consider the four-phonon scatterings and even higher order scattering.
To obtain the accurate κ of BAs from classical MD simulations, we performed the equilibrium MD (EMD) simulations based on the Green–Kubo (GK) method using the NNP models, where the thermal conductivity is evaluated based on the heat current autocorrelation function (HCACF):
where V is the volume, kB is the Boltzmann constant, T is the temperature, J is the heat flux, t is the integration time and 〈〉 represents the time average. The resulting HCACF is displayed in Fig. 3c. It is shown that 1200 ps EMD simulations can enable the generation of a converged κ of BAs. For obtaining the HCACF \(\left\langle {{{{{\bf{J}}}}}}\left(0\right)\cdot {{{{{\bf{J}}}}}}\left(t\right)\right\rangle\), the heat flux J is calculated as follows:
where \({E}_{i}\) and \({{{{{{\bf{v}}}}}}}_{i}\) are the atomic potential energy and velocity, respectively. The atomic virial stress tensor \({{{{{{\bf{S}}}}}}}_{i}\) is defined as the outer product of relative atomic position \({{{{{{\bf{r}}}}}}}_{i}-{{{{{{\bf{r}}}}}}}_{j}\) and the derivative of local potential energy with respect to the neighboring atom position:
In the MD simulations, each particle is initially assigned a random velocity using the velocity random seeds. The ensemble of the generated velocities is a uniform distribution, which can be scaled to produce the requested temperature. The introduction of velocity random seeds allows the system to evolve from a uniformly distributed state rather than from a specific ordered state. Such initial conditions help simulate the behavior of the system under different conditions and explore all the possible states and dynamics, as widely utilized in previous studies55,56,57,58. To reduce the simulation uncertainty and obtain reliable result, the κ is obtained by averaging 14 independent simulations as shown in Fig. 3d, where the shaded area indicates the statistical uncertainty on the mean value. As summarized in Table 1 including the results from previous calculations31,32,49 and experiments25,26,27, the κ of BAs obtained from MD simulations in this work (1179 ± 91 W m−1K−1) is well consistent with previous reports, especially compared with the BTE results involving four-phonon scattering and the experimental measurements. The length-dependent thermal conductivity of GaN and BAs is also calculated in the Supplementary Fig. 8. Note that the ultrahigh κ of BAs is verified from direct MD simulations of atomic motions. Besides, we also study other phonon related properties of GaN and BAs, such as group velocity, phonon relaxation time, and the contribution to κ from different phonon branches, which are shown in the Supplementary Fig. 1 and Supplementary Table. 1. Especially, the 4th phonon scattering phase space for BAs is also provided for further understanding.
The ITC of the GaN-BAs heterostructures
The interfacial heat transfer in the GaN-BAs heterostructures is further investigated by performing NEMD simulations. We put GaN on heat source and BAs on heat sink, as shown in Fig. 4a, which shows a stable temperature profile of a steady state. There is an obvious temperature jump (ΔT) at the interfaces, implying a finite ITR between BAs and GaN. Thus, the ITC of the heterostructures is evaluated as 260 MW m−2K−1 at 300 K, which is in good agreement with the results35 measured by time-domain thermoreflectance (TDTR) (250 MW m−2K−1) as collected in Fig. 4b. The relatively higher ITC in calculations may be due to the fact that there exists epilayer between GaN and BAs in the experimental measured samples35. It is worth pointing out that the ITC result may be affected by size due to the large phonon mean free path of BAs, and the size of the model used in this study is 30 nm (the length-dependent ITC is presented in Supplementary Fig. 7), which is similar as the heterostructure between graphene and boron nitride36. We also perform the calculations with GaN on heat sink and BAs on heat source, and the results are consistent, which indicates weak thermal rectification effect in the GaN-BAs interface.
It can be seen that ITC gradually increases with respect to the increasing temperature ranging from 300 to 450 K. The strong temperature dependence of ITC is different from the most interfaces including GaN-diamond and GaN-SiC, where the ITC is almost independent of temperature in the application temperature range10,59. To explore the underlying mechanisms of the temperature dependent ITC in GaN-BAs, the spectral heat flux at different temperatures is plotted in Supplementary Fig. 6a. With the increasing temperature, spectral heat flux gradually increases both at low and high frequencies and then converges, which are similar to the variation of ITC as shown in Fig. 4b. The phenomenon means that more heat carries are activated to across the GaN-BAs interfaces by the increased temperature, inducing more inelastic phonon interface scattering, and thus enhances ITC by enhancing phonon transmission coefficients [Supplementary Fig. 6b].
To fundamentally understand the behavior of ITR, the phonon eigenvectors of the GaN-BAs heterostructures interface at different frequencies are visualized in Supplementary Fig. 2. There are enormous phonon eigenvectors for both GaN and BAs, which indicate the active phonon vibration figure for 5 THz. In other frequencies, phonon eigenvectors are nearly negligible. It is worth noting that the phonon eigenvectors of GaN is strong at 20 THz, which is consistent with the large phonon relaxation time as shown in Supplementary Fig. 1b. Besides, the phonon density of states (PDOS) was explored for GaN and BAs. As shown in Fig. 4c, there is an obvious band gap ranging from 10 to 16 THz, coincided with the phonon dispersions in Fig. 2b, c. Moreover, the large overlap area of PDOS indicates the well-matched lattice vibrations of GaN and BAs. Thus, the small ITR and the corresponding high ITC are achieved in the GaN-BAs heterostructures. Such conclusions would benefit the potential applications of BAs as a competing cooling substrate to diamond with the advantage of not needing epilayer7,60.
To further figure out the heat flux dependence on frequency, we use MC simulations to calculate the distribution of heat flux across the heterostructure interfaces, and the results are shown in Fig. 4d. The frequency resolved heat flux from GaN to BAs is scaled by the thermal conductivity of materials. Apparently, there is a wide distribution range of heat flux for BAs, and the heat flux of GaN concentrates at low frequencies. Most importantly, the heat flux in the low frequency exhibits an excellent match across the interface, which explains the high ITC in the GaN-BAs heterostructures. Such behavior also implies that the low frequency phonons make greatly contributions to the ITC.
Multiscale modeling from 1 nm to 1000 μm
Based on the understanding of heat transfer process achieved from above DFT and MD simulations, the FEM can be employed to study the heterostructure models at a macroscopic scale. The combination of FEM and MD simulations is a promising approach to overcome the multiscale effects of grain sizes and the huge computational cost. Compared with MD and DFT simulations limited in the nanoscale, the macroscopic FEM can cohere with the practical applications and get the effective κ of GaN-BAs heterostructures in multiscale. Herein, a 1000 nm model is constructed with 50% BAs and 50% GaN as shown in Fig. 5a. To calculate the effective κ of such a heterostructure model, one dimensional Fourier law is applied as \({\kappa }_{{eff}}=q\frac{L}{\triangle T}\), where q is the heat flux across the model. The corresponding steady states are guaranteed when the value of the inward flux is equal to that of the outward flux. The \(\triangle T\) is the temperature drop between the top side and bottom side, and Fig. 5b shows the resulting temperature profile.
From the FEM, Fig. 5c shows the ununiform heat flux distribution of 50% GaN and 50% BAs, respectively. It is observed that BAs dominates the majority of heat flux, which lies in that the thermal conductivity of BAs is significantly higher than that of GaN. Moreover, similar phenomena can also be seen from the two insets in Fig. 5d, which consist of different percentages of GaN and BAs. To further understand the mechanism of grain size dependence of the effective κ, we perform a comparison study with grain size ranging from 1 nm to 1000 μm. As shown in Fig. 5d, there exists an important competition between the grain size and grain boundary. Firstly, when the grain size is below 10 nm, the effective κ is insensitive to grain size. Such a behavior lies in the competition between the increasing size benefiting phonon transport and the tiny effective κ, which is due to the decreased κ values at the much smaller size than the representative phonon mean free path as indicated in Fig. 3a, b. Secondly, when the grain size ranges from 10 nm to 100 μm, more and more phonons are gradually activated in GaN and BAs to participate in the heat transfer with the increasing grain size. Thus, the increasing grain size leads to increased κ in both GaN and BAs, and the role of grain boundary becomes relatively less significant, leading to the significantly increased effective κ. Thirdly, when the grain size ranges from 100 to 500 μm, the effective κ tends to saturate, which lies in the grain size greatly exceeding the phonon mean free path of GaN and BAs [Fig. 3a, b], and the largely weakened effect of grain boundary resistance. Finally, it is obviously seen that when the grain size over 500 μm, the effective κ decreases with the increasing grain size. The underlying mechanism lies in that the phonon scattering dominates the thermal transport, where the increasing grain size results in more significant ITR, and the κ of GaN and BAs hardly increases. The results as discussed above suggest that the grain size between 10 nm and 100 μm is the most favorable size scale for engineering phonon thermal transport in GaN and BAs systems.
Discussion
In summary, we have studied the thermal transport of GaN devices on BAs cooling substrates for high-performance thermal management. The state-of-the-art computational methods, i.e., ML, DFT, MD, and FEM, are employed to develop systematic multiscale simulations of the thermal transport properties together with quantitative evaluations and in-depth mechanistic evaluations. The comparison of DFT and MD simulations, and the excellent agreement with the reports from previous calculations and experiments show that the trained NNP models in this study are of high accuracy. And the ultrahigh thermal conductivity of BAs is verified from direct MD simulations of atomic motions. Ultrahigh ITC of 260 MW m−2K−1 is obtained in the GaN-BAs heterostructures, which agrees well with experimental measurements, promising the conducive heat dissipation. Detailed analysis reveals that the underlying mechanism lies in the well-matched lattice vibrations of BAs and GaN. In addition, the NEMD results also show relativity large temperature dependent ITC between 300 and 450 K, which is different from previously reported interfaces, such as GaN-diamond and GaN-SiC. Based on the understanding of heat transfer process achieved from nanoscale DFT and MD simulations, we successfully established the macroscopic FEM models of the GaN-BAs heterostructures and investigated the mechanism for the grain size dependent effective κ with the grain size ranging from 1 nm to 1000 μm. Our results provide holistic and fundamental insights into the interfacial heat transfer of the GaN-BAs heterostructures, which is expected to promote the practical applications of BAs as a competing cooling substrate to diamond for electronic devices. Most importantly, we believe that our approach based on machine learning interatomic potential driven multiscale simulations can be applied to engineer and design sophisticated thermal management systems, and hence further promote the development of miniaturized electronic devices.
Methods
DFT calculations
The Vienna ab-initio simulation package (VASP), a widely employed ab initio plane wave electronic structure code for atomic scale materials modeling, was used to perform first-principles calculations with the Perdew–Burke–Ernzerhof functional of generalized gradient approximation61. For the DFT calculations, the kinetic energy cutoff was set as 1000 eV, a 10 × 10 × 6 Monkhorst-Pack62 k-point grid are employed for BAs and GaN, respectively. For self-consistent field (SCF) calculations with convergence threshold of 10−6 eV, kinetic energy cutoff was set as 600 eV, and a 1 × 1 × 1 Monkhorst-Pack k-point grid is employed.
The construction of NNP models
To collect diverse training data, active learning workflow is adopted63. To initialize the training data, the supercell is firstly relaxed and compressed uniformly with a scaling factor α ranging from 0.98 to 1.02, where the interval is 0.02. Then, the atomic positions and cell vectors are randomly perturbed. The magnitude of perturbations is 0.01 Å for the atomic coordinates, which is 3% of the cell vector length for the simulation cell. 15 randomly perturbed structures were created for GaN, BAs, and heterostructure, respectively. They are then utilized to perform a 10-step canonical ab-initio molecular dynamics simulation at T = 50 K with VASP. For the training, the smooth edition of the NNP is employed. A skip connection is adopted between two neighboring fitting layers. The cutoff is set to 7 Å. Four neural network models with Adam optimizer only combined with different parameter initializations, the embedding net with size of {30,60}, and the fitting net with size of {240, 240, 240} were trained. To the exploration step, when the force deviation of configurations is in the trust range [0.05, 0.20], it will be labeled. During the Labeling step, VASP was adopt to performance first-principles calculations. Finally, the active learning cycles are performed 28 times, 21 times, and 29 times for GaN, BAs, and GaN-BAs heterostructure, respectively. With the collected data, an accurate NNP model was trained with learning rate and training steps of 0.95 and 1000000, respectively.
MD simulations
The LAMMPS software package was used to perform MD simulations. For EMD simulations, the structure was relaxed at canonical (NVT) ensembles with periodic boundary conditions for 0.1 ns with a time step of 1 fs. Then, the heat flux data can be started to collect. For NEMD simulations, first, the structure relaxed at isothermal–isobaric (NPT) ensemble. Then, the atomics of the two sides of the simulation system were fixed and 22 slabs were adopted to the remaining region. Heat source and heat sink is set to 320 and 280 K, respectively. For the further relaxation with NVT ensembles, the relaxation time is set as 1 ns. Finally, the temperature of each slab and the heat flux across the system can be calculated.
FEM simulations
To construct polycrystalline models, ABAQUS/Standard with python script is used. The models are comprised of 2197 individual grains with Voronoi cells feature, which are randomly assigned with BAs or GaN attributes. Besides, the ITR between BAs and GaN grains are defined based on the NEMD results. Assuming an equivalent average grain with cubic geometry64, we define the grain size as \(\root 3 \of {\frac{{L}^{3}}{N}}\), where the N is the number of grain, and the L is side length. Considering the GaN with anisotropic properties, we assign corresponding grain with random orientations. We apply two highly conductive sheets to construct heat and cold source. For the initial load condition, we set the temperature of cold source as zero.
Data availability
Source data is available as a Source data file. It has also been deposited in Figshare under accession code https://doi.org/10.6084/m9.figshare.25283617. Source data are provided with this paper.
Code availability
The datasets (NNP models, LAMMPS input files, ShengBTE output files and FE models) in this study have been deposited in the Zenodo database under Creative Commons Attribution 4.0 International Public License at https://doi.org/10.5281/zenodo.10793584.
Change history
16 April 2024
A Correction to this paper has been published: https://doi.org/10.1038/s41467-024-47636-3
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Acknowledgements
We acknowledge the support of the National Natural Science Foundation of China (Grant Nos. 52006057), National Key R&D Program of China (2023YFB2408100), the Fundamental Research Funds for the Central Universities (Grant No. 531119200237), the Natural Science Foundation of Chongqing, China (No. CSTB2022NSCQ-MSX0332), and the State Key Laboratory of Advanced Design and Manufacturing for Vehicle Body at Hunan University (Grant No. 52175013), and the Outstanding Youth Project (23B0024) of Hunan Provincial Department of Education. The numerical calculations in this paper have been done on the supercomputing system of the National Supercomputing Center in Changsha.
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G.Q. supervised the project; J.W. and E.Z. carried out the molecular dynamics simulations; J.W. and A.H. carried out the ab initio calculations; J.W. performed the analysis and wrote the manuscript; H.Z. and M.H. reviewed the manuscript; all of the authors discussed the results and edited the manuscript.
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Wu, J., Zhou, E., Huang, A. et al. Deep-potential enabled multiscale simulation of gallium nitride devices on boron arsenide cooling substrates. Nat Commun 15, 2540 (2024). https://doi.org/10.1038/s41467-024-46806-7
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DOI: https://doi.org/10.1038/s41467-024-46806-7
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