Seismological findings show a complex scenario of plume upwellings from a deep thermo-chemical anomaly (superplume) beneath the East African Rift System (EARS). It is unclear if these geophysical observations represent a true picture of the superplume and its influence on magmatism along the EARS. Thus, it is essential to find a geochemical tracer to establish where upwellings are connected to the deep-seated thermo-chemical anomaly. Here we identify a unique non-volatile superplume isotopic signature (‘C’) in the youngest (after 10 Ma) phase of widespread EARS rift-related magmatism where it extends into the Indian Ocean and the Red Sea. This is the first sound evidence that the superplume influences the EARS far from the low seismic velocities in the magma-rich northern half. Our finding shows for the first time that superplume mantle exists beneath the rift the length of Africa from the Red Sea to the Indian Ocean offshore southern Mozambique.
Extensive volcanism and tectonic activity in the East African Rift system (EARS) are regarded as the classic example of present-day plume-related rifting and continental breakup1,2,3. Rifting began in southern Ethiopia at approximately 45 Ma4 with volcanism in northern Ethiopia and Yemen starting ∼30 Ma5. This older part of the EARS stretches for >2000 km, originating from the Afar triple junction and traversing the Ethiopia Dome southward along the Main Ethiopian Rift (MER) before bifurcating into the Kenyan and Western rifts (Fig. 1).
Global and continental scale tomographic models show strong low-velocity regions in the mantle under East Africa (e.g. refs. 5,6,7,8,9). One scenario proposed to explain these markedly lower mantle seismic velocities is the upwelling of a large, continuous
-mantle plume (the African Superplume), originating at the core–mantle boundary10,11. The thermochemical nature of the seismic anomaly (superplume) in the lower mantle suggests a dense chemical layer within a buoyant upward-flowing thermal structure12.
The topography of the magma-rich northern half of the EARS is dominated by two prominent plateaus—the Ethiopia and East African domes—which are transected by the EARS, the Red Sea and the Gulf of Aden. These domes are compatible with dynamic support by plume upwellings from the lower mantle rising beneath the continental lithosphere (e.g. refs. 10,11), but it is unclear if one or more plumes support these high plateaus2,6,7,8,9,13. Moreover, recent tomographic models of the Afro-Arabian mantle reveal a laterally continuous, low-velocity region in the upper mantle beneath all of eastern Africa and western Arabia extending to depths of ~500–700 km9,10,11,14.
The relation between these seismically imaged upwellings and large-volume EARS magmatism is often considered in the context of the well cited explanation that the superplume is a thermal phenomenon. In this scenario large-volume melting occurs where hot plume material flows below areas of thinned lithosphere and the TP is above the solidus. Continental lithosphere is inherently heterogeneous, specifically in terms of thickness. In the case of Africa, the Archean cratonic roots are deep so melts could only be generated beneath pre-existing thinner Karoo and Palaeogene orogenic belts adjacent to cratons5. The scattered distribution of rift-related EARS magmatism can therefore be explained by a variable lithospheric topography at depths of 100–150 km, which channels hot plume material into streams and pools2,15. However, a new generation of petrologic models16 show that while the Tp of the East African mantle is characterized by elevated temperatures (+140 to +170 °C) consistent with a buoyant superplume, it is toward the cooler end of the spectrum for Large Igneous Provinces (LIPs)17. Thus, factors other than elevated temperature must be contributing to large-volume melting and the exceptionally slow seismic velocity under East Africa. Consequently, there is much uncertainty about how well seismic data and large-volume melting captures the scale and dynamics of the superplume at depth and its interconnectivity with the upper mantle/EARS.
A way of resolving this debate would be to find a unique isotopic fingerprint for linking EARS lavas to a single deep-seated superplume. A number of such plume isotopic signatures have been inferred by interpolation of arrays in Sr–Nd–Pb isotopic space for lavas from the magma-rich northern EARS (e.g. refs. 13,18,19,20,21), but it is unknown which, if any, of these isotopic signatures might be a unique tracer for the single superplume largely because of contamination/dilution by large-volume melting of the subcontinental lithospheric mantle. While rare gas isotopes are more successful in overcoming the problem of contamination/dilution22,23, they cannot be used as a robust superplume tracer because they do not define a distinct isotopic signature and are not coupled to the solid superplume mantle.
The southern half of the EARS continues south of the Western Rift as far as the Davie Ridge where it trends NNE–SSW across the Mozambique Channel24 and as far east as the Comoros-Mayotte and Madagascar system (Fig. 1). There is no seismic or geochemical evidence suggesting a connection between the African superplume and this magma-poor southern half of the EARS. But here we identify a unique non-volatile isotopic signature (‘C’) in the youngest (after 10 Ma) phase of widespread EARS rift-related magmatism where it extends into the Indian Ocean and the Red Sea. These offshore rock samples provide the first robust (isotopic) evidence that superplume material is present in the magma-poor southern half of the EARS, far from the very-low seismic velocities beneath the magma-rich northern half. This directly measured non-volatile superplume isotopic signature tracks for the first time superplume mantle the length of Africa from the Indian Ocean to the Red Sea. This more-or-less homogeneous isotopic composition is consistent with the inference from seismic mantle images of a single deep-seated superplume that is modifying the EARS mantle not only in northeast Africa but the length of Africa from the Red Sea to southern Mozambique. Finally, we offer some broader perspectives about how our finding raises some interesting questions for future lines of research.
Results and discussion
Volcanism on the northern Mozambique Ridge
The massive Jurassic/Early Cretaceous Mozambique Ridge is considered to be an LIP that formed during early Gondwana dispersal in the African–Antarctic corridor25,26,27,28,29,30,31. The northern Natal Valley was emplaced between M26r to M18n (157.1–144 Ma) and the entire Mozambique Ridge between M18n to M6n (144–131.7 Ma)27,30,31.
Recently collected multibeam swath bathymetry and seismic profiles from the Natal Valley and Mozambique Ridge reveal anomalous seafloor dome-like volcanic structures, which are interpreted in terms of Miocene to recent magmatism along a southward propagation of the western branch of the East African Rift System24,32,33,34,35,36 (Fig. 1). In the Natal Valley the domes are 25–31 km long and 16–18 km wide and rise some 400 m above the sedimentary deposits35 (Fig. 2). Detailed swath data of seafloor domes on the Mozambique Ridge33,34 guided TV-grab sampling of volcanic rock from a smaller topographic feature (∼3 km east–west and 1.2 km in diameter) at the northern end of the ridge (for details see ref. 34) (Fig. 2). Information about the samples used in this study is provided as Supplementary Table 1 and Supplementary Fig. 1.
We report here 40Ar/39Ar incremental heating isotopic ages, measured on acid-leached groundmass separates for three TV-grab samples recovered during the SO230 expedition (MW14DL2-2, MW14DL2-3 and MW14DL3-5) from the volcanic dome located at the northern end of the submarine Mozambique Ridge. 40Ar/39Ar incremental heating ages are summarized in Table 1 and Supplementary Fig. 2. Replicated (Vrije University Amsterdam and Oregon State University) robust ages for three samples from two different TV-grab stations demonstrate that the sampled dome volcanism is ≥6.9 ± 0.03 Ma. 40Ar/39Ar results, plateau ages and K/Ca spectra are provided in summary as Supplementary Data 1 and in full in Supplementary Data 2.
Based on silica and total alkali content samples DL2-2 and DL2-3 are basanites and DL3-5 is transitional between a basanite and an alkali basalt (Fig. 3). Trace element data show that the Mozambique Ridge samples are typical intraplate oceanic alkali basalts (Figs. 3 and 4) and have relatively radiogenic Pb isotope ratios (206Pb/204Pb = 19.52–19.54) and comparatively depleted Sr (86Sr/87Sr = 0.7031) and Nd (143Nd/144Nd = 0.5128) signatures (Fig. 5). Geochemical data are provided in Supplementary Data 3.
EARS magmatism since the Late Miocene
We consider first how an age of ∼7 Ma for volcanism on the Mozambique Ridge compares with published ages for the EARS and intraplate volcanism in the Indian Ocean (Fig. 1). The Comoro Islands are associated with the seaward extension of the EARS and have recently been linked with a deep-seated plume9,24,36. K–Ar ages for the oldest island of Mayotte show that volcanism started roughly 8 ± 1 Ma and continued to at least as recent as 2–1 Ma37,38. Grande Comore is still active and K–Ar ages for Grande Comore, Moheli, and Anjouan are all younger than 8 ± 1 Ma37,38. Thus, K–Ar dating of the Comoro Islands suggest that subaerial volcanism initiated roughly around the same time as the dome on the Mozambique Ridge.
A 40Ar/39Ar study of the Rungwe Volcanic Province (RVP) at the southern tip of the Western Rift (Fig. 1) yielded ages from 8.5 to 5.7 Ma39, consistent with prior results, supporting an eruptive episode concurrent with tectonic activity on the Malawi and Rukwa border faults40,41. Three additional samples yield ages from 18.5 to 17.6 Ma, consistent with the 18.6 ± 1.0 Ma age obtained previously (see ref. 39 and reference therein). These older ages are spatially limited to phonolite domes that predate the current tectonic extensional structure. No Rungwe samples dated yet can be the source of the of 26 Ma carbonatitic tuffs in the nearby Rukwa area42. A K–Ar age determination from Essimingor volcano on the southern tip of the eastern branch (Fig. 1) suggest an age ≥8 Ma43, whereas 40Ar/39Ar ages indicate that volcanism started at ~6 Ma and has continued episodically to the present44,45.
In the Ethiopian Plateau the oldest volcanic rocks have been dated at ∼45 Ma in southern Ethiopia2,4,46,47. The most voluminous eruptive stage is represented by flood and shield basalts in the Ethiopian plateau made up of several distinct volcanic centres ranging from a thick sequence of ∼30 Ma flood basalts overlain by a 30 Ma shield volcano. In the centre of the province are two ∼22 Ma shield volcanoes47,48,49 and younger shields developed ∼11 Ma48. Between 12 and 10 Ma, the southern Red Sea margin propagated southward as the MER propagated NE, effectively linking the southern Red Sea and Ethiopian rifts, and forming a triple junction for the first time, possibly in response to a (global) plate reorganization49. In the Gulf of Aden ages of off-axis seamounts point to a volcanic event at ~10 Ma that subsequently became more widespread roughly 6 Ma ago50.
In summary, the age of volcanism on the Mozambique Ridge and the Comoro Islands is similar to the overall timing of Late Miocene rift-related magmatism in the magma-rich northern half of the EARS and extending into the Red Sea-Gulf of Aden. Young volcanism on the Mozambique Ridge represents the southernmost known EARS-related magmatism, and extends the EARS volcanic province more than 2000 km to the south of Rungwe (Fig. 1).
EARS isotopic signatures
Sr–Nd–Pb isotopic fingerprints for plume mantle under the EARS were previously determined from the general convergence of lavas in Sr–Nd–Pb isotope space (see ref. 21 and reference therein). Three candidate plume isotopic signatures are proposed for the EARS: plume ‘C’20, plume ‘K’18 and plume ‘V’21.
Plume ‘C’: In the northern part of the EARS, recent volcanic and magmatic activity is largely confined to the tectonically active segments of the MER and the active spreading centres of the Red Sea and the Gulf of Aden49. Lavas from along and near the MER are predominantly transitional tholeiites with Th/Yb and Nb/Yb ratios similar to OIB and E-MORB (Fig. 4) and have less enriched and more homogeneous Sr, Nd and Pb isotope compositions than EARS lavas to the south (Fig. 5) (see e.g. refs. 13,20,51). A widely accepted explanation for the Sr–Nd–Pb isotopic signature of the MER is that it results from mixing between plume material and MORB mantle (DMM), and continental lithosphere (SCLM) (see e.g. refs. 20,52). Converging MER arrays in multi-isotope space define the composition of the plume endmember (centred about 87Sr/86Sr = 0.7035, 143Nd/144Nd = 0.51287 and 206Pb/204Pb = 19.5 (ref. 20) (Fig. 5). This plume endmember is similar to the ‘common’ isotopic composition observed globally in oceanic basalts20 known as ‘C’53. A key finding of our study is that the 7 Ma basanites-alkaline basalts from the Mozambique Ridge express a pure plume ‘C’ isotopic signature (Fig. 5).
Plume K: South of the Ethiopian Rift the EARS branches into the Kenyan and Western rifts. Lavas from the Kenyan Rift converge in Sr–Nd space to a composition referred to as plume K (87Sr/86Sr 0.7030–0.7035 and 143Nd/144Nd 0.5130–0.5127)4,13,18, which is largely indistinguishable from plume ‘C’ (Fig. 5).
Plume V: The compositional convergence of Western Rift lavas is attributed to the presence of a common superplume V, with a limited range of compositions, that had been continuously metasomatizing the compositionally variable lithosphere beneath the Western Rift for the last 500–1000 Ma21. The 87Sr/86Sr, 143Nd/144Nd, and 206Pb/204Pb composition of plume V is represented best by lavas from the Nyiragongo and Nyiramugira volcanoes (VVP)54 (average 87Sr/86Sr 0.7045; 143Nd/144Nd 0.5127; 206Pb/204Pb 19.4)21 (Fig. 5). Metasomatization of the lithospheric mantle at various times by this volatile-rich (primarily carbonatitic) plume material (ref. 21 and references therein and ref. 51) is reflected in the exceptionally high level of trace element enrichment compared to the rest of the EARS in lavas from volcanic provinces in the Western Rift (Rungwe (RVP), Virunga (VVP), Toro Ankole, and Kivu) (Fig. 4)55,56,57,58. This process raised the 3He/4He ratio and led to almost complete hybridization of the trace elements, Sr–Nd, and, to a large extent, Pb isotope compositions21,51. Plume V 206Pb/204Pb (constrained from the intersection of the Pb isotopic analyses from Western Rift volcanoes (e.g. refs. 59,60) is strikingly similar to that of plume C (calculated from the intersection of Pb isotopic analyses from the MER20) (Fig. 5). An indication that Pb and Sr–Nd isotopes might be behaving differently is the positive correlation between He and Pb isotopes, but not Sr–Nd, for RVP and MER lavas21. This decoupling might be explained by ‘outgassing’ of abundant CO2 from the superplume at depth acting as a carrier phase for the trace gases21 (see discussion in a following section about other drivers of melting). RVP magmas are among those produced by the lowest degrees of melting along the Western Rift21 (Fig. 4) suggesting that low-degree melting allows the Pb, if not the Sr–Nd, aspects of the common ‘C’ /V signature to bypass contamination by metasomatized SCLM.
In the following sections we discuss the evidence that a similar mechanism operating along the offshore extensions of the EARS in the Red Sea-Gulf of Aden, Southern Somali Basin and Indian Ocean results in lavas containing the Sr–Nd–Pb superplume isotopic signature without significant contamination or dilution by lithospheric sources.
Red Sea-Gulf of Aden
The Red Sea is a rift zone at a transient stage between continued development or failure where alkali volcanism dominates52 (Supplementary Fig. 3a). The oldest known oceanic crust formed ~5 Ma ago at about 17°N, and since then oceanic spreading has developed progressively northwards61. A pure plume ‘C’ isotopic signature is evident in basalts from Ramad Seamount (∼17°N) and in basanites from Jizan volcanic field located about 200 km to the east on the coastal plain61 (Fig. 5). In the Gulf of Aden, where seafloor spreading is well established, plume C lavas occur at ∼46°E52. An apparent mixing/dilution array between pure plume ‘C’ and DMM is indicated by alkali basalts from the Zubair (∼15°N) and Hanish-Zukur (∼14°N) archipelagos52, lavas from the rift zone extending northwest of Ramad, and from the Sheba Rift in the Gulf of Aden (Figs. 4 and 5). Another source of contamination of the plume C signature is subcontinental mantle lithosphere, which has affected lavas from the intersection of the Sheba Ridge and the African margin (Tadjoura Trough, Gulf of Tadjoura and Asal Rift)52 (Fig. 5). Schilling et al.52 interpret the Sheba spreading ridge in the Gulf of Aden and its SW extension into the Tadjour Trough, Gulf of Tadjoura and the Asal Rift in terms of mixing between Pan-African continental lithosphere, the Afar mantle plume, and DMM. Moreover, these lavas lie on Sr–Nd–Pb isotopic arrays defined by Late Oligocene–Quaternary continental basalts from the southern end of the onshore Yemen Traps62 and the Hamdan volcanic field to the north (15.30°–16°N)61. The Yemen Traps are associated with the Red Sea-Gulf of Aden rifting62 and the source of this subcontinental mantle lithosphere is presumed to be related to the Pan-African orogenic events5. The correspondence between the Yemen Traps and the MER Sr–Nd–Pb isotopic arrays suggests that the contamination of the plume ‘C’–DMM array by Pan-African continental lithosphere (e.g. refs. 13,20,51,52) is confined to lavas erupted onshore.
On a global scale, variations in the thickness of the oceanic lithosphere exert a first-order control on the geochemistry of OIB despite other effects such as fertile mantle compositional heterogeneity. That is, the lithosphere thickness limits the mean extent and pressure (depth) of melting63,64,65. The Mozambique Ridge OIB and other EARS lavas have higher Nb/Yb and TiO2/Yb ratios than MORB due to the thicker lithospheric cap resuting in lower degrees of melting at greater depth with residual garnet (Fig. 4). The intensity of the garnet signature in OIB melts is also affected by mantle temperature; higher temperatures result in a deeper onset of melting and thus a greater garnet signature for a given lithosphere thickness. The high Th/Nb and Ti/Yb ratios (Fig. 4) show that the Mozambique Ridge lavas erupted on older, thickened lithosphere (high mean pressure and low mean extent of melting)63,64,65,66. Smaller degrees of melting beneath thicker lithosphere will tend to yield melts with higher incompatible trace element concentrations and a lower depleted mantle contribution, which are less susceptible to contamination.
Southern Somali Basin
The magma-poor southern half of the EARS extends offshore into the Somali Basin along the Comoros-Mayotte and Madagascar tectono-volcanic system24,36 (Fig. 1). Grande Comore, the youngest of the Comoro islands, is composed of two active volcanoes, Karthala and La Grille, whereas volcanism on Mayotte started roughly 8 ± 1 Ma37,38. The overall isotopic variation of lavas from the islands of Grande Comore and Mayotte66 is explained by mixing between a plume source with a nearly uniform isotopic and chemical composition and alkalic low-degree melts of metasomatized oceanic lithospheric mantle67,68,69. A few samples from Mayotte and to a lesser extent La Grille show a pure plume ‘C’ signature (Fig. 5). These lavas represent lower degree melts (Fig. 4) of the metasomatized oceanic lithospheric mantle68. In contrast, the non-plume ‘C’-like Karthala alkali olivine basalts are the result of mixing between plume melts and higher degree melting of the metasomatized oceanic lithospheric mantle68. The lower degree La Grille melts might reflect a structural weakness in the 140-Ma-old oceanic lithosphere of the southern Somali Basin70 that allows easy migration of near-primary plume melts to the surface68.
In summary, low-degree melts of pure superplume ‘C’ mantle generated under thickened oceanic lithosphere are transported rapidly to surface offshore via the EARS in the southern Somalia Basin. But in contrast to the Red Sea-Gulf of Aden and the Mozambique Ridge, long-term plume-related metasomatized oceanic lithospheric mantle represents an additional source of contamination.
The EARS extends offshore along the Comoros-Mayotte and Madagascar system and as far south as the Davie Ridge where it trends NNE–SSW across the Mozambique Channel and the Mozambique Ridge24 (Supplementary Fig. 3). Seismic reflection and multibeam data24 and references therein show that activity along a fault zone related to EARS is associated with the development of seamounts, dykes and lava flows in the Mozambique Channel71,72 and the young volcanic domes on the Mozambique Ridge and in the northern Natal Valley35 (Supplementary Fig. 3). These volcanic edifices most likely developed initially during the Mid-Miocene71,72. We show here that the 7 Ma basanites-alkaline basalts from the Mozambique Ridge volcanic domes express a pure plume ‘C’ isotopic signature identical to that of Jizan-Ramad lavas in the Red Sea (Fig. 5). Trace element ratios indicate that these lavas result from small degrees of melting in the garnet stability field (Fig. 4). We argue that, as in the case of plume ‘C’ samples from the Red Sea-Gulf of Aden, the low mean extent of melting and absence of thick continental lithosphere minimizes dilution/contamination. This inference agrees with potential field data and magnetic lineations (Fig. 2) showing that the entire Natal Valley and Mozambique Ridge is floored by oceanic crust emplaced between 157.1–144 Ma and 144–131.7 Ma, respectively, with an anomalous thick oceanic layer 3 and/or significant magmatic underplate (refs. 26,31 and references therein) (Fig. 2).
In summary, we argue that as in the Red Sea and the Southern Somali Basin, the Mozambique Ridge lavas express the pure isotopic ‘C’ signature of the African superplume where complex tectonic settings such as thickened lithosphere and deep faults associated with the EARS facilitate rapid rise of low-volume melts to the surface without significant contamination/dilution by SCLM or DMM.
Non-thermal drivers of melting
We consider now various potential drivers of melting along the EARS that do not require a purely thermal superplume or its interaction with thinned/rapidly thinning lithosphere. Plate stretching in Ethiopia at different times during rift development seems to have generated large volumes of decompression melt in the asthenosphere leading to the lower seismic velocities observed in the underlying mantle (e.g. refs. 17,73,74).
According to Rooney et al.17, the compositional heterogeneity in the thermochemical superplume in the lower mantle12 is likely due to recycled slab material that has been converted into eclogites and pyroxenites (e.g. ref. 75). This suggestion is consistent with the apparent alignment of the EARS with the eastern side of the African Large-low-shear-wave-velocity provinces (LLSVPs) at the base of the mantle formed by the accumulation of piles of subducted ocean crust over Earth's history76,77,78. Slab mantle carries with it carbonate (CO2) that can trigger large-volume deep melting in both the recycled crust and associated peridotite host79, that likely contributes significantly to the low seismic wave speeds that characterize the East African mantle17. This notion is consistent with long-established abundant CO2 outgassing along the magma-rich northern half of the EARS80,81,82,83. Moreover, Lee et al.83 find that significant volumes of CO2, probably sourced from upper mantle or lower-crustal magma bodies, is transferred from upper mantle or lower-crustal magma bodies along the deep faults away from active volcanic centres (e.g., Rungwe) in the EARS. Subduction-related CO2-assisted large-volume melting can explain the apparent contradiction between the relatively cool mantle temperatures (+140 to +170 °C) and markedly low seismic wave speeds associated with the magma-rich northern half of the EARS17.
Superplume material in the upper mantle is also likely to occur as inherently more fusible mantle domains. For example, Rooney et al. 84 conclude that the widespread distribution of easily fusible lithospheric ‘metasomes’ within the EARS continental lithosphere mantle may facilitate magma generation without the need for substantial lithospheric thinning or elevated mantle potential temperatures. CO2 might also be an important volatile phase contributing to small volume partial melting of small-scale fusible mantle domains85 transferred from upper-mantle or lower-crustal magma bodies along the deep faults away from active volcanic centres in the EARS83.
Small-scale convection is a little-understood potential driver of low-volume EARS melting17. Small upwellings emanating from the African superplume are inferred petrologically48 and seismically86, and, recent tomography models for east Africa reveal that the scale of upwellings under the magma-rich half of the EARS is smaller than expected for lower mantle plume sources87,88.
In summary, large-volume melting along the continental EARS leads to contamination of the superplume signature by melting of (metasomatized) lithospheric sources. The Sr, Nd, and Pb isotopic superplume signature ‘C’ is seen most clearly in offshore lavas, where the EARS can act to transfer uncontaminated low-volume melts of more fusible (fertile ± CO2), relatively cool (TP that ranges from ambient mantle to only 1490 °C), widely distributed plume material to the surface, possibly in association with small-scale plume convection.
Rare gas vs. solid isotopic tracers
Trace gas signatures such as the high 3He/4He isotopic ratios in lavas from the Ethiopia Rift and Rungwe are a potential tracer of deep-seated plumes22. Nevertheless, they cannot distinguish between the presence of a single superplume source located in the EARS mantle, or if the deeper superplume is connected directly to the shallow mantle via multiple (plume) upwellings or indirectly via multiple mantle plumes rising from one or more boundary layers23. Halldórsson et al.23 show that combining He and Ne isotopes provide new insights into key aspects of the EARS mantle not possible using He isotopes alone. One finding is that there is a common mantle plume source beneath the magma-rich northern half of the EARS because hyperbolic mixing trajectories are compatible with admixture between an assumed PLUME and depleted (DMM) or subcontinental lithospheric (SCLM) mantle source endmembers. However, the He–Ne isotopic signature of their assumed PLUME source encompasses the range of many oceanic hot spots, such as Iceland23. Moreover, the authors note the extreme sensitivity of Ne isotopes to relatively small additions of the PLUME endmember to DMM and SCLM. A case in point is the hyperbolic mixing trajectory between PLUME and SCLM which provides the best fit to data from the Kenyan and Western rifts. But just a small amount of SCLM has a huge effect on 4He/3He, such that the lavas are infered to have up to 80% of this component (see yellow symbols in their Fig. 3).
A further complication in extending the use of trace gases to map the distribution of superplume mantle is the CO2-assisted large-scale melt production contributing significantly to the low seismic wave speeds in the East African mantle17. The ‘outgassing' of abundant CO2 acts as a carrier phase for the trace gases, as is proposed to explain the decoupling of helium from Sr–Nd–Pb in the Hawaiian plume89. Thus, trace gases behave differently from the non-volatile plume tracers such as Sr–Nd–Pb and reflect therefore the spatial decoupling of CO2 from the superplume. High CO2 flux from the superplume will also contaminate/dilute the He–Ne plume signature with variable amounts of SCLM and DMM. If, for example, the large-scale CO2 flux from the superplume differs between the magma-poor and magma-rich halves of the EARS then hyperbolic mixing trajectories will not predict the same/valid He–Ne superplume signature due to mixing with variable amounts of SCLM and DMM. In short, while hyperbolic mixing curves can provide a best estimate for the He–Ne isotopic signature of the African superplume it cannot be used as a robust isotopic tracer for superplume mantle. In contrast Sr, Nd and Pb isotopes can potentially measure directly a common plume isotopic signature, in part because the concentration contrast between plume and SCLM is far less significant. Thus, we report here the first robust, directly measured viable isotopic signature for tracking the influence of superplume in EARS lavas.
In summary, we have sampled basanites-alkaline basalts from one of the small domes on the Mozambique Ridge. These volcanic domes are located along the offshore southern extension of the EARS into the Indian Ocean on 144–157 Ma igneous crust. A ∼7 Ma 40Ar/39Ar age for these OIB lavas shows that the widespread youngest (after 10 Ma) phase of EARS magmatism extends from the Red Sea as far south as the Mozambique Ridge. The OIB lavas have an Sr–Nd–Pb isotopic signature (‘C’), which is also seen in lavas from the other ends of the EARS, at its offshore extension into the Red Sea and Somalia Basin. Beneath the continental EARS, the ‘C’ component is diluted due to contamination by large-volume melting of (metasomatized) lithospheric sources, but its presence can be inferred from variations in Sr–Nd–Pb isotope space. We conclude that the pure isotopic superplume signature ‘C’ is only sampled offshore where the EARS can act to transfer uncontaminated low-volume melts of more fusible (fertile ± CO2), relatively cool (TP that ranges from ambient mantle to only 1490 °C), widely distributed plume material to the surface, possibly in association with small-scale plume convection. These offshore rock samples provide the first sound evidence that superplume material is present in the magma-poor southern half of the EARS, far from the very-low seismic velocities associated with the magma-rich northern half. We argue that because the EARS can tap pure plume ‘C’ lavas wherever the tectonic setting is appropriate then common ‘plume ‘C’ superplume material must be widely distributed in the upper mantle under the entire EARS from the Mozambique Ridge to the Red Sea-Gulf of Aden. This finding implies that superplume material contributes to EARS magmatism not only in northeast Africa but along the length of the EARS from the Red Sea to southern Mozambique. We conclude therefore that we have isotopically tracked for the first time superplume mantle the length of Africa from the Indian Ocean to the Red Sea, which is consistent with seismic mantle images of a single deep-seated superplume with a more-or-less homogeneous isotopic composition. Our finding seems to offers some broader perspectives about the African superplume that raise some interesting questions for future lines of research as follows: Evidence that superplume mantle is associated with the magma-poor southern half of the EARS implies that the C mantle is reaching the EARS regardless of whether it is magma-rich or the existence of anomalously low mantle velocities (Fig. 6). This observation is consistent with the suggestion that the markedly low mantle velocities in the magma-rich northern half of the EARS reflect the thermochemical structure of the superplume due to, for example, recycling of crust into the mantle carrying with it carbonate (CO2) that can trigger deep melting. A further perspective is that it is increasingly more feasible to measure Sr–Nd–Pb signatures in melt inclusions in primary minerals90 that might carry the pure superplume ‘C’ signature to the surface. These primary melts lock in the ‘C’ signature before it can be overwhelmed by contamination from large-volume melting of lithospheric sources. Thus, in due course the superplume ‘C’ fingerprint could be used to track superplume mantle in contaminated continental EARS lavas.
Approximately 0.05 g of sample was accurately weighed into a Teflon beaker, and digested in 1 ml 15 M HNO3 and 3 ml 12 M HF for 12 h in sealed beakers on a hotplate at 80 °C. After cooling, 0.2 ml of HClO4 was added to the sample, and the solution evaporated to incipient dryness at 120 °C. Two millilitres of 15 M HNO3 was added to the sample, and evaporated to near dryness, and this step was repeated twice before increasing the hotplate temperature to 150 °C and fuming off excess HClO4. The sample was then redissolved in 4 ml 15 M HNO3 and 4 ml H2O, two drops of 12 M HF were added, and the sealed beakers left on a hotplate at 80 °C for 12 h. The samples were then placed in an ultrasonic bath for 30 min, before heating at 80 °C for another 12 h. At this stage, all samples were completely in solution. The sample solutions were then quantitatively transferred to 250 ml HDPE bottles and diluted to 200 g with MQ water to obtain a final solution of 2% HNO3 + 0.002 M HF with a sample dilution factor of about 4000 and total dissolved solids of 250 μg/ml. All reagents used were distilled in Teflon stills, and diluted with MQ 18.2 Ohm water.
Trace element measurements were carried out at the GeoZentrum Nordbayern using a Thermo Scientific X-Series 2 quadrupole inductively coupled plasma mass spectrometer. Samples were introduced into the instrument through a Cetac Aridus 2 desolvating nebulizer system in order to reduce molecular interferences. An ESI SC-2 DX FAST autosampler was used to reduce washout times between samples. The instrument was tuned using a 5 ppb solution of Be, In and U; typical sensitivity for 238U was 2 × 106 counts per second for a sample uptake rate of 50 μl/min. The Ce/CeO ratio was typically >4500, and thus corrections for interference of oxides of Ba and the light rare-earth elements on Eu and Gd were unnecessary. Before each measurement session, the instrument was calibrated using multielement solutions covering the relevant concentration range. A mixed Be, Rh, In and Bi solution (30, 10, 10, 5 ppb) was mixed with the sample online and these elements used as internal standards to correct for instrumental drift. Procedural blanks analysed during this work were negligible for all elements measured. Trace element data for the rock standard BHVO-2 measured as an unknown are given in the table.
Whole-rock powders for Sr, Nd and Pb isotope analysis were leached prior to dissolution. Approximately 1 g of powder was leached with 6 M HCl at 100 °C for 8 h, changing the acid every 2 h, and the remaining residue washed repeatedly with MQ H2O, and then dried. Plagioclase separates prepared for Ar–Ar analysis were rinsed with MQ H2O. For Pb isotope analysis, approximately 70 mg of sample was weighed into a Teflon beaker, and digested overnight in sealed beakers at 70 °C in a mixture of 10 drops 15 M HNO3 and 20 drops 14 M HF. All acids used were double-distilled, except for HF which was purchased as Suprapur grade. The resulting solution was evaporated to near dryness, treated with 15 drops 15 M HNO3, evaporated to complete dryness, redissolved in 20 drops 6 M HCl, evaporated and finally taken up in 20 drops 1 M HCl. The samples were transferred to 2 ml centrifuge tubes, centrifuged and the solution loaded onto ion-exchange columns containing 0.1 ml Eichrom SrSpec resin. Most elements were washed off the resin with 3 ml 1 M HCl, and this fraction was collected for Sr and Nd. Pb was recovered with 2 ml 6 M HCl, and this solution evaporated, redissolved in 1 M HCl and passed a second time through the columns. The final solution was dissolved in 2% HNO3 for mass spectrometry.
The 1 M HCl solution collected from the SrSpec resin was dried down and redissolved in 3.5 M HNO3. The REE were separated using ion-exchange columns containing 0.1 ml Eichrom TRUSpec resin, positioned to drip into a second column containing 0.1 ml SrSpec resin, which retained the Sr. After washing with 1 ml 3.5 M HNO3, the columns were decoupled, washed twice with 1 ml 3.5 M HNO3, and Sr and the REE recovered in H2O and 2.5 M HCl, respectively. Nd was separated from the other REE using Eichrom LnSpec resin in 0.25 M HCl. Blanks were below 120, 18 and 15 pg for Sr, Nd and Pb, respectively.
Sr and Nd isotope measurements were carried out using a Thermo Triton thermal ionization mass spectrometer in static mode. Sr was loaded onto single Ta filaments in 1 ml 1 M H3PO4, and the measured isotope ratios corrected for instrumental mass fractionation using 86Sr/88Sr = 0.1194. 87Rb interference was monitored and corrected for by measuring 85Rb, but was negligible for most samples. The NBS987 Sr standard yielded an 87Sr/86Sr value of 0.710266 ± 0.000012 (n = 10) over the period of analysis. Nd was loaded onto the Ta filament of a double Ta–Re filament assembly and analysed as the metal. A correction for mass fractionation was applied assuming 144Nd/146Nd = 0.7219. An in-house Nd standard yielded 143Nd/144Nd = 0.511539 ± 0.000008 (n = 6), equivalent to 0.511851 for the La Jolla Nd standard.
The Pb fraction was dissolved in 2% HNO3 to obtain a Pb concentration of about 30 ng/g, and spiked with approximately 3 ng/g SRM997 Tl standard. Isotope measurements were carried out on a Thermofisher Neptune Plus multicollector plasma mass spectrometer in static mode, using a 205Tl/203Tl ratio of 2.3871 to correct measured Pb isotope ratios for instrumental mass bias. Sample measurements were bracketed by measurements of the SRM981 Pb standard, which were used for external normalization assuming the values of ref. 91. Accuracy and reproducibility, as determined by multiple analysis of rock standards, was better than 80 ppm.
Sample preparation: The groundmass samples were prepared following the methods of ref. 92. The 200–180 μm samples measured at Oregon State were cleaned in a series of hour-long acid baths, progressing from 1 N HCl to 6 N HCl to 1 N HNO3 to 3 N HNO3, followed by a final milli-Q water bath. The 355–200 μm samples measured at the VU University were cleaned in 1 N HNO3 for 2 h, followed by an hour-long milli-Q water bath. Each separate was picked by hand under a binocular microscope to ensure the removal of alteration and to confirm the purity of the separate.
Oregon State University: Groundmass samples were irradiated for 6 h in the CLICIT position at the Oregon State University TRIGA reactor. Incremental heating experiments were conducted for each sample. Irradiated samples were loaded into copper planchettes for analysis using a Thermo Scientific ARGUS-VI multicollector mass spectrometer at the OSU Argon Geochronology Laboratory following the procedure described in ref. 93. All ages are calculated relative to Fish Canyon Tuff (FCT) sanidine with an age of 28.201 Ma94 and using the decay constants after ref. 95.
The correction factors for neutron interference reactions at the TRIGA are (2.64 ± 0.02) × 10−4 for (36Ar/37Ar)Ca, (6.73 ± 0.04) × 10−4 for (39Ar/37Ar)Ca, (1.21 ± 0.003) × 10−2 for (38Ar/39Ar)K and (8.6 ± 0.7) × 10−4 for (40Ar/39Ar)K. Ages were calculated using the ArArCALC v2.7.052 software of ref. 96, with errors including uncertainties on the blank corrections, irradiation constants, J-curve, collector calibrations, mass fractionation, and the decay of 37Ar and 39Ar.
VU University: The groundmass samples were irradiated together with Fish Canyon Tuff (FCT) sanidine for 18 h at the Oregon State University TRIGA reactor in the cadmium shielded CLICIT facility (irradiation ID VU107).40Ar/39Ar analyses were performed at the geochronology laboratory of the VU University on a Helix MC noble gas mass spectrometer. Single grains of FCs were fused and multiple grain groundmass samples were step-heated with a Synrad CO2 laser beam and released gas was exposed to a Lauda cooler (−70 °C) and hot NP10 and St172 getters and analysed on the Helix MC. The five argon isotopes are measured simultaneously with 40Ar on the H2-Faraday position with a 1013 Ω resistor amplifier, 39Ar on the H1-Faraday with a 1013 Ω resistor amplifier, 38Ar on the AX-CDD, 37Ar on the L1-CDD and 36Ar on the L2-CDD (CDD—compact discrete dynode). Gain calibration for the CDDs is done by peak jumping a CO2 reference beam on all detectors in dynamic mode. All intensities are corrected relative to the L2 detector. Air pipettes are run ~every 10 h and are used for mass discrimination corrections.
All ages are calculated relative to FCT of 28.201 Ma94 with ref. 95 decay constants. The atmospheric air value of 298.56 from ref. 97 is used. Detailed analytical procedures for the Helix MC are described in ref. 98. The correction factors for neutron interference reactions are (2.64 ± 0.02) × 10-4 for (36Ar/37Ar)Ca, (6.73 ± 0.04) × 10−4 for (39Ar/37Ar)Ca, (1.21 ± 0.003) × 10−2 for (38Ar/39Ar)K and (8.6 ± 0.7) × 10−4 for (40Ar/39Ar)K. All errors are quoted at the 1σ level and include all analytical errors. Data were reduced using the ArArCALC v2.7.052 software of ref. 96, with errors including uncertainties on the blank corrections, irradiation constants, J-curve, collector calibrations, mass fractionation, and the decay of 37Ar and 39Ar.
40Ar/39Ar step-heating experiments are widely assessed using criteria as follows:
An acceptable age plateau includes at least 50% of the gas released with a mean square weighted deviation (MSWD) of approximately 1.0.
Shows an inverse isochron with a 40Ar/36Ar intercept of about 295.5 ± 2σ (indicating equilibration with atmospheric argon).
Has concordant plateau and inverse isochron ages within 2σ internal error (validating the assumption of the 295.5 ratio used in determining the plateau age).
It is evident from the images of the samples used in this study that the smallest sample DL2-2 is significantly more altered compared to the other two samples. This is an obvious explanation for why mildly leached 355–200 μm groundmass did not give a plateau age. The influence of alteration on the inverse isochron 40Ar/39Ar intercept values is demonstrated by how they vary for DL3-5 depending on acid leaching. Mild acid leaching gives an intercept value indicating excess argon (i.e., greater than the atmospheric value of 295.5) whereas strong acid leaching gives an atmospheric/sub-atmospheric value. Yet, both analyses give the same plateau age so validating the assumption of the 295.5 ratio used in their calculation. Another important reason that plateau ages with non-atmospheric inverse isochron intercepts are acceptable in the case of this study is that heating steps are high in 40Ar(r) so the data points used for calculating the inverse isochrones plot close to the 39Ar/40Ar axis making it very difficult to pin any case to precisely define the 40Ar/36Ar intercept value. In summary, we consider that the plateau ages for the massive boulder sample DL3-5 most precisely defines the crystallization age of the dome samples.
The authors declare that all the data for the 40Ar/39Ar age determinations and geochemical analyses supporting the findings of this study are available within the paper and its supplementary information files.
Burke, K. The African plate. S. Afr. J. Geol. 99, 339–410 (1996).
Ebinger, C. & Sleep, N. Cenozoic magmatism throughout East Africa resulting from impact of a single plume. Nature 395, 788–791 (1998).
Buitner, S. How plumes help to break plates. Nature 513, 36–37 (2014).
George, R., Rogers, N. & Kelley, S. Earliest magmatism in Ethiopia: evidence for two mantle plumes in one flood basalt province. Geology 26, 923–926 (1998).
Fishwick, S. & Bastow, I. D. Towards a better understanding of African topography: a review of passive-source seismic studies of the African crust and upper mantle. Geol. Soc. Lond. Spec. Publ. 357, 343–371 (2011).
Ritsema, J., Deuss, A. A., Van Heijst, H. J. & Woodhouse, J. H. S40RTS: a degree-40 shear-velocity model for the mantle from new Rayleigh wave dispersion, teleseismic traveltime and normal-mode splitting function measurements. Geophys. J. Int. 184, 1223–1236 (2011).
Chang, S. J. & Van der Lee, S. Mantle plumes and associated flow beneath Arabia and East Africa. Earth Planet. Sci. Lett. 302, 448–454 (2011).
Gallacher, R. J. et al. The initiation of segmented buoyancy-driven melting during continental breakup. Nat. Commun. 7, 13110 (2016).
French, S. W. & Romanowicz, B. A. Broad plumes rooted at the base of the Earth's mantle beneath major hotspots. Nature 525, 95–99 (2015).
Nyblade, A. A. The upper-mantle low-velocity anomaly beneath Ethiopia, Kenya, and Tanzania: constraints on the origin of the African superswell in eastern Africa and plate versus plume models of mantle dynamics. Geol. Soc. Am. Spec. Pap. 478, 37–50 (2011).
Hansen, S., Nyblade, A. & Benoit, M. Mantle structure beneath Africa and Arabia from adaptively parameterized P-wave tomography: implications for the origin of Cenozoic Afro-Arabian tectonism. Earth Planet. Sci. Lett. 319–320, 23–34 (2012).
Ni, S., Tan, E., Gurnis, M. & Helmberger, D. Sharp sides to the African superplume. Science 296, 1850–1852 (2002).
Rogers, N. W. Basaltic magmatism and the geodynamics of the East African Rift. Geol. Soc. Spec. Publ. 259, 77–93 (2006).
Ritsema, J., van Heijst, H. J. & Woodhouse, J. H. Complex shear wave velocity structure beneath Africa and Iceland. Science 286, 1925–1928 (1999).
Davies, G. A. A channelled plume under Africa. Nature 395, 743–744 (1998).
Herzberg, C. & Asimow, P. D. Petrology of some oceanic island basalts: PRIMELT2.XLS software for primary magma calculation. Geochem. Geophys. Geosyst. 9, Q09001 (2008).
Rooney, T. O., Herzberg, C. & Bastow, I. D. Elevated mantle temperature beneath East Africa. Geology 40, 27–130 (2012).
Rogers, N. et al. Two mantle plumes beneath the East African Rift system; Sr, Nd and Pb isotope evidence from Kenya Rift basalts. Earth Planet. Sci. Lett. 176, 387–400 (2000).
George, R. M. & Rogers, N. W. Plume dynamics beneath the African Plate inferred from the geochemistry of the tertiary basalts of southern Ethiopia. Contrib. Mineral. Petrol. 144, 286–304 (2002).
Rooney, T. O. et al. Upper mantle pollution during Afar Plume-continental rift interaction. J. Petrol. 53, 365–389 (2012).
Castillo, P., Hilton, D. & Halldórsson, S. Trace element and Sr-Nd-Pb isotope geochemistry of Rungwe Volcanic Province, Tanzania: implications for a superplume source for East Africa Rift magmatism. Front. Earth Sci. 2, https://doi.org/10.3389/feart.2014.00021 (2014).
Hilton, D. R. et al. Helium isotopes at Rungwe Volcanic Province, Tanzania, and the origin of East African Plateaux. Geophys. Res. Lett. 38, L21304 (2011).
Halldórsson, S. A., Hilton, D. R., Scarsi, P., Abebe, T. & Hopp, J. A common mantle plume source beneath the entire East African Rift System revealed by coupled helium‐neon systematics. Geophys. Res. Lett. 4, 2304–2311 (2014).
Deville, E. et al. Active fault system across the oceanic lithosphere of the Mozambique Channel: implications for the Nubia–Somalia southern plate boundary. Earth Planet. Sci. Lett. 502, 210–220 (2018).
Jokat, W., Boebel, T., Koenig, M. & Meyer, U. Timing and geometry of early Gondwana breakup. J. Geophys. Res. 108, 2428 (2003).
König, M. & Jokat, W. Advanced insights into magmatism and volcanism of the Mozambique Ridge and Mozambique Basin in the view of new potential field data. Geophys. J. Int. 180, 158–180 (2010).
Leinweber, V. T. & Jokat, W. The Jurassic history of the Africa–Antarctica Corridor—new constraints from magnetic data on the conjugate continental margins. Tectonophysics 530, 87–101 (2012).
Fischer, M. D., Uenzelmann-Neben, G., Jacques, G. & Werner, R. The Mozambique Ridge: a document of massive multistage magmatism. Geophys. J. Int. 208, 449–467 (2017).
Jacques, G. et al. Nature and origin of the Mozambique Ridge, SW Indian Ocean. Chem. Geol. https://doi.org/10.1016/j.chemgeo.2018.12.027 (2018).
Mueller, C. O. & Jokat, W. Geophysical evidence for the crustal and distribution of magmatism along the central coast of Mozambique. Tectonophysics 712–713, 684–703 (2017).
Mueller, C. O. & Jokat, W. The initial Gondwana break-up: a synthesis based on new potential field data of the Africa-Antarctica Corridor. Tectonophysics 750, 301–328 (2019).
Mougenot, D., Recq, M., Virlogeux, P. & Lepvrier, C. Seaward extension of the East African Rift. Nature 321, 599–603 (1986).
Jokat, W. The expedition of the research vessel Pelagia to the natal basin and the Mozambique ridge in 2009 (Project AISTEK III). Alfred-Wegener-Institut für Polar- und Meeresforschung, 67, http://epic.awi.de (2009).
Jokat, W. The expedition of the research vessel ‘Sonne’ to the Mozambique Basin in 2014 (SO-230). Alfred-Wegener-Institut, Helmholtz-Zentrum für Polar- und Meeresforschung, 125, http://epic.awi.de (2014).
Wiles, E., Green, A., Watkeys, M., Jokat, W. & Krocker, R. Anomalous seafloor mounds in the northern Natal Valley, southwest Indian Ocean: implications for the East African Rift System. Tectonophysics 630, 300–312 (2014).
Franke, D. et al. The offshore East African Rift system: structural framework at the toe of a juvenile rift. Tectonics 34, 2086–2104 (2015).
Emerick, C. M. & Duncan, R. A. Age progressive volcanism in the Comoro Archipelago, western Indian Ocean and implications for Somali plate tectonics. Earth Planet. Sci. Lett. 60, 415–428 (1982).
Nougier, J., Cantagrel, J. M. & Karche, J. P. The Comoro archipelago in the western Indian Ocean: volcanology, geochronology and geodynamic setting. J. Afr. Earth Sci. 5, 135–144 (1986).
Mesko, G. T. et al. The timing of early magmatism and extension in the Southern East African rift: tracking geochemical source variability with 40Ar/39Ar geochronology at the Rungwe Volcanic Province, SW Tanzania. AGU Fall Meeting V51A–V54730, (San Francisco, CA 2014).
Ebinger, C. J., Deino, A. L., Drake, R. A. & Tesha, A. L. Chronology of volcanism and rift basin propagation: Rungwe volcanic province, East Africa. J. Geophys. Res. 94, 15785–15803 (1989).
Ebinger, C. J., Yemane, T., WoldeGabriel, G. & Aronson, J. Late Eocene–recent volcanism and faulting in the southern Main Ethiopian rift system. J. Geol. Soc. Lond. J. 150, 99–108 (1993).
Roberts, E. M. et al. Initiation of the western branch of the East African Rift coeval with the eastern branch. Nat. Geosci. 5, 289–294 (2012).
Bagdasaryan, G., Gerasimovskiy, V. I., Polykov, A. I. & Gukasyan, R. K. Age of volcanic rocks in the rift zones of East Africa. Geokhimiya 1, 84–90 (1973).
Mana, S. et al. Geochronology and geochemistry of the Essimingor volcano: melting of metasomatized lithospheric mantle beneath the North Tanzanian Divergence zone (East African Rift). Lithos 155, 310–325 (2012).
Mana, S., Furman, T., Turrin, B. D., Feigenson, M. D. & Swisher, C. C. III Magmatic activity across the East African North Tanzanian divergence zone. J. Geol. Soc. 72, 368–389 (2015).
Davidson, A. & Rex, D. C. Age of volcanism and rifting in southern Ethiopia. Nature 283, 657–658 (1980).
Ebinger, C. et al. Rift deflection, migration, and propagation: linkage of the Ethiopian and Eastern rifts. Afr. Geol. Soc. Am. Bull. 102, 163–176 (2000).
Kieffer, B. et al. Flood and shield basalts from Ethiopia: magmas from the African superswell. J. Petrol. 45, 793–834 (2004).
Wolfenden, E., Ebinger, C., Yirgu, G., Deino, A. & Ayalew, D. Evolution of the northern main Ethiopian rift: birth of a triple junction. Earth Planet. Sci. Lett. 224, 213–228 (2004).
Leroy, S. et al. Recent off-axis volcanism in the eastern Gulf of Aden: implications for plume–ridge interaction. Earth Planet. Sci. Lett. 293, 140–153 (2010).
Furman, T. Geochemistry of East African Rift basalts: an overview. J. Afr. Earth Sci. 48, 147–160 (2007).
Schilling, J.-G., Kingsley, R. H., Hanan, B. B. & Mccully, B. L. Nd-Sr-Pb isotopic variations along the Gulf of Aden: evidence for Afar mantle plume continental lithosphere interaction. J. Geophys. Res. 97, 10927–10966 (1992).
Hanan, B. B. & Graham, D. W. Lead and helium isotope evidence from oceanic basalts for a common deep source of mantle plumes. Science 272, 991–995 (1996).
Chakrabarti, R., Basu, A. R., Santo, A. P., Tedesco, D. & Vaselli, O. Isotopic and geochemical evidence for a heterogeneous mantle plume origin of the Virunga volcanics, Western rift, East African Rift system. Chem. Geol. 259, 273–289 (2009).
Rogers, N. W., James, D., Kelley, S. P. & De Mulder, M. The generation of potassic lavas from the eastern Virunga province, Rwanda. J. Petrol. 39, 1223–1247 (1998).
Rudnick, R. L., McDonough, W. F. & Chappell, B. W. Carbonatite metasomatism in the northern Tanzanian mantle: petrographic and geochemical characteristics. Earth Planet. Sci. Lett. 114, 463–475 (1993).
Rosenthal, A., Foley, S. F., Pearson, D. G., Nowell, G. M. & Tappe, S. Petrogenesis of strongly alkaline primitive volcanic rocks at the propagating tip of the western branch of the East African Rift. Earth Planet. Sci. Lett. 284, 236–248 (2009).
Foley, S. F., Link, K., Tiberindw, J. B. & Barifaijo, E. Patterns and origin of igneous activity around the Tanzanian craton. J. Afr. Earth Sci. 62, 1–18 (2012).
Vollmer, R. & Norry, M. J. Unusual isotopic variations in Nyiragongo nephelinites. Nature 301, 141–143 (1983).
Vollmer, R. & Norry, M. J. Possible origin of K-rich volcanic rocks from Virunga, East Africa, by metasomatism of continental crust material: Pb, Nd and Sr isotopic evidence. Earth Planet. Sci. Lett. 64, 374–386 (1983).
Volker, F., Altherr, R., Jochum, K.-P. & McCulloch, M. T. Quaternary volcanic activity of the southern Red Sea: new data and assessment of models on magma sources and Afar plume-lithosphere interaction. Tectonophysics 278, 15–29 (1997).
Chazout, G. & Bertrand, H. Mantle sources and magma-continental crust interactions during early Red Sea-Gulf of Aden rifting in southern Yemen: elemental and Sr, Nd, Pb isotope evidence. J. Geophys. Res. 98, 1819–1835 (1993).
Niu, Y. L. & O'Hara, M. J. Global correlations of ocean ridge basalt chemistry with axial depth: a new perspective. J. Petrol. 49, 633–664 (2008).
Niu, Y. L. & Hékinian, R. Spreading rate dependence of the extent of mantle melting beneath ocean ridges. Nature 385, 326–329 (1997).
Humphreys, E. R. & Niu, Y. On the composition of ocean island basalts (OIB): the effects of lithospheric thickness variation and mantle metasomatism. Lithos 112, 118–136 (2009).
Späth, A., Le Roex, A. P. & Duncan, R. A. The geochemistry of lavas from the Comoro Archipelago, Western Indian Ocean: petrogenesis and mantle source region characteristics. J. Petrol. 37, 961–991 (1996).
Class, C. & Goldstein, S. L. Plume–lithosphere interactions in the ocean basins: constraints from the source mineralogy. Earth Planet. Sci. Lett. 150, 245–260 (1997).
Class, C., Goldstein, S. L., Altherr, R. & Bachèchlery, P. The process of plume–lithosphere interaction in the ocean basins—the case of Grande Comore. J. Petrol. 39, 881–903 (1998).
Class, C., Goldstein, S. L., Stute, M., Kurz, M. D. & Schlosser, P. Grande Comore island: a well-constrained “low 3He/4He” mantle plume. Earth Planet. Sci. Lett. 233, 391–409 (2005).
Coffin, M. F. & Rabinowitz, P. D. Reconstruction of Madagascar and Africa: evidence from the Davie Fracture Zone and Western Somali Basin. J. Geophys. Res. 92, 9385–9406 (1987).
Courgeon, S. et al. Growth and demise of Cenozoic isolated carbonate platforms: new insights from the Mozambique Channel seamounts (SW Indian Ocean). Mar. Geol. 380, 90–105 (2016).
Courgeon, S. et al. Impact of tectonic and volcanism on the Neogene evolution of isolated carbonate platforms (SW Indian Ocean). Sediment. Geol. 355, 114–131m (2017).
Bastow, I. D., Pilidou, S., Kendall, J. M. & Stuart, G. W. Melt-induced seismic anisotropy and magma assisted rifting in Ethiopia: evidence from surface waves. Geochem. Geophys. Geosyst. Q0AB05, https://doi.org/10.1029/2010GC003036 (2010).
Bastow, I. D. & Keir, D. The protracted development of the continent-ocean transition in Afar. Nat. Geosci. 4, 248–250 (2011).
Kogiso, T., Hirschmann, M. M. & Frost, D. J. High-pressure partial melting of garnet pyroxenite: possible mafic lithologies in the source of ocean island basalts. Earth Planet. Sci. Lett. 216, 603–617 (2003).
Burke, K., Steinberger, B., Torsvik, T. & Smethurst, M. Plume generation zones at the margins of large low shear velocity provinces on the core–mantle boundary. Earth Planet. Sci. Lett. 265, 49–60 (2008).
Torsvik, T. H., Burke, K., Steinberger, B., Webb, S. J. & Ashwal, L. D. Diamonds sampled by plumes from the core–mantle boundary. Nature 466, 352–355 (2010).
Niu, Y. Origin of the LLSVPs at the base of the mantle is a consequence of plate tectonics—a petrological and geochemical perspective. Geosci. Front. 9, 1265–1278 (2018).
Dasgupta, R. & Hirschmann, M. M. Melting in the Earth’s deep upper mantle caused by carbon dioxide. Nature 440, 659–662 (2006).
Craig, H., Lupton, J. E. & Horowitz, R. Isotopic geochemistry and hydrology of geothermal waters in the Ethiopian Rift Valley. Scripps Inst. Oceanogr. Tech. Rep. 140, 77–14 (1977).
Fischer, T. P. et al. Upper−mantle volatile chemistry at Oldoinyo Lengai volcano and the origin of carbonatites. Nature 459, 77–80 (2009).
Barry, P. H., Hilton, D. R., Fischer, T. P., de Moor, J. M. & Mangasini, F. Helium and carbon isotope systematics of cold “mazuku” CO2 vents and hydrothermal gases and fluids from Rungwe volcanic province, southern Tanzania. Chem. Geol. 339, 141–156 (2013).
Lee, H. et al. Massive and prolonged deep carbon emissions associated with continental rifting. Nat. Geosci. 9, 145 (2016).
Rooney, T. O., Nelson, W. R., Dosso, L., Furman, T. & Hanan, B. The role of continental lithosphere metasomes in the production of HIMU-like magmatism on the northeast African and Arabian plates. Geology 42, 419–1422 (2014).
Dasgupta, R., Hirschmann, M. M. & Smith, N. D. Partial melting experiments of peridotite+CO2 at 3 GPa and genesis of alkali ocean island basalts. J. Petrol. 48, 2093–2124 (2007).
Bastow, I. D., Nyblade, A. A., Stuart, G. W., Rooney, T. O. & Benoit, M. H. Upper mantle seismic structure beneath the Ethiopian hot spot: rifting at the edge of the African low-velocity anomaly. Geochem. Geophys. Geosyst. 9, Q12022, https://doi.org/10.1029/2008GC002107 (2008).
Civiero, C. et al. Multiple mantle upwellings in the transition zone beneath the northern East‐African Rift system from relative P‐wave travel‐time tomography. Geochem. Geophys. Geosyst. 16, 2949–2968 (2015).
Civiero, C. et al. Small‐scale thermal upwellings under the northern East African Rift from S travel time tomography. J. Geophys. Res. Solid Earth 121, 7395–7408 (2016).
Hofmann, A., Farnetani, C. G., Spiegelman, M. & Class, C. Displaced helium and carbon in the Hawaiian plume. Earth Planet. Sci. Lett. 312, 226–236 (2011).
Koornneef, J. M. et al. TIMS analysis of Sr and Nd isotopes in melt inclusions from Italian potassium-rich lavas using prototype 1013 Ω amplifiers. Chem. Geol. 397, 14–23 (2015).
Todt, W., Cliff, R. A., Hanser, A. & Hofmann, A. W. in Evaluation of a 202Pb– 205Pb Double Spike for High-Precision Lead Isotope Analysis Vol. 95, 9–7 (American Geophysical Union, Washington, DC, 1996).
Koppers, A. A. P. et al. Limited latitudinal mantle plume motion for the Louisville hotspot. Nat. Geosci. 5, 911–917 (2012).
Konrad, K. et al. On the relative motions of long-lived Pacific mantle plumes. Nat. Commun. 9, 854 (2018).
Kuiper, K. F. et al. Synchronizing the rock clocks of Earth history. Science 320, 500–504 (2008).
Min, K. W., Mundil, R., Renne, P. R. & Ludwig, K. R. A test for systematic errors in Ar-40/Ar-39 geochronology through comparison with U/Pb analysis of a 1.1-Ga rhyolite. Geochim. Cosmochim. Acta 64, 63–98 (2000).
Koppers, A. A. P. ArArCALC—software for 40Ar/39Ar age calculations. Comput. Geosci. 5, 605–619 (2002).
Lee, J.-Y. et al. A redetermination of the isotopic abundance of atmospheric Ar. Geochim. Cosmochim. Acta 70, 4507–4512 (2006).
Monster, M. Multi-method palaeointensity data of the geomagnetic field during the past 500 kyrs from European volcanoes. Utrecht Stud. Earth Sci. 117, 103–123 (2016).
LeBas, M. J., LeMaitre, R. W., Streckeisen, A. & Zanettin, B. A chemical classification of volcanic rocks based on the total alkali-silica diagram. J.Petrol. 27, 745–750 (1986).
Pearce, J. Geochemical fingerprinting of oceanic basalts with applications to ophiolite classification and the search for Archean oceanic crust. Lithos 100, 14–48 (2008).
Sun, S. -s. & McDonough, W. F. Chemical and isotopic systematics of oceanic basalts: implications for mantle composition and processes. Geol. Soc. Lond. Spec. Publ. 42, 313–345 (1989)
Mahoney, J. J., Storey, M., Duncan, R. A., Spencer, K. J. & Pringle, M. S. in The Mesozoic Pacific: geology, tectonics and volcanism. Vol. 77 (eds Pringle, M. S. et al.) Geochemistry and age of the Ontong Java Plateau (1993)
Révillon, S., Hallot, E., Arndt, N. T. Chauvel, C. & Duncan, R.A. A complex history for the Caribbean Plateau: petrology, geochemistry and geochronology of the Béata Ridge, South Hispaniola. J. Geol. 108, 641–661 (2000).
Gale, A., Dalton, C. A., Langmuir, C. H., Su, Y. & Schilling, J.-G. The mean composition of ocean ridge basalts. Geochem. Geophys. Geosyst. 14, 489–518 (2013).
Class, C., Goldstein, S. L. & Shirey, S. B. Osmium isotopes in Grande Comore lavas: a new extreme among a spectrum of EM-type mantle endmembers. Earth Planet. Sci. Lett. 284, 219–227 (2009).
Hart, S. R., Hauri, E. H., Oschmann, L. A. & Whitehead, J. A. Mantle plumes and entrainment: isotopic evidence. Science 256, 517–520 (1992).
White, W. M. Oceanic island basalts and mantle plumes: the geochemical perspective. Annu. Rev. Earth Planet. Sci. 38, 133–160 (2010).
This project was funded through a grant by the German Federal Ministry of Education and Research (BMBF 03G0230A, 03G0231A) and AWI internal funding. We thank Captain Detlef Korte and his Crew of RV Sonne for their support and Melanie Hertel for providing the XRF analyses.
The authors declare no competing interests.
Peer review information Nature Communications thanks the anonymous reviewer(s) for their contribution to the peer review of this work. Peer reviewer reports are available.
Publisher’s note Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
About this article
Cite this article
O’Connor, J.M., Jokat, W., Regelous, M. et al. Superplume mantle tracked isotopically the length of Africa from the Indian Ocean to the Red Sea. Nat Commun 10, 5493 (2019) doi:10.1038/s41467-019-13181-7