Polyhydride CeH9 with an atomic-like hydrogen clathrate structure


Compression of hydrogen-rich hydrides has been proposed as an alternative way to attain the atomic metallic hydrogen state or high-temperature superconductors. However, it remains a challenge to get access to these states by synthesizing novel polyhydrides with unusually high hydrogen-to-metal ratios. Here we synthesize a series of cerium (Ce) polyhydrides by a direct reaction of Ce and H2 at high pressures. We discover that cerium polyhydride CeH9, formed above 100 GPa, presents a three-dimensional hydrogen network composed of clathrate H29 cages. The electron localization function together with band structure calculations elucidate the weak electron localization between H-H atoms and confirm its metallic character. By means of Ce atom doping, metallic hydrogen structure can be realized via the existence of CeH9. Particularly, Ce atoms play a positive role to stabilize the sublattice of hydrogen cages similar to the recently discovered near-room-temperature lanthanum hydride superconductors.


The realization of metallic hydrogen is highly desirable because of its attractive properties, such as high energy density, high-temperature superconductivity, and superfluidity. Pressure has been recognized as one of the most straightforward and robust way of getting metallic hydrogen, where changes in bond strength and geometry are induced without the complication of chemical adjustments. Tremendous efforts have been devoted, but unfortunately, solid hydrogen requires very high pressures to get into a metallic state1,2,3,4,5,6. Recently, metallization of solid hydrogen at 495 GPa has been reported, but such high pressure is a challenge for further experimental exploration7. Systematic studies on polyhydrides have indicated that nonhydrogen atoms maybe provide a chemical precompression effect inside hydrogen-rich compounds, which may potentially reduce the pressure required to metallization8. Moreover, these polyhydrides also present intriguing high-temperature superconductivity theoretically, such as H3S with 203 K at 200 GPa9,10, CaH6 with 235 K at 150 GPa11, LaH10 with 280 K at 210 GPa12, and YH10 with 310 K at 250 GPa13. Only the predicted high Tc exceeding 200 K of H3S14,15,16 and LaH1017,18 have been undoubtedly confirmed by experiments thus far. These discoveries have raised new prospects that polyhydrides could become a new family of high-temperature conventional superconductors, but the principal experimental challenge lies in the difficulty of synthesizing the novel hydrogen-rich compounds proposed by theory.

Until recently, polyhydrides were usually synthesized under high pressures combined with high-temperature condition. In these polyhydrides, hydrogen atoms exist in different forms, including unpaired H, H2, and H3 units, and extended H networks. For instance, FeH5 prepared from a laser-heated diamond anvil cell (DAC) above 130 GPa have been proposed as a layered structure built of atomic hydrogen only19. NaH7 was synthesized above 40 GPa and 2000 K, but it presents nonmetallic properties with H3 and H2 units processing higher-frequency vibrons in Raman spectrum20. Subsequent work turned to polyhydrides with three-dimensional hydrogen structure. These polyhydrides might be an analog of high-Tc superconductor and the representative example was reported in a body-centered cubic phase of LaH10 with clathrate H32 cage12, which was synthesized above 170 GPa and 1000 K. The surprising high Tc near room temperature in lanthanum hydride is mainly attributed to an intriguing H clathrate structure with large H-derived electron density of states at Fermi level and the strong electron–phonon coupling related to H cages21. Then, in-depth research in rare earth metal hydrides is urgently needed, including successful synthesis of H clathrate structure and observation of superconductivity.

For these synthesized polyhydrides, the laser-heating treatment at sufficient pressure is the necessary condition of successful synthesis, overcoming the possible energy barrier. In contrast, to obtain polyhydrides only through the high-pressure method is more feasible to explore the promising properties. Here, we report a study of the prototypical Ce hydrides to find the one with atomic-like hydrogen sublattice and high-Tc superconductor through cold-compression engineering. Among the Ce hydrides reported in the past decade, the studies of Ce hydrides are limited with a nonstoichiometric composition range (CeHx, x ≤ 3) by the combination of Ce in excess hydrogen22,23. In this work, the experimental syntheses of Ce polyhydrides have been successfully fulfilled under high pressures up to 159 GPa. Five stoichiometries of Ce polyhydrides are identified from experimental and theoretical results. Especially, we find that synthesized CeH9 has unique clathrate structure with H29 cages and exhibits a structure with atomic hydrogen sublattice.

Results and discussion

Synchrotron X-ray diffraction experiments

The experiments were performed with a direct reaction of Ce and H2 samples up to 159 GPa at room temperature. Compared with previously reported polyhydrides, the current reacted samples without laser heating are reliable enough to detect the X-ray diffraction (XRD) signals. Moreover, excess hydrogen in the sample chamber ensures the possible reaction of polyhydrides (Supplementary Fig. 1). We have identified the formation of Ce polyhydrides under high pressures. The newly synthesized phases were characterized by XRD from 3 to 159 GPa as shown in Fig. 1a. The evolution of d-spacing also proves the multiple phase transitions with increasing pressure (Supplementary Fig. 2). Because of the low-atomic scattering power of hydrogen, what we have directly determined are the positions of Ce atoms from XRD data. We have selected typical XRD patterns in Fig. 1b, and the results reveal dramatic changes in the formation of Ce polyhydrides.

Fig. 1

The evolution of XRD patterns of Ce polyhydrides at selected pressures. a Typical XRD patterns of Ce polyhydrides as a function of pressure upon cold-compression up to 159 GPa at room temperature. The black arrows show the abnormal trends of peaks with increasing pressure. b The Rietveld refinements of CeH3-Pm-3n, CeH4-I4/mmm and CeH9-P63/mmc and Le Bail refinements of CeH9−δ, respectively at selected pressures. The incident wavelength was λ = 0.6199 Å. Excess solid hydrogen remained transparent at 159 GPa as shown in inserted photomicrographs

At 3 GPa, just after the target sample loading into DAC, the diffraction pattern reveals that the sample crystallizes in a face-centered cubic (fcc) structure with the most possible space group Fm-3m (Supplementary Fig. 3). This is reminiscent of the cubic structure of the element Ce at similar pressures, but with significantly large volume. With increasing pressure, the diffraction peaks broaden and shift abnormally, indicating a distortion in the fcc Ce sublattice (Supplementary Fig. 4). Above 33 GPa, distorted fcc phase gradually transfers to another cubic phase and the new cubic phase is stable up to 72 GPa. We observe an emergence of tetragonal phase at 62 GPa with a small diffraction peak. Note that the tetragonal phase can stabilize in a wide pressure range from 62 to 159 GPa. Above 80 GPa, a new phase with hexagonal symmetry appears and coexists with the tetragonal phase. Above 103 GPa, the crystal symmetry and diffraction patterns remain hexagonal symmetry, but its unit cell volume changes as discussed below. Currently, XRD patterns suggest that the original sample undergoes four phase transitions under high pressures. Upon decompression to ambient conditions, the hexagonal phase was recovered to initial fcc phase.

Our PV data points are plotted in Fig. 2 together with literature data. The present data are less scattered thanks to the improved volume accuracy. The PV data points are fitted with a third-order Birch–Murnaghan (BM) equation of state24, yielding the zero pressure volume V0, the bulk modulus B0, and its pressure derivative B0´. At 3 GPa, the volume of fcc phase is 41.80 Å3/formula. Because of the very similar volumes between CeH2 and CeH325, we have identified fcc phase as CeH3 rather than CeH2, because H2 is excessive in the chamber and the enthalpy calculations indicate that CeH3 has a lower enthalpy value than CeH2 (Supplementary Fig. 5). Above 72 GPa, the mixing curve of Ce+ 4/2 H2 (here we use reported EOS of Ce26 and H227) is in good agreement with our experimentally fitted compression curve of tetragonal phase, thus this phase is likely to have an CeH4 stoichiometry. For the second cubic phase from 40 to 72 GPa, its volume is close to cubic CeH3 at 40 GPa, however, the volume becomes close to tetragonal CeH4 at 72 GPa. In this pressure range, we can also intuitively see that the compression curve of second cubic phase is approaching the ideal mixing curve of Ce+ 4/2 H2 and connects the compression curves of CeH3 and CeH4 smoothly, indicating a process of hydrogen absorption from CeH3 to CeH4 (Supplementary Figs. 6 and 7). In the pressure range of 80–103 GPa, anomalous compressibility behavior of hexagonal phase is interpreted as an increase of the hydrogen concentration, corresponding to the ideal mixing curve of Ce+ 8/2 H2. Above 103 GPa, the fitted compression curve of hexagonal phase lies above the ideal mixing curve of Ce+ 8/2 H2 and below the ideal mixing curve of Ce+ 9/2 H2. The calculation of enthalpy in this pressure range shows that the hexagonal phase is in favor of CeH9.

Fig. 2

The volume per formula unit as a function of pressure for Ce polyhydrides. The solid points represent the experimental P–V data. The solid curves represent the BM equation fits of experimental results. The fitted results are B0 = 54.5 (3.6) GPa, B0´ = 4 (fixed), and V0 = 44.0 (0.5) Å3 for CeH3-Fm-3m; B0 = 106.0 (13.4) GPa, B0´ = 4 (fixed), and V0 = 38.3 (0.9) Å3 for CeH3+x; B0 = 95.6 (2.5) GPa, B0´ = 3.4 (fixed), and V0 = 39.6 (0.3) Å3 for CeH4-I4/mmm; B0 = 135.9 (12.7) GPa, B0´ = 4 (fixed), and V0 = 47.4 (1.0) Å3 for CeH9-P63/mmc. The dashed curves represent the calculated EOS. The dotted curves represent the volume of mixtures of unreacted Ce and H2

Theoretical calculation of Ce polyhydrides

The theoretical calculation is urgently required to determine the hydrogen positions and consequently the stoichiometry of Ce polyhydrides. Previous theoretical work has predicted five stoichiometries of Ce polyhydrides: CeH3-R-3m, CeH4-I4/mmm, CeH8-P63mc, CeH9-P63/mmc, and CeH10-Fm-3m21. Inspired by the prediction on Ce polyhydrides, we did further detailed calculations on predicted structures of Ce polyhydrides to supplement our experimental results. Because Ce atoms with f electrons are an extremely delicate system for density functional theory (DFT) calculations, generalized gradient approximation (GGA) with Hubbard U correction was used for DFT calculations. We have done the structural searches at 0 K and 50, 100, and 150 GPa using CALYPSO and AIRSS methods28,29. We reproduced the three phases CeH4-I4/mmm, CeH8-P63mc, and CeH9-P63/mmc, and proposed a new stable phase CeH3-Pm-3n. As summarized in Supplementary Fig. 8, we have investigated the chemical stability of various Ce polyhydrides by calculating their formation enthalpies at pressures of 0, 50, 100, and 150 GPa, relative to the products of their dissociation into constituent. At 0 GPa, the formation enthalpies of all stoichiometries are positive, except CeH3-Pm-3n. Both CeH4-I4/mmm and CeH8-P63mc phases lie on the convex hull at 50 GPa. As pressure increases up to 100 GPa, CeH9-P63/mmc emerges, and CeH4-I4/mmm is the most stable stoichiometry. At 150 GPa, CeH3-Pm-3n, CeH4-I4/mmm, and CeH9-P63/mmc are energetically the most stable, falling on the convex hull. Besides, we investigated the dynamical stability of proposed CeH3-Pm-3n, CeH4-I4/mmm, CeH8-P63mc, and CeH9-P63/mmc by calculating their phonon dispersion curves, and found that all the phases are dynamically stable except CeH8-P63mc (Supplementary Fig. 9).

Crystal structures of Ce polyhydrides

By the joint of experimental and theoretical results, the stoichiometries and crystal structure of compounds were estimated as follows: (i) XRD data give the possible phase transitions and symmetry and match the structures of prediction; (ii) the volume changes obtained from XRD data indicate the stoichiometry of new phases; (iii) theoretical calculations help us to finally determine the crystal structure and stoichiometry through the calculated enthalpy difference, pressure–volume relation and phase stability. Particularly, Rietveld refinement combines the calculated and experimental XRD results. The stoichiometries and crystal structures of Ce polyhydrides have been unraveled through the analysis of theoretical simulation and XRD experiments. As shown in Fig. 1b, excellent Rietveld refinements of experimental pattern profiles enable us to unambiguously determine the crystal structures of these polyhydrides. The experimental refined lattice parameters are summarized in Supplementary Figs. 10 and 11. At 3 GPa, the patterns of fcc phase match the known structure of CeH3-Fm-3m. The second cubic phase matches our predicted CeH3-Pm-3n structure and its crystal structure is presented in Supplementary Fig. 12. Nevertheless, the P–V curves demonstrate that CeH3-Pm-3n would absorb hydrogen and become CeH3+x (0.7 ≤ x ≤ 1.1) as pressure increasing. The tetragonal phase matches the predicted CeH4 with I4/mmm structure and its crystal structure is shown in Fig. 3a. In the pressure range of 80–103 GPa, although the predicted CeH9-P63/mmc has been observed. The abnormal increase of d-spacing and lattice parameters indicates a significant expansion of volume (Fig. 2 and Supplementary Fig. 13), which is attributed to absorption of hydrogen in the process of forming CeH9-P63/mmc. Because of the continuous expansion of volume, we assign the phase in this pressure range noted as CeH9−δ (δ ≤ 0.85). Above 103 GPa, CeH9-P63/mmc is successfully synthesized, with Wyckoff positions Ce: 2d (2/3, 1/3, 1/4) and H:2b (0, 0, 1/4), 4f (1/3, 2/3, 0.149), and 12k (0.156, 0.312, 0.062) shown in Supplementary Table 1. Most interestingly, CeH9-P63/mmc presents a three-dimensional network in H sublattice. Figure 3b–d shows the crystal structure of CeH9-P63/mmc and the H structure within CeH9-P63/mmc. Each Ce atom is surrounded by 29 H atoms forming H29 cage and there are 6 H4 rings, 6 H5 rings, and 6 H6 rings in each H29 cage. Contiguous H29 cages share the rings and form an extended H network structure in three-dimensional space. Note that the P–V relation of these polyhydrides measured by the XRD are in excellent agreement with the theoretical calculation (Fig. 2), thus further confirming the stoichiometry. For the first time, the phase diagram of Ce–H system has been determined in experiment by the XRD patterns (Supplementary Fig. 14). The stable Ce polyhydrides in excess hydrogen have increasing stoichiometry under high pressure. Further discussion about stoichiometries is given in Supplementary Information.

Fig. 3

Crystal structure determination of Ce polyhydrides. a The crystal structure of CeH4-I4/mmm. b The crystal structure of CeH9-P63/mmc. c The extended H network in CeH9-P63/mmc. d The H29 cage in CeH9-P63/mmc. Large brown and small green spheres represent Ce and H atoms, respectively. e The evolution of nearest-neighbor H–H distances in polyhydrides and atomic metallic H2 as a function of pressure. These data were gained in previous work of H3S9, FeH519, LaH1012, CeH4-I4/mmm, and CeH9-P63/mmc (this work) and the calculation of atomic metallic hydrogen (solid curve for ref. 19 and dash curve from ref. 12)

Based on the above analysis, the polyhydrides especially CeH9-P63/mmc have been discovered merely through the cold-compression treatment. The present synthesized path facilitates further experimental characterization in contrast with other recently synthesized polyhydrides such as LaH10 and NaH7, which require laser-heating to overcome the energy barrier. Besides, we have also combined high-pressure and high-temperature conditions to trigger the formation of CeH9-P63/mmc and high-temperature is realized through laser-heating treatment. By means of Rietveld Refinement (Supplementary Fig. 15), we have confirmed the formation of CeH9-P63/mmc in these two synthetic routes—cold compression and high-temperature annealing.

Atomic-like hydrogen sublattice realized via CeH9-P63/mmc

The discovered Ce polyhydrides invite us to reveal rich chemistry of hydrogen atom at elevated pressures. We compared the nearest-neighbor H–H distances and volume collapse per H atom in Ce polyhydrides with other reported polyhydrides and metallic hydrogen in Fig. 3e and Supplementary Fig. 16. Some polyhydrides consisted of H2 or H3 units, such as Xe(H2)830 and NaH720, present undissociated H–H distances of about 0.75 Å. At 132 GPa, the nearest-neighbor H-H distance of CeH4-I4/mmm is 1.54 Å, which is slightly smaller than 1.56 Å in high-temperature superconducting phase H3S. The nearest-neighbor H–H distance of CeH9-P63/mmc is closest to atomic metallic hydrogen (predicted I41/amd structure31) with nearest-neighbor H–H distance of 1.09 Å at 132 GPa, which is also much lower than 1.2 Å in LaH1012, 1.32 Å in FeH519 at the same pressure, indicating that Ce atoms play a more positive on chemical precompression. Thus, the evolution of nearest-neighbor H–H distance is almost close to atomic metal hydrogen, which may be realized by Ce atom doping.

We have calculated the electron localization function to figure out the bonding nature in the CeH9-P63/mmc. Figure 4a shows that the lack of electron localization between Ce and H atoms indicates the absence of covalent bond characteristics and there is a weak electron localization (about 0.5–0.6) between H atoms forming a 3D network structure with H4, H5, and H6 rings. In Fig. 4b, an analysis of the electronic band structure illustrates that CeH9-P63/mmc presents metallic character owing to overlap of the conduction and valence bands at the Fermi level. The projected electronic density of states shows that both H and Ce make a sizable contribution to the density of states at the Fermi level (Fig. 4b and Supplementary Fig. 17). The density of electronic states of each phase illustrates that the contribution of hydrogen to the Fermi level would increase as stoichiometry and pressure increase (Supplementary Fig. 18), further confirming the indispensable role of hydrogen in these polyhydrides.

Fig. 4

Calculated electronic properties of CeH9-P63/mmc at 100 GPa. a Plot of electron localization function reveals a weak electron localization (about 0.5–0.6) between H atoms and confirms the formation of H4, H5, and H6 rings as the units of extended H network. b Electronic band structure and Partial density of electronic states of CeH9-P63/mmc

In conclusion, we have successfully synthesized a series of cerium polyhydrides by direct reaction of Ce and H2 upon cold-compression up to 159 GPa. The Ce polyhydrides (CeH3, CeH3+x, CeH4, CeH9−δ and CeH9) present an increase of hydrogen content as pressure increases. The formed CeH9 has a unique clathrate-like structure consisting of H29 cages surrounding Ce atoms occupying the hexagonal P63/mmc symmetry. CeH9 is also with the nearest-neighbor H–H distances closest to predictions for solid atomic metallic hydrogen in all synthesized hydrides. The electron localization function of CeH9 indicates an ionic bonding between Ce and H atoms, and a weak electron localization between two H atoms, and the band structure confirms its metallic character. The density of electronic states calculations indicates significant contribution of H at the Fermi level. Our cold-compression experiment provides a facile route to potential superconductors in superhydrides. The discovery of CeH9 with atomic-like hydrogen sublattice suggests a low-pressure route for bulk dense atomic hydrogen stabilized by other element atoms.


Experimental details

We have carried out several experiments and the highest pressure reached 159 GPa. The diamonds were coated with 100 nm thick layer of Al2O3 to prevent diamond failure by hydrogen diffusion. Tungsten gaskets were also coated with a 100 nm gold to prevent the diffusion of hydrogen. The symmetric DACs were used to generate pressure. Ce powder with a purity of 99.99% was purchased from Alfa Aesar. All the sample of Ce were loaded and sealed in DACs inside glove box with Ar atmosphere (less than 0.01 ppm of oxygen and water) and the cells were transferred to gas-loading apparatus. The hydrogen was compressed to 0.17 GPa, then the cells were unclamped to allow the hydrogen to flow into the chamber and resealed. The Raman shift of diamond edge was used to calibrate the pressure32.

The XRD experiments were performed at the 4W2 beamline of Beijing Synchrotron Radiation Facility (BSRF) and 15U1 beamline of Shanghai Synchrotron Radiation Facility (SSRF). The incident wavelength of X-ray was 0.6199 Å. The MAR image plate detectors were used to collect the diffraction patterns and the two-dimensional XRD images were radially integrated using DIOPTAS software33, yielding intensity versus diffraction angle 2θ patterns. Prior to measurement, a CeO2 standard was used to calibrate the geometric parameters. The cold-compression experiments (3–159 GPa) were carried out at ambient temperature. The Ce polyhydrides would be synthesized only through cold-compression without laser-heating treatment. Additional laser-heating experiments were performed at 96 GPa and below 1500 K. The Reflex module in Materials Studio Program34 and GSAS software35 were utilized to index and refine the XRD patterns.

Computational details

First-principles calculations were performed with the pseudopotential plane-wave method based on DFT implemented in VASP code36. The GGA with the Perdew–Burke–Ernzerhof exchange-correlation functional was used in the calculation. The project-augmented wave method was adopted with valence electrons of 4f15s25p65d16s2 and 1s1 for Ce and H atoms, respectively. A plane-wave cutoff energy of 1000 eV was employed for norm-conserving pseudopotentials and Brillouin zone sampling grids of spacing was 2π × 0.03 Å−1. Phonon calculations were performed by a finite displacement method with the PHONOPY code37. The proposed structures were predicted through AIRSS28 and CALYPSO29 methods. To verify the correction of Hubbard U, an effective Hubbard parameter of 4.0 eV was added for the Ce 4f states in all calculations, which was used in previous calculation work of cerium hydrides21. The method of Methfessel–Paxton was used in the calculation of geometry optimization, band structure, electron localization function, phonon spectrum and the tetrahedron method with Blöchl corrections was used in DOS calculations.

Data availability

All data supporting the findings of this study are included in this Article and its Supplementary Information, and are also available from the corresponding authors upon reasonable request. The source data underlying Figs. 1, 2, 3e, and 4b and Supplementary Figs. 28, 11, 12, 14–16, and 18 are provided as a Source Data file.


  1. 1.

    Huang, X. et al. High-pressure Raman study of solid hydrogen up to 300 GPa. Chin. Phys. B 25, 037401 (2016).

    ADS  Article  Google Scholar 

  2. 2.

    Zha, C.-S., Liu, Z. & Hemley, R. J. Synchrotron infrared measurements of dense hydrogen to 360 GPa. Phys. Rev. Lett. 108, 146402 (2012).

    ADS  Article  Google Scholar 

  3. 3.

    Loubeyre, P., Occelli, F. & LeToullec, R. Optical studies of solid hydrogen to 320 GPa and evidence for black hydrogen. Nature 416, 613–617 (2002).

    ADS  CAS  Article  Google Scholar 

  4. 4.

    Dalladay-Simpson, P., Howie, R. T. & Gregoryanz, E. Evidence for a new phase of dense hydrogen above 325 gigapascals. Nature 529, 63–67 (2016).

    ADS  CAS  Article  Google Scholar 

  5. 5.

    Eremets, M. I., Troyan, I. A., Lerch, P. & Drozdov, A. Infrared study of hydrogen up to 310 GPa at room temperature. High Press. Res. 33, 377–380 (2013).

    ADS  CAS  Article  Google Scholar 

  6. 6.

    Monserrat, B. et al. Structure and metallicity of phase V of hydrogen. Phys. Rev. Lett. 120, 7 (2018).

    Article  Google Scholar 

  7. 7.

    Dias, R. P. & Silvera, I. F. Observation of the Wigner-Huntington transition to metallic hydrogen. Science 355, 715–718 (2017).

    ADS  CAS  Article  Google Scholar 

  8. 8.

    Ashcroft, N. W. Hydrogen dominant metallic alloys: high temperature superconductors? Phys. Rev. Lett. 92, 4 (2004).

    Article  Google Scholar 

  9. 9.

    Duan, D. F. et al. Pressure-induced metallization of dense (H2S)2H2 with high-T c Superconductivity. Sci. Rep. 4, 6 (2014).

    Google Scholar 

  10. 10.

    Duan, D. F. et al. Pressure-induced decomposition of solid hydrogen sulfide. Phys. Rev. B 91, 5 (2015).

    Article  Google Scholar 

  11. 11.

    Wang, H., Tse, J. S., Tanaka, K., Iitaka, T. & Ma, Y. M. Superconductive sodalite-like clathrate calcium hydride at high pressures. Proc. Natl Acad. Sci. USA 109, 6463–6466 (2012).

    ADS  CAS  Article  Google Scholar 

  12. 12.

    Geballe, Z. M. et al. Synthesis and stability of lanthanum superhydrides. Angew. Chem. Int. Ed. 57, 688–692 (2018).

    CAS  Article  Google Scholar 

  13. 13.

    Liu, H. Y., Naumov, I. I., Hoffmann, R., Ashcroft, N. W. & Hemley, R. J. Potential high-T c superconducting lanthanum and yttrium hydrides at high pressure. Proc. Natl Acad. Sci. USA 114, 6990–6995 (2017).

    ADS  CAS  Article  Google Scholar 

  14. 14.

    Huang, X. et al. High-temperature superconductivity in sulfur hydride evidenced by alternating-current magnetic susceptibility. Natl Sci. Rev. https://doi.org/10.1093/nsr/nwz061 (2019).

  15. 15.

    Drozdov, A. P., Eremets, M. I., Troyan, I. A., Ksenofontov, V. & Shylin, S. I. Conventional superconductivity at 203 kelvin at high pressures in the sulfur hydride system. Nature 525, 73–76 (2015).

    ADS  CAS  Article  Google Scholar 

  16. 16.

    Einaga, M. et al. Crystal structure of the superconducting phase of sulfur hydride. Nat. Phys. 12, 835–838 (2016).

    CAS  Article  Google Scholar 

  17. 17.

    Drozdov, A. P. et al. Superconductivity at 250 K in lanthanum hydride under high pressures. Nature 569, 528 (2019).

    ADS  CAS  Article  Google Scholar 

  18. 18.

    Somayazulu, M. et al. Evidence for superconductivity above 260 K in lanthanum superhydride at megabar pressures. Phys. Rev. Lett. 122, 027001 (2019).

  19. 19.

    Pepin, C. M., Geneste, G., Dewaele, A., Mezouar, M. & Loubeyre, P. Synthesis of FeH5: a layered structure with atomic hydrogen slabs. Science 357, 382–385 (2017).

    ADS  CAS  Article  Google Scholar 

  20. 20.

    Struzhkin, V. V. et al. Synthesis of sodium polyhydrides at high pressures. Nat. Commun. 7, 8 (2016).

    Article  Google Scholar 

  21. 21.

    Peng, F. et al. Hydrogen clathrate structures in rare earth hydrides at high pressures: possible route to room-temperature superconductivity. Phys. Rev. Lett. 119, 6 (2017).

    Google Scholar 

  22. 22.

    Fujimori, A., . & Ishii, M. & Tsuda, N. Infrared and Raman spectra of non-stoichiometric cerium hydrides. Phys. Status Solidi B 99, 673–681 (1980).

    ADS  CAS  Article  Google Scholar 

  23. 23.

    Ao, B. Y. et al. Lattice contraction of cerium hydrides from first-principles LDA plus U calculations. Int. J. Hydrog. Energy 37, 5108–5113 (2012).

    CAS  Article  Google Scholar 

  24. 24.

    Birch, F. The effect of pressure upon the elastic parameters of isotropic solids, according to Murnaghan's theory of finite strain. J. Appl. Phys. 9, 279–288 (1938).

    ADS  Article  Google Scholar 

  25. 25.

    Drulis, M. & Biegański, Z. Low temperature phase transition in cerium trihydride. Specific heat measurements. Phys. Status Solidi A 46, K39–K41 (1978).

    ADS  CAS  Article  Google Scholar 

  26. 26.

    Vohra, Y. K., Beaver, S. L., Akella, J., Ruddle, C. A. & Weir, S. T. Ultrapressure equation of state of cerium metal to 208 GPa. J. Appl. Phys. 85, 2451–2453 (1999).

    ADS  CAS  Article  Google Scholar 

  27. 27.

    Loubeyre, P. et al. X-ray diffraction and equation of state of hydrogen at megabar pressures. Nature 383, 702–704 (1996).

    ADS  CAS  Article  Google Scholar 

  28. 28.

    Pickard, C. J. & Needs, R. J. Ab initio random structure searching. J. Phys. 23, 23 (2011).

    Google Scholar 

  29. 29.

    Wang, Y. C., Lv, J., Zhu, L. & Ma, Y. M. CALYPSO: A method for crystal structure prediction. Comput. Phys. Commun. 183, 2063–2070 (2012).

    ADS  CAS  Article  Google Scholar 

  30. 30.

    Somayazulu, M. et al. Pressure-induced bonding and compound formation in xenon-hydrogen solids. Nat. Chem. 2, 50–53 (2010).

    CAS  Article  Google Scholar 

  31. 31.

    Pickard, C. J. & Needs, R. J. Structure of phase III of solid hydrogen. Nat. Phys. 3, 473–476 (2007).

    CAS  Article  Google Scholar 

  32. 32.

    Akahama, Y. & Kawamura, H. Pressure calibration of diamond anvil Raman gauge to 310 GPa. J. Appl. Phys. 100, 4 (2006).

    Article  Google Scholar 

  33. 33.

    Prescher, C. & Prakapenka, V. B. DIOPTAS: a program for reduction of two-dimensional X-ray diffraction data and data exploration. High Press. Res. 35, 223–230 (2015).

    ADS  CAS  Article  Google Scholar 

  34. 34.

    Young, R. The Rietveld method. Int. Union Crystallogr. 5, 1–38 (1993).

    CAS  Google Scholar 

  35. 35.

    Toby, B. H. EXPGUI, a graphical user interface for GSAS. J. Appl. Crystallogr. 34, 210–213 (2001).

    CAS  Article  Google Scholar 

  36. 36.

    Kresse, G. & Furthmüller, J. Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set. Comput. Mater. Sci. 6, 15–50 (1996).

    CAS  Article  Google Scholar 

  37. 37.

    Togo, A., Oba, F. & Tanaka, I. First-principles calculations of the ferroelastic transition between rutile-type and CaCl2-type SiO2 at high pressures. Phys. Rev. B 78, 9 (2008).

    Article  Google Scholar 

Download references


The authors would like to thank professor Artem R. Oganov for many useful discussions, the Beijing Synchrotron Radiation Facility HP-Station 4W2, Shanghai Synchrotron Radiation Facility Beamline BL15U1 and its staff for allowing us to perform the XRD analyze. This work was supported by National Natural Science Foundation of China (Nos. 51572108, 51632002, 11504127, 11674122, 11574112, 11474127, and 11634004), the 111 Project (No. B12011), Program for Changjiang Scholars and Innovative Research Team in University (No. IRT_15R23) and National Found for Fostering Talents of basic Science (No. J1103202).

Author information




X.H. and T.C. designed the experiments. X.L. and D.Z. prepared the cells and loaded the hydrogen. X.L. and Y.H. performed the XRD experiments. X.L. and X.H. analyzed the experimental data. C.J.P., H.X., Qu Z., and D.D. performed and analyzed the calculations. X.L., X.H., and T.C. wrote and revised the paper. Qi Z. and B.L. discussed the results and commented on the paper.

Corresponding authors

Correspondence to Xiaoli Huang or Tian Cui.

Ethics declarations

Competing interests

The authors declare no competing interests.

Additional information

Peer review information Nature Communications thanks the anonymous reviewers for their contributions to the peer review of this work. Peer Reviewer Reports are available.

Publisher’s note: Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Supplementary information

Source data

Rights and permissions

Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/.

Reprints and Permissions

About this article

Verify currency and authenticity via CrossMark

Cite this article

Li, X., Huang, X., Duan, D. et al. Polyhydride CeH9 with an atomic-like hydrogen clathrate structure. Nat Commun 10, 3461 (2019). https://doi.org/10.1038/s41467-019-11330-6

Download citation

Further reading


By submitting a comment you agree to abide by our Terms and Community Guidelines. If you find something abusive or that does not comply with our terms or guidelines please flag it as inappropriate.


Nature Briefing

Sign up for the Nature Briefing newsletter — what matters in science, free to your inbox daily.

Get the most important science stories of the day, free in your inbox. Sign up for Nature Briefing