Hydrogenation is an effective way to tune the property of metal oxides. It can conventionally be performed by doping hydrogen into solid materials with noble-metal catalysis, high-temperature/pressure annealing treatment, or high-energy proton implantation in vacuum condition. Acid solution naturally provides a rich proton source, but it should cause corrosion rather than hydrogenation to metal oxides. Here we report a facile approach to hydrogenate monoclinic vanadium dioxide (VO2) in acid solution at ambient condition by placing a small piece of low workfunction metal (Al, Cu, Ag, Zn, or Fe) on VO2 surface. It is found that the attachment of a tiny metal particle (~1.0 mm) can lead to the complete hydrogenation of an entire wafer-size VO2 (>2 inch). Moreover, with the right choice of the metal a two-step insulator–metal–insulator phase modulation can even be achieved. An electron–proton co-doping mechanism has been proposed and verified by the first-principles calculations.
As a typical transition oxide, VO2 has a pronounced metal–insulator transition (MIT) behavior at the critical temperature near 68 °C, accompanying by a sharp resistance change up to five orders of magnitude and marked infrared switching effect within sub-ps time scale1,2,3,4,5. It has thus shown great potential for important applications in memory material6,7, smart window8,9 and ultra-fast optical switching device10. Many efforts have been devoted to improve the phase transition properties of metal oxides11,12,13,14,15,16, including the hydrogenation treatment, which has been demonstrated to be an effective way to tune the property of metal oxides17,18,19,20,21. Recent experiments observed that H-incorporations in M-VO2 could result in a very stable metallic phase at room temperature19,22, giving excellent thermoelectric performance23. Moreover, further injecting H into the lightly doped M-VO2 could create another insulating state at the heavily H-doping situation20, enabling the control of MIT in a reversible and consecutive manner. Previous studies examined the thermodynamic and kinetic properties of H or Li doping in VO2 lattice22,24,25, showing that H atoms preferred to diffuse along the c-axis of rutile VO2 or a-axis of monoclinic VO2. Although the hydrogenation techniques available are not sustainable as they are conventionally performed with noble-metal (Au, Pt, Pd) catalysts, high-temperature/pressure annealing treatment or high-energy proton implantation in vacuum condition22,26,27,28.
In this work, we report a facile approach to hydrogenate monoclinic VO2 film in acid solution at ambient condition by placing a low workfunction metal particle (Al, Cu, Ag, Zn, or Fe) on VO2 surface. The workfunction difference will cause electron flowing from metal particles to VO2, which in turn drives surrounding solution protons to penetrate into VO2 due to electrostatic attraction, resulting a stable H atoms doping. This process will not only stabilize the VO2 lattice in acid, but also induce the modulation of phase transitions under ambience conditions, which should be of great potentials for material applications. An electron–proton co-doping mechanism has been proposed and this synergetic doping method will stimulate more simple and cost-effective atomic doping techniques in the future.
Metal-acid treatment induced H-doped VO2 film
Is it possible to use acid solution as a natural proton source to achieve the hydrogenation of VO2 at ambient condition? At the first glance, this appears to be an impossible mission, as the textbook tells us that pristine metallic oxides including VO2 are easily dissolved in acid through the well-established reaction of VO2 + 4H+ → V4+ + 2H2O. Indeed, as shown in Fig. 1a, when a 30 nm M-VO2/Al2O3 (0001) epitaxial film grown by molecular beam epitaxy method29 (Supplementary Fig. 1) held by a plastic tweezers was put into a 2%wt H2SO4 acid solution, the yellowy VO2 epitaxial film completely disappeared within 3 h. Although when a steel tweezers was used to hold the sample, as shown in Fig. 1b, the same VO2 film suddenly demonstrated excellent anti-corrosion ability: it remains intact after 3 h in the acid solution. Scanning electron microscope (SEM) images in Fig. 1c show that the thickness and morphology of VO2 film hardly change even after 20 h in acid solution. In addition, the atomic force microscope (AFM) measurements show nearly zero thickness variation for metal-acid-treated samples (Supplementary Fig. 2a), which is consistent with the SEM cross-section image and confirms the anti-corrosion ability. More convincingly, the trace element analysis in Fig. 1d revealed that the concentration of V4+ cations in solution increased from 0.11 to 1.82 μg/ml after immersing a VO2 film held by a plastic tweezers in acid from 30 min to 20 h, whereas it kept very low value at 0.03–0.06 μg/ml with a steel tweezers. All these results firmly point to the fact that the attachment of a metal can give excellent anti-corrosion ability to VO2.
Interestingly, the hydrogenated VO2 produced by Au or Pd catalyst is found to be very stable in acid solution (Supplementary Fig. 2b). One can thus reasonably assume that the anti-corrosion ability of such metal-acid-treated VO2 is due to the hydrogenation. The X-ray diffraction (XRD) spectra in Fig. 1e show the dynamic shifts of (020) diffraction peak from 39.8° to 36.7° after the metal-acid treatment due to the cell expansion caused by H-incorporation, which agree well with the results for lightly and heavily hydrogenated VO2 through conventional noble-metal catalysis at high temperature (Supplementary Fig. 3a). These hydrogenated VO2 films show successive metallic and insulator states as the hydrogen doping concentration increasing30.
The X-ray photoelectron spectroscopy (XPS) measurements presented in Fig. 1f clearly indicate the conversion from V4+ to V3+ state as the result of H intercalation, which is further confirmed by the variations of O1s peak at ~531.6 eV for the O–H species. The change of valence state from V4+ to V(4−δ)+ or even to V3+ state is also verified by the X-ray absorption near-edge structure (XANES) spectra in Fig. 1g as the V L-edge curves shift continuously to lower energy. After the metal-acid treatment, the relative intensity ratio of the t2g and eg peaks in O K-edge curves decreased substantially, reflecting the variation of electron occupancy due to electron doping as well as the loss of the d// state upon hydrogenation31. All these spectroscopic features induced by metal-acid treatment for 1.5 and 10 h agree well with corresponding measurements on lightly and heavily hydrogenated VO2 through conventional catalysis techniques (Supplementary Fig. 3), respectively. It can thus be concluded that the metal-acid treatment can indeed create H-doping in the VO2 film.
Hydrogenation of a wafer-size VO2 film
It is noted that contact area between the metal tweezers and the VO2 film is actually quite small. To further quantitatively explore the effect of metal attachment, we have placed a tiny Cu particle (~1.0 mm in diameter) at the center of one 2-inch M-VO2/Al2O3(0001) epitaxial film, and immersed them together into 2%wt H2SO4 solution. It is observed in Fig. 2a that the bare VO2 film with yellowy color could be dissolved within 1.5–3 h. In sharp contrast, the small copper particle has provided the protection for the whole 2-inch wafer from acid corrosion. In addition, when the Cu particle is taken away after the treatment, the film remains stable in acid solution as it has already been hydrogenated (Supplementary Fig. 4).
A key evidence about the hydrogenation of VO2 is the insulator–metal transition at room temperature19,22, i.e., the hydrogenation converts the insulated M-VO2 to the metallic phase (Supplementary Fig. 5). In comparison with the original insulating M-VO2 film (Fig. 2b), the surface resistance of above Cu-acid-treated sample is decreased by almost three orders of magnitude (Fig. 2c). After cyclically heating the sample in air between 40 and 90 °C for about 2 h, the intercalated hydrogens could be completely removed, and the film is recovered back to the insulated phase (Fig. 2d), which is consistent with the results obtained from hydrogenated samples through conventional catalysis (Supplementary Fig. 6). From Fig. 2a, one can note that the small copper particle can be taken away to leave out pure H-doping material. It is certainly a much better approach than the conventional catalysis-based technique as those metal catalysts (Au or Pt) sputtered onto the VO2 film surface are hardly removable. In addition, the latter gives only limited hydrogenation area covered by catalysts (Supplementary Fig. 5b).
Hydrogenation effects controlled by different metals
We have found that several other metals, such as Al, Cu, Ag, Zn, or Fe, can all induce hydrogenation and thereby protect VO2 from corrosion in acid, whereas Au and Pt can not. The effects of different metals are illustrated in Fig. 3a. One important parameter associated with the choice of the metal is the workfunction. The workfunction values calculated for the metals (Supplementary Fig. 7), VO2 and H0.5VO2 are plotted together with the reported experimental values32 in Fig. 3b. Simulations of pristine and hydrogenated VO2 systems were based on the most stable atomic models obtained by previous studies30. Because of high lattice symmetry, the electronic structure of H-doped VO2 is sensitive to the H-doping concentration but not to the atomic sites of H in lattice. By testing all of the 16 possible H-doping sites (Supplementary Fig. 8; Supplementary Table 1), we have taken the one with lowest energy for further investigation. A clear pattern can be observed: with the respect to the workfunction of VO2, the metal with smaller workfunction value can induce the hydrogenation. With such a workfunction difference, metals with higher electric Fermi level (EF) would donate electrons to the interfaced VO2 with lower EF (Fig. 3c). Calculations show that one (1 × 1) VO2 unit could extract 0.47–2.50e− from metals with lower workfunction (Fig. 3d; Supplementary Fig. 9; Supplementary Table 2). On the other hand, higher workfunction metals, Au and Pt, give nearly no extra electrons at the interface of M-VO2. It should also be noted in Fig. 3b that Al and Zn metals hold even lower workfunction than the lightly H-doped system of H0.5VO2, suggesting the continuing donation of electrons from metal to lightly hydrogenated VO2 which later attracts more hydrogen to penetrate. Therefore, the final products of Al/Zn-acid treatment are heavily H-doped VO2 with insulator phase while those of Ag/Cu-acid are conductive lightly H-doped VO2, as validated by XRD, XPS, XANES, and Raman characterizations in Supplementary Fig. 3. These results thus demonstrate that the electron-rich VO2 interface can attract and interact with the protons in acid solution, resulting in a feasible way to generate hydrogen atoms needed by hydrogenation.
By examining six VO2 surface sites for a proton to adsorb (inset graph in Fig. 4a and Supplementary Fig. 10), it is found that more doped electrons lead to higher adsorption energies for all sites (Fig. 4a). For instance, on site 1, the proton adsorption energy of 3.68 eV in neutral circumstance is increased to 5.04 eV for a VO2 unit with 4e− charge. The doped electrons also promote the diffusion of surface hydrogens into the VO2 crystal, with a possible migration pathway along the  direction (Supplementary Fig. 11). We can therefore propose an electron–proton co-doping strategy to create stable neutral H-doping in VO2. More specifically, driving by the electrostatic attraction, the surrounding protons could penetrate into VO2 to meet electrons, resulting in neutral H intercalation. The incorporation of H in the VO2 crystal prohibits further attack/adsorption of protons to oxygen, and increases the formation energy required for oxygen vacancy defect (Supplementary Fig. 12), resulting in the anti-corrosion ability in acid solutions.
The H-doping changes the VO2 electronic structures. For a VO2 unit with small H-doping concentration of H0.25VO2 (Fig. 4b), the evolution of the electronic structure is reflected by the computed partial density of state (PDOS) of the V-3d orbitals in Fig. 4b. The formation of H–O bonds causes electrons transferring from H to O atoms (Supplementary Table 3), which in turn promotes the electron occupancy of V-3d orbitals. Such effects give rise to the up-shifting of Fermi level from the pure VO2 to H0.25VO2 (Fig. 4b). Originally, VO2 exhibits a typical insulating state, with wide energy gap consisting of fully occupied valence band and empty conduction band. The H-doping then makes the conduction band edge states partially occupied, as for the case of H0.25VO2.
The same concept can be also used to explain the contagious hydrogenation process that enables a ~1 mm metal particle to convert a 2-inch semiconductor wafer. As shown in Fig. 3b, the work functions of the lightly hydrogenated H0.25VO2 with three facets of (020), (011), (100) are 4.32–4.96 eV, which are all lower than those of pristine VO2 around 5.12–5.85 eV. For any H-doped VO2 parts created by metal-acid treatment, electrons would flow/dope into neighboring unhoped VO2 with lower Fermi level (Fig. 4c; Supplementary Fig. 13). The electron-rich area drives further proton penetration to the neighboring un-doped VO2.
Electron–proton co-doping mechanism
A contagious spreading of electron–proton co-doping mechanism is summarized in Fig. 4d: firstly the metal with lower workfunction donates electrons to the interfaced VO2 due to Fermi level difference, resulted in extra electrons accumulated in oxide layer; Then the doped electrons attract surrounding protons in acid solution to penetrate into the oxide semiconductor, creating H-doped structure at the top layer and causing the surface insulator-to-metal phase transition. Simultaneously, the attached metal particle is partially dissolved in acid, which balances the total charge in solution. This balance of charge is essential to drive the hydrogenation of VO2 as this route:
Otherwise, the reaction will follow the route of VO2 + 4H+ → V4+ + 2H2O, resulting the corrosion of VO2 in acid. The test of immersing only parts of a Cu/VO2 sample into acid without metal in solution causes no anticorrosive property (Supplementary Fig. 14), clearly showing this situation. After the above stage, the conductive H-doped structures delivery electrons to adjacent un-doped VO2 parts, triggering the next round of electron–proton co-doping and insulator-to-metal phase transition. Finally, the repeated electron flowing–proton penetration–phase transition–electron further flowing cycle expands toward full H-doped oxide material. This spreading of co-doping from metal center to edge is reflected by the onion-like contour map of resistance after metal-acid treatment (Fig. 2c), which decreases gradually from the metal-attached center to the wafer edge. In addition, the hydrogenation process is also gradually completed from the top to bottom layer with considering the time-dependent hydrogenation-related Raman or XRD signals (Supplementary Fig. 15).
It should be pointed out that since the corrosion of VO2 caused by oxygen atom moving out of lattice is much slower than the migrations of electrons or protons, the dynamics of this co-doping mechanism ensure the quick hydrogenation of VO2 surface before being corroded by acid, resulting in the anti-corrosion property of wafer-size VO2 film even at the beginning stage since we found the distinct resistance decrease of VO2 with several seconds metal-acid treatment.
On the basis of the proposed concept, one can anticipate that the metals with very low workfunction, such as Al or Zn, can lead to heavy hydrogenation of VO2 films in acid solution. It means that the induced metallic state would eventually be transferred into another new insulating state because of nearly saturated hydrogenation (Supplementary Fig. 3; Supplementary Fig. 16), which agree well with the different H concentrations revealed by secondary-ion mass spectrometry measurement (Supplementary Fig. 17). This observation is consistent with very recent findings of the consecutive insulator–metal–insulator transitions induced by increasing H-doping concentration20. In addition, based on this metal-acid treatment, partially hydrogenation process with a selected region can also be easily achieved by control the immersing area in acid solution (Supplementary Fig. 18). Remarkably, this simple metal-acid treatment is found to be a universal strategy that can be extended to doping ions in general. Replacing the acid solution by polymeric solution with Li+, metallic Li-doped VO2 films can also be obtained (Supplementary Fig. 19).
The ability to hydrogenate VO2 with protons in acid solution demonstrated here provides a facile strategy to induce phase modulation of VO2 materials, and the later successful doping of Li+ into VO2 suggests a general atomic doping approach of using proton or cation solvent sources together with electrons from metals. It is a sustainable approach that operates at ambient condition in an environment friendly manner by completely avoiding the use of precious catalysts and high-energy consumptions. The doping concept established in this study will have strong impact on the development of new functional materials in different applications.
The 2-inch wafer-size VO2 (020) epitaxial films were grown on c-cut sapphire by an rf-plasma assisted oxide molecular beam epitaxy (rf-OMBE) equipment and more details for the film preparation are reported elsewhere29.
Conventional hydrogenation treatment for VO2 film
Nano-sized Au islands were sputtered on M-VO2 surface as the catalysis. The Au/VO2 samples were annealed in tube furnace with the forming gas (15% H2/85% Ar) under various conditions. The lightly doped metallic H-VO2 (120 °C for 2 h) and heavily doped insulated H-VO2 (180 °C for 10 h) were prepared.
The resistance as the function of temperature was examined by Keithley 2400 sourcemeter with a variable temperature stage. For all of the measurements, the temperature sweeping rate was set at 0.1 K/s; The resistance distribution mapping for the prepared wafer-size VO2 film were tested on room temperature and 120 °C, respectively. The cross-section and surface morphologies were investigated by Scanning Electron Microscopy (Gemini Fe-SEM 500 and FEI Sirion 200). Raman spectra were recorded by an integrated laser Raman system (LABRAM HR, Jobin Yvon). The 632.8 nm He–Ne laser was used as the excitation source. To obtain direct information about the hydrogen concentration of the metal-acid VO2 film sample, the secondary-ion mass spectrometry (SIMS) measurements (Quad PHI6600) were conducted. The ICP-AES equipment (Optima 7300DV) was used to trace element concentration. The wavelength of Cu, V adopted 327.393, 290.880 nm respectively. The emission power is 1250 w. The distinguishability reached to 0.003 nm at 200 nm, and the detection limit is 4 ng/ml.
Synchrotron X-ray diffraction spectra, including θ − 2θ, X-ray reflectivity (XRR), Φ-scan, rocking-curve, were conducted at the BL14B beamline of the Shanghai Synchrotron Radiation Facility (SSRF). The SSRF is a third-generate accelerator with a 3.5 GeV storage ring. The BL14B beamline shows the energy resolution (ΔE/E) of 1.5 × 10−4 @10 keV and the beam size of 0.3 × 0.35 mm with the photo flux of up to 2 × 1012 phs/s@10 keV. Considering the photo flux distribution and the resolution, the 0.12398 nm X-ray was chosen during the experiment.
The X-ray absorption near-edge spectroscopy (XANES) was conducted at the XMCD beamline (BL12B) in National synchrotron radiation laboratory (NSRL), Hefei. The total electron yield (TEY) mode was applied to collect the sample drain current under a vacuum better than 3.75 × 10−10 Torr. The energy range is 100–1000 eV with an energy resolution of ca. 0.2 eV. The X-ray incident angle is 54.7°. During the measurement, the samples were firmly adhered on the conductive substrate with random orientation, so the polarization dependence is not considered.
The X-ray photoelectron spectroscopy (XPS) beamline was conducted in National synchrotron radiation laboratory (NSRL), Hefei. The photoemission beamline covers photon energies from 100 to 1000 eV with a typical photon flux of 1 × 1010 phs/s and a resolution (E/ΔE) better than 1000 at 244 eV. The analysis chamber is connected to the beamline and equipped with a VG Scienta R3000 electron energy analyzer, and the base pressure is 1.5 × 10−10 Torr.
All calculations are performed with density functional theory (DFT), using the Vienna ab initio simulation package (VASP) code33. The exchange and correlation terms are described using general gradient approximation (GGA) in the scheme of Perdew–Burke–Ernzerhof (PBE)34. Core electrons are described by pseudopotentials generated from the projector augmented-wave method35, and valence electrons are expanded in a plane-wave basis set with an energy cutoff of 480 eV. Slab model method is used to model the VO2 surface and metal–VO2 interface, the thickness of vacuum are larger than 15 Å. The DFT+U method is employed to optimize the structure, U and J are chosen to be 4 and 0.68 eV. The geometry relaxation is carried out until all forces on the free ions are converged to 0.01 eV/Å. In the calculation of electronic structures, DFT with hybrid functionals proposed by Heyd, Scuseria, and Ernzerhof (HSE06) is used36. Climbing image nudged elastic band (CI-NEB) method37 is used to find the minimum energy paths and the transition states for diffusion of H from surface to subsurface, with a force converge <0.05 eV/Å.
The remaining data contained within the paper and supplementary files are available from the authors upon request.
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This work was partially supported by the National Basic Research Program of China (2014CB848900), the National Key Research and Development Program of China (2016YFA0401004), the National Natural Science Foundation of China (U1432249, 11574279, 11404095, 21633006, 11704362), the Fundamental Research Funds for the Central Universities; the funding supported by the Youth Innovation Promotion Association CAS and the Open Research Fund of State Key Laboratory of Pulsed Power Laser Technology, Electronic Engineering Institute. We also acknowledge supports from the X-ray diffraction beamline (BL14B1) in Shanghai Synchrotron Radiation Facility, the XMCD beamline (BL12B) and photoelectron spectroscopy beamline (BL10B) in National Synchrotron Radiation Laboratory (NSRL) of Hefei.
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