Abstract
A decade has passed since organoboron π-conjugated systems highly extended through the empty p-orbital of the boron atom emerged as a new class of π-conjugated materials. Making use of convenient hydroboration polymerization, a variety of π-conjugated organoboron polymers exhibiting fluorescence emission, n-type electrochemical activity, electrical conductivity, third order non linear optical property, anion sensing ability is easily prepared. The organoboron π-conjugated polymers having highly bulky substituent on the boron atom shows high stability under air and moisture and therefore, potentially useful for versatile applications.The design of electron deficient organoboron π-systems led to observation of unique photophysical behavior such as extraordinary high third order non linear optical susceptibility, facilitation of pπ-dπ* transition, intramolecular charge transfer, unusually activated σ-π conjugative interaction and so forth.In addition to boration polymerization methods, polycondensation using di-Grignard reagent, Sonogashira type polycondensation, polycondensation via tin-boron exchange are useful for synthesis of π-conjugated organoboron polymers.
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Matsumi, N., Chujo, Y. π-Conjugated Organoboron Polymers via the Vacant p-Orbital of the Boron Atom. Polym J 40, 77–89 (2008). https://doi.org/10.1295/polymj.PJ2007170
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DOI: https://doi.org/10.1295/polymj.PJ2007170
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