Abstract
Thermal emission in the infrared range is important in various fields of research, including chemistry, medicine and atmospheric science1,2,3. Recently, the possibility of controlling thermal emission based on wavelength-scale optical structures has been intensively investigated with a view towards a new generation of thermal emission devices4,5,6,7,8,9,10,11. However, all demonstrations so far have involved the ‘static’ control of thermal emission; high-speed modulation of thermal emission has proved difficult to achieve because the intensity of thermal emission from an object is usually determined by its temperature, and the frequency of temperature modulation is limited to 10–100 Hz even when the thermal mass of the object is small12. Here, we experimentally demonstrate the dynamic control of thermal emission via the control of emissivity (absorptivity), at a speed four orders of magnitude faster than is possible using the conventional temperature-modulation method. Our approach is based on the dynamic control of intersubband absorption in n-type quantum wells, which is enhanced by an optical resonant mode in a photonic crystal slab. The extraction of electrical carriers from the quantum wells leads to an immediate change in emissivity from 0.74 to 0.24 at the resonant wavelength while maintaining much lower emissivity at all other wavelengths.
This is a preview of subscription content, access via your institution
Access options
Subscribe to this journal
Receive 12 print issues and online access
$259.00 per year
only $21.58 per issue
Buy this article
- Purchase on Springer Link
- Instant access to full article PDF
Prices may be subject to local taxes which are calculated during checkout
Similar content being viewed by others
References
Stuart, B. Infrared Spectroscopy: Fundamentals and Applications (John Wiley, 2004).
Meola, C. & Carlomagno, G. M. Recent advances in the use of infrared thermography. Meas. Sci. Technol. 15, R27–R58 (2004).
Hodgkinson, J. & Tatam, R. P. Optical gas sensing: A review. Meas. Sci. Technol. 24, 012004 (2013).
Greffet, J-J. et al. Coherent emission of light by thermal sources. Nature 416, 61–64 (2002).
Lin, S. Y., Moreno, J. & Fleming, J. G. Three-dimensional photonic-crystal emitter for thermal photovoltaic power generation. Appl. Phys. Lett. 83, 380–382 (2003).
Chan, D. L. C., Soljačić, M. & Joannopoulos, J. D. Thermal emission and design in 2D-periodic metallic photonic crystal slabs. Opt. Express 14, 8785–8796 (2006).
Ikeda, K. et al. Controlled thermal emission of polarized infrared waves from arrayed plasmon nanocavities. Appl. Phys. Lett. 92, 021117 (2008).
Mason, J. A., Smith, S. & Wasserman, D. Strong absorption and selective thermal emission from a midinfrared metamaterial. Appl. Phys. Lett. 98, 241105 (2011).
Liu, X. et al. Taming the blackbody with infrared metamaterials as selective thermal emitters. Phys. Rev. Lett. 107, 045901 (2011).
Zoysa, M. D. et al. Conversion of broadband to narrowband thermal emission through energy recycling. Nature Photon. 6, 535–539 (2012).
Inoue, T., Zoysa, M. D., Asano, T. & Noda, S. Single-peak narrow-bandwidth mid-infrared thermal emitters based on quantum wells and photonic crystals. Appl. Phys. Lett. 102, 191110 (2013).
Hildenbrand, J. et al. Micromachined mid-infrared emitter for fast transient temperature operation for optical gas sensing systems. IEEE Sensors J. 10, 353–362 (2010).
Brace, D. B. The Laws of Radiation and Absorption: Memoirs by Prévost, Stewart, Kirchhoff, and Kirchhoff and Bunsen (American Book Company, 1901).
Vassant, S. et al. Electrical modulation of emissivity. Appl. Phys. Lett. 102, 081125 (2013).
West, L. C. & Eglash, S. J. First observation of an extremely large-dipole infrared transition within the conduction band of a GaAs quantum well. Appl. Phys. Lett. 46, 1156–1158 (1985).
Asano, T., Noda, S., Abe, T. & Sasaki, A. Investigation of short wavelength intersubband transitions in InGaAs/AlAs quantum wells on GaAs substrate. J. Appl. Phys. 82, 3385–3391 (1997).
Imada, M. et al. Coherent two-dimensional lasing action in surface-emitting laser with triangular-lattice photonic crystal structure. Appl. Phys. Lett. 75, 316–318 (1999).
Imada, M., Chutinan, A., Noda, S. & Mochizuki, M. Multidirectionally distributed feedback photonic crystal lasers. Phys. Rev. B 65, 195306 (2002).
Chan, D. L. C., Celanovic, I., Joannopoulos, J. D. & Soljačić, M. Emulating one-dimensional resonant Q-matching behavior in a two-dimensional system via Fano resonances. Phys. Rev. A 74, 064901 (2006).
Asano, T., Mochizuki, K., Yamaguchi, M., Chaminda, M. & Noda, S. Spectrally selective thermal radiation based on intersubband transitions and photonic crystals. Opt. Express 17, 19190–19203 (2009).
Inoue, T., Asano, T., Zoysa, M. D., Oskooi, A. & Noda, S. Design of single-mode narrow-bandwidth thermal emitters for enhanced infrared light sources. J. Opt. Soc. Am. B 30, 165–172 (2013).
Werle, P. et al. Near- and mid-infrared laser-optical sensors for gas analysis. Opt. Laser Eng. 37, 101–114 (2002).
Inoue, T., Zoysa, M. D., Asano, T. & Noda, S. Filter-free nondispersive infrared sensing using narrow-bandwidth mid-infrared thermal emitters. Appl. Phys. Express 7, 012103 (2014).
Lee, B. G. et al. Widely tunable single-mode quantum cascade laser source for mid-infrared spectroscopy. Appl. Phys. Lett. 91, 231101 (2007).
Acknowledgements
This work was partially supported by a Grant-in-Aid for Scientific Research (S) from the Japan Society for the Promotion of Science (JSPS), Core Research for Evolutional Science and Technology (CREST) from the Japan Science and Technology Agency (JST), and by Grants for Excellent Graduate Schools from the Ministry of Education, Culture, Sports, Science and Technology (MEXT). T.I. also acknowledges support from a Research Fellowship of the JSPS.
Author information
Authors and Affiliations
Contributions
S.N. supervised the entire project with T.A. T.I. fabricated the samples, performed the experiments and analysed the data with M.D.Z. S.N., T.I., M.D.Z. and T.A. discussed the results and wrote the paper.
Corresponding author
Ethics declarations
Competing interests
The authors declare no competing financial interests.
Supplementary information
Supplementary Information
Supplementary file (PDF 1528 kb)
Rights and permissions
About this article
Cite this article
Inoue, T., Zoysa, M., Asano, T. et al. Realization of dynamic thermal emission control. Nature Mater 13, 928–931 (2014). https://doi.org/10.1038/nmat4043
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1038/nmat4043
This article is cited by
-
Transparent dynamic infrared emissivity regulators
Nature Communications (2023)
-
Self-evolving photonic crystals for ultrafast photonics
Nature Communications (2023)
-
Electrochemically modulated interaction of MXenes with microwaves
Nature Nanotechnology (2023)
-
Whole-infrared-band camouflage with dual-band radiative heat dissipation
Light: Science & Applications (2023)
-
Nanophotonic catalytic combustion enlightens mid-infrared light source
Nano Research (2023)