Abstract
Monolayer molybdenum disulfide (MoS2) has attracted tremendous attention due to its promising applications in high-performance field-effect transistors, phototransistors, spintronic devices and nonlinear optics. The enhanced photoluminescence effect in monolayer MoS2 was discovered and, as a strong tool, was employed for strain and defect analysis in MoS2. Recently, large-size monolayer MoS2 has been produced by chemical vapour deposition, but has not yet been fully explored. Here we systematically characterize chemical vapour deposition-grown MoS2 by photoluminescence spectroscopy and mapping and demonstrate non-uniform strain in single-crystalline monolayer MoS2 and strain-induced bandgap engineering. We also evaluate the effective strain transferred from polymer substrates to MoS2 by three-dimensional finite element analysis. Furthermore, our work demonstrates that photoluminescence mapping can be used as a non-contact approach for quick identification of grain boundaries in MoS2.
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Introduction
High-quality and single-layered molybdenum disulfide (MoS2) has been synthesized by chemical vapour deposition (CVD) over the past 2 years1,2,3,4,5,6,7,8,9, boosting its promise in applications involving hydrogen evolution reaction10, supercapacitors11, ultra-low power consumption field-effect transistors and phototransistor12,13, spintronic devices14, nonlinear optics15 and biosensors16. CVD-grown MoS2 atomic layers are also superior to samples prepared by mechanical exfoliation and chemical isolation methods, as continuous monolayer MoS2 (hereafter 1H-MoS2) can currently be grown at the centimetre-length scale3,11,17,18. However, concurrently with the large-scale growth of monolayer MoS2, variations in crystal geometries and atomic structures have been predicted and observed19. Geometrically, MoS2 triangles, hexagons, six-pointed stars, irregular shapes and continuous films can be synthesized, depending on the precise growth conditions such as pressure, temperature, substrates, precursors, cooling rate and so on3,4,5,18,20. Structurally, like graphene, a wide variety of grain boundaries (GBs) has been observed in polycrystalline CVD-grown MoS2 (refs 3, 4, 21). Thus, it is important to understand how these variations modify the physical properties of MoS2.
It is well known that MoS2 has an indirect-to-direct bandgap transition as it is thinned down from multi-layer to monolayer, producing a significant enhancement of photoluminescence (PL) quantum yield as a result of the direct bandgap excitonic transition22,23. However, the intensities and peak positions of such PL signals closely correlate with many other parameters such as crystal structure, local doping and strain within the sample and require more detailed examination. CVD-grown MoS2 with the richness of its intrinsic and extrinsic defects show significant heterogeneity in PL characteristics. Consequently, a systematic examination of PL characteristics in CVD-grown MoS2 could provide information to help better understand the growth mechanisms, crystal structure and band structure of these monolayers.
In this work we examine the PL characteristics of CVD-grown MoS2 monolayers with a focus on the role of growth-induced non-uniform strain and GBs. We examine the PL intensity and peak position variations observed in different samples and explore the possible contributions to such changes. We find that non-uniform tensile strain is intrinsic to CVD-grown MoS2 on SiO2 and such strain variation can be identified by PL mapping. Such strain is induced through interactions with the SiO2 substrate and can be released after transferring MoS2 to other substrates. On the other hand, controlled tensile strain could be purposely introduced to monolayer MoS2 by stretching the deformable substrates it sits on, therefore providing an effective method for bandgap engineering. To understand the role of substrate properties on effective strain transfer and corresponding band structure changes in MoS2, three-dimensional (3D) finite element analysis (FEA) and DFT calculations were performed. These results indicate that substrates with high Young’s modulus can dramatically reduce the strain loss during tensile experiments, while the commonly used polydimethylsiloxane (PDMS) can only transfer ~10% tensile strain to MoS2. Finally, examination of line defects in monolayer MoS2 samples shows that GBs can modulate the PL response of the material in ways different from what has been previously proposed. This not only gives insight into mechanisms of PL modulation at the GBs but also exemplifies a technique superior to dark-field imaging in transmission electron microscopy (TEM) for their non-destructive visualization in MoS2 monolayers.
Results
Sources of PL heterogeneity in CVD-grown MoS2
To explore the heterogeneity in CVD-grown MoS2 atomic layers, we synthesize MoS2 single-crystal and polycrystalline films using MoO3 nanoribbons and sublimated sulfur as the sources for Mo and S, respectively, and react at a temperature of ~850 °C followed by a fast-cooling phase (see Methods)4. The growth of large-area films has been proven to be a process of nucleation, growth and coalescence of single-crystalline triangular domains. More importantly, the formation of these films is nucleation limited, and using pristine silicon dioxide substrates, one can truncate the process to form isolated single crystals. Our experiments show that the configuration and position of the MoO3 relative to the designated growth substrate is critical to the shape and structure of the as-grown crystals. As a result, one can promote the growth of polycrystalline flakes and continuous films with unique geometries suitable for comprehensive study of PL in MoS2 (Fig. 1a–d).
Some general features of the MoS2 flakes and films grown using this method are shown in Fig. 1, such as single-crystal triangular MoS2 flake (Fig. 1a), irregular MoS2 shapes (Fig. 1b), symmetric six-pointed MoS2 star (Fig. 1c) and polycrystalline MoS2 films (Fig. 1d). The bright areas located at the centre of MoS2 layers (Fig. 1b) are the original nucleation sites for the crystals. The quality of the CVD-grown MoS2 is comparable to that of the exfoliated samples, which has been confirmed by multiple characterization techniques4. The perfect lattice of monolayer MoS2 (Fig. 1e) can be seen from the annular dark-field scanning TEM imaging. The brighter atomic sites are Mo atoms, while the weaker ones are double-S columns. GBs are also found in the CVD-grown MoS2 (Fig. 1f) with many variations as discussed in our previous work4,21. For large-area films, some GBs are observed from the optical images where a second-layer MoS2 tends to grow along the GBs, resulting in dark purple stripes indicated by the white arrows (Fig. 1d). Typical Raman spectra and intensity mapping from these mono-/bilayer topographies are shown in the Supplementary Fig. 1. These features indicate that GBs are preferred sites for nucleation of second layers. However, these optically identifiable features do not fully account for all the GBs present in the samples (Fig. 1b,c). PL characterization of these typical crystals can provide more information about distinctive features of different growth modes due to the enhanced intensity of monolayer MoS2 (ref. 22).
Native strain variations in CVD-grown MoS2 monolayers
Figure 2 presents high-resolution Raman and PL mapping of a MoS2 triangular single crystal, acquired with long integration times to observe subtle shifts in the signal. Raman mapping of the E12g and A1g peaks shows a uniform intensity (with <5% variation) over the triangle (Fig. 2a,b). However, significant variations are seen in the PL intensity mapping (Fig. 2c) and it can be seen that the edges and some regions within the triangles have up to a ~200% higher intensity. Raman and PL peak position mapping provide images with better contrast. Clear lines related to the shift in peak positions (~1.0 cm−1 hardening in E12g and 0.4 cm−1 in A1g) can be observed (Fig. 2d,e). More interestingly, the best contrast is seen in the PL peak position mapping (blue lines in Fig. 2f) along and perpendicular to the edges, corresponding to a blue shift of ~8 meV (Fig. 2g). We propose that these characteristics may arise from the growth process that ends with a fast-cooling phase. Since the coefficient of thermal expansion of silica is roughly six times smaller than MoS2 (refs 24, 25), a fast-cooling process from the growth temperature (~850 °C) could create a significant contraction mismatch (Supplementary Discussion). As a result, the monolayer MoS2 triangles will be in tensile strain. Local strain variation regions extended from the edges vertically are towards the centre (Fig. 2d–f). In other words, after cooling, the CVD MoS2 monolayer triangles are under a tensile strain but contains localized regions where this strain has been partially released (less strained) possibly due to combined effects of geometry and inevitable variations in interactions with the substrate. To estimate this CVD growth-induced strain variations, density functional theory (DFT) calculations are performed and a relationship between the PL peak position shift and the strain variations in the sample is established (Fig. 2h). The corresponding difference in strain is estimated to be ~0.2%. Although the DFT simulations do not account for the excitonic effects, the relative change of the calculated bandgap with respect to uniaxial strain (−44 meV per % strain) matches quite well with previous experiments on the PL peak position shift with strain (−45 meV per % strain26 and −36 meV per % strain27. Furthermore, as we mentioned, due to the fast cooling, a global tensile strain is found in MoS2. To support our conjecture, we transfer MoS2 to a new Si/SiO2 substrate and compare the PL mapping. As expected, the tensile strain in the film as well as the local variations are released after the transfer process (Supplementary Figs 2 and 3). The global tensile strain is estimated to be ~1%. This information provides insight into the role of thermal property mismatch between the substrate and MoS2 in the CVD process. Our observations suggest that PL studies can be effectively used as a strain-mapping tool and a tool to evaluate strain-induced bandgap engineering if an independent and robust link between the two parameters can be established. To further explore the role of substrate properties in MoS2 strain engineering, a well-controlled experiment is performed. This experiment will also correlate strain with optical and band structure properties of monolayer MoS2.
Bandgap engineering and effective strain transfer for MoS2
Substrate-induced straining of 2D materials for band structure engineering has been effectively explored in previous studies26,28. However, these experiments have only been performed on exfoliated samples and a comprehensive study of the role of substrate and homogeneity on the transferred strain has not been explored. Most recently, the strain-induced bandgap changes in monolayer MoS2, using polymer substrates, has been demonstrated26,28,29,30. However, because of the weak adhesion between MoS2 and substrates, strain cannot be completely transferred to MoS2 from the substrate, as exemplified in graphene strain-engineering studies31,32. Understanding how much strain is effectively transferred to the MoS2 samples becomes critical to bridge experimental data and theoretical calculations. In our work, monolayer MoS2 triangles have been transferred from SiO2 to PDMS (~0.5 mm in thickness; Fig. 3a). As we discussed in Fig. 1 and Supplementary Fig. 2, through the transfer, the thermal mismatch induced tensile strain in MoS2 and related local strain variations are released. Uniaxial force is then applied to the sample in the direction indicated by the arrows in Fig. 3a,c and was directly observed since the MoS2 on PDMS is visible under optical microscopy (Fig. 3b). Deformation of MoS2 flakes is clearly seen after the application of force on the PDMS (Fig. 3c, under 4.8% tensile strain). The PL intensity (Fig. 3d) and peak position (Fig. 3e) mapping were obtained for this sample under an increasing tensile strain from 0 to 4.8%. Individual PL spectra are shown in Fig. 3f. The corresponding energy shift and intensity versus tensile strain are plotted in Fig. 3g. It is worth noting that no hysteresis was observed for the loading and unloading processes, which exclude the possibility of sliding effect between MoS2 and substrates (Supplementary Fig. 4).
It is apparent that not all of the applied strain to the PDMS substrate was transferred to MoS2 crystals, if one were to compare the results from Figs 2g,h and 3f,g. The heterogeneity of PL at zero strain also suggests that the transfer process and PDMS surface properties result in a non-uniform contact between the substrate and material. To better explain the experimental results and estimate the strain transferred to MoS2 layer under such tensile tests, a 3D FE model was developed, as schematically shown in Fig. 4. Due to the symmetry, one half of the triangular sample was used in the model, and the model consists of one monolayer MoS2 with a thickness of 0.7 nm, placed on the surface of PDMS substrate with a thickness of 100 μm (Fig. 4a–c).
Figure 4d–h shows the strain distribution in the triangular MoS2 layer at different applied strains on PDMS. The tensile strain is clearly transferred from the substrate to the MoS2 layer. The strain transferred to MoS2 layer initiates from the top of the triangle (point A in Fig. 4c) and then propagates down along the triangle and finally extends to the bottom. Interestingly, the predicted strain distribution across the MoS2 is in good agreement with the PL peak position mapping shown in Fig. 3e, indicating that the PL peak position distribution is closely correlated to the local strain. The strains in MoS2 layer as a function of the applied strain on PDMS are shown in Fig. 4i, where a linear relationship is predicted within the range of 5% at which the substrates have still not yielded under such applied strain levels. When the applied strain reaches 4.8%, as in the experiment, the strain in MoS2 layer varies ranging from 0.50, 0.27 and 0.14% at points A, B and C (Fig. 4c), respectively. Thus, up to 10% of the applied strain has been effectively transferred to MoS2 layer in the case of assuming perfect van der Waals bonding between the MoS2 and the substrate. These results correlate well with the earlier PL peak position mapping of the CVD-grown MoS2 crystal with strain variations and corresponding DFT calculations, confirming the validity of the proposed method for strain detection and bandgap engineering evaluation using the PL peak position mapping technique. They also demonstrate the role of substrate and crystal geometry.
In addition, it is important to calculate the effective strain transfer from the polymer to MoS2 and demonstrate how to promote the strain transfer for bandgap engineering. In our experiments, with 4.8% tensile strain applied to the PDMS substrate, only a 15-meV shift was observed in the PL spectra near the centre of the triangle, corresponding to ~0.5% tensile strain according to DFT calculations. It should be noted here that DFT-LDA (local-density approximation) usually produces a relatively lower value than the true bandgap, yet the change in bandgap can be more accurately determined, although the absolute value is underestimated33. Our work suggests that only ~10% of the applied strain is effectively transferred to MoS2 when using PDMS as a substrate. Note that this strain transfer efficiency was also confirmed by the earlier FE simulation (Fig. 4). Therefore, it will be of practical importance to further investigate the strain loss mechanisms in such a system. We calculated the strain in the MoS2 layer for various substrates with Young’s modulus ranging from 0.35 KPa to 1 GPa. The maximum transfer strain versus Young’s modulus is shown in Fig. 4j. If the Young’s modulus of a substrate is below 1 MPa, the transferred strain is about 0.5% for an applied strain of 5%. With the increasing substrate modulus, the transferred strain quickly increases to 4.7% for the same applied strain, indicating that almost 90% of the applied strain is transferred to the MoS2 layer. As a controllable experiment, we transferred the MoS2 to polyvinyl alcohol with Young’s modulus around 650 MPa, around three orders of magnitude higher than PDMS (~430 KPa). It turns out ~60% strain that has been effectively transferred to MoS2 based on a linear extrapolation from Fig. 2h (Supplementary Fig. 5). This result supports our FE simulation predictions. Thus, increasing the substrate modulus could significantly increase the strain in MoS2 layer if a high-quality interface is preserved. This result provides a very useful guideline for the fabrication of highly tunable MoS2 electronic devices.
Structural heterogeneity in CVD-grown MoS2 monolayers
In addition to strain heterogeneity, GBs are one of the most significant structural features in CVD-grown polycrystalline MoS2 samples as shown in Fig. 1b–d. Attempts to grow large-area crystals of MoS2 has rendered an unavoidable polycrystallinity that calls for better and simpler identification method for detecting the GBs and understanding their role in the electronic and optical properties of the material. The experimental and theoretical work on the GBs of MoS2 has revealed a rich diversity in their structure19,21. It is known that monolayer MoS2 has a hexagonal lattice structure similar to graphene and h-BN. However, in contrast to single-atom-thick graphene, MoS2 monolayers consist of two layers of sulfur atoms sandwiching a layer of molybdenum atoms. This results in a variety of dislocation cores, constituting the grain boundary configurations in MoS2, as opposed to the most common 5–7 ring configuration in graphene34. In addition, variations in the lattice orientation mismatch at the boundaries and non-bonding second-layer growth are common features observed in CVD-grown large-area MoS2 films4. It was also found that the twin GB in MoS2 may exhibit metallic behaviour21. The most reliable method for identification of GBs has traditionally been the high-resolution TEM techniques, which can directly inspect its detailed atomic structural characteristics. This approach provides a unique atomic-level perspective of the MoS2 boundaries, but is not suitable for direct examination of large-area samples/devices that are ready for subsequent optical and electrical measurements. Consequently, optical-based microscopy techniques for identification and characterization of GBs have been explored using high-resolution PL mapping.
Non-contact optical techniques such as Raman spectroscopy can be employed to map the GBs of graphene. Since the Raman spectra for MoS2 is very sensitive to the number of layers, it has been proposed as a suitable approach for detection of over-layered MoS2 GBs (Supplementary Fig. 6). Nevertheless, for monolayer MoS2, this technique is not efficient in detecting GBs because the Raman signal is very weak and strongly dependent on the laser power for monolayer MoS2. PL variations at the GB have also been explored; however, little is known about the fundamental reasons for the observed changes. As discussed earlier, the PL peak position mapping is proven to be an effective method to detect intrinsic strains in monolayer MoS2 (ref. 21). It is well known that the grain boundary in 2D material consists of lined-up dislocations, which naturally may introduce localized strain in their vicinity. In addition, the variety in CVD-grown crystal geometries and grain boundary types can be utilized to further gather insight into their role in MoS2 PL characteristics.
To analyse the PL response of GBs in polycrystalline MoS2, we examine a representative six-pointed MoS2 star with six twin GBs (Fig. 5a). The PL intensity mapping (Fig. 5b) reveals the enhanced intensity characteristics of six mirror-twin GBs. Such twin structures have also been confirmed by the PL peak position mapping (Fig. 5c). The same structure has been observed under dark-field TEM3. It was found that the outer edges are oriented along the Mo-z-z (molybdenum zigzag) direction, while GBs occur along the S-z-z (sulfur zigzag) direction (Supplementary Fig. 7)3. Nevertheless, these GBs represent unique defect characteristics. PL line profiles and five individual PL spectrums along the lines indicated in their respective scans are recorded (Fig. 5d–f). Their locations are labelled in Fig. 5c. Three of the points are located at the pristine MoS2 and two of them at the GBs. An enhancement in the PL up to 250% is observed at the GBs (Fig. 5d,e). The highest PL intensity is found at the GBs and edges, which is opposite to the report from Van der Zande et al.3 who observed a lower PL intensity along the GBs in monolayer MoS2. The physical scenario of PL along the GBs is very complicated. According to previous studies, defects at the edges and the GBs may contribute the enhancement of PL intensity. New sub-bandgap emission peak as well as increase in overall PL intensity were found as a result of the vacancy generation35 via a defect-assisted process36. Here, our results also imply that a local interaction also plays an important role in the PL variations. We propose that the non-uniform strain due to the thermal mismatch of the substrate, randomness of interface properties and strain transfer and tensile straining native to GBs combined make the most significant contribution to the optical bandgap shifts. We find that, in Fig. 5, the PL peak shift is ~5 meV at the GBs and ~15 meV at the edges in monolayer MoS2. This small blue shift indicates that no matter what type of defects exist at the GBs, their behaviour tends to be very similar. This further supports our hypothesis that strain at the GBs is possibly the main reason for the observation of changes in the PL characteristics of MoS2. To confirm the strain in GBs, we collected low-temperature PL spectra at non-GB and GB locations. The shifts have been found for both locations and the difference in peak location increases, demonstrating that the PL spectra at the GBs are more sensitive to the change of strain (Supplementary Fig. 8). We have examined the temperature dependency of the bandgap and PL positions of MoS2 atomic layers using a modified Varshni model (Supplementary Fig. 8)37. These results show a good fit for the measurement of the optical gap in the crystalline region and the grain boundary regions of MoS2, implying that the changes seen in the PL characteristics are not results of disorder and localizations in the excitonic transitions. Also, not only for the symmetric MoS2 stars, similar results have been seen from the asymmetric polycrystalline MoS2 flakes with GBs (Supplementary Fig. 9). In addition, we have also noticed that, in some MoS2 polycrystalline flakes, the GBs were broken induced by tensile strain. It further confirms the vulnerability of GBs in MoS2 (Supplementary Fig. 10) and the impact of strain.
Discussion
In this work, we have used PL mapping to study strain and structural heterogeneity in PL characteristics of CVD-grown MoS2 monolayers. We observe and quantify the native non-uniform strain in such samples and propose that the difference in thermal expansion coefficient of MoS2 and the supporting SiO2 substrate leads to an intrinsic tensile strain in MoS2 during the fast-cooling process at the final stage of the growth. A relationship between the PL peak position shifts and strain is established and can be used for strain detection and bandgap engineering evaluation. Further examination of substrate-mediated straining process provides important insight into the role of substrate in effective strain transfer. Through FE simulation and controlled tensile experiments, we find that for PDMS substrates only ~10% of the applied strain can be effectively transferred to MoS2. Moreover, we demonstrate how strain concentration propagates in a triangular MoS2 monolayer crystal and propose substrates’ Young’s modulus as dominating mechanisms of strain loss. A substrate with a modulus >1 GPa may effectively transfer almost 90% of the applied strain to monolayer MoS2 when perfect interfacial contact conditions are provided. In addition, we examine the discrepancies in the literature about the role of GBs in PL characteristics of MoS2. Our results suggest that thermally induced non-uniform tensile strain plays a significant role in grain boundary optical properties. Our results also provide a promising way for fabrication and study of highly tunable MoS2 electronic devices and mechanisms of strain transfer in 2D atomic layers.
Methods
CVD of monolayer MoS2
To synthesize MoS2, the precursors, MoO3 films, were prepared through the filtration of their highly crystalline nanoribbons. These ribbons were produced hydrothermally through a process widely used for synthesis of this type of single-crystalline material. Sodium molybdate (Na2MoO4) or hexaammonium heptamolybdate tetrahydrate (NH4)6Mo7O24·4H2O was used as precursors for the preparation of MoO3 nanoribbons. We dissolve 1.2 g of these precursors in nitric acid and transfer to a Teflon container and heat it at 170 °C for 1–2 h. These MoO3 nanoribbons have a high aspect ratio, roughly 20 μm in length, 1–2 μm in width and thickness in the range of 10–40 nm. After the preparation of these MoO3 precursors, the ribbons were filtered, and large-area films were formed, cut into pieces and dispersed on silicon substrates. Several bare and clean substrates, designate for the growth of MoS2, and the MoO3 film were placed close to each other at the centre of the furnace vented with nitrogen at 200 sccm. A container was filled with 0.8–1.2 g of sublimated sulfur and placed at the opening of the furnace at a location that reaches an approximately maximum temperature of 600 °C. The heating procedure corresponding to the temperature at the centre of the furnace starts with a gradual heating from room temperature to 550 °C in 30 min at a rate of ~20 °C min−1. Then, at a slower pace, ~5 °C min−1, the chamber is heated to 850 °C. After 10–15 min at this temperature, the furnace is cooled naturally back to room temperature. At temperatures close to 550 °C at the centre, sulfur will slowly start to evaporate and the central interaction between this element and MoO3 follows.
Both Raman and PL data were collected using a 532-nm laser excitation focused through a × 100 objective lens. This resulted in a spot size of ~342 nm where scanning was performed using 200 nm steps on a piezoelectric stage to obtain high-resolution images. All Raman and PL spectra presented in this manuscript for MoS2 on SiO2/Si were taken at an incident laser power of 12.5 μW, which was sufficiently low to avoid any shifting of the Raman modes during scanning. Mapping on the PDMS substrate was performed at an incident laser power of 50 μW to improve the signal to noise ratio. The PL peak position was found to be much less sensitive to the laser power density. Specifically, the laser power dependence on Raman peak position and intensity is shown in Supplementary Figs 11 and 12 and shows that the layer number can easily be incorrectly determined when scanning at high power densities.
DFT calculations
DFT calculations within the LDA were performed using the projector-augmented wave (PAW) method38,39, as implemented in Vienna Ab-initio Simulation Package40,41. Twelve electrons were included for Mo pseudopotential. A vacuum layer >12 Å was introduced to make the spurious interactions negligible. A 11 × 11 × 1 Monkhorst-Pack k-point mesh centred at the Γ-point was adopted for the Brillouin zone integration. With an energy cutoff of 280 eV, a plane-wave-based total energy minimization scheme42 was employed until the force on each atom was <0.01 eV Å−1. The uniaxial strain was applied either in the armchair (AC) or zigzag (ZZ) direction.
3D FEA
The discretized FE models contain about 53,254 nodes and 49,584 elements with very fine meshes in the contact region. The final mesh density was determined through a series of convergence studies. Appropriate boundary conditions were used along two edges of the specimen to simulate the loading strain during testing. The interface between MoS2 and PDMS were modelled using perfect bonding. The calculations were performed using the commercial FE package ABAQUS (version 6.10). Young’s modulus and Poisson’s ratio for PDMS are 350 KPa and 0.5, and 300 GPa and 0.3, respectively, were used in the simulation.
Additional information
How to cite this article: Liu, Z. et al. Strain and structure heterogeneity in MoS2 atomic layers grown by chemical vapour deposition. Nat. Commun. 5:5246 doi: 10.1038/ncomms6246 (2014).
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Acknowledgements
This work was supported by the Welch Foundation grant C-1716, the NSF grant ECCS-1327093, the U.S. Army Research Office MURI grant W911NF-11-1-0362, the U.S. Army Research Lab (ARL) Director’s Strategic Initiative (DSI) program on interfaces in stacked 2D atomic layered materials, the U.S. Office of Naval Research MURI grant N000014-09-1-1066, the Nanoelectronics Research Corporation contract S201006, a Wigner Fellowship through the Laboratory Directed Research and Development Program of Oak Ridge National Laboratory, managed by UT-Battelle, LLC, for the U.S. DOE (W.Z.), and through a user project supported by ORNL’s Center for Nanophase Materials Sciences (CNMS), which is sponsored by the Scientific User Facilities Division, Office of Basic Energy Sciences, U.S. DOE. This work was also supported in part by the FAME Center, one of six centres of STARnet, a Semiconductor Research Corporation program sponsored by MARCO and DARPA. This work was also supported by the Singapore National Research Foundation under NRF RF Award No. NRF-RF2013-08, the start-up funding from Nanyang Technological University (M4081137.070). The computations were performed at the Cyberinfrastructure for Computational Research funded by NSF under Grant CNS-0821727 and the Data Analysis and Visualization Cyberinfrastructure funded by NSF under Grant OCI-0959097.
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Z.L., M.A. and S.N. contributed equally to this work. Z.L., M.A., A.G.B. and J.L. designed the experiments. Z.L., M.A. and A.G.B. carried out most of the PL and Raman characterizations and analysed the data. S.N. worked on the CVD growth of MoS2 and PL strain experiments. Q.X. and Z.X. performed the FEA simulation. X.Z. and B.I.Y. worked on the DFT calculation. W.Z. carried out STEM experiments. T.Y. and C.Q. conducted the PL characterizations for part of the samples and data analysis. Z.L., M.A., S.N., Q.X., Z.X., W.Z. and J.L. co-wrote the paper. All the authors discussed the results.
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Supplementary Figures 1-12, Supplementary Discussion and Supplementary References (PDF 1260 kb)
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Liu, Z., Amani, M., Najmaei, S. et al. Strain and structure heterogeneity in MoS2 atomic layers grown by chemical vapour deposition. Nat Commun 5, 5246 (2014). https://doi.org/10.1038/ncomms6246
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DOI: https://doi.org/10.1038/ncomms6246
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