Abstract
ZSM-5 (ref.1) and ZSM-11 (ref. 2) are silica-rich aluminosilicate zeolites with similar two-dimensional intersecting channel structures. They are conventionally synthesised from Na+–tetraalkylammonium (Na+–TAA) systems at high pH and temperatures around 160°C (refs 3–6). We report here what we believe to be the first use of systems free of alkali metal ions in the synthesis of the zeolites ZSM-5 and ZSM-11.
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References
Kokotailo, G. T., Lawton, S. L., Olson, D. H. & Meier, W. M. Nature 272, 437–438 (1978).
Kokotailo, G. T., Chu, P., Lawton, S. L. & Meier, W. M. Nature 275, 119–120 (1978).
US Patent 3 702 886.
US Patent 3 728 408.
US Patent 3 709 979.
UK Patent 1 161 974.
Rollman, L. D. in Inorganic Compounds with Unusual Properties Vol. II (ed. King, R.B.) 387–395 (American Chemical Society, New York, 1979).
Meisel, S. L., McCullough, J. P., Lechthaler, C. H. & Weisz, P. B. Chem. Technol. 6, 86 (1976).
Chang, C. D. & Silvestri, A. J. J. Catal. 47, 249–259 (1977).
Barrer, R. M. & Denny, P. J. J. chem. Soc. 971–982 (1961).
Baerlocher, Ch. & Meier, W. M. Helv. chim. Acta 52, 1853–1860 (1969).
Baerlocher, Ch. & Meier, W. M. Helv. chim. Acta 53, 1285–1293 (1970).
US Patent 3 306 922.
Flanigen, E. M. et al. Nature 271, 512–516 (1978).
Bibby, D. M., Milestone, N. B. & Aldridge, L. P. Nature 280, 664–665 (1979).
Australian Patent 70481/74.
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Bibby, D., Milestone, N. & Aldridge, L. NH4+-tetraalkyl ammonium systems in the synthesis of zeolites. Nature 285, 30–31 (1980). https://doi.org/10.1038/285030a0
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DOI: https://doi.org/10.1038/285030a0
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