Abstract
The ground state of the perhydroxyl ion has been studied theoretically by the Pople–Segal self-consistent field molecular orbital method. The results suggest that 2-electron equivalent atom transfer processes may be important in the redox chemistry of peroxides.
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References
Pople, J. A., Santry, D. P., and Segal, G. A., J. Chem. Phys., 43, S, 129 (1965). Pople, J. A., and Segal, G. A., ibid., 43, S, 136 (1965).
Roothaan, C. C. J., J. Chem. Phys., 19, 1445 (1951).
Tables of Interatomic Distances and Configuration in Molecules and Ions (Chem. Soc., Special Publ. No. 11, 1958).
Khan, A. V., and Kasha, M., J. Chem. Phys., 39, 2, 105 (1963); Nature, 204, 241 (1964); J Amer. Chem. Soc., 88, 1574 (1966).
Erdey, L., and Inczedy, J., Acta Chim. Hung., 11, 125 (1956).
Anbar, M., J. Amer. Chem. Soc., 88, 5924 (1966).
Higginson, W. C. E., and Marshall, J. W., J. Chem. Soc., 447 (1957).
Edwards, J. O., Inorganic Reactions Mechanisms, chap. 5 (W. A. Benjamin, Inc., New York, 1965).
Anbar, M., and Taube, H., J. Amer. Chem. Soc., 76, 6243 (1954).
Ibne-Rasa, K. M., and Edwards, J. O., J. Amer. Chem. Soc., 84, 763 (1962).
Overberger, C. G., and Cummins, R. W., J. Amer. Chem. Soc., 75, 4250 (1953).
Kremer, M. L., and Stein, G., Trans. Faraday Soc., 55, 959 (1959); 58, 702 (1962).
Wang, J. H., J. Amer. Chem. Soc., 77, 4715 (1955); 80, 6477 (1958).
Nicholls, P., and Schonbaum, G. R., in Boyer, P. D., Lardy, H., and Myrbäck, K. (eds.), 8, 147 (Academic Press, Inc., New York, 1963).
Jones, P., and Wynne-Jones, W. F. K., Trans. Faraday Soc., 58, 1148 (1962).
Yonetani, T., J. Biol. Chem., 240, 4509 (1965).
Kremer, M. L., and Stein, G., Actes du 2eme Congres Intern. de Catalyse, Paris, 551 (1960).
Ingraham, L. L., Biochemical Mechanisms, 70 (John Wiley and Sons, Inc., New York, 1962).
Ball, R. E., Edwards, J. O., Haggett, M. L., and Jones, P., J. Amer. Chem. Soc., May, 1967, and earlier papers. Goodman, J. F., Robson, P., and Wilson, E. R., Trans. Farad. Soc., 58, 1846 (1962).
Koubek, E., Haggett, M. L., Battaglia, C. J., Ibne-Rasa, K. M., Pyun, H. Y., and Edwards, J. O., J. Amer. Chem. Soc., 85, 2263 (1963).
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JONES, P., PERKINS, P. Redox Chemistry of Peroxides: Energy Surface of the Perhydroxyl Ion (HO2−). Nature 215, 129–132 (1967). https://doi.org/10.1038/215129a0
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DOI: https://doi.org/10.1038/215129a0
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