Abstract
A RELATIONSHIP can be found by plotting the potential barrier to internal rotation of ethyl halides against the ionization energy of the substituent halogen atom (Fig. 1). The results are given in Table 1.
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References
Smith, D. C., Saunders, R. A., Nielsen, J. R., and Ferguson, E. E., J. Chem. Phys., 20, 847 (1952).
Fateley, W. G., and Miller, F. A., Spectrochim. Acta, 19, 611 (1963).
Lide, D. R., J. Chem. Phys., 30, 37 (1959).
Flanagan, C., and Pierce, L., J. Chem. Phys., 38, 2963 (1963).
Kasuyo, T., Phys. Soc. Japan J., 15, 1273 (1960).
American Institute of Physics Handbook (1957).
Morgan, J. P., unpublished thesis, Univ. British Columbia (1964).
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LIELMEZS, J., MORGAN, J. Relation between Internal Rotational Barrier and Ionization Energy of Substituent Atoms in Ethyl Halides. Nature 202, 1106–1107 (1964). https://doi.org/10.1038/2021106b0
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DOI: https://doi.org/10.1038/2021106b0
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